The electrokinetic characteristics and coagulation behaviors of polyaluminum silicate chloride (PASiC) and polyaluminum chloride (PAC) were studied and compared by streaming current (SC) measurement and jar test metho...The electrokinetic characteristics and coagulation behaviors of polyaluminum silicate chloride (PASiC) and polyaluminum chloride (PAC) were studied and compared by streaming current (SC) measurement and jar test method. The experimental results showed that the interaction between polysilicic acid characterized negative charge and hydrolyzed aluminum species result in a decrease of the charge neutralizing ability of PASiC, compared to PAC. The decrease has a close relationship with the basicity ( B ) and Al/Si molar ratio in PASiC. The less the B value and the Al/Si molar ratio, the lower the charge neutralizing ability of PASiC is. In contrast, the preparation technique for PASiC affects the charge-neutralization of PASiC to a smaller extent. In addition, compared with PAC, PASiC may enhance aggregating efficiency and give better coagulating effects.展开更多
A N 2 flotation tank combined with coagulation was developed as a pretreatment equipment of biological process to remove oil and other pollutants in coal gasification wastewater( CGW). With optimal PAC dosage of 20 mg...A N 2 flotation tank combined with coagulation was developed as a pretreatment equipment of biological process to remove oil and other pollutants in coal gasification wastewater( CGW). With optimal PAC dosage of 20 mg / L,the sole coagulation process achieves removal efficiencies of 29. 34% and 26. 83% for oil and COD,respectively. For the sole N 2 floatation process,the optimal N 2 flux and HRT are 20 m3/ h and 20 min. Meanwhile,the oil and COD removal efficiencies are 35. 41% and 14. 26%,respectively. For the combined system of coagulation and N 2 floatation,the optimal parameter values are the same as the ones of separate processes. Correspondingly,the removal efficiencies are 46. 28% and 31. 89% for oil and COD, respectively. Besides,BOD 5 / COD of the effluent is improved. In contrast with conventional dissolved air floatation,the inert gas- N 2 prevents the formation of cyclopentenone, pyridine derivatives, and other heterocyclic aromatic hydrocarbons,thus improving the biodegradability of influent for the subsequent biological processes.展开更多
Pulse electro-coagulation flotation was used to treat oil wastewater of high oil content.Different operational conditions were examined,including current density,reactive time,electrode distance,pH and pole switching ...Pulse electro-coagulation flotation was used to treat oil wastewater of high oil content.Different operational conditions were examined,including current density,reactive time,electrode distance,pH and pole switching time.Orthogonal tests were carried out to identify the optimal operational conditions for this technique.Considering the treatment cost and efficiency together,the optimal operational conditions were an electrode distance of 3.3 cm,pH of 4,current density of 49.38 mA/cm2,reaction time of 15 min and pole switching time of 10 s.The removal efficiency of oil wastewater under normal conditions reached up to 96.21%.The influences of different factors on removal efficiency were in the following decreasing sequence:pH> current density > pole switching time > reactive time > board distance.展开更多
Water supply and sanitation demands are foreseen to face enormous challenges over the coming decades to meet the fast growing needs in a global perspective. Significant growth in the industry is predicted and membrane...Water supply and sanitation demands are foreseen to face enormous challenges over the coming decades to meet the fast growing needs in a global perspective. Significant growth in the industry is predicted and membrane separation technologies have been identified as one of the possible solutions to meet future demands. Application and implementation of membrane technology is expected both in production of potable water as well as in treatment of wastewater. In potable water production membranes are substituting conventional separation technologies due to the superior performance, potential for less chemical use and sludge production, as well as the potential to fulfill hygienic barrier requirements. Membrane bio-reactor (MBR) technology is probably the membrane process which has had most success and has the best prospects for the future in wastewater treatment. Trends and developments indicate that this technology is becoming accepted and is rapidly becoming the best available technology for many wastewater treatment applications. A major drawback of MBR systems is membrane fouling. Studies have shown that fouling mitigation in MBR systems can potentially be done by coupling coagulation and flocculation to the process.展开更多
The effluent from the pulping of E. urophylla by alkali sodium sulfite chemi mechanical process(AS-CMP) was characterized for its biodegradability by photosynthetic bacteria (PSB). Chemical coagulation post treat...The effluent from the pulping of E. urophylla by alkali sodium sulfite chemi mechanical process(AS-CMP) was characterized for its biodegradability by photosynthetic bacteria (PSB). Chemical coagulation post treatment of biotreated wastewater was also studied. One month continuous treatment in the laboratory indicated that the COD Cr , BOD 5 and SS removals in biotreatment stages reached 56%, 83% and 89% respectively, and the CH 2Cl 2 extractives decreased from 10.7 mg/L to 7.7 mg/L. In chemical coagulation post treatment stage, the effects of process conditions, such as coagulant dosage, pH value and the coordinated coagulation flocculation treatment of three kinds of coagulants on coagulation effectiveness were discussed. The optimum operating conditions were given.展开更多
In order to extract gold fines from pyrite slag, the hydrophobic flocculation flotation (HFF) was studied and compared with conventional flotation. The main parameters of HFF such as flotation reagent, surfactant dosa...In order to extract gold fines from pyrite slag, the hydrophobic flocculation flotation (HFF) was studied and compared with conventional flotation. The main parameters of HFF such as flotation reagent, surfactant dosage. the duration of agitation and the amount of non-polar oil were investigated, and the effect of non-polar oil was analyzed particularly. It is demonstrated that the HFF is better for gold extraction from pyrite slag than the conventional flotation, and the non-polar oil and the intensive agitation are the key to improve the Au contents and recovery in the concentrate. HFF was used to treat the pyrite slag from the west of Jiangxi province, whose gold contentsare 2.949/t and the size of which are smaller than 10μm. The gold concentrate with gold grade 126.3 g/t and 51 .35% recovery was obtained. Thus, a new method of extracting gold fines from pyrite slag is developed using HFF.展开更多
