Crustal Composition of China Continent Constrained from Heat Flow Data and Helium Isotope Ratio of Underground Fluid

Based on conservation of energy principle and heat flow data in China continent, the upper limit of 1.3 μW/m3 heat production is obtained for continental crust in China. Furthermore, using the data of heat flow and helium isotope ratio of underground fluid, the heat productions of different tectonic units in China continent are estimated in range of 0.58-1.12 μW/m3 with a median of 0.85 μW/m3. Accordingly, the contents of U, Th and K20 in China crust are in ranges of 0.83-1.76 μg/g, 3.16-6.69 μg/g, and 1.0%-2.12%, respectively. These results indicate that the abundance of radioactive elements in the crust of China continent is much higher than that of Archean crust; and this fact implies China＇s continental crust is much evolved in chemical composition. Meanwhile, significant lateral variation of crustal composition is also exhibited among different tectonic units in China continent. The crust of eastern China is much enriched in incompatible elements such as U, Th and K than that of western China; and the crust of orogenic belts is more enriched than that of platform regions. It can also be inferred that the crusts of eastern China and orogenic belts are much felsic than those of western China and platform regions, respectively, derived from the positive correlation between the heat production and SiO2 content of bulk crust. This deduction is consistent with the results derived from the crustal seismic velocity data in China. According to the facts of the lower seismic velocity of China than the average value of global crust, and the higher heat production of China continent compared with global crust composition models published by previous studies, it is deduced that the average composition models of global continent crust by Rudnick and Fountain （1995）, Rudnick and Gao （2003）, Weaver and Tarney （1984）, Shaw et al. （1986）, and Wedepohl （1995） overestimate the abundance of incompatible elements such as U, Th and K of continental crust.

Early Cretaceous Magma Mingling in Xiaocuo,Southeastern China Continental Margin:Implications for Subduction of Paleo-Pacific Plate

Magma mingling has been identified within the continental margin of southeastern China.This study focuses on the relationship between mafic and felsic igneous rocks in composite dikes and plutons in this area,and uses this relationship to examine the tectonic and geodynamic implications of the mingling of mafic and felsic magmas.Mafic magmatic enclaves（MMEs） show complex relationships with the hosting Xiaocuo granite in Fujian area,including lenticular to rounded porphyritic microgranular enclaves containing abundant felsic/mafic phenocrysts,elongate mafic enclaves,and back-veining of the felsic host granite into mafic enclaves.LA-ICP-MS zircon U-Pb analyses show crystallization of the granite and dioritic mafic magmatic enclave during ca.132 and 116 Ma.The host granite and MMEs both show zircon growth during repeated thermal events at-210 Ma and 160-180 Ma.Samples from the magma mingling zone generally contain felsic-derived zircons with well-developed growth zoning and aspect ratios of 2-3,and maficderived zircons with no obvious oscillatory zoning and with higher aspect ratios of 5-10.However,these two groups of zircons show no obvious trace element or age differences.The Hf-isotope compositions show that the host granite and MMEs have similar ε（Hf）（t） values from negative to positive which suggest a mixed source from partial melting of the Meso-Neoproterozoic with involvement of enriched mantlederived magmas or juvenile components.The lithologies,mineral associations,and geochemical characteristics of the mafic and felsic rocks in this study area indicate that both were intruded together,suggesting Early Cretaceous mantle—crustal interactions along the southeastern China continental margin.The Early Cretaceous magma mingling is correlated to subduction of Paleo-Pacific plate.

Three Stages of Mesozoic Bimodal Igneous Rocks and Their Tectonic Implications on the Continental Margin of Southeastern China

There are large-scale Mesozoic bimodal igneous rock associations on the continental margin of southeastern China. They aroused extensive attention in the 1980s because of their specific tectonic implications, and have been found frequently during recent geological surveys. This paper reviews the studies of regional Mesozoic bimodal rocks, and concludes that they can be subdivided into three stages, i.e., the Early Jurassic (209-170 Ma, the first (Ⅰ) stage), the Late Jurassic-early Early Cretaceous (154-121 Ma, the second (Ⅱ) stage), and the late Early Cretaceous-Late Cretaceous (115-85 Ma, the third (Ⅲ) stage). These three stages of bimodal rocks were formed in different tectonic settings, and are important indicators for regional Mesozoic tectonic evolution.

