Origin of the Yueguang gold deposit in Xinhua, Hunan Province, South China: insights from fl uid inclusion and hydrogen–oxygen stable isotope analysis

The Yueguang gold deposit is located in Fengjia,Xinhua County,Hunan Province,South China.It represents a recently discovered small-scale gold deposit situated in the southwestern region of the Jiangnan Orogenic Belt,west of the Baimashan granitic batholith.In order to discern the characteristics of the ore-formingfluids,the underlying mineralization processes,and establish a foundation for the origin of the Yueguang gold depositfluid inclusion micro-thermometry,as well as quartz hydrogen and oxygen isotope analysis,have been carried out on samples obtained from various stages of mineralization.The hydrothermal miner-alization stages within the Yueguang gold deposit can be categorized into three stages:(i)the barren,pre-ore quartz-pyrite stage(Stage Ⅰ),the quartz-pyrite-gold stage(Stage Ⅱ),and the post-ore quartz-carbonate stage(Stage Ⅲ),with the second stage being the main mineralization stage.Thefluid inclusions identified in samples from the main min-eralization stage can predominantly be described with the NaCl–H_(2)O and CO_(2)–NaCl–H_(2)O systems.These inclusions display homogenization temperatures ranging from 158.8 to 334.9℃,and thefluid salinity ranges from 0.3%to 4.0%(wt.%NaCl equiv.).Laser Raman spectroscopy analysis of individual inclusions further reveals the presence of gas-phases such as CO_(2),CH_(4),and N_(2).Isotopic analysis indicatesδ^(18)Ofluid values ranging from 3.95 to 6.7‰ and δDH_(2)O values ranging from-71.9 to-55.7‰.These results indi-cate that the ore-formingfluid of the Yueguang gold deposit belongs to metamorphic hydrothermalfluids of middle-low temperature and low salinity.In the process of ore formation,gold is transported in the form of Au(HS)2-complexes,with gold deposition being driven byfluid immiscibility.Therefore,the Yueguang gold deposit is categorized as an orogenic gold deposit dominated by metamorphic hydrother-malfluid.It may become a new target for gold exploration in the Baimashan region,central Hunan Province.

Discovery of scheelite in the Zaozigou gold deposit of West Qinling Orogen,Northwest China and its implications for ore genesis

1.Objective The West Qinling Orogen extends east-west over 1500 km and is endowed with dozens of large-super large scale gold deposits.The Zaozigou gold deposit has a proven reserve of 134 t with an average grade of 3.08 g/t thus is one of the largest deposits in the West Qinling Orogen.However,whether the fluid type is metamorphic or magmatichydrothermal and ore-formation processes of the Zaozigou gold deposit are equivocal.Scheelite is a ubiquitous accessory mineral in geologically diverse ore-deposit types and attested to be a strong indicator of ore-forming conditions and oredeposit genesis.

Geology and Geochemistry of K-feldspar Veins in Lamprophyre at the Zhenyuan Gold Deposit,Yunnan,Southwest China:Implications for Gold Mineralization

Lamprophyres typically appear in hydrothermal gold deposits.The relationship between lamprophyres and gold deposits is investigated widely.Some researchers suggest that the emplacement of lamprophyres triggers gold mineralization,whereas others hypothesize that the formation of lamprophyres increases the fertility of mantle sources and ore-forming fluids.K-feldspar veins,with ages between those of lamprophyres and gold deposits,appear in lamprophyres in Zhenyuan.Therefore,K-feldspar veins are ideal for investigating the relationship between lamprophyres and gold deposits.Phlogopite in K-feldspar veins has lower Mg#,Ni,and Cr contents and higher TiO2,Li,Ba,Sr,Sc,Zr,Nb,and Cs contents than phlogopite in lamprophyres.The in-situ Sr isotopic values of apatites(0.7063–0.7066)in K-feldspar veins are within the range for apatites(0.7064–0.7078)from lamprophyres.High large-ion lithophile element concentrations and low Nb and Ta concentrations in phlogopite from lamprophyres,in addition to high(87Sr/86Sr)i values of apatite(0.7064–0.7078),indicate that the magma parental to these phlogopite and apatite crystals is derived from an enriched mantle.Kfeldspar veins are genetically correlated with lamprophyres,whereas sulfide mineral assemblage and trace element compositions of pyrite in K-feldspar veins suggest that K-feldspar veins in lamprophyres are not directly related to gold mineralization of the Zhenyuan deposit.

