Successive cultivation of Chinese fir(Cunninghamia lanceolata) would markedly affect the distribution and accumulation of soil inorganic phosphorus(Pi).However,how different chronosequence phases of Chinese fir planta...Successive cultivation of Chinese fir(Cunninghamia lanceolata) would markedly affect the distribution and accumulation of soil inorganic phosphorus(Pi).However,how different chronosequence phases of Chinese fir plantations exerting influences on the quality and quantity of soil Pi fractions in aggregate-scale remain poorly understood. This study researched the dynamic changes of aggregate-related Pi fractions encompassing occluded-P(O-P), aluminum-bound P(Al-P), iron-bound P(Fe-P), and calcium-bound P(Ca-P) in topsoil(0-20 cm) from different stand aged(9-, 17-, and 26-yr) Chinese fir plantations and one nearby abandoned land(CK) in Rongshui County,Guangxi, China. In this study, soil aggregates were classified into micro-aggregates(< 0.25 mm), small macro-aggregates(1-0.25 mm), medium macroaggregates(2-1 mm), and large macro-aggregates(> 2 mm) by one wet-sieving process. As the primary aggregate fractions correlated with better soil aggregate stability, the large macro-aggregates took the highest proportion in all aggregate sizes regardless of various stand ages of Chinese fir plantations. Besides, the 17-yr plantations of Chinese fir displayed the highest stability of aggregates structure. Compared with CK, all four soil Pi fractions from three different stand ages of Chinese fir plantations generally showed increasing trends.Irrespective of chronosequence phases, Al-P was mainly carried by small macro-aggregates. O-P showed the opposite tendency to Al-P, which had the lowest content in small macro-aggregates. Fe-P and Ca-P showed an even distribution in all aggregates.The contribution rates and stocks of each Pi fraction exhibited close relevance to the content of soil aggregates. As revealed from the results, planting of Chinese fir before 17-yr was beneficial to prompt the formation of large macro-aggregates and the level of soil P. But after 17-yr, successive monoculture planting of Chinese fir would reduce the stability of soil aggregates and render the losses of soil P. The dynamics of soil total phosphorous(TP) and Pi fractions contents were highly related to the stand ages of Chinese fir plantations, but less related to the distribution of soil aggregate sizes. As the major carriers for soil P stocks, the large macro-aggregates played a vital role in the cycles and reserves of soil P.展开更多
In order to improve the leaching resistance of active ingredient-copper in ammoniacal copper quat-type D (ACQ-D) treated Chinese fir (Cunninghamia lanceolata Hook.), microwave post-treatments were carried out. The...In order to improve the leaching resistance of active ingredient-copper in ammoniacal copper quat-type D (ACQ-D) treated Chinese fir (Cunninghamia lanceolata Hook.), microwave post-treatments were carried out. The percentages of leached copper from ACQ-D treated Chinese fir with different microwave post-treatments were obtained after leaching tests by analyzing the copper retention in treated wood. The fixation mechanism of copper in the treated wood was determined with the help of SEM and FTIR spectra, while the valence conversion of copper after microwave post-treatments was studied by UV spectroscopy. Our experimental results show that the percentage of leached copper was reduced significantly after microwave post-treatment over time. This development was reinforced by allowing even more time for the treatment as well as with an increase in the power of microwave post-treatment. The leaching resistance of copper in wrapped samples was better than that in unwrapped samples, which is attributed to the combined effects of temperature and moisture content. Compared with air-dried samples, the valence conversion in the samples with microwave post-treatments changed slightly, which demonstrates that microwave post-treatments cannot impair the natural decay resistance of ACQ-D treated wood. SEM and FTIR spectra showed the presence of crystal particles formed by chemical reactions between copper and wood ingredients in wood cell walls and wood pits. Only a small amount of copper reacted with cellulose, while lignin and hemicellulose were the major bonding sites for copper in wood. Given the experimental results of mechanical properties, microwave post-treatments had a slight effect on the compression strength parallel to the grain and on the erystallinity of ACQ-D treated Chinese fir.展开更多
