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Impacts of Water-Sediment Regulation Scheme on Chromophoric Dissolved Organic Matter in the Lower Yellow River
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作者 LIU Xiao JIANG Xueyan +2 位作者 LIU Qian SUI Juanjuan ZOU Li 《Journal of Ocean University of China》 CAS CSCD 2024年第2期455-466,共12页
As a river with more than 3000 reservoirs in its watershed,the Yellow River has been affected by dams not only on the sediment load,but also on the water quality.Water-sediment regulation scheme(WSRS),which has been c... As a river with more than 3000 reservoirs in its watershed,the Yellow River has been affected by dams not only on the sediment load,but also on the water quality.Water-sediment regulation scheme(WSRS),which has been carried out annually in the Yellow River since 2002,is a typical human activity affecting river water quality.Chromophoric dissolved organic matter(CDOM)in river is susceptible to changes in ecological and environmental conditions as well as human activities.Here,we report variations in dissolved organic carbon concentrations,compositions and sources of CDOM in time series samples in the lower Yellow River during WSRS.In addition,a parallel factor fluorescence analysis(PARAFAC)method is applied to identify different fluorescent components in water samples during WRSR,showing four major components including tryptophan-like component(C1),microbial humic-like component(C2),terrestrial humic-like component(C3)and tyrosine-like component(C4).In general,C1 increased after water regulation,while C2 and C3 increased after sediment regulation,indicating that the water and sediment released by the dam have different effects on CDOM compositions.Under the impacts of the dam,source of CDOM in the lower Yellow River is mainly autochthonous related to microbial activities,and is regulated by the terrestrial input during WSRS period.Sediment resuspension inhibits microbial activities and reduces the production of autochthonous CDOM.Overall,human activities especially WSRS,as exemplified here,significantly alter the quality and quantity of CDOM in the lower Yellow River,affecting CDOM dynamics and biogeochemical processes in the estuarine environment. 展开更多
关键词 chromophoric dissolved organic matter(cdom) water-sediment regulation scheme(WSRS) Yellow River optical properties
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Optical Characteristics of Chromophoric Dissolved Organic Matter(CDOM)in Upstream and Downstream Lakes of Taihu Lake Basin:New Insights for Water Environmental Management
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作者 REN Weixiang WU Xiaodong +4 位作者 CHEN Bingfa CHAO Jianying GE Xuguang YANG Jiuyun YANG Hui 《Chinese Geographical Science》 SCIE CSCD 2022年第4期606-619,共14页
Chromophoric dissolved organic matter(CDOM)is a key component of organic matter that contributes to the ecological functioning of lakes.The lakes in Taihu Lake Basin play an important role in maintaining regional ecol... Chromophoric dissolved organic matter(CDOM)is a key component of organic matter that contributes to the ecological functioning of lakes.The lakes in Taihu Lake Basin play an important role in maintaining regional ecological stabilities;however,the optical characteristics of the CDOM in the upstream and downstream lakes in this basin have not yet been systematically studied.Here,the optical characteristics of CDOM in ten lakes of upstream and downstream of the Taihu Lake Basin were studied using UV-Visible and excitation-emission matrix spectroscopies.Three different fluorophores consisting of two humic-like components(C1,C2)and one protein-like component(C3)were identified by parallel factor analysis.Soil or surface erosion was responsible for the higher abund-ance of C1 in the upstream lakes,and increased biological activities accounted for the higher abundance of C3 in the downstream lakes.Rainfall erosion in the wet season led to an increase in CDOM.We also found that the photodegradation and flocculation degree,which played a significant role in reducing CDOM,were higher in downstream lakes than in upstream lakes.Optical analysis of CDOM provides a promising method for monitoring water qualities(e.g.,total phosphorus and potassium permanganate index)in each lake.Re-ductions in soil or surface erosion in the upstream are needed to improve water quality. 展开更多
