The stepwise stability constants of coordination compounds from sulfonatedsheoak tannin with metal ions have been determined by pH potential method with catechol asmodel compounds at 20℃and constant ionic strength.
The stability constants of the mononuclear complexes of BDBPH-Zn(II), Cd(II) and Mn (II) were determined by the potentiometric equilibrium measurements, and species distributions were also discussed. The metal ions do...The stability constants of the mononuclear complexes of BDBPH-Zn(II), Cd(II) and Mn (II) were determined by the potentiometric equilibrium measurements, and species distributions were also discussed. The metal ions do not combine with the ligand until the first two protons of the ligand have almost been completely neutralized. The main species were mononuclear complexes with the diprotonated ligand, MH,L. The three metal ions also form mono- and noprotonated (fully deprotonated) complexes, MHL, ML. The relative order of stabilities of the mononuclear complexes, ML, is Zn(II) > Cd(II) > Mn(II). The ligand has strong tendency to form mononuclear complexes with Zn(II), Cd(II) and Mn(II), and it can also form dinuclear complexes at high pH.展开更多
In this paper,we report the deductive formula used for the method of dual-wavelength corresponding solutions under condition of having ligand interference and the stability constants of three new coordination compound...In this paper,we report the deductive formula used for the method of dual-wavelength corresponding solutions under condition of having ligand interference and the stability constants of three new coordination compounds [AuL_2]^+determined with this method.The stability of the three compounds,the necessity of controlling pH in experimental systems and the advantage of this method are discussed in detail.展开更多
A potentiometric study on the complexes of His,Gly-His,ALa-His,Gly-Gly and Gly—Gly—Gly with Zn(Ⅱ)and Cd(Ⅱ)has been reported.Small-scale potentiometric titrations were car- ried out to determine stabil ity constant...A potentiometric study on the complexes of His,Gly-His,ALa-His,Gly-Gly and Gly—Gly—Gly with Zn(Ⅱ)and Cd(Ⅱ)has been reported.Small-scale potentiometric titrations were car- ried out to determine stabil ity constants of complexes at 25℃ with I=0.10 mol dm^(-3)(KNO_3).The com- puter programs SUPERQUAD were applied for data treatment with satisfactory results.展开更多
This paper reports the determination of stability constants for complexes of Cd(Ⅱ)with Gly, Ala,Val,Asp,Gly—Asp,Asp Gly,Gly—Gly and Gly—Gly—Gly using both micro—pH—metric titra- tions and the application of con...This paper reports the determination of stability constants for complexes of Cd(Ⅱ)with Gly, Ala,Val,Asp,Gly—Asp,Asp Gly,Gly—Gly and Gly—Gly—Gly using both micro—pH—metric titra- tions and the application of convolution—deconvolution cyclic voltammetry at 25℃ and I=0.10 mol· dm^(-3)(KNO_3).Stability constants were calculated from pH—metric data using the SUPERQUAD com- puter program and cyclic voltammograms were collected,stored and manipulated using the EG and G CONDECON 300 software.A considerably larger ligand:metal ratio(e,g.50:1)was possible using voltammetry.Evaluation of results from the two techniques suggests that stability constants for the species[CdL_2]and[CdL_3]are reliable when calculated fromvoltammetry while those for[CdL]are more reliable when determined by pH-metric titration.展开更多
基于模块化多电平换流器的高压柔性直流输电系统(modular multilevel converter-based high voltage direct current,MMC-HVDC)常采用双极接线方式以提高系统功率输送能力和可靠性。然而目前对于风电场经柔直外送系统的稳定性研究集中...基于模块化多电平换流器的高压柔性直流输电系统(modular multilevel converter-based high voltage direct current,MMC-HVDC)常采用双极接线方式以提高系统功率输送能力和可靠性。然而目前对于风电场经柔直外送系统的稳定性研究集中于单极接线方式,孤岛直驱风电场与采用不同双极协调控制的双极MMC-HVDC互联系统小信号稳定性问题还有待进一步探究。该文首先考虑频率耦合特性、参考系初相位和直流侧耦合特性的影响,分别建立了采用双U/f下垂控制和定U/f-P/Q控制的双极MMC-HVDC系统交流侧等效SISO阻抗模型,并详细分析了金属回线阻抗和双极间功率均分度对交流阻抗特性的影响。接着对比研究了两种协调控制中共有控制环路和特有控制环路对交流侧负电阻特性及互联系统稳定性的影响规律。最后,孤岛直驱风电场经两种双极协调控制下双极MMC-HVDC外送系统Matlab/Simulink时域仿真结果和硬件在环半实物实时仿真实验结果验证了所提出的小信号阻抗模型的精确性和稳定性分析结论的有效性。展开更多
文摘The stepwise stability constants of coordination compounds from sulfonatedsheoak tannin with metal ions have been determined by pH potential method with catechol asmodel compounds at 20℃and constant ionic strength.