Two clonal trial stands of Chinese Fir (Cunninghamia lanceolata) were used in this study, one was 19-year-old stand which included 38 clones, and the other was 17-year-old stand including 102 clones.The statistical ...Two clonal trial stands of Chinese Fir (Cunninghamia lanceolata) were used in this study, one was 19-year-old stand which included 38 clones, and the other was 17-year-old stand including 102 clones.The statistical analyses showed that there were very significant genetic variations in height, DBH,volume and ratio of heartwood(R<sub>hw</sub>),wood basic density(ρ<sub>b</sub> ) of the clones in the two stands. The repeatability of clones was in median to high level,and the genetic CV was different over the all five traits.There were very significant phenotypic and genetic correlations among height,DBH and volume,and negative correlations among growth, R<sub>hw</sub> andρ<sub>b</sub>.The selection method experiment indicated that index selection could improve volume, R<sub>hw</sub> andρ<sub>b</sub>,showing synthetically superior selection effects compared to any individual trait selection methods.展开更多
In this work, Chinese fir samples with a size of 400 mm (L) by 50 mm (W) 30 mm (H) weretaken as specimens, and drying rate and energy consumption were compared under the conditions, inwhich the absolute pressure was 0...In this work, Chinese fir samples with a size of 400 mm (L) by 50 mm (W) 30 mm (H) weretaken as specimens, and drying rate and energy consumption were compared under the conditions, inwhich the absolute pressure was 0.02 , 0.04 , 0.06 and 0.10 MPa, respectively, and the temperature was80 oC. The results showed that, when the moisture content (MC) of the samples was above fibersaturation point (FSP), the vacuum drying rate was 0.96-1.24 times as high as the ambient pressuredrying rate. However, when it was below FSP, the vacuum drying rate was 1.26-1.32 times as high as theambient pressure drying rate. At the same time, when the MC was above FSP, the energy consumptionof vacuum drying was 81.1%-95.9% of that of ambient pressure drying; when the MC was below FSP,the energy consumption of vacuum drying was 62.40%-69.40% of that of ambient pressure drying.Therefore, the vacuum drying was superior to the ambient pressure drying in terms of drying rate andenergy consumption.展开更多
Near infrared (NIR) spectroscope and X-ray diffractometry have been used for rapid prediction of the microfibril angle (MFA) which is one of the important factors affecting wood properties. Wood property evaluation in...Near infrared (NIR) spectroscope and X-ray diffractometry have been used for rapid prediction of the microfibril angle (MFA) which is one of the important factors affecting wood properties. Wood property evaluation in breeding and resource evaluation requires effective and rapid analysis methods for thousands of samples. In the experiment, all samples from increment cores with moisture content of 60% to 150% were used for measuring MFA by X-ray scanning diffractometry. Then, a partial least squares regression (PLS) model was built based on NIR data and MFA measured. As a result, a strong linear relationship was found between NIR spectroscope fitted and X-ray measured with coefficient of calibration 0.95 and prediction model rate 0.88. NIR estimating is in consist with X-ray determining closely, which indicates that NIR spectroscopy can be successfully used to estimate MFA of increment cores of Chinese fir.展开更多
This paper studied the variation of cleavage resistance of Chinese fir wood from plantation. Six trees of 36 years old were investigated, and the cleavage resistance properties for 672 samples made of the trees were t...This paper studied the variation of cleavage resistance of Chinese fir wood from plantation. Six trees of 36 years old were investigated, and the cleavage resistance properties for 672 samples made of the trees were tested. The samples were cut from the sapwood and heartwood at different directions (south and north) and heights (1.3, 3.3, 5.3 and 7.3 m) of the trees. The result showed that: tangential cleavage resistance was higher than radial one, and cleavage resistance of sapwood was higher than that of heartwood, but there was no significant difference in cleavage resistances between sections of the north and the south of the trees. There was a little variation in cleavage resistance between the radial and tangential from butt to top log, which shows a little decrease with the height from 1.3 to 5.3 m , but a rise in the top of the trees.展开更多
The variability of main chemical composition of radial Chinese fir was studied. Analysis of variance showed that variance was significant, especially for holocellulose and α-celluloSe; the hblocellulose content in he...The variability of main chemical composition of radial Chinese fir was studied. Analysis of variance showed that variance was significant, especially for holocellulose and α-celluloSe; the hblocellulose content in heart wood was lower than that in sapwood; the lignin content decreased from Position t to Position 3, but increased gradually from Position 4 to Position 8; the a ~ cellulose content in heart wood was lower than that in sapwood; and the relative crystallinity was 59.97% in Position 1, 60i80% in Position 2, and about 42% in others.展开更多
