Chlorinated organic pollutants(COPs)have caused serious contaminants in soil and groundwater,hence developing methods to remove these pollutants is necessary and urgent.By a simple hydrothermal method,we synthesized t...Chlorinated organic pollutants(COPs)have caused serious contaminants in soil and groundwater,hence developing methods to remove these pollutants is necessary and urgent.By a simple hydrothermal method,we synthesized the bimetallic iron-nickel sulfide(FeNiS)particles which exhibited excellent catalytic property of COPs removal.FeNiS was chosen as the peroxydisulfate(PDS)activator to removal COPs including 4-chlorophenol(4-CP),1,4-dichlorophenol(1,4-DCP)and 2,4,6-trichlorophenol(2,4,6-TCP).The results show that FeNiS can efficiently activate PDS to produce sulfate radical(SO4·-)which plays major role in the oxidative dechlorination and degradation due to its strong oxidizing property and the ability of producing hydroxyl radicals(·OH)in the alkaline condition.Meanwhile,the Cl-abscised from COPs during the dechlorination can turn into the chlorine radicals and enhance the degradation and cause further mineralization of intermediate products.This bimetallic FeNiS catalyst is a promising PDS activator for removal of chlorinated organics.展开更多
The organic compounds contaminated soil substantially threatens the growth of plants and food safety.In this study,we synthesis zero-valent bimetallic Fe/Cu catalysts for the degradation of 2,4-dichlorophenol(DCP)in s...The organic compounds contaminated soil substantially threatens the growth of plants and food safety.In this study,we synthesis zero-valent bimetallic Fe/Cu catalysts for the degradation of 2,4-dichlorophenol(DCP)in soils with persulfate(PS)in combination of organic surfactants and exploring the main environmental impact factors.The kinetic experiments show that the 5%(mass)dosage of Fe/Cu exhibits a higher degradation efficiency(86%)of DCP in soils,and the degradation efficiency of DCP increases with the increase of the initial PS concentration.Acidic conditions are favorable for the DCP degradation in soils.More importantly,the addition of Tween-80,and Triton-100 can obviously desorb DCP from the soil surface,which enhances the degradation efficiency of DCP in soils by Fe/Cu and PS reaction system.Furthermore,the Quenching experiments demonstrate that SO_(4)^(-1)·and·OH are the predominant radicals for the degradation of DCP during the Fe/Cu and PS reaction system as well as non-radical also exist.The findings of this work provide an effective method for remediating DCP from soils.展开更多
基金supported by the National Natural Science Foundation of China(Nos.21806106,51861145101,21777096 and 21777097)Shanghai Shuguang Grant(No.17SG11)the China Postdoctoral Science Foundation(Nos.2017M621483 and 2018T110397)。
文摘Chlorinated organic pollutants(COPs)have caused serious contaminants in soil and groundwater,hence developing methods to remove these pollutants is necessary and urgent.By a simple hydrothermal method,we synthesized the bimetallic iron-nickel sulfide(FeNiS)particles which exhibited excellent catalytic property of COPs removal.FeNiS was chosen as the peroxydisulfate(PDS)activator to removal COPs including 4-chlorophenol(4-CP),1,4-dichlorophenol(1,4-DCP)and 2,4,6-trichlorophenol(2,4,6-TCP).The results show that FeNiS can efficiently activate PDS to produce sulfate radical(SO4·-)which plays major role in the oxidative dechlorination and degradation due to its strong oxidizing property and the ability of producing hydroxyl radicals(·OH)in the alkaline condition.Meanwhile,the Cl-abscised from COPs during the dechlorination can turn into the chlorine radicals and enhance the degradation and cause further mineralization of intermediate products.This bimetallic FeNiS catalyst is a promising PDS activator for removal of chlorinated organics.
基金financially supported by the National Natural Science Foundation of China(2187616141420104007)+3 种基金the National Key Research and Development Project of China(No.2018YFF0213403)Guangdong Academy of Sciences’Project(2019GDASYL-01020062019GDASYL-03010022018GDASCX-0501)。
文摘The organic compounds contaminated soil substantially threatens the growth of plants and food safety.In this study,we synthesis zero-valent bimetallic Fe/Cu catalysts for the degradation of 2,4-dichlorophenol(DCP)in soils with persulfate(PS)in combination of organic surfactants and exploring the main environmental impact factors.The kinetic experiments show that the 5%(mass)dosage of Fe/Cu exhibits a higher degradation efficiency(86%)of DCP in soils,and the degradation efficiency of DCP increases with the increase of the initial PS concentration.Acidic conditions are favorable for the DCP degradation in soils.More importantly,the addition of Tween-80,and Triton-100 can obviously desorb DCP from the soil surface,which enhances the degradation efficiency of DCP in soils by Fe/Cu and PS reaction system.Furthermore,the Quenching experiments demonstrate that SO_(4)^(-1)·and·OH are the predominant radicals for the degradation of DCP during the Fe/Cu and PS reaction system as well as non-radical also exist.The findings of this work provide an effective method for remediating DCP from soils.