Compatibility of Fly Ash and Slag from Circulating Fluidized Bed Boiler for Concrete Beam

The applications of fly ash and slag from circulating fluidized bed boiler were studied as mineral admixture and aggregate for steel reinforced concrete beam.The results show that the concrete beam with fly ash and slag from circulating fluidized bed boilers has a similar ultimate cracking load coefficient as the ordinary cement concrete and a higher bending moment limit.Under the same load,it has a smaller deformation than the ordinary concrete.

Effects of particle type on the particle fluidization and distribution in a liquid–solid circulating fluidized bed boiler

A liquid-solid circulating fluidized bed boiler is designed and built for visualization research by applying the fluidized bed heat transfer and fouling prevention technology to the water side of the boiler. Four types of engineering plastic particles with different physical properties are selected as the solid working media. The effect of particle types on the fluidization and distribution of particles in the boiler is investigated under different feedwater flow rates and amount of added particles by using the charge couple device image measurement and acquisition system. The results show that all kinds of particles can't be normally fluidized and accumulate in the drum at low amount of added particles and feedwater flow rate. The particles with great density and low sphericity are more likely to accumulate. The average solid holdup in the riser tubes increases with the increase in feedwater flow rate and the amount of added particles. The non-uniform degree of particle distribution in the riser tubes generally decreases with the increase in feedwater flow rate and the amount of added particles. The particles with small density and settling velocity have high average solid holdup in the riser tubes under close sphericity. In generally,the smaller the density and settling velocity, the more uniform the particle distribution in the riser tubes.Three-dimensional diagrams of the non-uniform degree of particle distribution in the riser tubes of the boiler are established.

Model prediction of the operating behavior of a circulating fluidized bed boiler

An improved mathematical model for a circulating fluidized bed (CFB) boiler based on the model developed earlier by the authors was applied to simulate the operation of a 12 MW CFB boiler. The influences of the excess air ratio, primary air ratio, coal particle size distribution, coal properties (ash content and volatile content) and Ca/S ratio on the boiler operation were analyzed. The results showed that the model simulation may be applied to the optimum design and economic operation of the CFB boiler.

I MWth Test Facilities for Circulating Fluidized Bed Combustion

This paper presents the technical parameters and features of 1 MWth test facilities for circulating fluidized bed combustion (CFBC) at Thermal Power Research Institute (TPRI) of State Power Corporation (SP), introduces the test items that can be proceeded and trial combustion projects completed. The development status of CFBC technologies abroad and the level of China in this field are also introduced in the paper.

Hardening Properties of Foamed Concrete with Circulating Fluidized Bed Boiler Ash, Blast Furnace Slag, and Desulfurization Gypsum as the Binder

Recently, a large amount of circulating fluidized bed boiler ash (CFBA) and desulfurization gypsum (DSG) has been produced, and it is essential to develop technology to utilize them. These materials have CaO and SO3, which are considered to be a stimulant for blast furnace slag (BFS). This study presents an experimental investigation of the compressive strength and heavy metal ions immobilization properties of cement-free materials comprising CFBA, BFS, and DSG. The feasibility of manufacturing foamed concrete using these materials was examined, and field test of foamed concrete was conducted. Experimentally, the flow, compressive strength, and heavy metal ions concentration were evaluated via inductively coupled plasma atomic emission spectroscopy (ICP-AES) of the paste and foamed concrete. The experimental investigation revealed the self-healing hardening ability of fluidized bed boiler ash. In addition, the compressive strength was increased with the increasing replacement rates of BFS and DSG in the CFBA paste, and the compressive strength of 14.6 - 17.2 MPa was recorded over 28 days of curing. From the result obtained, the feasibility of manufacturing foamed concrete with a foam volume of 120 L, incorporating the aforementioned materials, is confirmed. It was also found that after 28 days of age, a 7.9-MPa compressive strength of the foamed concrete was attained, and heavy metal ions elution in this foamed concrete was also significantly reduced. Therefore, CFBA, BFS, and DSG could be used as a binder for the foamed concrete.