Genesis of the Jianbeigou Gold Deposit on the Southern Margin of the North China Craton: Insights from Fluid Inclusions, H-O-S Isotopes, and Pyrite in situ Trace Element Analyses

The Jianbeigou gold deposit is a typical lode gold deposit in the Qinling metallogenic belt, located on the southern margin of the North China Craton. Three stages of the hydrothermal process can be distinguished, including the quartz ± pyrite, quartz-polymetallic sulfide, and quartz-carbonate ± pyrite stages. From the early to late stages, the homogenization temperatures of primary fluid inclusions are 281–362°C, 227–331°C, and 149–261°C, respectively. The corresponding salinities estimated for these fluids are 3.9–9.9 wt%, 0.4–9.4 wt%, and 0.7–7.2 wt% Na Cl equiv. Combined with laser Raman spectroscopy data, the ore-forming fluid belongs to a H_(2)O-CO_(2)-Na Cl ± CH_4 system with medium–low temperature and salinity. The δ~(18)Ofluid and δD values for the quartz veins are-1.0‰ to 6.0‰ and-105‰ to-84‰, respectively, which indicates that the ore-forming fluid is of mixed source, mainly derived from magma, with a contribution from meteoric water. Pyrite has been identified into three generations based on mineral paragenetic sequencing, including Py1, Py2, and Py3. The pyrites have δ~(34)S sulfur isotopic compositions from three stages between 3.7‰ and 8.4‰, indicating that sulfur mainly originated from magma. Te, Bi, Sb, and Cu contents in pyrite were all high and showed a strong correlation with Au concentrations. Native gold and the Au-Ag-Bi telluride minerals were formed concurrently, and the As concentration was low and decoupled from the Au content. Therefore, Te, Bi, Sb and other low-melting point chalcophile elements play an important role for gold mineralization in arsenic-deficient ore-forming fluid. Combined with the geological setting, evolution of pyrite, and ore-fluids geochemistry, we propose that the Jianbeigou deposit can be classified as a magmatic–hydrothermal lode gold deposit. Gold mineralization on the southern margin of the North China Craton is related to Early Cretaceous magmatism and formed in an extensional setting.

Effects of nitrogen deposition on the carbon budget and water stress in Central Asia under climate change

Atmospheric deposition of nitrogen(N)plays a significant role in shaping the structure and functioning of various terrestrial ecosystems worldwide.However,the magnitude of N deposition on grassland ecosystems in Central Asia still remains highly uncertain.In this study,a multi-data approach was adopted to analyze the distribution and amplitude of N deposition effects in Central Asia from 1979 to 2014 using a process-based denitrification decomposition(DNDC)model.Results showed that total vegetation carbon(C)in Central Asia was 0.35(±0.09)Pg C/a and the averaged water stress index(WSI)was 0.20(±0.02)for the whole area.Increasing N deposition led to an increase in the vegetation C of 65.56(±83.03)Tg C and slightly decreased water stress in Central Asia.Findings of this study will expand both our understanding and predictive capacity of C characteristics under future increases in N deposition,and also serve as a valuable reference for decision-making regarding water resources management and climate change mitigation in arid and semi-arid areas globally.

The Geology, Fluid Inclusions, and O-S Isotopes of the Mibei Gold Deposit, Hunan Province, Southern China