关键词 Taihu Lake Basin chromophoric dissolved organic matter(cdom) excitation-emission spectra parallel factor analysis(PARAFAC)
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Origin and three-dimensional fluorescence spectrum of the chromophoric dissolved organic matter in Yangtze estuary, East China
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作者 Fan YANG Qinghui HUANG Jianhua LI Xiaomin ZHU 《Chinese Journal Of Geochemistry》 EI CAS 2006年第B08期262-262,共1页
关键词 溶解有机物 cdom 荧光性 长江 水文化学
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Impact of transparent exopolymer particles on the dynamics of dissolved organic carbon in the Amundsen Sea,Antarctica
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作者 HU Ji XUE Siyou +6 位作者 ZHAO Jun LI Dong ZHANG Haifeng YU Peisong ZHANG Cai YANG Xufeng PAN Jianming 《Advances in Polar Science》 CSCD 2024年第1期123-131,共9页
The Southern Ocean is an important carbon sink pool and plays a critical role in the global carbon cycling.The Amundsen Sea was reported to be highly productive in inshore area in the Southern Ocean.In order to invest... The Southern Ocean is an important carbon sink pool and plays a critical role in the global carbon cycling.The Amundsen Sea was reported to be highly productive in inshore area in the Southern Ocean.In order to investigate the influence of transparent exopolymer particles(TEP)on the behavior of dissolved organic carbon(DOC)in this region,a comprehensive study was conducted,encompassing both open water areas and highly productive polynyas.It was found that microbial heterotrophic metabolism is the primary process responsible for the production of humic-like fluorescent components in the open ocean.The relationship between apparent oxygen utilization and the two humic-like components can be accurately described by a power-law function,with a conversion rate consistent with that observed globally.The presence of TEP was found to have little impact on this process.Additionally,the study revealed the accumulation of DOC at the sea surface in the Amundsen Sea Polynya,suggesting that TEP may play a critical role in this phenomenon.These findings contribute to a deeper understanding of the dynamics and surface accumulation of DOC in the Amundsen Sea Polynya,and provide valuable insights into the carbon cycle in this region. 展开更多
关键词 dissolved organic matter chromophoric dissolved organic matter excitation-emission matrix coupled with parallel factor analysis transparent exopolymer particles Amundsen Sea ANTARCTICA
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Concentration and Characterization of Colored Dissolved Organic Matter in the Surface Microlayer and Subsurface Water of the Yellow Sea and the East China Sea 被引量:5
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作者 ZHANG Jing ZHAO Junjie +1 位作者 YANG Guipeng LIU Weifeng 《Journal of Ocean University of China》 SCIE CAS CSCD 2019年第2期383-393,共11页
The distribution and chemical properties of colored dissolved organic matter(CDOM) in the Yellow Sea and the East China Sea during December 2011-January 2012 were investigated. The input of freshwater and biological a... The distribution and chemical properties of colored dissolved organic matter(CDOM) in the Yellow Sea and the East China Sea during December 2011-January 2012 were investigated. The input of freshwater and biological activities had an evident influence on the CDOM levels(characterized by the light absorption coefficient at the wavelength of 355 nm a_(355)) in the study area. The spatial distribution of CDOM levels displayed a gradually decreasing trend from the coastal waters(0.37 m^(-1)) to the open sea(0.18 m^(-1)). The spectral slope ratio(the slope ratio S_R defined as S_(275-295):S_(350-400)) during the cruise was correlated with salinity, and exhibited a large variation from inshore(average of 2.515) to offshore sites(average of 5.327) compared with the distribution of a_(355). The values of S_R were related to CDOM molecular weight(MW). The a_(355), S_R, and chlorophyll a in 37 samples collected from the surface microlayer were significantly correlated with those in the corresponding subsurface water samples, implying a strong exchange action between the microlayer and bulk water. The a_(355) and S_R of CDOM exhibited significant microlayer enrichment, with mean enrichment factors(EFs) of 1.72 and 1.62, respectively. 展开更多