Element Abundances of China's Continental Crust and Its Sedimentary Layer and Upper Continental Crust

China's continental crust (CCC)has an average thickness of 47km,with the uppercontinental crust (CUCC)being 31 km and the sedimentary layer(CSL)5 km in thickness.The CCC,CUCC and CSL measure 12.437×10^17,8.005×10^17 and 1.146×10^17 metric tons in mass,respectively.The mass ratio of the upper continental crust to the lower one is 1.8:1.The element abundances were calculated for the CCC,CUCC and CSL respectively in terms of the chemical compositions of 2246 samples of various types and some complementary trace element data.The total abundance of 13 major elements accounts for 99.6% of the CCC mass while the other minor elements only account for 0.4%.REE characteristics,the abundance ratios of element pairs and the amounts of ore-forming elements are also discussed in the present paper.

Types,Characteristics and Significances of Migrating Pathways of Gas-bearing Fluids in the Shenhu Area,Northern Continental Slope of the South China Sea

The first marine gas hydrate expedition in China has been conducted by Guangzhou Marine Geological Survey in the Shenhu Area, northern continental slope of the South China Sea. Previous study has analyzed the P-T conditions, geophysical anomalies and saturation calculations of these gas hydrates, but has not documented in detail the migration of gas-bearing fluids in the study area. Based on the interpretations of 2D/3D seismic data, this work identified two types of migration pathways for gas-bearing fluids in the Shenhu area, i.e., vertical and lateral pathways. The vertical pathways（largescale faults, gas chimneys and mud diapirs） presented as steep seismic reflection anomalies, which could be traced downward to the Eocene source rocks and may penetrate into the Late Miocene strata. The deeper gases/fluids might be allowed migrating into the shallower strata through these vertical conduits. However, the distributions showed distinct differences between these pathways. Large-scale faults developed only in the north and northeast of the Shenhu area, while in the drilling area gas chimneys were the sole vertical migration pathways. Since the Pliocene, normal faults, detachment faults and favorable sediments have constituted the lateral pathways in the Shenhu gas hydrate drilling area. Although these lateral pathways were connected with gas chimneys, they exerted different effects on hydrate formation and accumulation. Gas-bearing fluids migrated upward along gas chimneys might further migrate laterally because of the normal faults, thereby enlarging the range of the chimneys. Linking gas chimneys with the seafloor, the detachment faults might act as conduits for escaping gases/fluids. Re-deposited sediments developed at the early stage of the Quaternary were located within the gas hydrate stability zone, so hydrates would be enriched in these favorable sediments. Compared with the migration pathways（large-scale faults and mud diapirs） in the LW3-1 deep-sea oil/gas field, the migration efficiency of the vertical pathways（composed of gas chimneys） in the gas hydrate drilling area might be relatively low. Description and qualitative discrimination of migration pathways in the Shenhu gas hydrate drilling area are helpful to further understand the relationship between good-quality deep source rocks and shallow, mainly biogenicallyproduced, hydrates. As the main source rocks of the Baiyun sag, lacustrine mudstones in the Wenchang and Enping Formations may provide thermogenic methane. Gas chimneys with relatively low migration efficiency created the vertical pathways. Caused by the Dongsha tectonic movement, the release of overpressured fluids might reduce the vertical migration rates of the thermogenic methane. The thick bathyal/abyssal fine-grained sediments since the Late Miocene provided migration media with low permeability. These preconditions may cause carbon isotopic fractionation ofthermogenic methane during long-distance vertical migrations. Therefore, although geochemical analyses indicate that the methane forming gas hydrate in the Shenhu area was mainly produced biogenically, or was mixed methane primarily of microbial origin, thermogenic methane still contribute significantly.