As one of the most important plantations,Chinese fir has drawn more and more attention from domestic wood researchers.And as the development and increasing of plantation resource of Chinese fir,research and developmen...As one of the most important plantations,Chinese fir has drawn more and more attention from domestic wood researchers.And as the development and increasing of plantation resource of Chinese fir,research and development of the product will become a hot point.In this paper,we chose 1 571 pieces of structural lumbers from 4 areas to research grading.After sawing,drying and dressing,the lumbers were separated into 3 main grades by GB50005-2003 Code for Design of Timber Structures,namely SS,No.1 and No.2.The conclusions are that knot as the maximum strength reduced defect(MSRD)is a main character in the lumber,the visual quality of Fujian structural lumbers is polarized,and the applicability of visual grading to the lumber is poor,so we hold the point that we should adjust the grading rules to gain a better grading result.展开更多
The variation of tensile strength parallel to grain in Chinese fir and 1-214 poplar wood from plantations was studied in this paper. Aaccording to the national standards The Testing Methods for Physical and Mechanical...The variation of tensile strength parallel to grain in Chinese fir and 1-214 poplar wood from plantations was studied in this paper. Aaccording to the national standards The Testing Methods for Physical and Mechanical Properties of Wood (GB 1927 to 1943 -- 1991), the small clear wood samples were cut and tested, which represent the south and north of trees with heights of 1.3, 3.3, 5.3 and 7.3 m. The results showed: the tensile strength parallel to grain of the north wood was higher than that of south wood. ANOVA shows that the tensile strength parallel to the grain with height is of significant difference (at 0.05 level).展开更多
The carbohydrate compositions of poplar Ⅰ-214 and Chinese fir were investigated by the methods of hydrolysis and HPLC. The result showed that the contents of glucose, xylose and arabinose in poplar I-214 are higher t...The carbohydrate compositions of poplar Ⅰ-214 and Chinese fir were investigated by the methods of hydrolysis and HPLC. The result showed that the contents of glucose, xylose and arabinose in poplar I-214 are higher than those in Chinese fir, while contents of rhamnose and mannose in poplar I-214 are lower than those in Chinese fir.展开更多
Microfibril angle (MFA) in Chinese fir was tested by X-ray diffraction apparatus and calculated by computer software. The results were as follows: MFA was controlled strongly by inheritance, and there was no signif...Microfibril angle (MFA) in Chinese fir was tested by X-ray diffraction apparatus and calculated by computer software. The results were as follows: MFA was controlled strongly by inheritance, and there was no significant difference in MFA among interspecies, juvenile and mature wood. In the longitudinal, MFA reduces with the height rising from 0 to 5.5 m, especially in the heights from 0 to 1.5 m. The values of MFA are nearly consistence from 1.5 to 7.5 m. The variation range was between 10.82°and 12.57°from 1.5 to 7.5 m, R2 of power equation achieved 0.932 1, and analysis of variance indicated that the variation of MFA was not significant from 1.5 to 7.5 m, The age of the trees had an important influence on MFA, consequently, the difference in MFA was significant among annual rings in radial, which was maximal in near pith and reduced rapidly from the pith to sapwood, and its decline tendency was slow beyond the ninth annual ring. MFA reached minimum value at the 15th annual ring, and the difference reached more than 20° and R^2 of binomial equation achieved 0.755 6.展开更多
The volatile organic compounds(VOCs) are emitted by a wide array of products, which include a variety of chemicals, some of them may have short- and long-term adverse health effects. Several analytical instrument incl...The volatile organic compounds(VOCs) are emitted by a wide array of products, which include a variety of chemicals, some of them may have short- and long-term adverse health effects. Several analytical instrument including gas chromatograph, high preferment liquid chromatograph, mass spectrometry and solid phase microextraction (SPME) technique were used in this study. The results showed the aldehyde and ketone components of Chinese fir wood were little composed of formaldehyde, syn- acetaldehyde, anti-acetadehyde and acrolein, VOCs obtained by Tenax GR absorber consisted of the major component cedrene (42.92%) and another 28 components, and the major components of the VOCs from the sample by using solid phase microextraction (SPME) technique were cedrene and cedrol.展开更多