关键词 COLORED dissolved organic matter(cdom) absorption coefficient spectral SLOPE ratio YELLOW SEA East China SEA
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Spectral Characterization of Colored Dissolved Organic Matter for Productive Inland Waters and Its Source Analysis 被引量:5
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作者 SONG Kaishan LI Lin +3 位作者 Lenore TEDESCO Nicolas CLERCIN LI Linhai SHI Kun 《Chinese Geographical Science》 SCIE CSCD 2015年第3期295-308,共14页
This study examined the spatiotemporal dynamics of colored dissolved organic matter (CDOM) and spectral slope (S), and further to analyze its sources in three productive water supplies (Eagle Creek, Geist and Mor... This study examined the spatiotemporal dynamics of colored dissolved organic matter (CDOM) and spectral slope (S), and further to analyze its sources in three productive water supplies (Eagle Creek, Geist and Morse reservoirs) from Indiana, USA. The re- sults showed that he absorption coefficient aCDOM(440) ranged from 0.37 m-1 to 3.93 m-1 with an average of 1.89 ± 0.76 m-1 (±SD) for the aggregated dataset, and S varied from 0.0048 nm -1 to 0.0239 nm-1 with an average of 0.0108 ±0.0040 nmI. A significant relation- ship between S and aCDOM(440) can be fitted with a power equation (S = 0.013 × aCDOM(440)-0.42, R2 = 0.612), excluding data from Geist Reservoir during high flow (12 April 2010) and the Morse Reservoir on 25 June 2010 due to a T-storm achieves even higher determina- tion coefficient (R2 = 0.842). Correlation analysis indicated that aCDOM(440) has strong association with inorganic suspended matter (ISM) concentration (0.231 〈 R2 〈 0.786) for each of the field surveys, and this trend followed the aggregated datasets (R2 = 0.447, p 〈 0.001). In contrast, chlorophyll-a was only correlated with aCDOM(440) in summer and autumn (0.081 〈 R2 〈 0.763), indicating that CDOM is mainly from terrigenous sources in early spring and that phytoplankton contributed during the algal blooming season. The S value was used to characterize CDOM origin. The results indicate that the CDOM source is mainly controlled by hydrological varia- tions, while phytoplankton originated organic matter also closely linked with CDOM dynamics in three productive reservoirs. 展开更多
关键词 absorption coefficient colored dissolved organic matter (cdom CHLOROPHYLL-A spectral slope (S) inorganic suspendedmatter (ISM)
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Chemical properties of colored dissolved organic matter in the sea-surface microlayer and subsurface water of Jiaozhou Bay, China in autumn and winter
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作者 ZHANG Jing YANG Guipeng 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2013年第6期26-39,共14页
The distribution and chemical properties of chromophoric dissolved organic matter (CDOM) in the Jiaozhou Bay, China were examined during four cruises in 2010-2011. The influence of freshwater and industrial and muni... The distribution and chemical properties of chromophoric dissolved organic matter (CDOM) in the Jiaozhou Bay, China were examined during four cruises in 2010-2011. The influence of freshwater and industrial and municipal sewage along the eastern coast of the bay was clearly evident as CDOM level- s (defined as a30s), and dissolved organic carbon (DOC) concentrations were well correlated with salinity during all the cruises. Moreover, DOC concentrations were significantly correlated with chlorophyll a con- centrations in the surface microlayer as well as in the subsurface water. The concentrations of DOC and CDOM displayed a gradually decreasing trend from the northwestern and eastern coast to the central hay, and the values and gradients of their concentrations on the eastern coast were generally higher than those on the western coast. In addition, CDOM and DOC levels were generally higher in the surface microlayer than in the subsurface water. In comparison with DOC, CDOM exhibited a greater extent of enrichment in the microlayer in each cruise, with average enrichment factor (EF) values of 1.38 and 1.84, respectively. Four fluorescent components were identified from the surface microlayer and subsurface water samples and could be distinguished as peak A, peak T, peak B and peak M. For all the cruises, peak A levels were higher in the surface microlayer than in the subsurface water. This pattern of variation might be attributed to the terrestrial input. 展开更多