Emissions of SO_2, NO and N_2O in a circulating fluidized bed combustor during co-firing coal and biomass

This paper presents the experimental investigations of the emissions of SO2, NO and N20 in a bench scale circulating fluidized bed combustor for coal combustion and co-firing coal and biomass. The thermal capacity of the combustor is 30 kW. The setup is electrically heated during startup. The infuence of the excess air, the degree of the air staging, the biomass share and the feeding position of the fuels on the emissions of SO2, NO and N2O were studied. The results showed that an increase in the biomass shares resulted in an increase of the CO concentration in the flue gas, probably due to the high volatile content of the biomass. In co-firing, the emission of SO2 increased with increasing biomass share slightly, however, non-linear increase relationship between SO2 emission and fuel sulfur content was observed. Air staging significantly decreased the NO emission without raising the SO2 level. Although the change of the fuel feeding position from riser to downer resulted in a decrease in the NO emission level, no obvious change was observed for the SO2 level. Taking the coal feeding position R as a reference, the relative NO emission could significantly decrease during co-firing coal and biomass when feeding fuel at position D and keeping the first stage stoichiometry greater than 0.95. The possible mechanisms of the sulfur and nitrogen chemistry at these conditions were discussed and the ways of simultaneous reduction of SO2, NO and N2O were proposed.

Hydrothermal synthesis of zeolitic material from circulating fluidized bed combustion fly ash for the highly efficient removal of lead from aqueous solution

The utilization of coal fly ash derived from circulating fluidized bed combustion(CFBFA)still faces great challenges because of its unique characteristics.In this study,a zeolitic material with Na-P1 zeolite as the main phase was successfully synthesized via a hydrothermal method by using CFBFA as the raw material.The effects of hydrothermal temperature,time,and added CTAB amount on the characterizations of synthesized materials were investigated by XRD,SEM,and XPS.The properties of the optimal zeolitic material and its adsorption performance for Pb^(2+)in aqueous solution were evaluated.The influences of pH,initial concentration,dosage,and temperature on Pb^(2+)adsorption were also examined.Results revealed the following optimal parameters for the synthesis of zeolitic material:NaOH concentration of 2 mol·L^(-1),solid-to-liquid ratio of 1:10 g·ml^(-1),hydrothermal temperature of 110℃,hydrothermal time of 9 h,and CTAB amount of 1 g(per 100 ml solution).The adsorption capacities of the zeolitic material reached 329.67,424.69,and 542.22 mg·g^(-1) when the pH values of aqueous solution were 5,6,and 7,respectively.The Pb^(2+)removal efficiency can reach more than 99%in aqueous solution with the initial concentrations of 100-300 mg·L^(-1) under pH 6 and suitable adsorbent dosage.The adsorption and kinetics of Pb^(2+)on the zeolitic material can be described by Langmuir isotherm and pseudo-second-order kinetic models,respectively.The ion exchange between Pb^(2+)and Na^(+)and chemisorption are the main adsorption mechanism.All these findings imply that the synthesis of low-cost adsorbent for Pb^(2+)removal from weak acid and neutral aqueous solution provides a highly effective method to utilize CFBFA.

Combustion characteristics of low-quality lignite for different bed material sphericities in a circulating fluidized bed boiler:A numerical study

This study delves into the combustion behavior of various lignite types within a circulating fluidized bed boiler(CFBB),with a primary focus on the impact of different bed material sphericity ratios(0.5,0.7,and 0.9).Utilizing bed material with a sphericity ratio of 0.9 sourced from theÇan power plant and verified through experimentation,the research reveals several key findings.Notably,furnace temperatures tended to rise with higher sphericity ratios,albeit with variations between lignite types,particularly highlighting the complexity of this relationship in the case of GLI-Tunçbilek lignite.Pressure levels in the combustion chamber remained consistent across different sphericity ratios,indicating minimal influence on pressure dynamics.Improved combustion efficiency,especially at the bottom of the boiler,was observed at lower sphericity levels(0.5 and 0.7)forÇan lignite,as reflected in CO_(2) mole fractions.While NO_(x) emissions generally decreased with lower sphericity,the sensitivity to sphericity varied by lignite type,with Ilgın lignite showcasing low NO_(x) but high SO_(2) emissions,underscoring the intricate interplay between lignite properties,sphericity,and emissions.Overall,this study advances our understanding of CFBB combustion dynamics,offering insights valuable for optimizing performance and emissions control,particularly in lignite-based power.

基于TF-NGO算法的CFB锅炉床温系统建模研究

床温是循环流化床(CFB)锅炉重要的运行参数之一。针对床温耦合性强、干扰因素多、控制复杂的问题,亟需建立床温的数学模型,以实现床温控制,从而保证CFB锅炉安全、平稳地运行。为此,首先引入了混沌映射、切线飞行(TF)和柯西变异策略改进北方苍鹰优化(NGO)算法,并用实际工况的系统模型测试TF-NGO算法。测试结果表明,TF-NGO算法拥有更快的收敛速度和更高的寻优精度。其次,采集并预处理山西某电厂350 MW超临界CFB锅炉的现场运行数据。最后,采用TF-NGO算法对所建模型的参数进行辨识,并用实际工况数据进行模型验证。辨识和验证结果表明,由TF-NGO算法辨识的床温模型与实际输出拟合度高,能有效反映床温的动态特性,证明所建模型的有效性。该研究为后续对350 MW超临界CFB锅炉床温的优化控制研究奠定了基础。

