期刊文献+
共找到1篇文章
< 1 >
每页显示 20 50 100
Component regulation in novel La-Co-O-C composite catalyst for boosted redox reactions and enhanced thermal stability in methane combustion 被引量:1
1
作者 Peiqi Chu Saifei Wang +4 位作者 Yi Zhang Shiguang Zhao Yahan Wang Jiguang Deng Erhong Duan 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2023年第4期459-469,共11页
A novel La-Co-O-C (LC-C) composites were prepared via a facile co-hydrothermal route with oxides and glycerol and further optimized for methane catalytic activity and thermal stability via component regulation.It was ... A novel La-Co-O-C (LC-C) composites were prepared via a facile co-hydrothermal route with oxides and glycerol and further optimized for methane catalytic activity and thermal stability via component regulation.It was demonstrated that Co3O_(4)phase was the main component in regulation.The combined results of X-ray photoelectron spectroscopy (XPS),temperature-programmed desorption of oxygen (O_(2)-TPD),temperature-programmed reduction of hydrogen (H_(2)-TPR),temperature-programmed desorption of ammonia/carbon dioxide (NH_(3)/CO_(2)-TPD) revealed that component regulation led to more oxygen vacancies and exposure of surface Co_(2)+,lower surface basicity and optimized acidity,which were beneficial for adsorption of active oxygen species and activation of methane molecules,resulting in the excellent catalytic oxidation performance.Especially,the (3.5)LC-C (3.5 is Co-to-La molar ratio) showed the optimum activity and the T50and T90(the temperature at which the CH_(4)conversion rate was 50%and 90%,respectively) were 318 and 367℃,respectively.Using theoretical calculations and in situ diffuse reflection infrared Fourier transform spectroscopy characterization,it was also found that the catalytic mechanism changes from the “Rideal-Eley” mechanism to the “Two-term” mechanism depending on the temperature windows in which the reaction takes place.Besides,the use of the “Flynn-Wall-Ozawa” model in thermoanalytical kinetics revealed that component regulation simultaneously optimized the decomposition activation energy,further expanding the application scope of carboncontaining composites. 展开更多
关键词 Methane combustion Composite oxides co3o_(4) Component regulation
原文传递
上一页 1 下一页 到第
使用帮助 返回顶部