The title complex CoCl(ieaa)(C10H7-ieai)(C10H7NH2), C32H32ClCoN4O7, Mr= 679.00; (ieaa- and C10H7-ieai- are the anions of isonitrosoethylacetoacetate and its N-a- naphthylamine derivative of Schiff base, respectively, ...The title complex CoCl(ieaa)(C10H7-ieai)(C10H7NH2), C32H32ClCoN4O7, Mr= 679.00; (ieaa- and C10H7-ieai- are the anions of isonitrosoethylacetoacetate and its N-a- naphthylamine derivative of Schiff base, respectively, C10H7NH2 is a-naphthylamine), crystallizes in the monoclinic system, space group P21/n with a=11.846(2), b=23.912(5), c=12.783(3)? b=116.54(3), V=3239(1)?, Dc=1.392g/cm3, F(000)=1408, Mr=679.00, m(MoKa)=0.665mm-1, Z=4, final R=0.0584 and wR=0.1388 for 4177 observed reflections (I ≥ 2s(I)). A nitrogen atom of the ieaa- ligand and two nitrogen atoms of the C10H7-ieai- ligand define one of the triangular faces in the distorted octahedral geometry about the cobalt atom. The title complex contains isonitroso-b-ketoimine.展开更多
文摘The title complex CoCl(ieaa)(C10H7-ieai)(C10H7NH2), C32H32ClCoN4O7, Mr= 679.00; (ieaa- and C10H7-ieai- are the anions of isonitrosoethylacetoacetate and its N-a- naphthylamine derivative of Schiff base, respectively, C10H7NH2 is a-naphthylamine), crystallizes in the monoclinic system, space group P21/n with a=11.846(2), b=23.912(5), c=12.783(3)? b=116.54(3), V=3239(1)?, Dc=1.392g/cm3, F(000)=1408, Mr=679.00, m(MoKa)=0.665mm-1, Z=4, final R=0.0584 and wR=0.1388 for 4177 observed reflections (I ≥ 2s(I)). A nitrogen atom of the ieaa- ligand and two nitrogen atoms of the C10H7-ieai- ligand define one of the triangular faces in the distorted octahedral geometry about the cobalt atom. The title complex contains isonitroso-b-ketoimine.