关键词 colored dissolved organic matter (cdom absorption coefficient dissolved organic carbon (DOC) fluorescence excitation emission matrix (EEMs) Iiaozhou Bay
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Spatiotemporal characteristics and remote sensing estimation of colored dissolved organic matter around the Leizhou Peninsula
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作者 Dongyang FU Shiyun WEI +3 位作者 Guo YU Yafei LUO Huabing XU Zhaoguang CHEN 《Journal of Oceanology and Limnology》 SCIE CAS CSCD 2023年第4期1405-1424,共20页
Colored dissolved organic matter(CDOM)is an important optically active substance in marine environment.Its biochemical conservatism makes it an important indicator to offshore pollution process.Monitoring the content,... Colored dissolved organic matter(CDOM)is an important optically active substance in marine environment.Its biochemical conservatism makes it an important indicator to offshore pollution process.Monitoring the content,composition,and diffusion process of CDOM is a good approach to analyze the terrestrial input,optical properties,and ecological environment of offshore areas.The spatiotemporal characteristics of CDOM around the Leizhou Peninsula were analyzed based on field observation data collected in the autumn 2020 and spring 2021,and an empirical inversion model of the ag(355)(absorption coefficient at 355 nm)and spectral slope(Sg)(g stands for gelbstoff/gilvin,which is called CDOM)based on Sentinel-3A ocean and land color instrument(OLCI)images was constructed.The results show(1)the order of average ag(355)value around the Leizhou Peninsula was east coast(0.503/m)>Qiongzhou Strait(0.502/m)>west coast(0.365/m);(2)the best band combinations of CDOM inversion in spring and autumn were(B4+B11)/B3 and(B7-B1)/B6(B stands for the band of spectral images),and the final inversion results are close to the measured results,indicating that the model has good accuracy;(3)the S_(g)value of the CDOM absorption spectrum was fitted to the hyperbolicexponential model.The fitting accuracy of the model was higher than those of the exponential model and the hyperbolic model,and the best S_(g)inversion model was constructed by selecting Sg(275-295)and Sg(250-295)in spring and autumn;(4)the spatial distributions of ag(355)and S_(g)were inverted,and CDOM in the waters around the Leizhou Peninsula originated from terrestrial organic matter carried by coastal aquaculture zones and runoff in the northeast Zhanjiang and the northern Beibu Gulf. 展开更多
关键词 colored dissolved organic matter(cdom) ocean and land color instrument(OLCI) spectral slope hyperbolic-exponential model INVERSION
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Assessing the dynamics of chromophoric dissolved organic matter(CDOM) in the Yellow Sea and the East China Sea in autumn by EEMs-PARAFAC 被引量:6
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作者 YAN LiHong SU RongGuo +2 位作者 ZHANG ChuanSong SHI XiaoYong ZHU ChenJian 《Science China Chemistry》 SCIE EI CAS 2012年第12期2595-2609,共15页