The Relationship between Tectonic Subsidence and BSR of Upper Neogene in the Deep-Water Area of the Northern Continental Slope, South China Sea

BSR （Bottom Simulating Reflector） occurs widely in the strata since the late Miocene in the deep-water area of the northern continental slope of South China Sea （SCS）. It is an important seismic reference mark which identifies the gas hydrate and its distribution influenced by the tectonic movements. Single-point basin modeling was conducted using 473 points in the study area. To discuss the relationships between the tectonic subsidence and BSR, the volume and rate of tectonic subsidence in each geological time have been simulated. The results show that there are three tectonic accelerate subsidence processes in the study area since the late Miocene, especially since 1.8Ma the tectonic subsidence accelerates more apparently. Since the Late Miocene to Pleistocene, the rate of tectonic subsidence in deep-water underwent a transformation from weak to strong. The ratio of tectonic subsidence to the total subsidence was relatively high （65-70%）. Through the superposition of the BSR developed areas and the contours of tectonic subsidence in this area, it was discovered that more than 80% of BSR tend to be distributed at the slope break or depression-uplift structural transfer zone and the average tectonic subsidence rate ranges from 70 m/Ma to 125 m/Ma.

Structural Characteristics and Formation Dynamics: A Review of the Main Sedimentary Basins in the Continent of China

The formation and evolution of basins in the China continent are closely related to the collages of many blocks and orogenic belts. Based on a large amount of the geological, geophysical, petroleum exploration data and a large number of published research results, the basement constitutions and evolutions of tectonic-sedimentary of sedimentary basins, the main border fault belts and the orogenesis of their peripheries of the basins are analyzed. Especially, the main typical basins in the eight divisions in the continent of China are analyzed in detail, including the Tarim, Ordos, Sichuan, Songliao, Bohai Bay, Junggar, Qiadam and Qiangtang basins. The main five stages of superimposed evolutions processes of basins revealed, which accompanied with the tectonic processes of the Paleo-Asian Ocean, Tethyan and Western Pacific domains. They contained the formations of main Cratons （1850-800 Ma）, developments of marine basins （800-386 Ma）, developments of Marine- continental transition basins and super mantle plumes （386-252 Ma）, amalgamation of China Continent and developments of continental basins （252-205 Ma） and development of the foreland basins in the western and extensional faulted basin in the eastern of China （205~0 Ma）. Therefore, large scale marine sedimentary basins existed in the relatively stable continental blocks of the Proterozoic, developed during the Neoproterozoic to Paleozoic, with the property of the intracontinental cratons and peripheral foreland basins, the multistage superimposing and late reformations of basins. The continental basins developed on the weak or preexisting divisional basements, or the remnant and reformed marine basins in the Meso-Cenozoic, are mainly the continental margins, back-arc basins, retroarc foreland basins, intracontinental rifts and pull-apart basins. The styles and intensity deformation containing the faults, folds and the structural architecture of regional unconformities of the basins, responded to the openings, subductions, closures of oceans, the continent-continent collisions and reactivation of orogenies near the basins in different periods. The evolutions of the Tianshan-Mongol-Hinggan, Kunlun-Qilian-Qinling-Dabie-Sulu, Jiangshao-Shiwandashan, Helanshan-Longmengshan, Taihang-Wuling orogenic belts, the Tibet Plateau and the Altun and Tan- Lu Fault belts have importantly influenced on the tectonic-sedimentary developments, mineralization and hydrocarbon reservoir conditions of their adjacent basins in different times. The evolutions of basins also rely on the deep structures of lithosphere and the rheological properties of the mantle. The mosaic and mirroring geological structures of the deep lithosphere reflect the pre-existed divisions and hot mantle upwelling, constrain to the origins and transforms dynamics of the basins. The leading edges of the basin tectonic dynamics will focus on the basin and mountain coupling, reconstruction of the paleotectonic-paleogeography, establishing relationship between the structural deformations of shallow surface to the deep lithosphere or asthenosphere, as well as the restoring proto-basin and depicting residual basin of the Paleozoic basin, the effects of multiple stages of volcanism and paleo- earthquake events in China.

