The lithology, lithofacies, reservoir properties and shale oil enrichment model of the fine-grained sedimentary system in a lake basin with terrigenous clastics of large depression are studied taking the organic-rich ...The lithology, lithofacies, reservoir properties and shale oil enrichment model of the fine-grained sedimentary system in a lake basin with terrigenous clastics of large depression are studied taking the organic-rich shale in the first member of Cretaceous Qingshankou Formation(shortened as Qing 1 Member) in the Changling Sag, southern Songliao Basin as an example. A comprehensive analysis of mineralogy, thin section, test, log and drilling geologic data shows that lamellar shale with high TOC content of semi-deep lake to deep lake facies has higher hydrocarbon generation potential than the massive mudstone facies with medium TOC content, and has bedding-parallel fractures acting as effective reservoir space under over pressure. The sedimentary environments changing periodically and the undercurrent transport deposits in the outer delta front give rise to laminated shale area. The laminated shale with medium TOC content has higher hydrocarbon generation potential than the laminated shale with low TOC content, and the generated oil migrates a short distance to the sandy laminae to retain and accumulate in situ. Ultra-low permeability massive mudstone facies as the top and bottom seals, good preservation conditions, high pressure coefficient, and lamellar shale facies with high TOC are the conditions for "lamellation type" shale oil enrichment in some sequences and zones. The sequence and zone with laminated shale of medium TOC content in oil window and with micro-migration of expelled hydrocarbon are the condition for the enrichment of "lamination type" shale oil. The tight oil and "lamination type" shale oil are in contiguous distribution.展开更多
The Changling fault depression passed through three stages of evolution: a period of faulting, a period of subsidence, and an inversion period. The fault lifted the whole area and the formation was eroded during the l...The Changling fault depression passed through three stages of evolution: a period of faulting, a period of subsidence, and an inversion period. The fault lifted the whole area and the formation was eroded during the late Yingcheng formation, the late Nenjiang formation, and the late Mingshui formation. The denudation quantity of eight wells located in the study area is estimated by the interval transit time method and by the formation trend extension method using seismic and drilling data. Inversion back stripping technology with de-compaction correction was used to restore the original sedimentary thickness step by step and to recover the burial history at a single well. Two profiles were selected for the recovery and study of the tectonic evolution. The study confirmed that the primary major gas bearing structure formed due to thermal shrinkage lifting during the late Yingcheng formation. Successive development in a pattern during the late Mingshui formation led to the formation of the primary gas pool. Vertical differential uplift during the late Nenjiang formation formed the Fulongquan structure during the late Paleogene. At this same time a secondary gas pool formed. A large scale reverse developed late in the Mingshui formation that provided the impetus for formation of a secondary gas pool. It is thought that the migration and accumulation of oil and gas was controlled by lithologic character, fracture, and structure. The local uplift in the vicinity of the hydrocarbon recession is most conducive to the collection of hydrocarbon gas.展开更多
The Songliao basin in northeast China is a Mesozoic rift basin characterized by Mesozoic and Cenozoic hydrocarbon systems.The Changling fault depression located in the south of the Songliao Basin,
Through natural gas exploration in the Changling Fault Depression,abundant natural gas flows were obtained and high-quality source rocks were also reveiled.Based on bulk analyses,organic matter abundance,organic matte...Through natural gas exploration in the Changling Fault Depression,abundant natural gas flows were obtained and high-quality source rocks were also reveiled.Based on bulk analyses,organic matter abundance,organic matter type and thermal maturity of the source rocks were studied systematically.At the same time,gas gener-ating intensity and gas generating quantity were quantitatively analyzed by using basin modeling technologies.The results indicated that gas source rocks of the Shahezi Formation are characterized by abundant organic matter and dark mudstone distributions and high-over thermal maturity.They possess high gas generating intensity with the biggest value surpassing 500×108 m3/km2,and large gas generating quantity,accounting from 74.40% of the total amount.The Yingcheng Formation has good gas-source rocks with moderate dark mudstone and relatively high organic