In this study we have successfully characterized the fluorescent components of chromophoric dissolved organic matter(CDOM) in the Yellow Sea and the East China Sea in autumn using excitation-emission matrix fluorescen... In this study we have successfully characterized the fluorescent components of chromophoric dissolved organic matter(CDOM) in the Yellow Sea and the East China Sea in autumn using excitation-emission matrix fluorescence spectroscopy(EEMs) combined with parallel factor analysis(PARAFAC).PARAFAC aids the characterization of fluorescence CDOM by decomposing the fluorescence matrices into individual components.Four humic-like components(C1,C2,C3,and C4),one marine biological production component(C6),and two protein-like components(C5 and C7) were identified by PARAFAC.We researched the distributional patterns of fluorescence intensity,regression analyses between salinity,chlorophyll a concentration and fluorescence intensities of individual fluorophore,and regression analysis between salinity and fluorescence intensities percent of individual fluorophore.The results revealed that C2 and C4 showed conservative mixing behavior,while C1 and C3 possessed conservative mixing behavior in high salinity region and additional behavior in low and middle salinity region,which were considered to be derived from riverine and degradation of organic matter from resuspended and/or sinking particles and show non-conservative mixing behavior.In addition to riverine sources,the tryptophan-like C5 may receive widespread addition(likely from photo-degradation or biodegradation),while the most likely sources for the one marine humic-like C6 and tyrosine-like C7 were biological activity and microbial processing of plankton-derived CDOM,which were suggested to be of autochthonous origin and biologically labile.The application of EEM-PARAFAC modeling presents a unique opportunity to observe compositional changes,different mixing behavior and temporal variability in CDOM in the Yellow Sea and the East China Sea. 展开更多
关键词 chromophoric dissolved organic matter fluorescence excitation emission Matrix spectroscopy PARAFAC model the Yellow Sea the East China Sea Yangtze Estuary conservative mixing behavior non-conservative mixing behavior
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Characterization of chromophoric dissolved organic matter(CDOM) in the East China Sea in autumn using excitationemission matrix(EEM) fluorescence and parallel factor analysis(PARAFAC) 被引量:3
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作者 BAI Ying SU RongGuo +3 位作者 YAN LiHong YAO Peng SHI XiaoYong WANG XiuLin 《Science China Chemistry》 SCIE EI CAS 2013年第12期1790-1799,共10页
Samples of chromophoric dissolved organic matter (CDOM) in the East China Sea in autumn (October in 2011) were analyzed by excitation emission matrix (EEM) fluorescence spectroscopy combined with parallel factor... Samples of chromophoric dissolved organic matter (CDOM) in the East China Sea in autumn (October in 2011) were analyzed by excitation emission matrix (EEM) fluorescence spectroscopy combined with parallel factor analysis (PARAFAC). Three terrestrial humic-like components (C1, C2 and C3) and one protein-like component (C4) were identified. Based on spatial dis- tributions, as well as relationships with salinity, the following assignments were made. The three humic-like components (CI, C2 and C3) showed conservative mixing behavior and came mainly from riverine input. The protein-like component (C4) was considered a combination of autochthonous production and terrestrial inputs and a biologically labile component. Path analysis of samples from the middle and bottom layers revealed that the causal effects on C1 were -78.46% for salinity, and -21.54% for apparent oxygen utilization (AOU); those on C2 were -76.43% for salinity, and -23.57% for AOU; those on C3 were -70.49% for salinity, 7.01% for Chl-a, and -22.50% for AOU; those on C4 were -55.54% for salinity, 14.6% for Chl-a, and -29.86% for AOU in middle layer; and those on C4 were -57.37% for salinity, 29.02% for Chl-a, and -13.61% for AOU in bottom layer. Results indicated that CDOM in tile East China Sea was mainly affected by terrestrial inputs, and microbial ac- tivities also played a key role in biogeochemical processes of CDOM. The application of the EEM-PARAFAC model present- ed a unique opportunity to observe compositional changes in CDOM in the East China Sea. In addition, the humification index (HIX) suggested that CDOM from the East China Sea was less stable and stayed shorter in the environment. 展开更多
关键词 East China Sea chromophoric dissolved organic matter fluorescence excitation emission matrix spectroscopy parallelfactor analysis humification index fluorescence index
