Lacustrine turbidite of Chang-7 Member in the studied area consists of sihstone and fine sandstone with respect to grain size, which is feldspathic lithie sandstone, syrosem arkose and arkose with respect to mineral c...Lacustrine turbidite of Chang-7 Member in the studied area consists of sihstone and fine sandstone with respect to grain size, which is feldspathic lithie sandstone, syrosem arkose and arkose with respect to mineral constitution affected by provenance. There are such apparent signatures as lithology, sedimentary structure, sedimentary sequence and well logs, to recognize turbidite. During the paleogeographic evolution of Chang-7 Member, lake basin and deep lake are both at their maximum extent during Chang-73 stage, resulting in the deposition of Zhangjiatan shale with widespread extent and of turbidite with fragmental-like. Deep lake line is gradually moving toward lake center and turbidite sand bodies are gradually turning better with better lateral continuity, connectivity and more thickness, from stages of Chang-73, Chang-72 and Chang-7t, which can be favorable reservoir in deep-water.展开更多
In the Triassic Yanchang Formation, Jiyuan-Wuqi area, Ordos Basin, the Chang 6 reservoir is contacted to the Chang 7 high-quality source rock, but the oil pools are unevenly distributed, and complex in oil and water d...In the Triassic Yanchang Formation, Jiyuan-Wuqi area, Ordos Basin, the Chang 6 reservoir is contacted to the Chang 7 high-quality source rock, but the oil pools are unevenly distributed, and complex in oil and water distribution. Through cores observation and fracture statistics, combined with comprehensive analyses of physical property, mercury injection, logging and geochemical data, and comparisons of the sandbodies scales, reservoir physical properties, argillaceous laminae and fractures between source and reservoir in the eastern and western oil-bearing areas and in the central water producing area, it is found that the hydrocarbon accumulation patterns are different in the eastern, central and western areas, and the characteristics of hydrocarbon migration under the background of double-provenance were sorted out. The study results show that the crude oil in the eastern area has different Pr/Ph and sterane distribution from that in the western area. The oil and gas primarily migrated vertically. The high-quality source rocks and favorable source-reservoir-cap combinations lay the foundation for large-scale oil and gas accumulations. Vertically, the oil and gas enrichment is controlled by the scale of sandbody and the difference of physical properties, while on the plane, it is controlled by the connectivity of sandbodies, the argillaceous laminae between source rock and reservoir, the reservoir physical property and the fractures. The sandbodies of oil-rich zones in the eastern and western areas have large thickness, low shale content, good physical properties, weak heterogeneity, few argillaceous laminae and abundant fractures, all of which are favorable for the vertical migration and accumulation of oil and gas. In contrast, in the middle area with converging provenances, the reservoirs, composed of thin sandbodies, features rapid variation in lithology and physical properties, strong heterogeneity, poor continuity of sandbodies, abundant argillaceous laminae between source rock and reservoir, and few fractures, makes it difficult for the oil and gas to migrate vertically, and results in low oil enrichment degree ultimately. For the exploration of continental multiple-provenance tight reservoirs, not only the good-property source rocks and reservoirs, but more importantly the source-reservoir contact relationship and the effect of fractures on the hydrocarbon migration and accumulation should be considered.展开更多
A new complex, [Ni（L）2]·2（H2O） I （HL = 2-iminomethyl-6-methoxyphenol）, has been synthesized and structurally determined. The crystal belongs to the trigonal system, space group R3- with a = 1.9341 （3）, b ...A new complex, [Ni（L）2]·2（H2O） I （HL = 2-iminomethyl-6-methoxyphenol）, has been synthesized and structurally determined. The crystal belongs to the trigonal system, space group R3- with a = 1.9341 （3）, b = 1.9341 （3）, C = 1.2048（2） nm, V = 3.9029（11） nm^3, Mr = 395.05, Z = 9, Dc = 1.513 g·cm^-3, F（000） = 1854,μ= 1.153 mm^-1 and S = 1.014. Each Ni^Ⅱ atom is four-coordinated by two N and two O atoms from two different L anions to give a slightly distorted square-plane geometry. The complex forms a 3-D network structure through N-H...O and O-H...O hydrogen bonds containing an interesting six-membered water ring.展开更多
文摘Lacustrine turbidite of Chang-7 Member in the studied area consists of sihstone and fine sandstone with respect to grain size, which is feldspathic lithie sandstone, syrosem arkose and arkose with respect to mineral constitution affected by provenance. There are such apparent signatures as lithology, sedimentary structure, sedimentary sequence and well logs, to recognize turbidite. During the paleogeographic evolution of Chang-7 Member, lake basin and deep lake are both at their maximum extent during Chang-73 stage, resulting in the deposition of Zhangjiatan shale with widespread extent and of turbidite with fragmental-like. Deep lake line is gradually moving toward lake center and turbidite sand bodies are gradually turning better with better lateral continuity, connectivity and more thickness, from stages of Chang-73, Chang-72 and Chang-7t, which can be favorable reservoir in deep-water.
