Energetic,bio-oil,biochar,and ash performances of co-pyrolysis-gasification of textile dyeing sludge and Chinese medicine residues in response to K_(2)CO_(3),atmosphere type,blend ratio,and temperature

Hazardous waste stream needs to be managed so as not to exceed stock-and rate-limited properties of its recipient ecosystems.The co-pyrolysis of Chinese medicine residue(CMR)and textile dyeing sludge(TDS)and its bio-oil,biochar,and ash quality and quantity were characterized as a function of the immersion of K_(2)CO_(3),atmosphere type,blend ratio,and temperature.Compared to the mono-pyrolysis of TDS,its co-pyrolysis performance with CMR(the comprehensive performance index(CPI))significantly improved by 33.9%in the N_(2)atmosphere and 33.2%in the CO_(2)atmosphere.The impregnation catalyzed the co-pyrolysis at 370℃,reduced its activation energy by 77.3 kJ/mol in the N_(2)atmosphere and 134.6 kJ/mol in the CO_(2)atmosphere,and enriched the degree of coke gasification by 44.25%in the CO_(2)atmosphere.The impregnation increased the decomposition rate of the co-pyrolysis by weakening the bond energy of fatty side chains and bridge bonds,its catalytic and secondary products,and its bio-oil yield by 66.19%.Its bio-oils mainly contained olefins,aromatic structural substances,and alcohols.The immersion of K_(2)CO_(3)improved the aromaticity of the copyrolytic biochars and reduced the contact between K and Si which made it convenient for Mg to react with SiO_(2)to form magnesium-silicate.The co-pyrolytic biochar surfaces mainly included-OH,-CH_(2),C=C,and Si-O-Si.The main phases in the co-pyrolytic ash included Ca_(5)(PO_(4))_(3)(OH),Al_(2)O_(3),and magnesium-silicate.

Effects of Different Padding on Air Quality in Broiler House and Growth Physiological Index of Broilers

[Objective] This study aimed to investigate the effects of different padding on ammonia concentration in broiler house and growth performance and blood indi- cators of broilers. [Method] A total of 480 one-day-old 817 broilers were selected. They were randomly divided into four groups with different paddings, and each group was in triplicate. The weights of broilers and feed were weighed weekly. The growth performance of broilers was determined. On day 30, the ammonia concentra- tions in broiler houses were determined. On day 35, 6 broilers were randomly se- lected from each group, and their vein blood was sampled. In the sampled vein blood, the concentrations of ammonia, glucose, globulin, serum total protein and urea nitrogen were determined. [Result] There were significant differences in ammo- nia concentration among broiler houses laid with different paddings （P〈0.05）. The ammonia concentration in group 1 was significantly lower than those in group 3 and group 4 （P〈0.05）. No significant difference was found in ammonia concentrations in broiler houses between group 2 and group 3 （P〉0.05）. The ammonia concentration in group 4 was significantly higher than those in group1, group 2 and group 3 （,0〈 0.05）. There were also significant differences in blood indicators among different groups （P〈0.05）. The blood ammonia, blood glucose and serum urea nitrogen con- centrations in group 1 were significantly lower than those in other groups （P〈0.05）, the serum total protein concentration was significantly higher than those in group 3 and group 4 （P〈0.05）, and the serum globulin concentration was significantly higher than those in group 2, group 3 and group 4 （P〈0.05）. Significant differences were observed in feed intake, body weight gain and slaughter weight between different groups （P〈0.05）, but there were no significant differences in feed to grain ratio （P〉 0.05）. [Conclusion] Under the experimental conditions, the padding of Chinese medicine residue showed better effect on reducing ammonia concentration in broiler house, which was conducive to play of production potential of broilers.