The Mibei gold deposit,located in the southwestern part of the Xuefengshan uplift zone,the middle section of the Jiangnan orogenic belt in southern China,has estimated gold resources of approximately seven tons.This deposit is primarily a quartz vein-type gold deposit,with ore bodies occurring mainly within Neoproterozoic metasediments.The main metallic minerals in the ore are pyrite,chalcopyrite,and arsenopyrite.In this study,the petrography and microthermometry of ore-forming fluid inclusions,oxygen isotopes of gold-bearing quartz,and sulfur isotopes of goldbearing sulfides and arsenopyrite were analyzed.Three types of fluid inclusions were identified:type Ⅰa three-phase inclusions comprising vapor and two phases of liquids(V_(CO_(2))+L_(CO_(2))+L_(H2O)),type Ⅰb two-phase liquids(L_(CO_(2))+L_(H2O)),typeⅡ two-phase vapor-rich inclusions(V/V+L> 50%),and type Ⅲ pure liquid inclusions.Type Ⅰ inclusions were heated uniformly to the liquid phase,type Ⅱ inclusions were heated uniformly to the gas phase,and type Ⅲ inclusions were heated without change.In general,the temperature range of homogenization to liquid phase of fluid inclusions in the Mibei gold deposit is 204-227℃.The salinity of the inclusion ranges from 4.6 to 12.2 wt% NaCl equiv.The δ~(18)O_(SMOW) of gold-bearing quartz varies from 16.9‰ to 17.5‰.The δ~(18)O_(H2O) of gold-bearing quartz are varied from 6.5‰ to 7.5‰.The δ~(34)S values of gold-bearing pyrite range from 1.7‰ to 6.8‰.The δ~(34)S values of gold-bearing arsenopy rite range from 5.6%o to 5.9‰.Theδ~(34)S values of pyrite from wall rocks slate range from 6.4‰ to 11.6‰.This evidence implies that the ore-forming fluids of the Mibei gold deposit originated from magmatic-hydrothermal processes,mixing with minor S from the surrounding metasediments.Combined with the evolution of the Jiangnan orogenic belt,due to the magmatic and tectonic activities of the Xuefengshan uplift during the Caledonian period,the fault seal mechanism controlled the ore-forming process.Overall,the Mibei gold deposit is more akin to a magmatic-hydrothermal gold deposit.

Research on the Application of Electromagnetic Method in the Exploration of Altered Rock-type Gold Deposits in the East Kunlun Metallogenic Belt

Introduction The East Kunlun Orogenic Belt is located in the northeastern part of the Qinghai–Tibet Plateau(Li et al.,2007),stretching from the East Kunlun to the Elashan area in an east–west direction(Guo et al.,2018).It is an important part of the Central Orogenic Belt(Xiong et al.,2023).It is considered one of the important gold mineralization regions in the Tethys tectonic domain(Norbu et al.,2023)and an essential potential base for mineral resources in China.Wulonggou and Gouli gold mines have been discovered successively,earning the reputation of the"Golden Belt of Qinghai Province"(Feng et al.,2004;He et al.,2023).

Genesis, metallogenic model, and prospecting prediction of the Nibao gold deposit in the Guizhou Province, China

Southwestern Guizhou province is one of China’s most important distribution areas of Carlin-type gold deposits. The Nibao deposit is a typical gold deposit in southwestern Guizhou. To elucidate the genesis of the Nibao gold deposit, establish a metallogenic model, and guide prospecting prediction, we systematically collected previously reported geological, geochemical, and dating data and discussed the genesis of the Nibao gold deposit,based on which we proposed the metallogenic model.Earlier works show that the Nibao anticline, F1 fault, and its hanging wall dragged anticline(Erlongqiangbao anticline) were formed before or simultaneously with gold mineralization, while F2, F3, and F4 faults postdate gold mineralization. Regional geophysical data showed extensive low resistivity anomaly areas near the SBT(the product of tectonic slippage and hydrothermal alteration)between the P2/P3 and the strata of the Longtan Formation in the SSE direction of Nibao anticline in the lower plate of F1 and hanging wall dragged anticline(Erlongqiangbao anticline), and the anomaly areas are distributed within the influence range of anticlines. Simultaneously, soil and structural geochemistry show that F1, Nibao anticline,Erlongqiangbao anticline, and their transition areas all show good metallogenic elements(Au, As, and S) assemblage anomalies, with good metallogenic space and prospecting possibilities. There are five main hypotheses about the source of ore-forming fluids and Au in the Nibao gold deposit:(1) related to the Emeishan mantle plume activity;(2) source from the Emeishan basalt;(3) metamorphic fluid mineralization;(4) basin fluid mineralization;(5) related to deep concealed magmatic rocks;of these, the mainstream understanding is the fifth speculation. It is acknowledged that the ore-forming fluids are hydrothermal fluids with medium–low temperature, high pressure, medium–low salinity, low density, low oxygen fugacity, weak acidity, weak reduction, and rich in CO_(2)and CH_(4). The fluid pressure is 2–96.54 MPa, corresponding to depths of 0.23–3.64 km. The dating results show that the metallogenic age is ~141 Ma, the extensional tectonic environment related to the westward subduction of the Pacific Plate. Based on the above explanation, the genetic model related to deep concealed magmatic rocks of the Nibao gold deposit is established, and favorable prospecting areas are outlined;this is of great significance for regional mineral exploration and studying the genesis of gold deposits.

