Golden yellow cerium conversion film was obtained on magnesium alloys surface by immersion method and the preparation parameters were established. The influence of different process parameters on the surface morpholog...Golden yellow cerium conversion film was obtained on magnesium alloys surface by immersion method and the preparation parameters were established. The influence of different process parameters on the surface morphology and performance of the conversion film were analyzed by means of SEM and electrochemical method. Formation dynamics about cerium conversion film on magnesium alloy in solution containing cerium salt and the anti-corrosion behavior of the conversion film in 3.5% NaCl solution were studied by electrochemical method respectively. The results shows that the conversion film is more compact at room temperature when concentration of cerium sulfate is 10 g·L-1 in the solution; the open circuit potential of the magnesium sample moves up to positive direction about 100 mV, the surface of conversion film becomes even and lustrous, and the adhesion intensity of conversion film increases when adding aluminum nitrate into the solution containing cerium salt. The pH value of the solution and immersion time of the sample in the solution also affect the surface morphology and anti-corrosion property of the conversion film. After covered by rare earths conversion film, the anti-corrosion property of magnesium alloy is obviously improved. Rare earth conversion film has self-repairing capability in corrosion medium.展开更多
A conversion film was obtained on zinc deposit by immersing zinc coated specimens in a mischmetal salt solution. Several factors affecting the anticorrosive efficiency of the conversion film were studied. The suitabl...A conversion film was obtained on zinc deposit by immersing zinc coated specimens in a mischmetal salt solution. Several factors affecting the anticorrosive efficiency of the conversion film were studied. The suitable technological conditions were established. The composition and the thickness of the conversion film were determined by Auger electron spectroscopy(AES).展开更多
Cerium sulfate was used as main composite in solution to prepare golden yellow chemical conversion film on magnesium alloy. The influence of solution composition on the surface morphology of golden yellow rare earth c...Cerium sulfate was used as main composite in solution to prepare golden yellow chemical conversion film on magnesium alloy. The influence of solution composition on the surface morphology of golden yellow rare earth conversion film on magnesium alloy was studied by means of SEM; potential-time curves in the formation process of rare earth conversion film and the anti-corrosion property of the conversion film were tested through ECT. The results show that, when there is no other component in the solution besides cerium sulfate, yellow film can be obtained on magnesium alloy, but there are some dusts on the film surface and the solution is not stable. The stability of cerium sulfate solution increases with adding hydrogen peroxide, while the film is thin and its color turn light. After adding combination additive containing Al 3+, smooth and compact golden yellow film was obtained on magnesium alloy. The polarization curves tested in 3.5% NaCl solution show that the anti-corrosion property of magnesium alloy is increased obviously by rare earth conversion film, and the film has self-repairing capability in the corrosion process.展开更多
基金Project supported by the Science and Technology Foundation of Sci. & Tec. Office of Qinhuangdao City (200507)
文摘Golden yellow cerium conversion film was obtained on magnesium alloys surface by immersion method and the preparation parameters were established. The influence of different process parameters on the surface morphology and performance of the conversion film were analyzed by means of SEM and electrochemical method. Formation dynamics about cerium conversion film on magnesium alloy in solution containing cerium salt and the anti-corrosion behavior of the conversion film in 3.5% NaCl solution were studied by electrochemical method respectively. The results shows that the conversion film is more compact at room temperature when concentration of cerium sulfate is 10 g·L-1 in the solution; the open circuit potential of the magnesium sample moves up to positive direction about 100 mV, the surface of conversion film becomes even and lustrous, and the adhesion intensity of conversion film increases when adding aluminum nitrate into the solution containing cerium salt. The pH value of the solution and immersion time of the sample in the solution also affect the surface morphology and anti-corrosion property of the conversion film. After covered by rare earths conversion film, the anti-corrosion property of magnesium alloy is obviously improved. Rare earth conversion film has self-repairing capability in corrosion medium.
文摘A conversion film was obtained on zinc deposit by immersing zinc coated specimens in a mischmetal salt solution. Several factors affecting the anticorrosive efficiency of the conversion film were studied. The suitable technological conditions were established. The composition and the thickness of the conversion film were determined by Auger electron spectroscopy(AES).
文摘Cerium sulfate was used as main composite in solution to prepare golden yellow chemical conversion film on magnesium alloy. The influence of solution composition on the surface morphology of golden yellow rare earth conversion film on magnesium alloy was studied by means of SEM; potential-time curves in the formation process of rare earth conversion film and the anti-corrosion property of the conversion film were tested through ECT. The results show that, when there is no other component in the solution besides cerium sulfate, yellow film can be obtained on magnesium alloy, but there are some dusts on the film surface and the solution is not stable. The stability of cerium sulfate solution increases with adding hydrogen peroxide, while the film is thin and its color turn light. After adding combination additive containing Al 3+, smooth and compact golden yellow film was obtained on magnesium alloy. The polarization curves tested in 3.5% NaCl solution show that the anti-corrosion property of magnesium alloy is increased obviously by rare earth conversion film, and the film has self-repairing capability in the corrosion process.