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Photodegradation of chromophoric dissolved organic matters in the water of Lake Dianchi, China 被引量:2
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作者 Yuan ZHANG 《Frontiers of Environmental Science & Engineering》 SCIE EI CAS CSCD 2015年第4期575-582,共8页
Water samples were taken from Lake Dianchi, on the Yungui Plateau of southwest China, and experi- ments were conducted to simulate the photochemical degradation characteristic of chromophoric dissolved organic matter ... Water samples were taken from Lake Dianchi, on the Yungui Plateau of southwest China, and experi- ments were conducted to simulate the photochemical degradation characteristic of chromophoric dissolved organic matter (CDOM) in the lake water. Three groups of experiments under different light conditions: ultraviolet (UV) light, visible light, and dark, were done and variations of fluorescence properties, UV absorbance, and dissolved organic carbon (DOC) concentrations during the experiments were analyzed to study the photodegradation process of CDOM with time. The result showed that light irradiation led to significant photochemical degradation of CDOM, resulting in changes in florescent properties, absorbance losses, decreases in aromaticity and average molecular weight, as well as decline in DOC concentration in the water. It was also observed that UV irradiation had greater effect than visible light did. However, various fluorophores had different sensitivities to the same irradiation condition, that is, protein-like fluorophore at the low excitation wavelengths is more sensitive to UV irradiation than the other fluorophores, and is more readily to undergo photo-degradation. In addition, visible light irradiation did not have significant impact on DOC in the water, with DOC concentration decrease by 5.57% -59.9% during the experiment time. These results may provide new knowledge on the environment behavior of CDOM in the water of Lake Dianchi. 展开更多
关键词 chromophoric dissolved organic matter photodegradation ultraviolet radiation dissolved organic carbon
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An ultraviolet to visible scheme to estimate chromophoric dissolved organic matter absorption in a Case-2 water from remote sensing reflectance 被引量:1
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作者 Xia LEI Jiayi PAN Adam DEVLIN 《Frontiers of Earth Science》 SCIE CAS CSCD 2020年第2期384-400,共17页
In a typical Case-2 coastal water environment(here,the Pearl River Estuary(PRE),China),chromophoric dissolved organic matter(CDOM)and suspended particulates dominate the water optical properties,and CDOM fluorescence ... In a typical Case-2 coastal water environment(here,the Pearl River Estuary(PRE),China),chromophoric dissolved organic matter(CDOM)and suspended particulates dominate the water optical properties,and CDOM fluorescence contributes considerably to surface water reflectance.In this paper,an ultraviolet(UV)to visible scheme to retrieve CDOM absorption(ag)is developed based on a set of in situ observations.First,the CDOM UV absorption and spectral slope(Sg)are derived directly from the visible remote sensing reflectance;then the Sg is extrapolated to obtain the spectrum from UV to visible spectral range.This algorithm performs well,with an overall mean absolute percent difference(MAPD)of^30%,~5%and^6%for the estimation of ag in 250–450 nm,Sg over 250–400 nm,and 250–700 nm,respectively.The effectiveness and stability of the algorithm is further demonstrated in capturing the distribution pattern of CDOM absorption in the PRE from satellite ocean color imagery with multiple spatial and spectral resolution,namely:the Visible Infrared Imaging Radiometer Suite(VIIRS)(750 m/Multispectral),the Ocean and Land Color Instrument(OLCI)(300 m/Multispectral),the Hyperspectral Imager for the Coastal Ocean(HICO)(100 m/Hyperspectral),and the Landsat 8 Operational Land Imager(OLI)(30 m/Multispectral).The UV to visible scheme can benefit the CDOM absorption estimation in two aspects:1)it is free from the disturbance of suspended matter;2)it avoids uncertainties caused by the low signalto-noise ratio(SNR)of ag measurements in the visible range.The algorithm is effective in revealing multiple scales of variation of CDOM absorption from ocean color observations. 展开更多