Microthermometry and Synchrotron Radiation X-ray Fluorescence Analysis of Fluid Inclusions in the Dongping Gold Deposit,Northern Margin of the North China Craton

To shed light on the genesis of the Dongping deposit and reveal the behaviour of CO_(2),Au and other ore elements(e.g.,Cu,Fe,Zn,As,Sb,Co etc.)in ore-forming fluids,petrographic,microthermometric and synchrotron radiation X-ray fluorescence(SRXRF)analyses of fluid inclusions were conducted.The ore-forming fluid is characterized as an H_(2)O-CO_(2)-NaCl system with medium-high temperatures and low salinity.Four mineralization stages are identified,namely,feldsparquartz(stage 1);pyrite-white quartz(stage 2);sulfide-smoky grey quartz(stage 3);and carbonate-quartz(stage 4).Three types of inclusions were distinguished,based on fluid composition,phase assemblages and mode of homogenization.Type A:H_(2)O-rich fluid inclusions show 2 phases(liquid H_(2)O(LH_(2)O)+vapour H_(2)O(VH_(2)O))at room temperature and homogenize to the liquid phase.Type B:H_(2)O-CO_(2)fluid inclusions contain 2–3 phases(liquid H_(2)O(LH_(2)O)+vapour CO_(2)(VCO_(2));liquid H_(2)O(LH_(2)O)+liquid CO_(2)(LCO_(2)));liquid H_(2)O(LH_(2)O)+liquid CO_(2)(LCO_(2))+vapour CO_(2)(VCO_(2)))at room temperature and homogenized to the liquid H_(2)O phase.Type C:H_(2)O-CO_(2)fluid inclusions show 2 phases(liquid H_(2)O(LH_(2)O)+liquid CO_(2)(LCO_(2))at room temperature and homogenize to a critical state.CO_(2)is clearly more enriched in the fluid inclusions of stages 2 and 3 than in stage 1.Stage 1 is dominated by type A(H_(2)O-rich)inclusions with homogenization temperatures(Th)of 220–359℃and salinities of 1.1–3.1 wt%NaCl equivalent.Type B(CO_(2)-rich)inclusions gradually increase in stages 2 and 3.The Th range of type B inclusions in stage 2 is 241–397℃with salinities of 2.2–6.9 wt%NaCl equivalent;the Th range of type A inclusions is 217–373℃with salinities of 1.2–8.1 wt%NaCl equivalent.The Th range of type B inclusions in stage 3 is 215–361℃with salinities of 2.9–6.1 wt%NaCl equivalent;the range of type A inclusions is 158–351℃with a salinity of 0.7–5.5 wt%NaCl equivalent.Stage 4 is characterized by type A with Th of 151–250℃and salinities of 0.9–8.3 wt%NaCl equivalent.The mapping results show that elements As,Te and Sb are more concentrated in vapour CO_(2)than in liquid H_(2)O at room temperature,which suggests that vapour components are more able to transport elements when phase separation occurs.The SRXRF quantitative results show that Au,Cl,S and some other metals are obviously more enriched in the fluid inclusions of stages 2 and 3 than those in stage 1.Additionally,the contents of S in stages 1–3 are much lower than those of Cl,which suggests that gold might migrate mainly in the form of a gold-chloride complex.Au is more enriched in type B fluid inclusions than in type A fluid inclusions,which suggests that the enrichment and migration of gold are closely related to CO_(2)and CO_(2)plays a critical role in the migration and enrichment of gold.The trace elements in the fluid have a similar change trend to those in the Yanshanian syenogranite distributed in the southeastern part of the mining area,which may provide some evidence for an intrusion-related genesis for the Dongping gold deposit.