Development of a supercritical and an ultra-supercritical circulating fluidized bed boiler

The supercritical circulating fluidized bed(CFB)boiler,which combines the advantages of CFB combustion with low cost emission control and supercritical steam cycle with high efficiency of coal energy,is believed to be the future of CFB combustion technology.It is also of greatest importance for low rank coal utilization in China.Different from the supercritical pulverized coal boiler that has been developed more than 50 years,the supercritical CFB boiler is still a new one which requires further investigation.Without any precedentor engineering reference,Chinese researchers have con ducted fundamental research,development,design of the supercritical CFB boilers independently.The design theory and key technology for supercritical CFB boiler were proposed.Key components and novel structures were invented.The first 600 MWe supercritical CFB boiler and its auxiliaries were successfully developed and demonstrated in Baima Power Plant,Shenhua Group as well as the simulator,control technology,installation technology,commissioning technology,system integration and operation technology.Compared with the 460 MWe supercritical CFB in Poland,developed in the same period and the only other supercritical one of commercial running in the word beside Baima,the 600 MWe one in Baima has a better performance.Besides,supercritical CFB boilers of 350 MWe have been developed and widely commercialized in China.In this paper,the updated progress of 660 MWe ultra-supercritical CFB boilers under development is introduced.

Comparison of Fully 3-D,Simplified 3-D and 2-D Numerical Simulations on a Circulating Fluidized Bed Boiler

Based on the fully three-dimensional(3-D)and two-dimensional(2-D)comprehensive CFD(Computational Fluid Dynamics)combustion models for a circulating fluidized bed boiler,a simplified 3-D computational domain considering the corrections of furnace side wall openings is proposed.It aims to compensate for the deficiencies of the large amount of computation in the fully 3-D model and improve the air and gas flow treatments at the openings in the simplified 2-D model.Three different computational domains,named as the fully 3-D model,simplified 3-D model and 2-D model,were implemented to perform a comparative CFD analysis in an ultra-supercritical circulating fluidized bed boiler including the hydrodynamics,penetration depth of secondary air,temperature and species distribution.The simulation results computed by the simplified3-D model yield better agreement with the fully 3-D simulation results than those of the 2-D model.The simplified 3-D model is recommended as an alternative computational domain for the conventional 2-D model in the numerical simulation of large-scale circulating fluidized bed boiler.

烟气再循环对350 MW CFB锅炉深调运行特性影响

为解决超临界CFB锅炉超低负荷时流化安全性及NO_(x)超低排放,引入烟气再循环技术,以某电厂超临界350 MW CFB锅炉为研究对象,搭建了循环半干法脱硫后烟气的再循环辅助调峰系统,基于运行实测数据,研究该锅炉在30%~60%负荷率下烟气再循环对平均床温、分离器入口温度、排烟温度、炉膛出口烟气NO_(x)、CO质量浓度、飞灰及底渣可燃物含量、汽水参数等运行参数的影响,试验结果表明:烟气再循环协同下,30%~60%负荷SNCR脱硝后NO_(x)最终排放小于50 mg/m^(3),30%负荷实现锅炉原始NO_(x)超低排放;床温降低15~22℃,炉膛出口烟温提高10~13℃,主再热汽温在558℃以上;随锅炉负荷降低,飞灰及底渣含碳量升高,CO质量浓度未见大幅增加;40%负荷炉膛二次风SNCR脱硝NO_(x)降幅约15 mg/m^(3);负荷上升/下降变化最小速率1.23%Pe;30%负荷及以上保持干态运行,水冷壁壁温最大偏差55℃,屏过及屏再最大壁温差分别55、47℃,均未出现壁温超温。

Experimental Study on an On-Line Measurement of High Temperature Circulating Ash Flux in a Circulating Fluidized Bed Boiler

A new Kind of measuring method that may be used to measure high temperature circulating solid particles flux in a circulating fluidized bed boiler is studied in this paper. The measuring method is founded on the principle of thermal equilibrium. A series of cold tests and hot tests were carried to optimize the structure and collocation of water-cooling tubes and showed that the method had the advantage of simple, accurate, reliable and good applicability for on-line "usage in a circulating fluidized bed boiler.