基金The financial support from the Robert A. Welch Foundation (A-0259) in the U.S and China Scholarship Council (97837086) is gratefully acknowledged.
文摘The stability constants of the mononuclear complexes of BDBPH-Zn(II), Cd(II) and Mn (II) were determined by the potentiometric equilibrium measurements, and species distributions were also discussed. The metal ions do not combine with the ligand until the first two protons of the ligand have almost been completely neutralized. The main species were mononuclear complexes with the diprotonated ligand, MH,L. The three metal ions also form mono- and noprotonated (fully deprotonated) complexes, MHL, ML. The relative order of stabilities of the mononuclear complexes, ML, is Zn(II) > Cd(II) > Mn(II). The ligand has strong tendency to form mononuclear complexes with Zn(II), Cd(II) and Mn(II), and it can also form dinuclear complexes at high pH.
文摘In this paper,we report the deductive formula used for the method of dual-wavelength corresponding solutions under condition of having ligand interference and the stability constants of three new coordination compounds [AuL_2]^+determined with this method.The stability of the three compounds,the necessity of controlling pH in experimental systems and the advantage of this method are discussed in detail.
文摘A potentiometric study on the complexes of His,Gly-His,ALa-His,Gly-Gly and Gly—Gly—Gly with Zn(Ⅱ)and Cd(Ⅱ)has been reported.Small-scale potentiometric titrations were car- ried out to determine stabil ity constants of complexes at 25℃ with I=0.10 mol dm^(-3)(KNO_3).The com- puter programs SUPERQUAD were applied for data treatment with satisfactory results.
文摘This paper reports the determination of stability constants for complexes of Cd(Ⅱ)with Gly, Ala,Val,Asp,Gly—Asp,Asp Gly,Gly—Gly and Gly—Gly—Gly using both micro—pH—metric titra- tions and the application of convolution—deconvolution cyclic voltammetry at 25℃ and I=0.10 mol· dm^(-3)(KNO_3).Stability constants were calculated from pH—metric data using the SUPERQUAD com- puter program and cyclic voltammograms were collected,stored and manipulated using the EG and G CONDECON 300 software.A considerably larger ligand:metal ratio(e,g.50:1)was possible using voltammetry.Evaluation of results from the two techniques suggests that stability constants for the species[CdL_2]and[CdL_3]are reliable when calculated fromvoltammetry while those for[CdL]are more reliable when determined by pH-metric titration.
文摘基于模块化多电平换流器的高压柔性直流输电系统(modular multilevel converter-based high voltage direct current,MMC-HVDC)常采用双极接线方式以提高系统功率输送能力和可靠性。然而目前对于风电场经柔直外送系统的稳定性研究集中于单极接线方式,孤岛直驱风电场与采用不同双极协调控制的双极MMC-HVDC互联系统小信号稳定性问题还有待进一步探究。该文首先考虑频率耦合特性、参考系初相位和直流侧耦合特性的影响,分别建立了采用双U/f下垂控制和定U/f-P/Q控制的双极MMC-HVDC系统交流侧等效SISO阻抗模型,并详细分析了金属回线阻抗和双极间功率均分度对交流阻抗特性的影响。接着对比研究了两种协调控制中共有控制环路和特有控制环路对交流侧负电阻特性及互联系统稳定性的影响规律。最后,孤岛直驱风电场经两种双极协调控制下双极MMC-HVDC外送系统Matlab/Simulink时域仿真结果和硬件在环半实物实时仿真实验结果验证了所提出的小信号阻抗模型的精确性和稳定性分析结论的有效性。