基金supported by the Guangxi Special Fund Project for Innovation Driven Development (AA 17204087-8)the Innovation Project of Guangxi Graduate Education (YCSW2020022)。
文摘Successive cultivation of Chinese fir(Cunninghamia lanceolata) would markedly affect the distribution and accumulation of soil inorganic phosphorus(Pi).However,how different chronosequence phases of Chinese fir plantations exerting influences on the quality and quantity of soil Pi fractions in aggregate-scale remain poorly understood. This study researched the dynamic changes of aggregate-related Pi fractions encompassing occluded-P(O-P), aluminum-bound P(Al-P), iron-bound P(Fe-P), and calcium-bound P(Ca-P) in topsoil(0-20 cm) from different stand aged(9-, 17-, and 26-yr) Chinese fir plantations and one nearby abandoned land(CK) in Rongshui County,Guangxi, China. In this study, soil aggregates were classified into micro-aggregates(< 0.25 mm), small macro-aggregates(1-0.25 mm), medium macroaggregates(2-1 mm), and large macro-aggregates(> 2 mm) by one wet-sieving process. As the primary aggregate fractions correlated with better soil aggregate stability, the large macro-aggregates took the highest proportion in all aggregate sizes regardless of various stand ages of Chinese fir plantations. Besides, the 17-yr plantations of Chinese fir displayed the highest stability of aggregates structure. Compared with CK, all four soil Pi fractions from three different stand ages of Chinese fir plantations generally showed increasing trends.Irrespective of chronosequence phases, Al-P was mainly carried by small macro-aggregates. O-P showed the opposite tendency to Al-P, which had the lowest content in small macro-aggregates. Fe-P and Ca-P showed an even distribution in all aggregates.The contribution rates and stocks of each Pi fraction exhibited close relevance to the content of soil aggregates. As revealed from the results, planting of Chinese fir before 17-yr was beneficial to prompt the formation of large macro-aggregates and the level of soil P. But after 17-yr, successive monoculture planting of Chinese fir would reduce the stability of soil aggregates and render the losses of soil P. The dynamics of soil total phosphorous(TP) and Pi fractions contents were highly related to the stand ages of Chinese fir plantations, but less related to the distribution of soil aggregate sizes. As the major carriers for soil P stocks, the large macro-aggregates played a vital role in the cycles and reserves of soil P.
基金the FANEDD of China (No. 200352)the Fok Ying Tong Education Foundation (No. 101028) for financial support
文摘In order to improve the leaching resistance of active ingredient-copper in ammoniacal copper quat-type D (ACQ-D) treated Chinese fir (Cunninghamia lanceolata Hook.), microwave post-treatments were carried out. The percentages of leached copper from ACQ-D treated Chinese fir with different microwave post-treatments were obtained after leaching tests by analyzing the copper retention in treated wood. The fixation mechanism of copper in the treated wood was determined with the help of SEM and FTIR spectra, while the valence conversion of copper after microwave post-treatments was studied by UV spectroscopy. Our experimental results show that the percentage of leached copper was reduced significantly after microwave post-treatment over time. This development was reinforced by allowing even more time for the treatment as well as with an increase in the power of microwave post-treatment. The leaching resistance of copper in wrapped samples was better than that in unwrapped samples, which is attributed to the combined effects of temperature and moisture content. Compared with air-dried samples, the valence conversion in the samples with microwave post-treatments changed slightly, which demonstrates that microwave post-treatments cannot impair the natural decay resistance of ACQ-D treated wood. SEM and FTIR spectra showed the presence of crystal particles formed by chemical reactions between copper and wood ingredients in wood cell walls and wood pits. Only a small amount of copper reacted with cellulose, while lignin and hemicellulose were the major bonding sites for copper in wood. Given the experimental results of mechanical properties, microwave post-treatments had a slight effect on the compression strength parallel to the grain and on the erystallinity of ACQ-D treated Chinese fir.