循环流化床锅炉(CFB)系统流程模拟

以某石化项目450 t/h超高压循环流化床锅炉系统为对象,采用Thermoflex软件建模并对其进行变工况分析,通过与锅炉厂提供的实际数据进行对比,验证了该流程模拟的准确性。利用该模型进行了不同煤种工况对系统的影响因素分析,研究结果可为该锅炉系统设计和设备选型提供理论依据,对该项目动力站实际生产运行提供指导。

探讨CFB锅炉结焦事故原因和应对措施

循环流化床锅炉在实际生产中,因锅炉煤炭燃烧、物料流化不良、风帽大面积损坏、操作控制不当等各种原因,导致锅炉出现结焦,严重影响设备安稳运行。通过对锅炉结焦原因和案例分析,进行技术改造和参数优化,加强日常管理,避免了锅炉结焦事故,确保了装置长周期运行。

600 MW CFB锅炉汽冷式旋风分离器受热面管失效分析及优化措施

基于超临界循环流化床(CFB)锅炉汽冷式旋风分离器受热面管发生的1次失效,为防止类似失效的再次发生,对失效进行试验分析。超低排放选择性非催化还原(SNCR)脱硝系统对耐火材料和受热面管有腐蚀,在高温下分解的产物与受热面管金属发生反应,引起受热面的有效壁厚减薄,最终受热面管因无法承受内部介质的压力而发生失效。结合运行状况及失效原因分析,对耐火材料进行固定方式优化和材料优化,以及提高防磨防爆检查力度、优化雾化空气压力等优化措施,有效提升了运行的可靠性,在汽冷式旋风分离器检修管理方面有推广意义。

EXPERIMENTAL RESEARCH OF FLOW STRUCTURE IN A GAS-SOLID CIRCULATING FLUIDIZED BED RISER BY PIV

Particle Imaging Velocimetry （PIV） techniques were applied to investigate the particle motion and cluster properties in a gas-solid two-phase flow in a circulating fluidized bed riser. Visual images and micro-structure of various clusters were captured. After the boundary of clusters was determined by the gray level threshold method, clusters were classified by the distance between particles and the shape and position of clusters. In addition, the process of clusters forming and breaking up was described, and the sizes of clusters were also obtained. With the Minimum Quadric Difference （MQD） cross-correlation algorithm suitable for high-density particles, the axial velocities of the particles were obtained in the dilute phase section. The features of particle motion were revealed by investigating statistically the magnitude and distribution of particle axial velocity in the radial direction. At most radial cross-sections, there exists a parabola-shaped distribution of upward axial velocity of particles, namely, the magnitude of axial velocity in the core region is higher than that near the wall region of the riser.

Modeling of Sulfur Retention in Circulating Fluidized Bed Coal Combustors

A comprehensive model for predicting the sulfur retention performance in circulating fluidized bed combustors was developed which involves the different residence times, the wide particle size distribution and the different forms of sulfur in the coal. In addition, the reductive decomposition of CaSO 4 is highlighted. The simulation results from the model show that the sulfur contents, the bed temperature, the sorbent particle size distribution and the sorbent activity or the maximum conversion rate can significantly influence the sulfur retention performance in circulating fluidized bed (CFB) combustors.

Progress of circulating fluidized bed combustion technology in China:a review

Circulating fluidized bed(CFB)technology plays an important role in the utilization of low-grade coal in China.This article reviews CFB combustion technology development in China and summarizes recent achievements.Since 1990 Chinese engineers and researchers have been undertaking work to improve CFB boiler technology.A completely novel CFB boiler design theory was developed and used in the domestic manufacturing of CFB boilers with various capacities.China is the largest supplier and customer of CFB boilers in the world due to the widespread use of CFB boilers.In 2007,the lower energy consumption CFB technology was successfully developed by re-specifying the fluidization state,which reduced the power consumption of forced fans and solved the potential erosion problems on the water wall.Afterwards,in order to increase the electric power generation efficiency,the supercritical CFB(SCCFB)boiler was developed and the first 600 MW SCCFB boiler was demonstrated and put into commercial operation in 2013.The success of the technology is evident with over 80 SCCFB boilers on order with capacities of 350 MW to 660 MW.Chinese scientists and engineers are also developing technology to lower the emissions of CFB combustion to meet the requirements of China’s strict emission regulations.This emission reduction is through high-efficiency desulfurization by limestone injection into the furnace and low NOx combustion,ultra-low emission of SO2 and NOx in the furnace can be realized by improving the bed quality and increasing the solid circulation rate.There is currently further research and design development being undertaken to develop a 660 MW ultra-supercritical CFB(USCCFB)boiler.The new boiler is expected to be operational before 2020 resulting in higher efficiency and lower energy consumption and emissions.