In this work, four empirical models of statistical thickness, namely the models of Harkins and Jura, Hasley, Carbon Black and Jaroniec, were compared in order to determine the textural properties (external surface and...In this work, four empirical models of statistical thickness, namely the models of Harkins and Jura, Hasley, Carbon Black and Jaroniec, were compared in order to determine the textural properties (external surface and surface of micropores) of a clay concrete without molasses and clay concretes stabilized with 8%, 12% and 16% molasses. The results obtained show that Hasley’s model can be used to obtain the external surfaces. However, it does not allow the surface of the micropores to be obtained, and is not suitable for the case of simple clay concrete (without molasses) and for clay concretes stabilized with molasses. The Carbon Black, Jaroniec and Harkins and Jura models can be used for clay concrete and stabilized clay concrete. However, the Carbon Black model is the most relevant for clay concrete and the Harkins and Jura model is for molasses-stabilized clay concrete. These last two models augur well for future research.展开更多
This work deals with phosphate ions removal in aqueous solution by adsorption carried out using two clays, both in activated form. One, non-swelling clay, rich in kaolinite, is associated with illite and quartz. The o...This work deals with phosphate ions removal in aqueous solution by adsorption carried out using two clays, both in activated form. One, non-swelling clay, rich in kaolinite, is associated with illite and quartz. The other, swelling, richer in montmorillonite, is associated with kaolinite, illite and quartz. Seven factors including these two clays were taken into account in a series of experimental designs in order to model and optimize the acidic activation process favoring a better phosphate removal. In addition to the choice of clay nature, the study was also interested in the identification of the mineral acid, between hydrochloric acid and sulfuric acid, which would promote this acidic activation. Response Surface Methodology (RSM) was used for this purpose by sequentially applying Plackett and Burman Design and Full Factorial Design (FD) for screening. Then, a central composite design (CCD) was used for modeling the activation process. A mathematical surface model has been successfully established. Thus, the best acidic activation conditions were obtained by activating the montmorillonite clay with a 2N sulfuric acid solution, in an acid/clay mass ratio of 7.5 at 100°C for 16H. The phosphate removal maximum rate obtained was estimated at 89.32% ± 0.86%.展开更多
A shape hardening function is developed that improves the predictive capabilities of the generalized bounding surface model for cohesive soils, especially when applied to overconsolidated specimens. This improvement i...A shape hardening function is developed that improves the predictive capabilities of the generalized bounding surface model for cohesive soils, especially when applied to overconsolidated specimens. This improvement is realized without any changes to the simple elliptical shape of the bounding surface, and actually reduces the number of parameters associated with the model by one.展开更多
Widely distributed in natural deposits,the overconsolidated(OC)clays have attracted extensive experimental investigations on their mechanical behaviors,especially in the 1960s and 1970s.Based on these results,numerous...Widely distributed in natural deposits,the overconsolidated(OC)clays have attracted extensive experimental investigations on their mechanical behaviors,especially in the 1960s and 1970s.Based on these results,numerous constitutive models have also been established.These models generally fall into two categories:one based on the classical plasticity theory and the other the bounding surface(BS)plasticity theory,with the latter being more popular and successful.The BS concept and the subloading surface(SS)concept are the two major BS plasticity theories.The features of these two concepts and the representative models based on them are introduced,respectively.The unified hardening(UH)model for OC clays is also based on the BS plasticity theory but distinguishes itself from other models by the integration of the reference yield surface,unified hardening parameter,potential failure stress ratio,arid transformed stress tensor.Modification is made to the Hvorslev envelop employed in the UH model to improve its capability of describing the behaviors of clays with extremely high overconsolidation ratio in this paper.The comparison among the BS model,SS model,and UH model is performed.Evidence shows that all these three models can characterize the fundamental behaviors of OC clays,such as the stress dilatancy,strain softening and attainment of the critical state.The UH model with the revised Hvorslev envelop has the fewest parameters which are identical to those of the modified Cam-Clay model.展开更多
The clay minerals in the surface sediments from 354 stations have been analyzed qualita-tively and semiquantitatively. The obtained data are dealt mathematically. According to thecalculated results, the distribution l...The clay minerals in the surface sediments from 354 stations have been analyzed qualita-tively and semiquantitatively. The obtained data are dealt mathematically. According to thecalculated results, the distribution laws and the trends of content changes of clay mineralsare discussed. The studied area is divided into four main provinces of sediments with differ-ent sources. Finally the author approached the laws of the migration and dispersal of thefine-grained matter carried into the seas by the Huanghe River, the Changjiang River, theZhujiang River and the Philippine Archipelagoes, and set up the transport model of the fine-grained matter in the China Sea and adjacent seas.展开更多
文摘In this work, four empirical models of statistical thickness, namely the models of Harkins and Jura, Hasley, Carbon Black and Jaroniec, were compared in order to determine the textural properties (external surface and surface of micropores) of a clay concrete without molasses and clay concretes stabilized with 8%, 12% and 16% molasses. The results obtained show that Hasley’s model can be used to obtain the external surfaces. However, it does not allow the surface of the micropores to be obtained, and is not suitable for the case of simple clay concrete (without molasses) and for clay concretes stabilized with molasses. The Carbon Black, Jaroniec and Harkins and Jura models can be used for clay concrete and stabilized clay concrete. However, the Carbon Black model is the most relevant for clay concrete and the Harkins and Jura model is for molasses-stabilized clay concrete. These last two models augur well for future research.