Regional Metallogenesis of the Chang'an Gold Ore Deposit in Western Yunnan:Evidences from Fluid Inclusions and Stable Isotopes

The Chang＇an gold ore deposit in western Yunnan is located at the southern segment of the Ailaoshan metallogenic belt.The ore bodies are preserved in fractured Ordovician sedimentary clastic rocks.The gold-bearing minerals occur dominantly in sulfide-quartz veins.Fluid inclusion analysis shows that the Chang＇an gold ore deposit is characterized by epithermal gold mineralization at temperatures between 200℃and 280℃at a shallow crustal level.The mineralizing fluids have intermediate to low salinity（6%-18%） and low densities（0.72-1.27 g/cm^3）.The ore minerals haveδ^（34）S in a range from -13‰to 3.57‰,concentrated from -2.06‰to 3.57‰with an average of 1.55‰.The ^（206）Pb/^（204）Pb,^（207）Pb/^（204）Pb and ^（208）Pb/^（204）Pb values are 18.9977-19.5748,15.7093-15.784,39.3814-40.2004 respectively.These isotope data suggest that the ore-forming elements were mainly derived from mixed crustal and mantle sources.The Chang＇an gold ore deposit and Tongchang Cu-Mo deposit are closely related to each other in their spatial distribution and age of formation.They have similar sources of mineralizing elements and identical ore-forming metal elements,and show a close relationship in physical and chemical conditions of mineralization.The two deposits constitute an epithermal-porphyry -skarn type Cu-Mo-Au mineralization system in the Tongchang-Chang＇an area,which is related to the Cenozoic high-K alkaline magmatism.

Geophysical Features of the Ore-Controlling Fault in the Chang'an Gold Deposit, Southern Yunnan Province

The Ailao Mountain is one of the most important metallogenic belts ofpolymetallic deposits in the Sanjiang region, southwestern China. Located in the southern segment of this metallogenic belt, the newly-discovered Chang＇an gold deposit is large in scale （Fig. 1A）, and has attracted much attention among geologists. The ore-hosted rocks in the district include the Late Ordovician Xiangyang Fm. sandstone and clastic rocks and the Early Silurian Kanglang Fm. dolomite. Affected by the multistage tectonic activities, stocks and dykes of lamprophyre, dolerite, syenite porphyry and orthoclasite are widely exposed, and the orebodies are in symbiosis with or crosscut the dyke rocks.

The first discovery of Xinlong epithermal gold deposit in southern margin of the Bangonghu-Nujiang metallogenic belt: A new expansion of gold prospecting in Northern Tibet

The Xinlong gold deposit is located in Niyma County,Naqu area of Tibet and was discovered by the Institute of Mineral Resources,Chinese Academy of Geological Sciences through the 1∶50000 mineral geological survey.The ore bodies occur in the Zenong Group volcanic rocks in the middle section of the central Lhasa subterrane and are structurally controlled by the NNW-striking faults.Four ore bodies have been found,exhibiting cloddy,dense-sparse,disseminated,and breccia structures.The ore minerals are mainly tetrahedrite group minerals,and other ore minerals include pyrite,chalcopyrite,nevskite,bornite,anglesite,native gold,and silver-gold bearing selenide,etc.The types of alteration are dominated by silicification,as well as middle-and high-graded argillization.The alteration mineral assemblages contain quzrtz,pyrophyllite,and kaolinite.The Zaliela Formation volcanic rocks of Zenong Group are silicified by later hydrothermal fluid with vuggy quartz in some fractured zones.The middle-and high-graded argillization are characterized by pyrophyllitization and kaolinization.The Xinlong gold deposit shows great metallogenetic potentiality and has been revealed by 1∶10000 geological mapping,IP sounding,and trial trenching in the mining area.Combined with the regional metallogenic geological setting,we suppose that a potential epithermal gold belt probably exists in the middle of the Lhasa terrane.The discovery of the Xinlong gold deposit opens a new chapter for the gold prospecting in Northern Tibet.

