In this study,zirconia containing refractory samples were decomposed by dilute nitric acid.The chloride ion content in the leaching solution was determined by thiocyanate spectrophotometry.The influences of the leachi...In this study,zirconia containing refractory samples were decomposed by dilute nitric acid.The chloride ion content in the leaching solution was determined by thiocyanate spectrophotometry.The influences of the leaching method of the sample pretreatment and the coloration condition of the solution to be tested on the test results were studied.The precision test was carried out and the results were compared with those determined by ion chromatography.The results showed that the zirconia containing refractories were boiled with dilute nitric acid to obtain the test solution.The influence of zirconium hydrolysis on determination was removed by centrifugation.The chlorine contents in zirconia containing refractories determined by spectrophotometry have low relative standard deviation(RSD),showing slight testing difference with those determined by ion chromatograghy.展开更多
As one of the best established low temperature thermochronology techniques,apatite fission-track(AFT)analysis has proved an important tool for constraining a wide variety of upper crustal processes,e.g.,landscape evol...As one of the best established low temperature thermochronology techniques,apatite fission-track(AFT)analysis has proved an important tool for constraining a wide variety of upper crustal processes,e.g.,landscape evolution,hydrocarbon exploration and tectonics[1].The most common method employed for AFT analysis is the external detector method(EDM)[1]and this involves the thermal neutron irradiation of samples for determination of展开更多
文摘In this study,zirconia containing refractory samples were decomposed by dilute nitric acid.The chloride ion content in the leaching solution was determined by thiocyanate spectrophotometry.The influences of the leaching method of the sample pretreatment and the coloration condition of the solution to be tested on the test results were studied.The precision test was carried out and the results were compared with those determined by ion chromatography.The results showed that the zirconia containing refractories were boiled with dilute nitric acid to obtain the test solution.The influence of zirconium hydrolysis on determination was removed by centrifugation.The chlorine contents in zirconia containing refractories determined by spectrophotometry have low relative standard deviation(RSD),showing slight testing difference with those determined by ion chromatograghy.
基金jointly supported by the Fundamental Scientific Research of the Institute of Geology, China Earthquake Administration (IGCEA1509)the National Natural Science Foundation of China (41603054 and 41474053)China Scholarship Council
文摘As one of the best established low temperature thermochronology techniques,apatite fission-track(AFT)analysis has proved an important tool for constraining a wide variety of upper crustal processes,e.g.,landscape evolution,hydrocarbon exploration and tectonics[1].The most common method employed for AFT analysis is the external detector method(EDM)[1]and this involves the thermal neutron irradiation of samples for determination of