文摘This work deals with phosphate ions removal in aqueous solution by adsorption carried out using two clays, both in activated form. One, non-swelling clay, rich in kaolinite, is associated with illite and quartz. The other, swelling, richer in montmorillonite, is associated with kaolinite, illite and quartz. Seven factors including these two clays were taken into account in a series of experimental designs in order to model and optimize the acidic activation process favoring a better phosphate removal. In addition to the choice of clay nature, the study was also interested in the identification of the mineral acid, between hydrochloric acid and sulfuric acid, which would promote this acidic activation. Response Surface Methodology (RSM) was used for this purpose by sequentially applying Plackett and Burman Design and Full Factorial Design (FD) for screening. Then, a central composite design (CCD) was used for modeling the activation process. A mathematical surface model has been successfully established. Thus, the best acidic activation conditions were obtained by activating the montmorillonite clay with a 2N sulfuric acid solution, in an acid/clay mass ratio of 7.5 at 100°C for 16H. The phosphate removal maximum rate obtained was estimated at 89.32% ± 0.86%.
基金supported by the Fulbright Colombia-Colciencias Scholarship and Universidad Militar Nueva Granada
文摘A shape hardening function is developed that improves the predictive capabilities of the generalized bounding surface model for cohesive soils, especially when applied to overconsolidated specimens. This improvement is realized without any changes to the simple elliptical shape of the bounding surface, and actually reduces the number of parameters associated with the model by one.
基金Project supported by National Natural Science Foundation of China for Young Scholars under Grant No.11402260。
文摘Widely distributed in natural deposits,the overconsolidated(OC)clays have attracted extensive experimental investigations on their mechanical behaviors,especially in the 1960s and 1970s.Based on these results,numerous constitutive models have also been established.These models generally fall into two categories:one based on the classical plasticity theory and the other the bounding surface(BS)plasticity theory,with the latter being more popular and successful.The BS concept and the subloading surface(SS)concept are the two major BS plasticity theories.The features of these two concepts and the representative models based on them are introduced,respectively.The unified hardening(UH)model for OC clays is also based on the BS plasticity theory but distinguishes itself from other models by the integration of the reference yield surface,unified hardening parameter,potential failure stress ratio,arid transformed stress tensor.Modification is made to the Hvorslev envelop employed in the UH model to improve its capability of describing the behaviors of clays with extremely high overconsolidation ratio in this paper.The comparison among the BS model,SS model,and UH model is performed.Evidence shows that all these three models can characterize the fundamental behaviors of OC clays,such as the stress dilatancy,strain softening and attainment of the critical state.The UH model with the revised Hvorslev envelop has the fewest parameters which are identical to those of the modified Cam-Clay model.
文摘The clay minerals in the surface sediments from 354 stations have been analyzed qualita-tively and semiquantitatively. The obtained data are dealt mathematically. According to thecalculated results, the distribution laws and the trends of content changes of clay mineralsare discussed. The studied area is divided into four main provinces of sediments with differ-ent sources. Finally the author approached the laws of the migration and dispersal of thefine-grained matter carried into the seas by the Huanghe River, the Changjiang River, theZhujiang River and the Philippine Archipelagoes, and set up the transport model of the fine-grained matter in the China Sea and adjacent seas.