Fe-bearing minerals and implications for gold mineralization for the Wangu deposit in Central Jiangnan Orogen

Hydrothermal alteration with bleaching of host rocks is the most important prospecting indicator for gold deposits in the Jiangnan Orogen Belt.The alteration has been identified as pre-ore carbonate(siderite)-sericitization and the Fe of siderite in the alteration zone is derived from the host rocks rather than fluids.In addition,such alteration decreases in intensity and width with depth and gold mineralization also occur in the non-bleached rocks,casting doubt on the reliability of the prospecting indicator.Detailed petrographic work and SEM analysis on the Wangu deposit indicate that there are two types of siderites,i.e.,Sd1 and Sd2.Among them,Sd1 grains are relatively small and distributed along the planes of unaltered host rocks,while Sd2 grains,only occurring in the altered slates,are commonly larger.Both types of siderites were altered by auriferous fluids,producing porous cores and minerals such as pyrite,quartz,and ankerite.Compared with unaltered parts,the altered parts have lower Fe,but higher U,Pb,and REE.In addition,Sd1 and Sd2 are similar in Mn,Na,V,and Sr concentrations but different in Fe and Mg.The occurrence and geochemical compositions of both siderites indicate that Sd1 could be transformed into Sd2 by pre-mineralization alteration through dissolution-reprecipitation.Chlorite is another important Fe-bearing mineral in the host rocks,and EPMA analysis suggests that it is ripidolite with relatively high Fe contents.Consequently,chlorite can also provide Fe to form the pre-ore carbonate(siderite)-sericitization.Geochemical modeling demonstrates that both ripidolite and siderite can result in sulfidation and therefore gold precipitation.As a result,this study demonstrates that pre-ore alteration with characterized bleaching is not a prerequisite for gold mineralization despite of its prominent features.Due to the presence of Fe-bearing Sd1 and chlorite,gold mineralization could still occur through sulfidation in the unaltered rocks.

In Situ Rb-Sr Dates of Muscovite and Sulfur Isotope of Pyrite from the Yangshan Gold Deposit in Western Qinling,China

Located along the southern part of the West Qinling orogenic belt,the Yangshan gold deposit is one of the largest in China.The major gold ores of Yangshan are disseminated in metasedimentary host rocks with minor native gold amounts in stibnite-gold quartz veins.Pyrite and arsenopyrite are the major Au-bearing minerals.Hydrothermal muscovite from gold-bearing quartz veins was dated using the in situ Rb-Sr method to determine the formation age of the Yangshan gold deposit.The Rb-Sr isochron date of the muscovite yielded 210.1±5.6 Ma(MSWD=1.2).This date is near the lower end of the period of the mineralized granitic dykes(210.49-213.10 Ma).Two stages of gold enriching process are recognized in the gold-bearing pyrite:the first is incorporated with the Co,Cu,As,Ni enrichment;and the second is accompanied by Bi,Co,Ni,Pb,Cu,Sb concentration.The in-situ sulfur isotopic values of pyrites show a restrictedΔ34s range of-1.43‰to 2.86‰with a mean value of 0.43‰.Trace-element mapping and in-situ sulfur isotopic analysis of pyrite suggest that the sulfur deposits are likely derived from a magmatic source and likely assimilated by sulfur from the sedimentary bedrock.Thus,magmatism plays a critical role in the formation of the Yangshan gold deposit.

Correlations between trace elements in pyrite and gold mineralization of gold deposits on the North China platform

By studying both the microscopic physical and chemical typomorphic characteristics of typical mineral pyrite samples associated with representative gold deposits on the north-central margin of the North China Platform,this paper seeks to identify macroscopic metallogenic mechanisms of gold deposits and to reveal the formation mechanism of lattice gold in pyrite.Typomorphic characteristics of pyrite reveal that pyrite grain size has a negative correlation with gold content.Cubic pyrite,as the dominant crystal form,contains more gold than pentagonal dodecahedral pyrite.Both pyrite crystal forms and chemical compositions indicate that the replacement style of gold deposit formed in a low saturability,low sulfur fugacity,and at temperatures either much higher or much lower than its best forming temperature;comparatively,that of the quartz vein style of gold deposit occurred under conditions with the best temperature,rich in sulfur,and with high sulfur fugacity.The Au/Ag ratios of the pyrites show that both the replacement and quartz vein styles of deposits are mesothermal and hypothermal,while the Co/Ni ratios of the pyrites indicate that the quartz vein style is of magmatic-hydrothermal origin.The X-ray diffraction intensity of pyrite rich in gold is lower than that of pyrite poor in gold at the quartz vein style.In general,with an increase in gold content in pyrite,the total sum intensityΣI decreases.The pyroelectricity coefficient has a negative correlation trend with the values of(Co+Ni+Se+Te)-As and(Co+Ni+Se+Te)/As.The pyrite pyroelectricity of the replacement style is N-type,indicating that it formed under low sulfur fugacity,while that of the quartz vein style is a mixture of P-N types,indicating that it formed under high sulfur fugacity.On the pyroelectricity-temperature diagram,pyrite of the replacement style is mainly distributed between 200 and 270°C,while that of the quartz vein style varies between 90–118 and274–386°C,demonstrating a multistage forming process.In contrast to previous researchers'conclusions,the authors confirm the existence of lattice gold in pyrites through the use of an electron paramagnetic resonance(EPR)test.Au in the form of Au~+,entering pyrite as an isomorph and producing electron–hole centers,makes the centers produce spin resonance absorption and results in EPR absorption peak II.The intensity of auriferous pyrite absorption peak II has certain direct positive correlations with pyrite gold content.The#I and#III absorption peaks of pyrites possibly result from the existence of Ni^(2+)and/or Cu^(2+).γ1,γ2,andγ3 are the strongest and most typical absorption peaks of the infrared spectra of the pyrites.Generally,with the increase in gold content in the pyrite samples,γ1,γ2,andγ3 tend to shift to higher wavenumbers,and the gold content in the pyrite samples has a positive correlation with their relative absorbance.