关键词 chromophoric dissolved organic matter ocean color remote sensing Pearl River Estuary ULTRAVIOLET
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鄱阳湖碟形湖和通江水域有色可溶性有机物(CDOM)的吸收与荧光特性对比研究
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作者 简正军 徐健 +1 位作者 刘甲庆 胡启武 《环境科学研究》 CAS CSCD 北大核心 2024年第4期741-751,共11页
有色可溶性有机物(CDOM)在水生态系统的生物地球化学循环中起着重要的作用.近年来,在全球气候变暖和人类活动的双重影响下,全球大部分湖泊出现了水文隔离现象.然而,水文隔离如何影响大型湖泊CDOM组成变化仍然知之甚少.本研究于2021年在... 有色可溶性有机物(CDOM)在水生态系统的生物地球化学循环中起着重要的作用.近年来,在全球气候变暖和人类活动的双重影响下,全球大部分湖泊出现了水文隔离现象.然而,水文隔离如何影响大型湖泊CDOM组成变化仍然知之甚少.本研究于2021年在鄱阳湖碟形湖和通江水域采集水样,运用紫外-可见吸收光谱与三维荧光光谱,结合平行因子分析法(PARAFAC)研究CDOM光学特性,揭示鄱阳湖碟形湖和通江水域CDOM组成和来源的差异.结果表明:①碟形湖溶解性有机碳(DOC)浓度以及CDOM在355 nm处的吸收系数〔a(355)〕的平均值均显著高于通江水域(p<0.001),表明受水文隔离影响的碟形湖水体中存在更丰富的有机物.②基于PARAFAC分析得出的类腐殖质荧光组分(C1、C2)和蛋白质荧光组分(C3)最大荧光强度值(Fmax)的平均值均表现为碟形湖高于通江水域;碟形湖和通江水域的类腐殖质组分(C1+C2)占总荧光强度的比例分别为71.96%和59.93%,且通江水域CDOM中蛋白质荧光组分C3的贡献率高于碟形湖.③通过碟形湖和通江水域CDOM特征参数的对比分析,得出碟形湖CDOM相对分子量和腐殖化程度均高于通江水域.研究显示,水文隔离对鄱阳湖CDOM空间分布及组成变化有显著的影响. 展开更多
关键词 鄱阳湖 水文隔离 有色可溶性有机物(cdom) 荧光组成差异 来源解析
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基于CDOM光谱特征的泥页岩产气特征评价
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作者 郑晓璇 田继先 +4 位作者 田聪 蒋峥文 杨磊 贺秋芳 薛红蕾 《地质科技通报》 CAS CSCD 北大核心 2024年第4期128-140,共13页
泥页岩中可溶有机质(DOM)组成和可降解性是影响生物气形成的重要因素,开发简便有效的方法来评估可溶有机质的组成、官能团特征和微生物活性等,可为泥页岩生物气田产气机制分析提供关键的基础信息。采集了柴达木盆地涩探1井1219~1309 m... 泥页岩中可溶有机质(DOM)组成和可降解性是影响生物气形成的重要因素,开发简便有效的方法来评估可溶有机质的组成、官能团特征和微生物活性等,可为泥页岩生物气田产气机制分析提供关键的基础信息。采集了柴达木盆地涩探1井1219~1309 m泥质岩心,基于有色可溶有机质(CDOM)的三维荧光(EEM)和紫外可见吸收光谱特征,分析了可溶有机质的组分、官能团特征和易降解程度,了解了产甲烷菌可利用底物的分布情况。结果表明:涩探1井岩心有机质以易降解的类色氨酸荧光组分C1和C3为主,占比70.54%;荧光组分、荧光参数HIX、BIX和吸光系数E_(253)/E_(203)、SUVA_(254)共同指示1219~1222 m和1285~1301 m2个层位有机质腐殖化程度较低,芳香性较弱,为潜在的产气活跃层位。研究表明CDOM光谱可以作为分析泥页岩可溶有机质特征的有效方法,其结果反映了产甲烷菌可利用底物和微生物活性等特征,为烃源层系内生物产气预测提供有效的重要信息。 展开更多
关键词 生物气 可溶有机质(DOM) cdom三维荧光光谱 紫外-可见吸收光谱 柴达木盆地 泥页岩
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Photo-production of dissolved inorganic carbon from dissolved organic matter in contrasting coastal waters in the southwestern Taiwan Strait, China 被引量:7
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作者 Weidong Guo Liyang Yang +2 位作者 Xiangxiang Yu Weidong Zhai Huasheng Hong 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2012年第7期1181-1188,共8页
Photo-production of dissolved inorganic carbon (DIC) from chromophoric dissolved organic matter (CDOM) is an important transformation process in marine carbon cycle, but little is known about this process in Chine... Photo-production of dissolved inorganic carbon (DIC) from chromophoric dissolved organic matter (CDOM) is an important transformation process in marine carbon cycle, but little is known about this process in Chinese coastal systems. This study investigated an estuarine water sample and a coastal seawater sample from the subtropical waters in southeast of China. Water samples were exposed to natural sunlight and the absorption and fluorescence of CDOM as well as the DIC concentration were measured in the summer of 2009. The estuarine water had higher CDOM level, molecular weight and proportion of humic-like fluorescent components than the seawater that exhibited abundant tryptophan-like fluorescent component. After a 3-day irradiation, the CDOM level decreased by 45% in the estuarine water and 20% in the seawater, accompanied with a decrease in the molecular weight and aromaticity of DOM which was inferred from an increase in the absorption spectral slope parameter. The photo-degradation rates of all the five fluorescent components were also notable, in particular two humic-like components (C4 and C5) were removed by 78% and 69% in the estuarine water and by 69% and 56% in the seawater. The estuarine water had a higher photo-production rate of DIC than the seawater (4.4 vs. 2.5 μmol/(L-day)), in part due to its higher CDOM abundance. The differences in CDOM compositions between the twO types of waters might be responsible for the higher susceptibility of the estuarine water to photo-degradation and hence could also affect the photo-production process of DIC. 展开更多
