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纳米晶块体Co-45Ni-10Cr合金在H 2SO 4溶液中腐蚀电化学行为 被引量:3
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作者 王晴 范馨月 +5 位作者 张昊鑫 韩漾 曹中秋 张轲 王艳 辛士刚 《有色金属工程》 CAS 北大核心 2024年第1期1-8,共8页
利用粉末冶金工艺制备常规尺寸(CS)Co-45Ni-10Cr合金粉末,再利用机械合金化法制备纳米尺寸(NS)Co-45Ni-10Cr合金粉末,采用真空热压技术得到相应的块体Co-45Ni-10Cr合金。腐蚀介质选择不同浓度的H_(2)SO_(4)溶液,利用电化学工作站分别测... 利用粉末冶金工艺制备常规尺寸(CS)Co-45Ni-10Cr合金粉末,再利用机械合金化法制备纳米尺寸(NS)Co-45Ni-10Cr合金粉末,采用真空热压技术得到相应的块体Co-45Ni-10Cr合金。腐蚀介质选择不同浓度的H_(2)SO_(4)溶液,利用电化学工作站分别测试两种Co-45Ni-10Cr(CS和NS)块体合金的自腐蚀电位、动电位极化曲线和交流阻抗谱,对比研究了两者腐蚀行为以及晶粒细化对于它们腐蚀行为产生的影响。结果表明:两种Co-45Ni-10Cr(CS和NS)块体合金的自腐蚀电位均随着腐蚀介质H_(2)SO_(4)溶液浓度增大而发生负移,腐蚀倾向逐渐加剧,同时腐蚀电流密度均增大,电荷传递电阻相应减小,因此腐蚀速度加快。此外,两种Co-45Ni-10Cr(CS和NS)块体合金的交流阻抗谱均为单一容抗弧,说明腐蚀速率均由电化学过程控制。与Co-45Ni-10Cr(CS)合金相比,Co-45Ni-10Cr(NS)合金的腐蚀速率减慢,表明纳米化后Co-45Ni-10Cr块体合金的耐腐蚀性能有所提高。 展开更多
关键词 腐蚀电化学 块体纳米晶 co-45ni-10cr合金 机械合金化 热压
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Brazeability evaluation of Ti-Zr-Cu-Ni-Co-Mo filler for vacuum brazing TiAl-based alloy 被引量:10
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作者 Li LI Xiao-qiang LI +2 位作者 Ke HU Bo-lin HE Hua MAN 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2019年第4期754-763,共10页
Ti-47Al-2Nb-2Cr-0.15B(mole fraction,%)alloy was vacuum brazed with amorphous and crystalline Ti.25Zr-12.5Cu-12.5Ni-3.0Co-2.0Mo(mass fraction,%)filler alloys,and the melting,spreading and gap filling behaviors of the a... Ti-47Al-2Nb-2Cr-0.15B(mole fraction,%)alloy was vacuum brazed with amorphous and crystalline Ti.25Zr-12.5Cu-12.5Ni-3.0Co-2.0Mo(mass fraction,%)filler alloys,and the melting,spreading and gap filling behaviors of the amorphous and crystalline filler alloys as well as the joints brazed with them were investigated in details.Results showed that the amorphous filler alloy possessed narrower melting temperature interval,lower liquidus temperature and melting active energy compared with the crystalline filler alloy,and it also exhibited better brazeability on the surface of the Ti.47Al.2Nb.2Cr.0.15B alloy.The TiAl joints brazed with crystalline and amorphous filler alloys were composed of two interfacial reaction layers and a central brazed layer.Under the same conditions,the tensile strength of the joint brazed with the amorphous filler alloy was always higher than that with the crystalline filler alloy.The maxmium tensile strength of the joint brazed at 1273 K with the amorphous filler alloy reached 254 MPa. 展开更多
关键词 vacuum brazing Ti.47Al.2Nb.2cr.0.15B alloy amorphous Ti-25Zr-12.5Cu-12.5ni-3.0co-2.0Mo filler alloy tensile strength interfacial microstructure brazeability
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