Geochemistry and metallogenic age of Sishanlinchang gold-silver deposit in Jidong of Heilongjiang

the Sishanlinchang gold-silver deposit is mainly composed of gold-quartz vein type ores. It has many kinds of sulfides and gold in high grade. The Au has a close correlation with As, Pb, Ag and Cu. Geochemi- cally, the deposit is characterized by relatively enrichment in LREE with moderate or lower Eu negative anoma- ly. Sulfur isotopes appear as single and deep source, and lead isotopes indicate the Pb is from the earth＇s mantle and crust, which mainly are orogenic belt Pb, the ore-forming fluid has a temperature of 215~C -350~C and a low salinity with a mixture of characteristics of magmaitc hydrothermal and meteoric water. The ore-forming age is 111. 1 - 111.4 Ma. The deposit is formed in mineralization and precipitation of metallogenie materials caused by the mixture of the magmatic hydrothermal fluid and meteoric water.

Paleoenvironmental changes recorded by grain size of loess/paleosol sequence from the Chifeng City,Northeastern China since the Last Glacial

The accumulation processes of loess in northeastern(NE)China record the varying characteristics of the East Asian Monsoons(EAM)and the evolution of the local environment.In this study,grain size end-member analysis of the Dajiugang(DJG)section deposited since the Last Glacial in Chifeng City,NE China was used to reveal the dynamic depositional characteristics of loess and environmental evolution of NE China.Results showed that the Chifeng loess comprises three grain size end-members(EM),EM1(7.38μm),EM2(49.4μm)and EM3(90.00μm),indicating the three transport dynamics of dust delivered to the region.The EM1 represents atmospheric dust as the background.The EM2,mainly derived from relatively distant-sources deposition,and EM3,material transported over a short distance,correspond to the intensity of southwesterly winds and the East Asian Winter Monsoon(EAWM),respectively.Results of climate reconstruction,combined with other records,showed that the climate was generally cold and dry with a strong EAWM and a weak East Asian summer monsoon(EASM)during the stadial-period[Marine Isotope Stage(MIS)4 and MIS 2 stage].The climate was predominantly warm and humid,with weak EAWM and surface winds and strong EASM in interstadial-period(MIS 3 and MIS 1 stage).Comparisons between indicators,e.g.,EM3,the LR04 benthicδ18O stack and summer insolation at 65°N suggest that the strong EAWM is induced by increasing the Northern Hemisphere ice volume and reduced summer solar radiation.

Land Use and Land Cover Dynamics in the Eseka Alluvial Gold Mining District, Centre Region, Cameroon