文摘Two clonal trial stands of Chinese Fir (Cunninghamia lanceolata) were used in this study, one was 19-year-old stand which included 38 clones, and the other was 17-year-old stand including 102 clones.The statistical analyses showed that there were very significant genetic variations in height, DBH,volume and ratio of heartwood(R<sub>hw</sub>),wood basic density(ρ<sub>b</sub> ) of the clones in the two stands. The repeatability of clones was in median to high level,and the genetic CV was different over the all five traits.There were very significant phenotypic and genetic correlations among height,DBH and volume,and negative correlations among growth, R<sub>hw</sub> andρ<sub>b</sub>.The selection method experiment indicated that index selection could improve volume, R<sub>hw</sub> andρ<sub>b</sub>,showing synthetically superior selection effects compared to any individual trait selection methods.
基金supported by National Natural Science Foundation of China - The Key Theory Study on Vacuum-superheated Vapor Wood Drying (30871978)
文摘In this work, Chinese fir samples with a size of 400 mm (L) by 50 mm (W) 30 mm (H) weretaken as specimens, and drying rate and energy consumption were compared under the conditions, inwhich the absolute pressure was 0.02 , 0.04 , 0.06 and 0.10 MPa, respectively, and the temperature was80 oC. The results showed that, when the moisture content (MC) of the samples was above fibersaturation point (FSP), the vacuum drying rate was 0.96-1.24 times as high as the ambient pressuredrying rate. However, when it was below FSP, the vacuum drying rate was 1.26-1.32 times as high as theambient pressure drying rate. At the same time, when the MC was above FSP, the energy consumptionof vacuum drying was 81.1%-95.9% of that of ambient pressure drying; when the MC was below FSP,the energy consumption of vacuum drying was 62.40%-69.40% of that of ambient pressure drying.Therefore, the vacuum drying was superior to the ambient pressure drying in terms of drying rate andenergy consumption.
文摘Near infrared (NIR) spectroscope and X-ray diffractometry have been used for rapid prediction of the microfibril angle (MFA) which is one of the important factors affecting wood properties. Wood property evaluation in breeding and resource evaluation requires effective and rapid analysis methods for thousands of samples. In the experiment, all samples from increment cores with moisture content of 60% to 150% were used for measuring MFA by X-ray scanning diffractometry. Then, a partial least squares regression (PLS) model was built based on NIR data and MFA measured. As a result, a strong linear relationship was found between NIR spectroscope fitted and X-ray measured with coefficient of calibration 0.95 and prediction model rate 0.88. NIR estimating is in consist with X-ray determining closely, which indicates that NIR spectroscopy can be successfully used to estimate MFA of increment cores of Chinese fir.
文摘This paper studied the variation of cleavage resistance of Chinese fir wood from plantation. Six trees of 36 years old were investigated, and the cleavage resistance properties for 672 samples made of the trees were tested. The samples were cut from the sapwood and heartwood at different directions (south and north) and heights (1.3, 3.3, 5.3 and 7.3 m) of the trees. The result showed that: tangential cleavage resistance was higher than radial one, and cleavage resistance of sapwood was higher than that of heartwood, but there was no significant difference in cleavage resistances between sections of the north and the south of the trees. There was a little variation in cleavage resistance between the radial and tangential from butt to top log, which shows a little decrease with the height from 1.3 to 5.3 m , but a rise in the top of the trees.