matter.It has type-Ⅲ organic matter and low-over thermal maturity.The gas generating intensity is moderate,between 20×108 and 60×108 m3/km2.The gas generating quantity is 13.63% of the total amount.The Huoshiling Formation has relatively good source rocks with limited dark mudstone and low organic matter.It has type-Ⅲ kerogen and over-thermal maturity.The gas generating quantity is 7.10% of the total amount.The Denglouku Formation has poor-gas source rocks,and is characterized by undeveloped dark mudstone and low organic matter abundance.It has type-Ⅲ organic matter and low-high thermal maturity.Hydrocarbon gases in the Changling Fault Depression mainly originated from the Shahezi Formation,and secondarily from the Yingcheng Formation.The contribution of the Huoshiling Formation gas source rocks is relatively small.展开更多
The Changling gas field is occurs in tight sandstone reservoirs of the Lower Cretaceous Denglouku Formation in the Changling fault depression,southern Songliao Basin,China,which constitutes a new gas-producing area in...The Changling gas field is occurs in tight sandstone reservoirs of the Lower Cretaceous Denglouku Formation in the Changling fault depression,southern Songliao Basin,China,which constitutes a new gas-producing area in the depression. Using information on the source-reservoir-cap rock assemblage of the Denglouku Formation,fault activity,and single well burial history of well CS1,together with data on reservoir fluid inclusion and laser Raman spectroscopy,we described the formation of the Changling gas field and determine that this fault depression did not possess suitable conditions for hydrocarbon generation. Coal-derived methane generated from underlying hydrocarbon source rock accumulated in the Lower Cretaceous Yingcheng Formation. At the end of the Late Cretaceous Qingshankou Stage,underwater volcanic eruptions occurred in the northern part of the Changling gas field near Qian'an,resulting in the reactivation of deep faults. Mantle-sourced inorganic CO2 migrated along faults to hydrocarbon gas reservoirs in volcanic rocks of the Yingcheng Formation; Meanwhile,displaced methane( hydrocarbon gas) migrated upward to sand reservoirs of the Denglouku Formation.The methane accumulated and formed secondary gas reservoirs,Therefore fault activity was the main factor controlling the generation of gas reservoirs in the Denglouku Formation. The main accumulation period of the Yingcheng hydrocarbon gas reservoirs was 82 Ma. Whereas gas reservoir formation in the overlying Denglongku Formation was 79 Ma,slightly later than the time of formation of the Yingcheng gas reservoir in CS1 well area.At 79 Ma,the burial depth of the Denglouku Formation was 1 800--2 000 m,the diagenesis is relatively weak and the physical properties of the reservoir are relatively favorable for accumulation. This period is not only at gas generation peak time of three sets of source rock but also at the reactivation of deep faults during the formation of fault-bound depressions,thereby providing favorable conditions for the migration and accumulation of methane.展开更多
Abundant melt-and fluid inclusions occur in corundum megacrysts of alkaline basalt from the Changle area,Shandong province,eastern China.One type of melt inclusions,i.e.muhiphase melt inclusions(glass+bubbles+daughter...Abundant melt-and fluid inclusions occur in corundum megacrysts of alkaline basalt from the Changle area,Shandong province,eastern China.One type of melt inclusions,i.e.muhiphase melt inclusions(glass+bubbles+daughter minerals)were identified,which occur along growth zones of host corundum megacrysts.Microthermometry and laser Raman microprobe analysis were performed on the melt inclusions.The bubbles within the melt inclusions are confirmed to be CO_2-rich phase and the daughter minerals are probably silicates,such as augite and okenite.The results of high temperature homogenization experiment strongly suggest that two immiscible melts,i.e.a H_2O-and CO_2-rich melt and an anhydrous and CO_2-poor melt were trapped by melt inclusions in corundum megacryst.展开更多
Metabolic profiles caused by rare earth complex were investigated using NMR and ICP-MS techniques. Male and female Wistar rats were treated orally with Changle （A kind of rare earth complex applied in agriculture to ...Metabolic profiles caused by rare earth complex were investigated using NMR and ICP-MS techniques. Male and female Wistar rats were treated orally with Changle （A kind of rare earth complex applied in agriculture to raise the production of crops） at dose of 2, 5 and 20 mg·kg^-1 body weight/day respectively for 90 d. Urine and serum samples are collected on 90 d. The relative concentrations of important endogenous metabolites in urine and serum are determined from ^1H NMR spectra and the contents of the four rare earth elements （La, Ce, Pr and Nd） constituting Changle in the serum samples are measured by ICP-MS technique. Changle-induced renal and liver damage in rats is found based on the increase in the amounts of the amino acids, trimethylamine N-oxide, N, N-dimethyglycine, dimethylamine, succinate, α- ketoglutarate and ethanol as well as rare earth concentrations. The similarities and differentiations are found in the alteration patterns of metabolites and rare earth concentrations in serum.展开更多