Local populations in Cameroon thrive on forest resources and the flow of ecosystem services they provide are pivotal in sustaining national economy, improving people’s lives, safeguarding biodiversity, and mitigating the impacts of environmental changes. The exploitation of these resources invariably leads to deforestation and forest degradation. This study was designed to evaluate land use land cover change (LULCC) in the Eseka alluvial gold mining district with the aid of Landsat images. In the investigation of forest cover change, four Landsat satellite images for (1990, 2002, 2015 and 2022) were used. Ground-truthing also helped to identify the activities carried out by the local population and to determine agents, drivers and pressures of land use and land cover change. Four main land cover classes namely: forest, agricultural land, settlement/mining camps and water bodies were selected. Between 1990 and 2022, the proportion of forest decreased from 98% to 34% while those of agricultural land and settlement/mining camps increased from 2% to 60% and 0.54% to 6% respectively. Analysis showed ongoing deforestation with forest cover loss of ~98,263 ha in 32 years giving a cover change percentage of 63.94%. Kappa coefficient for the study period ranged from 0.92 to 0.99. Forest cover loss could be attributed to farming activities, wood extraction and alluvial gold mining activities. Economic motives notably the need to increase household income from a frequent demand for farm and wood products in neighbouring towns and the quest for gold were the main drivers of these activities. Hence, this study assesses the impact of human activities from the mining sector on the forest ecosystem in a bid to inform mitigation policies.

Geology and mineralization of the Dongping supergiant alkalic-hosted Au-Te deposit(>100 t Au)in Northern Hebei Province,China:A review

The Dongping deposit is the largest alkalic-hosted gold deposit in China containing>100 t of Au.This paper presents a new understanding for Dongping ore system,based on the previous studies.The mineralization originally occurred at 400-380 Ma,simultaneous with emplacement of the Shuiquangou alkaline complex,and was overprinted by the hydrothermal activity in the Yanshanian.Isotope compositions of ores indicate metals of the deposit are mainly provided by the Shuiquangou complex.Ore-forming fluids are characterized by increasing oxygen fugacity and decreasing sulfur fugacity,while tellurium fugacity increased in the Stage II-2 and decreased in Stage II-3.These systematic changes are closely related to the processes of mineral precipitation and fluid evolution.Sulfide precipitation from Stage Ⅰ to Stage Ⅱ was triggered by fluid boiling,which leads to the precipitation of Pb-Bi-Te,due to decrement of sulfur fugacity.Condensation of gas phase containing high concentration of H_2Te leads to precipitation of Te-Au-Ag minerals and native tellurium.Based on these hypotheses,this paper present a polyphase metallogenic model as follow.During the Devonian,fluids were released from alkaline magmas,which carried ore-forming materials form the surrounding rocks and precipitate the early ores.During the Jurassic-Cretaceous,fluorine-rich fluids exsolved from highly factionated Shangshuiquan granite,which extracted and concentrated Au from the Shuiquangou complex and the Sanggan Group metamorphic rocks,and finally formed the Dongping gold deposit.

Geology and Genesis of the Superlarge Jinchang Gold Deposit,NE China

The superlarge Jinchang gold deposit is located in the joint area between the Taipingling uplift and the Laoheishan depression of the Xingkai Block in both eastern Jilin and eastern Heilongjiang Province. Wall rocks of the gold deposits are the Neoproterozoic Huangsong Group of metamorphic rocks. Yanshanian magmatism in this region can be divided into 5 phases, the diorite, the graphic granite, the granite, the granite porphyry and the diorite porphyrite, which resulted in the magmatic domes and cryptoexplosive breecia chimney followed by large-scale hydrothermal alteration. Gold mineralization is closely related to the fourth and fifth phase of magmatism. According to the occurrences, gold ores can be subdivided into auriferous pyritized quartz vein, auriferous quartz-pyrite vein, auriferous polymetailic sulfide quartz vein and auriferous pyritized calcite vein. The ages of the gold deposit are ranging from 122.53 to 119.40 Ma. The ore bodies were controlled by a uniform tectono-magmatic hydrothermal alteration system that the ore-forming materials were deep derived from and the ore-forming fluids were dominated by magmatic waters with addition of some atmospheric water in the later phase of mineralization. Gold mineralization took place in an environment of medium to high temperatures and medium pressures. Ore-forming fluids were the K^＋-Na^＋-Ca^2＋-Cl^--SO4^2- type and characterized by medium salinity or a slightly higher, weak alkaline and weak reductive. Au in the ore-forming fluids was transported as complexes of [Au （HS）2]^-, [AuCl2]^-, [Au（CO2）]^- and [Au（HCO3）2]^-. Along with the decline of temperatures and pressures, the ore-forming fluids varied from acidic to weak acidic and then to weak alkaline, which resulted in the dissociation of the complex and finally the precipitation of the gold.