基金Supported by the Key Foundation Research Project (G1999016001) of China.
文摘The variability of main chemical composition of radial Chinese fir was studied. Analysis of variance showed that variance was significant, especially for holocellulose and α-celluloSe; the hblocellulose content in heart wood was lower than that in sapwood; the lignin content decreased from Position t to Position 3, but increased gradually from Position 4 to Position 8; the a ~ cellulose content in heart wood was lower than that in sapwood; and the relative crystallinity was 59.97% in Position 1, 60i80% in Position 2, and about 42% in others.
文摘As one of the most important plantations,Chinese fir has drawn more and more attention from domestic wood researchers.And as the development and increasing of plantation resource of Chinese fir,research and development of the product will become a hot point.In this paper,we chose 1 571 pieces of structural lumbers from 4 areas to research grading.After sawing,drying and dressing,the lumbers were separated into 3 main grades by GB50005-2003 Code for Design of Timber Structures,namely SS,No.1 and No.2.The conclusions are that knot as the maximum strength reduced defect(MSRD)is a main character in the lumber,the visual quality of Fujian structural lumbers is polarized,and the applicability of visual grading to the lumber is poor,so we hold the point that we should adjust the grading rules to gain a better grading result.
基金This work was supported by State Science and Technology Infrastructure Platform Projects (2004DEA70900).
文摘The variation of tensile strength parallel to grain in Chinese fir and 1-214 poplar wood from plantations was studied in this paper. Aaccording to the national standards The Testing Methods for Physical and Mechanical Properties of Wood (GB 1927 to 1943 -- 1991), the small clear wood samples were cut and tested, which represent the south and north of trees with heights of 1.3, 3.3, 5.3 and 7.3 m. The results showed: the tensile strength parallel to grain of the north wood was higher than that of south wood. ANOVA shows that the tensile strength parallel to the grain with height is of significant difference (at 0.05 level).
基金Supported by key foundation research project (G1999016001) of China and Japan International Cooperation Agency.
文摘The carbohydrate compositions of poplar Ⅰ-214 and Chinese fir were investigated by the methods of hydrolysis and HPLC. The result showed that the contents of glucose, xylose and arabinose in poplar I-214 are higher than those in Chinese fir, while contents of rhamnose and mannose in poplar I-214 are lower than those in Chinese fir.
文摘Microfibril angle (MFA) in Chinese fir was tested by X-ray diffraction apparatus and calculated by computer software. The results were as follows: MFA was controlled strongly by inheritance, and there was no significant difference in MFA among interspecies, juvenile and mature wood. In the longitudinal, MFA reduces with the height rising from 0 to 5.5 m, especially in the heights from 0 to 1.5 m. The values of MFA are nearly consistence from 1.5 to 7.5 m. The variation range was between 10.82°and 12.57°from 1.5 to 7.5 m, R2 of power equation achieved 0.932 1, and analysis of variance indicated that the variation of MFA was not significant from 1.5 to 7.5 m, The age of the trees had an important influence on MFA, consequently, the difference in MFA was significant among annual rings in radial, which was maximal in near pith and reduced rapidly from the pith to sapwood, and its decline tendency was slow beyond the ninth annual ring. MFA reached minimum value at the 15th annual ring, and the difference reached more than 20° and R^2 of binomial equation achieved 0.755 6.
基金Supported by key foundation research project (G1999016001) of China and Japan International Cooperation Agency.
文摘The volatile organic compounds(VOCs) are emitted by a wide array of products, which include a variety of chemicals, some of them may have short- and long-term adverse health effects. Several analytical instrument including gas chromatograph, high preferment liquid chromatograph, mass spectrometry and solid phase microextraction (SPME) technique were used in this study. The results showed the aldehyde and ketone components of Chinese fir wood were little composed of formaldehyde, syn- acetaldehyde, anti-acetadehyde and acrolein, VOCs obtained by Tenax GR absorber consisted of the major component cedrene (42.92%) and another 28 components, and the major components of the VOCs from the sample by using solid phase microextraction (SPME) technique were cedrene and cedrol.