Crustal S-wave velocity structure across the northeastern South China Sea continental margin: implications for lithology and mantle exhumation

The northeastern margin of the South China Sea (SCS), developed from continental rifting and breakup, is usually thought of as a non-volcanic margin. However, post-spreading volcanism is massive and lower crustal high-velocity anomalies are widespread, which complicate the nature of the margin here. To better understand crustal seismic velocities, lithology, and geophysical properties, we present an S-wave velocity (VS) model and a VP/VS model for the northeastern margin by using an existing P-wave velocity (VP) model as the starting model for 2-D kinematic S-wave forward ray tracing. The Mesozoic sedimentary sequence has lower VP/VS ratios than the Cenozoic sequence;in between is a main interface of P-S conversion. Two isolated high-velocity zones (HVZ) are found in the lower crust of the continental slope, showing S-wave velocities of 4.0–4.2 km/s and VP/VS ratios of 1.73–1.78. These values indicate a mafic composition, most likely of amphibolite facies. Also, a VP/VS versus VP plot indicates a magnesium-rich gabbro facies from post-spreading mantle melting at temperatures higher than normal. A third high-velocity zone (VP : 7.0–7.8 km/s;VP/VS: 1.85–1.96), 70-km wide and 4-km thick in the continent-ocean transition zone, is most likely to be a consequence of serpentinization of upwelled upper mantle. Seismic velocity structures and also gravity anomalies indicate that mantle upwelling/ serpentinization could be the most severe in the northeasternmost continent-ocean boundary of the SCS. Empirical relationships between seismic velocity and degree of serpentinization suggest that serpentinite content decreases with depth, from 43% in the lower crust to 37% into the mantle.

GRAVITY-DRIVEN SEDIMENTATION ON THE NORTHWESTERN CONTINENTAL SLOPE IN THE SOUTH CHINA SEA:RESULTS FROM HIGH-RESOLUTION SEISMIC DATA AND PISTON CORES

A distinct echo-character was assigned to sedimentation processes, which were then verified using data from surface sediment samples and piston cores. of echo types on the continental slope perfectly reflecting both sediment erosion and deposition, four edimentary types have been recognized:(1) submarine clides distributed on the shelfbreak and characterized by high silt and water conten, loose struture, poor consolidation and low shearing strength; (2) slumps occurring on the shelfbreak, middle slope channel and reef margin near Dongsha Islands, but having different origins; (3) debris flow occurring either in sea areas around Dongsha Atoll, or on the continental slope’s three channels, where the transparent debris flow deposits often overlie or abruptly truncate highly stratified hemipelagic sediments;are of limited to local extent, ranging from a few square kilometers to hundreds of square kilometers in area; but on the lowr slope, usually occur as 1000 km2, about 100 km2 individual complexes; and (4) turbidites, limited on the continental slope; are occurring as migrating waves of sediments at the the of the slope, and are rhythmically-bedded, coarse-grained. Their migration is a result of overbank flow downslope through the submarine channel at the west. The slope faces are dominated by mass wasting deposition, and a few turbidite current sediments. As wasting is an important process. Some debris flow eomplexes on the west are buried by well-stratified confomable sediments, whereas others on the east appear on the present seafloor and therefore are relatively recent.

A continental slope stability evaluation in the Zhujiang River Mouth Basin in the South China Sea