To assess the potential health risks of mixed rare earths Changle for human embryo, whether it crosses placenta membrane or placenta barrier should be determined. In order to arrive at the aim placenta tissue was obs...To assess the potential health risks of mixed rare earths Changle for human embryo, whether it crosses placenta membrane or placenta barrier should be determined. In order to arrive at the aim placenta tissue was observed after contamination with optical and electron microscope to show distribution and destiny of mixed rare earth Changle in placenta tissue. Meanwhile the amount of rare earths in serum of pregnant rat, amniotic fluid and extract of embryo tissue were measured by using Inductively Coupled Plasma Mass Spectrometer (ICP MS). The rats were administered to 0 3, 2, 5 and 20 mg·kg -1 mixed rare earths Changle every day, respectively by oral from the 6th to 18th day after pregnancy. The results show that many particles are found in syncytiotrophoblast around capillaries of placental villi in contaminated groups under light microscope, and there are more particles following increased dose. It also was observed that some dense bodies with the envelope in placenta membrane and to difference extent damages the mitochondria crista within syncytiotrophoblast cytoplasm in contaminated groups under transmission electron microscope (TEM). Results of ICP MS assay indicate that the level of Ce increases with contamination dose in the serum of pregnant rats, and the level of total rare earth element remarkably rises in amniotic fluid and serum of pregnant rats for 20 mg·kg -1 group as compared with the control without change for the other groups.展开更多
The Fujian coast Changle-Nanao metamorphism zone rocks are composed of gneiss, schist andhornblendite which had gone through metamorphism of amphilbolite facies, and followed the large-scaleintrusive mass of gneissic ...The Fujian coast Changle-Nanao metamorphism zone rocks are composed of gneiss, schist andhornblendite which had gone through metamorphism of amphilbolite facies, and followed the large-scaleintrusive mass of gneissic granite. The zone was orginally composed of Early Palaeozoiccontinental margin and island arc volcanic and sedimentary rocks. In 180-150 Ma, the zone undermentductile shear deformation and amphibolite facies metamorphism; and in 130-80 Ma, rose rap1dly andco1lided with the Southeastem China continen1al rnargln volonic rocks a10ng the NE trending ductileshear belt. The above geologic setting laid the present Fujian coast tectonic foundation whose formationand evolution are known to be interrlatal with the sueduction and collision of the Taiwan CentralRange.展开更多
The Fuzhou Changle International Airport, the largest international airport in China, was given approval to open to air traffic on June 23 by the Civil Aviation Administration of China (CAAC).
基金Supported by the National Natural Science Foundation of China(41972156)。
文摘The lithology, lithofacies, reservoir properties and shale oil enrichment model of the fine-grained sedimentary system in a lake basin with terrigenous clastics of large depression are studied taking the organic-rich shale in the first member of Cretaceous Qingshankou Formation(shortened as Qing 1 Member) in the Changling Sag, southern Songliao Basin as an example. A comprehensive analysis of mineralogy, thin section, test, log and drilling geologic data shows that lamellar shale with high TOC content of semi-deep lake to deep lake facies has higher hydrocarbon generation potential than the massive mudstone facies with medium TOC content, and has bedding-parallel fractures acting as effective reservoir space under over pressure. The sedimentary environments changing periodically and the undercurrent transport deposits in the outer delta front give rise to laminated shale area. The laminated shale with medium TOC content has higher hydrocarbon generation potential than the laminated shale with low TOC content, and the generated oil migrates a short distance to the sandy laminae to retain and accumulate in situ. Ultra-low permeability massive mudstone facies as the top and bottom seals, good preservation conditions, high pressure coefficient, and lamellar shale facies with high TOC are the conditions for "lamellation type" shale oil enrichment in some sequences and zones. The sequence and zone with laminated shale of medium TOC content in oil window and with micro-migration of expelled hydrocarbon are the condition for the enrichment of "lamination type" shale oil. The tight oil and "lamination type" shale oil are in contiguous distribution.