关键词 dissolved inorganic carbon photo-production and -degradation chromophoric dissolved organic matter ESTUARY seawater
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基于三维荧光光谱-平行因子分析技术的蠡湖CDOM分布特征 被引量:54
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作者 王书航 王雯雯 +2 位作者 姜霞 赵丽 张博 《中国环境科学》 EI CAS CSCD 北大核心 2016年第2期517-524,共8页
利用三维荧光光谱(EMMs),并结合平行因子分析法,研究了蠡湖水体中有色可溶性有机物(CDOM)的分布特征及其来源,并探讨了不同组分荧光强度与其他水质因子间的相关性.结果表明,蠡湖水体中CDOM主要由2个荧光组分组成,分别为类色氨酸荧光组分... 利用三维荧光光谱(EMMs),并结合平行因子分析法,研究了蠡湖水体中有色可溶性有机物(CDOM)的分布特征及其来源,并探讨了不同组分荧光强度与其他水质因子间的相关性.结果表明,蠡湖水体中CDOM主要由2个荧光组分组成,分别为类色氨酸荧光组分C1(225,280/335)和类腐殖质荧光组分C2(250,300/435),并且C1和C2对总荧光强度的贡献率分别75.70%和24.30%.空间上C1和C2荧光强度自东向西依次递减,呈现东蠡湖高于西蠡湖、沿岸区高于湖心区的趋势.荧光指数(FI)、生物源指数(BIX)和腐殖化指数(HIX)都显示蠡湖水体CDOM来源于自生微生物、藻类等新近自生源,整体呈现弱腐殖质特征.相关性分析表明,CDOM与N、P元素的迁移转化密切相关,并且对透明度有重要影响. 展开更多
关键词 蠡湖 有色可溶性有机物 三维荧光光谱 平行因子分析
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太湖CDOM紫外吸收特性及其分子量时空分布特征 被引量:20
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作者 黄昌春 李云梅 +2 位作者 孙德勇 乐成峰 王利珍 《中国环境科学》 EI CAS CSCD 北大核心 2009年第3期261-268,共8页
基于2006年8月16日、2007年3月28日对太湖梅梁湾15个样点和2007年11~12月对全湖61个样点的有色溶解性有机物(CDOM)吸收系数观测数据,对CDOM分子量相对大小的时空差异及其影响因素进行了分析.结果表明,梅梁湾地区主要富集的是高分子量CD... 基于2006年8月16日、2007年3月28日对太湖梅梁湾15个样点和2007年11~12月对全湖61个样点的有色溶解性有机物(CDOM)吸收系数观测数据,对CDOM分子量相对大小的时空差异及其影响因素进行了分析.结果表明,梅梁湾地区主要富集的是高分子量CDOM,而大太湖地区则较为复杂,北部地区主要是高分子量的CDOM占据主导地位;而在太湖东西部,主要是低分子量的CDOM;南太湖区域,高分子量的CDOM和低分子量的CDOM相对平衡.不同波长范围内CDOM吸收模型的斜率系数(S)值对CDOM的分子组成的敏感性具有一定的差异性,UVR最为敏感,其次是UV-A,再次为UV-B,UV-C最不敏感.梅梁湾CDOM主要影响因素是陆源,陆源影响的强度随季节的变化具有一定的差异,其中8月份最强,其次是3月份,最弱为11月份. 展开更多
关键词 太湖 有色溶解性有机物(cdom) 紫外吸收 时空分布
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长江中游湖泊CDOM光学特性及其空间分布对比 被引量:21
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作者 陈晓玲 陈莉琼 +2 位作者 于之锋 田礼乔 张伟 《湖泊科学》 EI CAS CSCD 北大核心 2009年第2期248-254,共7页
根据2007年秋季洪湖、东湖和梁子湖的调查结果,分析了长江中游3个典型湖泊CDOM光学特性及其空间分布差异.结果表明:(1)CDOM吸收系数在洪湖最高,梁子湖最低;(2)在洪湖,CDOM吸收系数受陆源影响较大,与悬浮泥沙浓度呈现较好正相关关系,而... 根据2007年秋季洪湖、东湖和梁子湖的调查结果,分析了长江中游3个典型湖泊CDOM光学特性及其空间分布差异.结果表明:(1)CDOM吸收系数在洪湖最高,梁子湖最低;(2)在洪湖,CDOM吸收系数受陆源影响较大,与悬浮泥沙浓度呈现较好正相关关系,而在梁子湖,CDOM吸收系数主要受到浮游植物降解贡献,与叶绿素浓度具有显著的正相关关系;(3)洪湖与东湖指数函数斜率S值变化不大;梁子湖CDOM吸收系数空间分布差异较大,指数函数斜率S值与400nm波段CDOM吸收系数ag(400)显著负相关.在建立梁子湖CDOM遥感反演模型时,应引入上述指数函数斜率S值与400nm波段CDOM吸收系数之间的线性函数,对CDOM吸收系数的指数模型进行优化. 展开更多
关键词 有色可溶性有机物质 洪湖 东湖 梁子湖 长江流域
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利用三维荧光光谱和吸收光谱研究雨水中CDOM的光学特性 被引量:14
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作者 程远月 郭卫东 +1 位作者 龙爱民 陈绍勇 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2010年第9期2413-2416,共4页
利用荧光激发-发射矩阵光谱(excitation-emission matrix spectroscopy,EEMs)技术并结合吸收光谱初步研究了2007年厦门梅雨季节期间雨水中有色溶解有机物(CDOM)的光学特性。结果表明,雨水CDOM的吸收光谱随波长呈指数衰减,代表雨水C... 利用荧光激发-发射矩阵光谱(excitation-emission matrix spectroscopy,EEMs)技术并结合吸收光谱初步研究了2007年厦门梅雨季节期间雨水中有色溶解有机物(CDOM)的光学特性。结果表明,雨水CDOM的吸收光谱随波长呈指数衰减,代表雨水CDOM相对含量的吸收系数a(300)范围在0.27~3.45 m-1,均值为1.08 m-1;且降雨初期CDOM含量高于降雨后期。这表明人类活动和当地的大气污染或空气质量对雨水中CDOM的贡献。雨水CDOM的EEMs光谱揭示出2类4个主要荧光峰(2个类腐殖质荧光A和C与2个类蛋白质荧光B和S)的存在。其中2个类腐殖质荧光A和C之间以及2个类蛋白质荧光B和S之间均存在一定的正相关性,说明其具有相同来源或存在某种内部联系。2个类腐殖质荧光与吸收系数a(300)之间的强正相关性,说明其控制吸收特性的基团可能与控制其荧光特性的基团具有相似性质。结果表明雨水CDOM高吸收和荧光特性在大气化学中的作用不容轻视,在受大气水体影响的太阳辐射的光谱衰减中可能起着潜在的重要作用。 展开更多
关键词 有色溶解有机物 荧光激发-发射矩阵光谱 吸收 雨水
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太湖梅梁湾水体悬浮颗粒物和CDOM的吸收特性 被引量:60
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作者 张运林 秦伯强 杨龙元 《生态学报》 CAS CSCD 北大核心 2006年第12期3969-3979,共11页
通过测定滤膜上悬浮颗粒物和过滤液中CDOM吸光度的方法计算得到太湖梅梁湾总颗粒物和CDOM的光谱吸收系数,并计算了各吸收组份的贡献份额以及吸收与PAR衰减的比值。总颗粒物的吸收系数从400nm到600nm大致呈下降趋势,到675nm附近由于叶... 通过测定滤膜上悬浮颗粒物和过滤液中CDOM吸光度的方法计算得到太湖梅梁湾总颗粒物和CDOM的光谱吸收系数,并计算了各吸收组份的贡献份额以及吸收与PAR衰减的比值。总颗粒物的吸收系数从400nm到600nm大致呈下降趋势,到675nm附近由于叶绿素a的特征吸收会出现明显峰值,峰值高低随叶绿素4浓度的变化而变化,aρ(440)在3.58-9.86m^-1间变化。非藻类颗粒物和CDOM的吸收随波长增加大致按指数规律下降,αd(440)和αg(440)的变化范围分别为2.23-7.07m^-1和1.06-1.70m^-1。非藻类颗粒物在400—700nm波段的指数函数斜率Sd的平均值为(10.91±0.62)μm^-1;CDOM在280—500nm波段指数函数斜率Sg的平均值为(15.52±0.49)μm^-1。浮游藻类的光谱吸收表现为在440、675nm附近存在两个明显的峰值,分别为(2.55±1.14)、(1.34±0.69)m^-1。ap(440)与TSS、OSS、ISS均存在显著性正相关,而ad(440)则只与TSS、ISS有显著性相关,aph(440)只与OSS、Chla有显著性相关。CDOM吸收系数与DOC浓度没有显著正相关,但与Chla存在显著幂函数关系,浮游藻类降解产物是水体中CDOM的重要来源之一。水体中物质吸收主要以颗粒物为主,对总吸收的贡献率在70%以上,而颗粒物中又以非藻类颗粒物占主导,一般超过加%,总吸收对漫射衰减的贡献也在40%以上。 展开更多
关键词 梅梁湾 非藻类颗粒物 浮游藻类 有色可溶性有机物 叶绿素A 吸收光谱
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