In nature, a slope stability is determined by the ratio of a sliding resistance to a slide force. The slide force of a marine deep-water continental slope is mainly affected by sediment mechanics properties, a topography, and a marine seismic. However, the sliding resistance is mainly affected by sedimentary patterns and a sedimentary stress history. Both of these are different from case to case, and their impact can be addressed when the data are organized in a geographic information system（GIS）. The study area on the continental slope in Zhujiang River Mouth Basin in South China Sea provides an excellent opportunity to apply GIS spatial analysis technology for the evaluation of the slope stability. In this area, a continental slope topography and a three-dimension（3-D） topography mapping show a sea-floor morphology and the distribution of a slope steepness in good detail, and the sediment analysis of seabed samples and an indoor appraisal reveals the variability of a sediment density near the sea-floor surface. On the basis of the results of nine geotechnical studies of submarine study areas, it has worked out that an equivalent cyclic shear stress ratio is roughly between 0.158 and 0.933, which is mainly depending on the initial water content of sediment. A regional density, slope and level of anticipated seismic shaking information are combined in a GIS framework to yield a map that illustrates a continental slope stability zoning under the influencing factors in Zhujiang River Mouth Basin in the South China Sea. The continental slope stability evaluation can contribute to north resources development in the South China Sea, the marine functional zoning, the marine engineering construction and adjust measures to local conditions, at the same time also can provide references for other deep-water slope stability analysis.

Geothermal investigation of the thickness of gas hydrate stability zone in the north continental margin of the South China Sea

The exploration of unconventional and/or new energy resources has become the focus of energy research worldwide,given the shortage of fossil fuels.As a potential energy resource,gas hydrate exists only in the environment of high pressure and low temperature,mainly distributing in the sediments of the seafloor in the continental margins and the permafrost zones in land.The accurate determination of the thickness of gas hydrate stability zone is essential yet challenging in the assessment of the exploitation potential.The majority of previous studies obtain this thickness by detecting the bottom simulating reflectors（BSRs） layer on the seismic profiles.The phase equilibrium between gas hydrate stable state with its temperature and pressure provides an opportunity to derive the thickness with the geothermal method.Based on the latest geothermal dataset,we calculated the thickness of the gas hydrate stability zone（GHSZ） in the north continental margin of the South China Sea.Our results indicate that the thicknesses of gas hydrate stability zone vary greatly in different areas of the northern margin of the South China Sea.The thickness mainly concentrates on 200–300 m and distributes in the southwestern and eastern areas with belt-like shape.We further confirmed a certain relationship between the GHSZ thickness and factors such as heat flow and water depth.The thickness of gas hydrate stability zone is found to be large where the heat flow is relatively low.The GHSZ thickness increases with the increase of the water depth,but it tends to stay steady when the water depth deeper than 3 000 m.The findings would improve the assessment of gas hydrate resource potential in the South China Sea.

Classification and Source Materials of Continental Crust Transformation Series Granitoids in South China

The granitoids of the continental crust transformation series in South China may be divided into threetypes: (1) synorogenic migmatic and magmatic type. (2) anorogenic continental crust anatexis type, and (3)syncollision type. Based on the results of Sr and Nd isotopic determinations, the source material compositionof the three types of granitoids is calculated with crust-mantle binary mixing simulation. The calculations indi-cate that the granitoids of the first type consist of 78.6-89.7% upper crust endmember materials and15.0-10.3% depleted mantle endmember materials, the granitoids of the second type are composed of 63.7%upper crust endmember materials and 36.3% depleted mantle endmember materials, and those of the third type100% upper crust endmember materials. Hence. the source material composition of the granitoids of all thethree types is dominated by upper crust endmembers.

Bottom Currents Observed in and Around a Submarine Valley on the Continental Slope of the Northern South China Sea

Bottom currents at about 1000 m depth in and around a submarine valley on the continental slope of the northern South China Sea were studied by a 14-month long experiment from July 2013 to September 2014. The observations reveal that bottom currents are strongly influenced by the topography, being along valley axis or isobaths. Power density spectrum analysis shows that all the currents have significant peaks at diurnal and semi-diurnal frequencies. Diurnal energy is dominant at the open slope site, which is consistent with many previous studies. However, at the site inside the valley the semi-diurnal energy dominates, although the distance between the two sites of observation is quite small(11 km) compared to a typical horizontal first-mode internal tide wavelength(200 km). We found this phenomenon is caused by the focusing of internal waves of certain frequencies in the valley. The inertial peak is found only at the open slope site in the first deployment but missing at the inside valley site and the rest of the deployments. Monthly averaged residual currents reveal that the near-bottom currents on the slope flow southwestward throughout the year except in August and September, 2013, from which we speculate that this is a result of the interaction between a mesoscale eddy and the canyon/sag topography. Currents inside the valley within about 10 mab basically flow along slope and in the layers above the 10 mab the currents are northwestward, that is, from the deep ocean to the shelf. The monthly mean current vectors manifest an Ekman layer-like vertical structure at both sites, which rotate counter-clockwise looking from above.