基金the Marine Prospective Project of China Petrochemical Corporation (No.G0800-06-ZS324) for the financial support
文摘The Changling fault depression passed through three stages of evolution: a period of faulting, a period of subsidence, and an inversion period. The fault lifted the whole area and the formation was eroded during the late Yingcheng formation, the late Nenjiang formation, and the late Mingshui formation. The denudation quantity of eight wells located in the study area is estimated by the interval transit time method and by the formation trend extension method using seismic and drilling data. Inversion back stripping technology with de-compaction correction was used to restore the original sedimentary thickness step by step and to recover the burial history at a single well. Two profiles were selected for the recovery and study of the tectonic evolution. The study confirmed that the primary major gas bearing structure formed due to thermal shrinkage lifting during the late Yingcheng formation. Successive development in a pattern during the late Mingshui formation led to the formation of the primary gas pool. Vertical differential uplift during the late Nenjiang formation formed the Fulongquan structure during the late Paleogene. At this same time a secondary gas pool formed. A large scale reverse developed late in the Mingshui formation that provided the impetus for formation of a secondary gas pool. It is thought that the migration and accumulation of oil and gas was controlled by lithologic character, fracture, and structure. The local uplift in the vicinity of the hydrocarbon recession is most conducive to the collection of hydrocarbon gas.
文摘The Songliao basin in northeast China is a Mesozoic rift basin characterized by Mesozoic and Cenozoic hydrocarbon systems.The Changling fault depression located in the south of the Songliao Basin,
基金supported by the National Science and Technology Major Project (2008ZX05002-006-007HZ)
文摘Through natural gas exploration in the Changling Fault Depression,abundant natural gas flows were obtained and high-quality source rocks were also reveiled.Based on bulk analyses,organic matter abundance,organic matter type and thermal maturity of the source rocks were studied systematically.At the same time,gas gener-ating intensity and gas generating quantity were quantitatively analyzed by using basin modeling technologies.The results indicated that gas source rocks of the Shahezi Formation are characterized by abundant organic matter and dark mudstone distributions and high-over thermal maturity.They possess high gas generating intensity with the biggest value surpassing 500×108 m3/km2,and large gas generating quantity,accounting from 74.40% of the total amount.The Yingcheng Formation has good gas-source rocks with moderate dark mudstone and relatively high organic matter.It has type-Ⅲ organic matter and low-over thermal maturity.The gas generating intensity is moderate,between 20×108 and 60×108 m3/km2.The gas generating quantity is 13.63% of the total amount.The Huoshiling Formation has relatively good source rocks with limited dark mudstone and low organic matter.It has type-Ⅲ kerogen and over-thermal maturity.The gas generating quantity is 7.10% of the total amount.The Denglouku Formation has poor-gas source rocks,and is characterized by undeveloped dark mudstone and low organic matter abundance.It has type-Ⅲ organic matter and low-high thermal maturity.Hydrocarbon gases in the Changling Fault Depression mainly originated from the Shahezi Formation,and secondarily from the Yingcheng Formation.The contribution of the Huoshiling Formation gas source rocks is relatively small.
基金Supported by Project of National Natural Science Foundation of China(No.41472101)
文摘The Changling gas field is occurs in tight sandstone reservoirs of the Lower Cretaceous Denglouku Formation in the Changling fault depression,southern Songliao Basin,China,which constitutes a new gas-producing area in the depression. Using information on the source-reservoir-cap rock assemblage of the Denglouku Formation,fault activity,and single well burial history of well CS1,together with data on reservoir fluid inclusion and laser Raman spectroscopy,we described the formation of the Changling gas field and determine that this fault depression did not possess suitable conditions for hydrocarbon generation. Coal-derived methane generated from underlying hydrocarbon source rock accumulated in the Lower Cretaceous Yingcheng Formation. At the end of the Late Cretaceous Qingshankou Stage,underwater volcanic eruptions occurred in the northern part of the Changling gas field near Qian'an,resulting in the reactivation of deep faults. Mantle-sourced inorganic CO2 migrated along faults to hydrocarbon gas reservoirs in volcanic rocks of the Yingcheng Formation; Meanwhile,displaced methane( hydrocarbon gas) migrated upward to sand reservoirs of the Denglouku Formation.The methane accumulated and formed secondary gas reservoirs,Therefore fault activity was the main factor controlling the generation of gas reservoirs in the Denglouku Formation. The main accumulation period of the Yingcheng hydrocarbon gas reservoirs was 82 Ma. Whereas gas reservoir formation in the overlying Denglongku Formation was 79 Ma,slightly later than the time of formation of the Yingcheng gas reservoir in CS1 well area.At 79 Ma,the burial depth of the Denglouku Formation was 1 800--2 000 m,the diagenesis is relatively weak and the physical properties of the reservoir are relatively favorable for accumulation. This period is not only at gas generation peak time of three sets of source rock but also at the reactivation of deep faults during the formation of fault-bound depressions,thereby providing favorable conditions for the migration and accumulation of methane.