基金Supported by the National Natural Science Foundation of China(41872165,41572137)
文摘In the Triassic Yanchang Formation, Jiyuan-Wuqi area, Ordos Basin, the Chang 6 reservoir is contacted to the Chang 7 high-quality source rock, but the oil pools are unevenly distributed, and complex in oil and water distribution. Through cores observation and fracture statistics, combined with comprehensive analyses of physical property, mercury injection, logging and geochemical data, and comparisons of the sandbodies scales, reservoir physical properties, argillaceous laminae and fractures between source and reservoir in the eastern and western oil-bearing areas and in the central water producing area, it is found that the hydrocarbon accumulation patterns are different in the eastern, central and western areas, and the characteristics of hydrocarbon migration under the background of double-provenance were sorted out. The study results show that the crude oil in the eastern area has different Pr/Ph and sterane distribution from that in the western area. The oil and gas primarily migrated vertically. The high-quality source rocks and favorable source-reservoir-cap combinations lay the foundation for large-scale oil and gas accumulations. Vertically, the oil and gas enrichment is controlled by the scale of sandbody and the difference of physical properties, while on the plane, it is controlled by the connectivity of sandbodies, the argillaceous laminae between source rock and reservoir, the reservoir physical property and the fractures. The sandbodies of oil-rich zones in the eastern and western areas have large thickness, low shale content, good physical properties, weak heterogeneity, few argillaceous laminae and abundant fractures, all of which are favorable for the vertical migration and accumulation of oil and gas. In contrast, in the middle area with converging provenances, the reservoirs, composed of thin sandbodies, features rapid variation in lithology and physical properties, strong heterogeneity, poor continuity of sandbodies, abundant argillaceous laminae between source rock and reservoir, and few fractures, makes it difficult for the oil and gas to migrate vertically, and results in low oil enrichment degree ultimately. For the exploration of continental multiple-provenance tight reservoirs, not only the good-property source rocks and reservoirs, but more importantly the source-reservoir contact relationship and the effect of fractures on the hydrocarbon migration and accumulation should be considered.
基金the Key Laboratory of Non-ferrous Metal Materials and New Processing Technology, Ministry of Education and the State Key Laboratory of Coordination Chemistry
文摘A new complex, [Ni（L）2]·2（H2O） I （HL = 2-iminomethyl-6-methoxyphenol）, has been synthesized and structurally determined. The crystal belongs to the trigonal system, space group R3- with a = 1.9341 （3）, b = 1.9341 （3）, C = 1.2048（2） nm, V = 3.9029（11） nm^3, Mr = 395.05, Z = 9, Dc = 1.513 g·cm^-3, F（000） = 1854,μ= 1.153 mm^-1 and S = 1.014. Each Ni^Ⅱ atom is four-coordinated by two N and two O atoms from two different L anions to give a slightly distorted square-plane geometry. The complex forms a 3-D network structure through N-H...O and O-H...O hydrogen bonds containing an interesting six-membered water ring.