Measurement of the current and spectral analysis on the continental shelf in the East China Sea

Direct measurements of current velocity and water temperature were undertaken at the mooring Sta. M (125°29.38' N, 31°49.70' E) on the continental shelf area in the East China Sea in June 1999 by R/V Xiangyanghong 14. The relationship between various time series of oceanic fluctuations is calculated by spectral analysis. The major results are as follows: (1) an average (u,v) of (6.9,-3.0 cm/s) at the 30 m depth is obtained during the 9-day observation, and that at the 45 m depth is (3.7,-1.1 cm/s), i. e., the mean flows are southeastward at both the 30 and 45 m depths;the currents become stronger gradually during the observation period; this may be mainly attributed to the transition of the tidal currents from neap to spring; (2)semidiurnal fluctuation is the most dominant in the current fluctuations, and rotates mainly clockwise; in the next place, there is also diurnal fluctuation;the local inertial period is close to the period of diurnal fluctuation, and an inertial motion is clockwise; thus, local inertial motion combines with diurnal fluctuation, and makes the spectral peaks in clockwise components much higher than those in counterclockwise ones; except for the fluctuations of above main periods, there is also the peak at 3 d period for counterclockwise compo-nents in the upper and lower layers; (3) the calculation of cross spectra between two time series of current velocities at the 30 and 45 m depths shows that both the current fluctuations at the 30 and 45 m depths are much alike, i. e., they are synchro; this shows that the flow field here is rather vertically homogeneous; (4)power spectra of tempera-ture time series at both the 30 and 45 m depths show that the semidiurnal peak is the most predominant, and the second highest peak is the diurnal period; besides spectral peaks at above periods, there are also obvious spectral peaks at 6.8 h and 2 d; (5)plots of temperature time series at 16 , 30 , 35 , 45 and 50 m depths show that the temporal variations of temperature at these depths are synchro, which are like those in the velocity field; temperature records also show a gradual rise in temperature, which are also like those in the velocity field.

The China Seismological Reference Model project

The importance of developing high-resolution seismic models to improve understanding of tectonic processes and enhance seismic hazard mitigation programs,along with the rapid expansion of seismic coverage in China,called for a seismological reference model to be established in China.The China Seismological Reference Model(CSRM)project was initiated by the National Natural Science Foundation of China with two primary goals:(1)the CSRM would serve as a primary source for the current state of seismological research in China,and(2)the seismic data and constraints used to construct the CSRM would be used as a backbone open-access cyberinfrastructure for future research in seismology.The CSRM project was also intended to promote data exchange and scientific collaboration in seismology in China.Accordingly,two parallel efforts of the project are being pursued:(1)construction of the CSRM,and(2)development of a CSRM product center.The CSRM is jointly constrained by various types of seismic constraints extracted from the seismic data recorded at 4511 seismic stations in continental China following a top-down approach,with the seismic structures in the shallower part of the Earth constrained first.Construction of the CSRM involves three preparation steps:(1)building datasets of various seismic constraints from the seismic data,(2)developing a method to incorporate the constraints of surface wave observations from regional earthquakes into the inversion of the seismic structure,and(3)constructing high-resolution pre-CSRM seismic models of the velocity structure in the shallow crust and the Pn-velocity structure in the uppermost mantle.In the final process,the CSRM will be constructed by jointly inverting all the seismic constraints using the pre-CSRM models as starting models or a priori structures.The CSRM product center(http://chinageorefmodel.org)archives and distributes three types of products:CSRM models,the Level 1 original seismic data used to extract seismic constraints in the construction of the CSRM,and Level 2 data on the seismic constraints derived from the Level 1 data and the inferred earthquake parameters in the construction of the CSRM.The CSRM product center has archived 141 TB of Level 1 data from 1120 permanent broadband stations in the China Seismic Network Center and 3391 temporary stations from various institutions and data centers around the world,as well as 140 GB of Level 2 data on various seismic constraints and inferred event parameters from the construction of the CSRM.The CSRM is expected to provide significant insights into the composition and tectonic dynamics in continental China and to enhance the capability of various seismic hazard mitigation programs in China from near real-time rapid determination of earthquake parameters to an earthquake early warning system.The CSRM could also provide guidance for focuses in future seismological research and the design of future active and passive seismic experiments in China.Several focuses are suggested for future seismological research in China,along with the building of a national cyberinfrastructure to sustain and expand the operations of the CSRM project.