基金National Natural Science Foundation of China （ Grant No. 402213101）.
文摘Abundant melt-and fluid inclusions occur in corundum megacrysts of alkaline basalt from the Changle area,Shandong province,eastern China.One type of melt inclusions,i.e.muhiphase melt inclusions(glass+bubbles+daughter minerals)were identified,which occur along growth zones of host corundum megacrysts.Microthermometry and laser Raman microprobe analysis were performed on the melt inclusions.The bubbles within the melt inclusions are confirmed to be CO_2-rich phase and the daughter minerals are probably silicates,such as augite and okenite.The results of high temperature homogenization experiment strongly suggest that two immiscible melts,i.e.a H_2O-and CO_2-rich melt and an anhydrous and CO_2-poor melt were trapped by melt inclusions in corundum megacryst.
文摘Metabolic profiles caused by rare earth complex were investigated using NMR and ICP-MS techniques. Male and female Wistar rats were treated orally with Changle （A kind of rare earth complex applied in agriculture to raise the production of crops） at dose of 2, 5 and 20 mg·kg^-1 body weight/day respectively for 90 d. Urine and serum samples are collected on 90 d. The relative concentrations of important endogenous metabolites in urine and serum are determined from ^1H NMR spectra and the contents of the four rare earth elements （La, Ce, Pr and Nd） constituting Changle in the serum samples are measured by ICP-MS technique. Changle-induced renal and liver damage in rats is found based on the increase in the amounts of the amino acids, trimethylamine N-oxide, N, N-dimethyglycine, dimethylamine, succinate, α- ketoglutarate and ethanol as well as rare earth concentrations. The similarities and differentiations are found in the alteration patterns of metabolites and rare earth concentrations in serum.
文摘To assess the potential health risks of mixed rare earths Changle for human embryo, whether it crosses placenta membrane or placenta barrier should be determined. In order to arrive at the aim placenta tissue was observed after contamination with optical and electron microscope to show distribution and destiny of mixed rare earth Changle in placenta tissue. Meanwhile the amount of rare earths in serum of pregnant rat, amniotic fluid and extract of embryo tissue were measured by using Inductively Coupled Plasma Mass Spectrometer (ICP MS). The rats were administered to 0 3, 2, 5 and 20 mg·kg -1 mixed rare earths Changle every day, respectively by oral from the 6th to 18th day after pregnancy. The results show that many particles are found in syncytiotrophoblast around capillaries of placental villi in contaminated groups under light microscope, and there are more particles following increased dose. It also was observed that some dense bodies with the envelope in placenta membrane and to difference extent damages the mitochondria crista within syncytiotrophoblast cytoplasm in contaminated groups under transmission electron microscope (TEM). Results of ICP MS assay indicate that the level of Ce increases with contamination dose in the serum of pregnant rats, and the level of total rare earth element remarkably rises in amniotic fluid and serum of pregnant rats for 20 mg·kg -1 group as compared with the control without change for the other groups.
文摘The Fujian coast Changle-Nanao metamorphism zone rocks are composed of gneiss, schist andhornblendite which had gone through metamorphism of amphilbolite facies, and followed the large-scaleintrusive mass of gneissic granite. The zone was orginally composed of Early Palaeozoiccontinental margin and island arc volcanic and sedimentary rocks. In 180-150 Ma, the zone undermentductile shear deformation and amphibolite facies metamorphism; and in 130-80 Ma, rose rap1dly andco1lided with the Southeastem China continen1al rnargln volonic rocks a10ng the NE trending ductileshear belt. The above geologic setting laid the present Fujian coast tectonic foundation whose formationand evolution are known to be interrlatal with the sueduction and collision of the Taiwan CentralRange.
文摘The Fuzhou Changle International Airport, the largest international airport in China, was given approval to open to air traffic on June 23 by the Civil Aviation Administration of China (CAAC).
