The Clegg Pitzer semi empirical thermodynamic equations were applied to the calculation of 1 1 type potassium salt aqueous solution.At 25 ℃ and over the whole concentration range,from 8 single electrolyte solut...The Clegg Pitzer semi empirical thermodynamic equations were applied to the calculation of 1 1 type potassium salt aqueous solution.At 25 ℃ and over the whole concentration range,from 8 single electrolyte solutions (KF,KCl,KBr,KI,KOH,KNO 3,KClO 3,KBrO 3),the parameters W H 2O,KX ,U H 2O,KX ,and B KX were calculated,and then 8 solubility products were calculated.From 9 bi salt saturated aqueous solutions,the parameters W KXY ,U XY ,and Q H 2O,KXY were regressed,the F test was passed.展开更多
Soil strength is an important quality of agricultural soils prone to traffic. Surface hardness (SH) measured by the Clegg Impact Tester (CIT) was evaluated as an indicator for assessing soil strength. Proctor tests we...Soil strength is an important quality of agricultural soils prone to traffic. Surface hardness (SH) measured by the Clegg Impact Tester (CIT) was evaluated as an indicator for assessing soil strength. Proctor tests were performed on a diverse range of soils to examine the relationships between bulk density (BD), penetration resistance (PR), SH and water content. All three indices showed typical response curves with increasing water content, with notable differences among the soils. Maximum dry bulk density (MDBD), peak penetration resistance (PPR) and peak surface hardness (PSH) showed values of 1.98 Mg m-3, 8.2 MPa and 248 Cmax for Piarco, River Estate and Piarco respectively. Corresponding critical moisture contents (CMC) were much greater for MDBD compared to PPR and PSH. SH showed a significant positive correlation with PR, but not BD. Further divulgence into the relationships between SH and other soil properties as well as crop response will facilitate greater use of the CIT.展开更多
A comprehensive review of recent advances in study on thermodynamic models for real electrolyte solutions is presented. The differences between primitive and non-primitive electrolyte models are demonstrated. Some new...A comprehensive review of recent advances in study on thermodynamic models for real electrolyte solutions is presented. The differences between primitive and non-primitive electrolyte models are demonstrated. Some new thermodynamic models for electrolyte solutions based on the mean spherical approximation and perturbation theory are introduced. An extended scaled-particle theory and modified CleggPitzer equation are presented for physical and chemical absorption processes with mixed solvents, respectively. A pseudo one-component two-Yukawa equation of state is used for the aqueous two-phase extraction process in charged colloidal systems.展开更多
文摘The Clegg Pitzer semi empirical thermodynamic equations were applied to the calculation of 1 1 type potassium salt aqueous solution.At 25 ℃ and over the whole concentration range,from 8 single electrolyte solutions (KF,KCl,KBr,KI,KOH,KNO 3,KClO 3,KBrO 3),the parameters W H 2O,KX ,U H 2O,KX ,and B KX were calculated,and then 8 solubility products were calculated.From 9 bi salt saturated aqueous solutions,the parameters W KXY ,U XY ,and Q H 2O,KXY were regressed,the F test was passed.
文摘Soil strength is an important quality of agricultural soils prone to traffic. Surface hardness (SH) measured by the Clegg Impact Tester (CIT) was evaluated as an indicator for assessing soil strength. Proctor tests were performed on a diverse range of soils to examine the relationships between bulk density (BD), penetration resistance (PR), SH and water content. All three indices showed typical response curves with increasing water content, with notable differences among the soils. Maximum dry bulk density (MDBD), peak penetration resistance (PPR) and peak surface hardness (PSH) showed values of 1.98 Mg m-3, 8.2 MPa and 248 Cmax for Piarco, River Estate and Piarco respectively. Corresponding critical moisture contents (CMC) were much greater for MDBD compared to PPR and PSH. SH showed a significant positive correlation with PR, but not BD. Further divulgence into the relationships between SH and other soil properties as well as crop response will facilitate greater use of the CIT.
基金Supported by the Fundamental Research Fund of Tsinghua Universitof China (No. JZ 2002003)
文摘A comprehensive review of recent advances in study on thermodynamic models for real electrolyte solutions is presented. The differences between primitive and non-primitive electrolyte models are demonstrated. Some new thermodynamic models for electrolyte solutions based on the mean spherical approximation and perturbation theory are introduced. An extended scaled-particle theory and modified CleggPitzer equation are presented for physical and chemical absorption processes with mixed solvents, respectively. A pseudo one-component two-Yukawa equation of state is used for the aqueous two-phase extraction process in charged colloidal systems.