pCO_2 distribution and CO_2 flux on the inner continental shelf of the East China Sea during summer 2011

Measurements of pH,total alkalinity(TA),partial pressure of CO2(pCO2) and air-sea CO2 flux(FCO2) were conducted for the inner continental shelf of the East China Sea(ECS) during August 2011.Variations in pCO2 distribution and FCO2 magnitude during the construction of the Three Gorges Dam(TGD)(2003-2009),and the potential effects of the TGD on the air-sea CO2 exchange were examined.Results showed that the ECS acts as an overall CO2 sink during summer,with pCO2 ranging from 107 to 585 μatm and an average FCO2 of-6.39 mmol/(m2·d).Low pCO2(<350 μatm) levels were observed at the central shelf(28°-32°N,123°-125.5°E) where most CO2-absorption occurred.High pCO2(>420 μatm) levels were found in the Changjiang estuary and Hangzhou Bay which acted as the main CO2 source.A negative relationship between pCO2 and salinity(R2=0.722 0) in the estuary zone indicated the predominant effect of the Changjiang Diluted Water(CDW) on the seawater CO2 system,whereas a positive relationship(R2=0.744 8) in the offshore zone revealed the influence of the Taiwan Current Warm Water(TCWW).Together with the historical data,our results indicated that the CO2 sink has shown a shift southwest while FCO2 exhibited dramatic fluctuation during the construction of the TGD,which is located in the middle reaches of the Changjiang.These variations probably reflect fluctuation in the Changjiang runoff,nutrient import,phytoplankton productivity,and sediment input,which are likely to have been caused by the operations of the TGD.Nevertheless,the potential influence of the TGD on the CO2 flux in the ECS is worthy of further study.

REGIONAL ELEMENT ABUNDANCES OFCONTINENTAL CRUSTOBODIES IN CHINA

The continental crustobody of China is composed of three regional crustobodies, i. e., the Cathaysian crustobody, the West China crustobody and the South Tibet crustobody. This paper gives their mass models and element abundance values and discusses their regional abundance characteristics from metallogenic elernents, heat source elements and lanthanide elements. The conclusion is that their geochemical backgrounds are quite different from each other.

Vertical Structure of the Tidal Currents on the Continental Shelf of the East China Sea

The available data on tidal currents spanning periods greater than six months for the continental shelf of the East China Sea (26°30.052′N, 122°35.998′E) were analyzed using several methods. Tidal Current Harmonic Analysis results demonstrated that semi-diurnal tides dominated the current movement. The tidal currents of the principal diurnal and semidiurnal rotated clockwise with depth, with the deflection of the major semi-axes to the right in the upper layer and to the left in the lower layer. The vertical structures of two principal semi-diurnal constituents-M2 and S2-were similar, which indicates that the tidal currents are mainly barotropic in this area. The main features of the variation of the four principal tidal constituents with depth demonstrate that the currents in this region are influenced by the upper and lower boundary layers. Therefore, the tidal constituents of the shallow water are similar. Different vertical modes were calculated based on the Empirical Orthogonal Function (EOF) analysis of the Eastern and Northern components of the tidal currents, with a variance contribution for the zero-order model of at least 90%. The variance contribution of the baroclinic model is minimal, which further reveals a strong barotropic character for the tidal currents of this region.