Lacustrine turbidite of Chang-7 Member in the studied area consists of sihstone and fine sandstone with respect to grain size, which is feldspathic lithie sandstone, syrosem arkose and arkose with respect to mineral c...Lacustrine turbidite of Chang-7 Member in the studied area consists of sihstone and fine sandstone with respect to grain size, which is feldspathic lithie sandstone, syrosem arkose and arkose with respect to mineral constitution affected by provenance. There are such apparent signatures as lithology, sedimentary structure, sedimentary sequence and well logs, to recognize turbidite. During the paleogeographic evolution of Chang-7 Member, lake basin and deep lake are both at their maximum extent during Chang-73 stage, resulting in the deposition of Zhangjiatan shale with widespread extent and of turbidite with fragmental-like. Deep lake line is gradually moving toward lake center and turbidite sand bodies are gradually turning better with better lateral continuity, connectivity and more thickness, from stages of Chang-73, Chang-72 and Chang-7t, which can be favorable reservoir in deep-water.展开更多
The bicyclic cryptand 1,4,7, 10,13,16,21, 24-octaaza-bigcyclo [8, 8,8] hexacosan-3, 8, 12, 17, 20, 25-hex-one (COBH) bearing diaminoethane groups along the eight-atom bridges was synthesized. The structure consists of...The bicyclic cryptand 1,4,7, 10,13,16,21, 24-octaaza-bigcyclo [8, 8,8] hexacosan-3, 8, 12, 17, 20, 25-hex-one (COBH) bearing diaminoethane groups along the eight-atom bridges was synthesized. The structure consists of discrete neutral macrobicyclic units; the two cycles share the two tertiary amine nitrogen atoms, which exhibit an endo-cndo conformation. Three identical branches formed by 1, 2-diaminoethane link the two tertiary amine groups. The protonation reactions of cryptand (COBH) and its complex formation with copper (II) were investigated by potentiometry in water and in a DMSO/water (80:20 in mass ratio) mixture as solvents. The cryptand acts as a his-base through its two N-bridgehead and exhibits a strong cooperativity that favors the first protonation and makes the second one difficult (△pK= 5.0). An inward rotation of the amide groups to form hydrogen bonds accounts for this cooperativity. The interaction of COBH with copper (II) leads to several binuclear complex proton contents.展开更多
Based on the cores from 47 wells and logging data of 130 wells,the main types of sand bodies in the shallow water delta of the Chang 8_(2) sub-member in the Triassic Yanchang Formation,Longdong Area,Ordos Basin were c...Based on the cores from 47 wells and logging data of 130 wells,the main types of sand bodies in the shallow water delta of the Chang 8_(2) sub-member in the Triassic Yanchang Formation,Longdong Area,Ordos Basin were comprehensively analyzed,the distribution characteristics of sand bodies more than 20 m thick were identified,and the genetic types of the thick sand bodies were sorted out.In this region,thick-bed sand bodies can be divided into two types according to the shape and position:type 1 is the sand body in wide strip and is distributed between the average high water mark and the average low water mark;type 2 is distributed on both sides of the average low water mark and is in irregular lump shape.Based on the principle of the volume distribution of sediments and the change rule of accommodation space,the genetic models of two types of thick-bed sand bodies in the Chang 8_(2) sub-member are superimposed distributary channel sand bodies in high accommodation space and superimposed composite sand bodies in low accommodation space.展开更多
文摘Lacustrine turbidite of Chang-7 Member in the studied area consists of sihstone and fine sandstone with respect to grain size, which is feldspathic lithie sandstone, syrosem arkose and arkose with respect to mineral constitution affected by provenance. There are such apparent signatures as lithology, sedimentary structure, sedimentary sequence and well logs, to recognize turbidite. During the paleogeographic evolution of Chang-7 Member, lake basin and deep lake are both at their maximum extent during Chang-73 stage, resulting in the deposition of Zhangjiatan shale with widespread extent and of turbidite with fragmental-like. Deep lake line is gradually moving toward lake center and turbidite sand bodies are gradually turning better with better lateral continuity, connectivity and more thickness, from stages of Chang-73, Chang-72 and Chang-7t, which can be favorable reservoir in deep-water.
基金the National Natural Science Foundation of China (No.29875018) and the Natural Science Foundation of Gansu Province (ZS991-A25-
文摘The bicyclic cryptand 1,4,7, 10,13,16,21, 24-octaaza-bigcyclo [8, 8,8] hexacosan-3, 8, 12, 17, 20, 25-hex-one (COBH) bearing diaminoethane groups along the eight-atom bridges was synthesized. The structure consists of discrete neutral macrobicyclic units; the two cycles share the two tertiary amine nitrogen atoms, which exhibit an endo-cndo conformation. Three identical branches formed by 1, 2-diaminoethane link the two tertiary amine groups. The protonation reactions of cryptand (COBH) and its complex formation with copper (II) were investigated by potentiometry in water and in a DMSO/water (80:20 in mass ratio) mixture as solvents. The cryptand acts as a his-base through its two N-bridgehead and exhibits a strong cooperativity that favors the first protonation and makes the second one difficult (△pK= 5.0). An inward rotation of the amide groups to form hydrogen bonds accounts for this cooperativity. The interaction of COBH with copper (II) leads to several binuclear complex proton contents.
基金Supported by the National Basic Research Program of China (973 Program)(2014CB239000)China Petroleum Scientific Research and Technology Development Project (YJXK2019-16)。
文摘Based on the cores from 47 wells and logging data of 130 wells,the main types of sand bodies in the shallow water delta of the Chang 8_(2) sub-member in the Triassic Yanchang Formation,Longdong Area,Ordos Basin were comprehensively analyzed,the distribution characteristics of sand bodies more than 20 m thick were identified,and the genetic types of the thick sand bodies were sorted out.In this region,thick-bed sand bodies can be divided into two types according to the shape and position:type 1 is the sand body in wide strip and is distributed between the average high water mark and the average low water mark;type 2 is distributed on both sides of the average low water mark and is in irregular lump shape.Based on the principle of the volume distribution of sediments and the change rule of accommodation space,the genetic models of two types of thick-bed sand bodies in the Chang 8_(2) sub-member are superimposed distributary channel sand bodies in high accommodation space and superimposed composite sand bodies in low accommodation space.