This paper reports an approach to estimate the sludge density in a physicochemical treatment of municipal wastewater, experiments considered 4 coagulants (aluminum sulfate SAl, iron sulfate SFe, aluminum polychloride ...This paper reports an approach to estimate the sludge density in a physicochemical treatment of municipal wastewater, experiments considered 4 coagulants (aluminum sulfate SAl, iron sulfate SFe, aluminum polychloride PAX, iron polychloride PIX), and 2 flocculant products (cationic CP and anionic AP polymers). Experimental approach is based on running a set of jar tests at different coagulant concentrations. After the stirring and resting times took place, pH and conductivity were registered finding that SAl and SFe either with or without polymers are the coagulants producing the higher pH drop. Conductivity measures also establish two kind of data since higher conductivity (about 2000 ) was observed for SAl, and PIX, PIX + CP, PIX + AP;otherwise a conductivity about 1300 was observed for SAl + PC, SFe and PAX alone and with CP or AP. Settleable solids (SST) determined with an Imhoff cone were similar for sulfates and polychlorides, but dry sludge (DS) clearly set up two groups the one with higher sludge content corresponds to sulfates group. The quotient of DS divided by the SST provided an estimation of the apparent sludge density, in this way it was observed that higher densities were obtained for sludge from sulfates at lower coagulant concentrations;also sludge from SFe was heavier than the one from SAl. Otherwise, polychlorides produced a lighter sludge in respect to the one obtained with sulfates, and between them the PIX coagulant provided a heavier sludge than the PAX coagulant.展开更多
For the wastewater containing high-concentration Hg,the feasibility of high-concentration Hg in wastewater treated by coagulation sedimentation,adsorption and the combined process was studied. Research results showed ...For the wastewater containing high-concentration Hg,the feasibility of high-concentration Hg in wastewater treated by coagulation sedimentation,adsorption and the combined process was studied. Research results showed that if using the single coagulation sedimentation process,when FeSO_4·7H_2O dosage was 1. 39 g / L,and NaOH dosage was 0. 40 g / L,it could meet discharge requirement,but the reagent cost was 13. 1yuan / t,which was high. Because that there was subsequent adsorption process,it was selected 0. 28 g / L of FeSO_4·7H_2O and 0. 36 g / L of NaOH,and the estimated reagent cost was 2. 62 yuan / t. In selection process of adsorption materials,powdered activated carbon,granular activated carbon and diatomite all could effectively adsorb Hg,and the technology was feasible. When using the combined process of coagulation sedimentation + adsorption to treat the wastewater containing high-concentration Hg( 800 μg / L),removal rate could reach 99%,and operation cost was 2. 71 yuan. It could meet the requirement of sewage discharged into sewer( 20 μg / L) at the technology,and was acceptable at the economy.Therefore,treatment of wastewater containing high-concentration Hg by the combined process was feasible at the aspects of technology and economy.展开更多
Characterization of water, waste water and natural organic matter are involved in this paper, and as well as the features of flocculation and coagulation for removing natural organic matter from water and waste water ...Characterization of water, waste water and natural organic matter are involved in this paper, and as well as the features of flocculation and coagulation for removing natural organic matter from water and waste water Novel flocculant and coagualant is strongly asked for improving removal efficiency and environment friendly. Enhanced coagulation is introduced to meet the experimental and practical requirement.展开更多
Flotation mechanism of kaolinite was investigated through flotation test, SEM analysis and quantum chemical simulation calculation. It is shown that the (001) face of kaolinite easily adsorb cationic collector to exhi...Flotation mechanism of kaolinite was investigated through flotation test, SEM analysis and quantum chemical simulation calculation. It is shown that the (001) face of kaolinite easily adsorb cationic collector to exhibit hydrophobicity; the (001) face is easily interacted with the reagent carrying the group of high electronegativity (-O-, -N-, F-) to show hydrophilicity. The cationic and anionic polyacrylamide are adsorbed onto the (001) face of kaolinite and the flocculation of kaolinite particles may take place; the (001) faces are exposed to interact with cationic collector to be rendered hydrophobicity. Thus, the macromolecules can evidently enhance the flotation of kaolinite in alkaline media.展开更多
[Objective] The study aimed to discover the effects of powder active carbon( PAC) /flotation /micro-flocculation /ultrafiltration combined process on the treatment of reservoir water. [Method]Taken the water from a ...[Objective] The study aimed to discover the effects of powder active carbon( PAC) /flotation /micro-flocculation /ultrafiltration combined process on the treatment of reservoir water. [Method]Taken the water from a mountainous reservoir for the initial samples,the parameters such as turbidity,COD Mn,chlorophyll-a and methylisobormeol( MIB) of water samples were monitored before and after treated with combined processes of micro-flocculation /ultrafiltration, flotation /micro-flocculation /ultrafiltration, PAC /flotation /micro-flocculation /ultrafiltration. [Result] The results showed that the removal rates of turbidity of water samples by the above three processes were 97. 5%,98. 0% and 98. 6%,respectively. The removal rates of COD Mn were 30. 9%,35. 0% and 52. 0%. The removal rates of chlorophyll-a were 80. 6%,91. 0% and 99. 0%. The removal rates of MIB were 17. 0%,34. 2% and 97. 0%. [Conclusion]The PAC /flotation /micro-flocculation ultrafiltration combined process can be flexibly combined based on the characteristics of algae and odor in water,and is suitable for water plant construction or reconstruction.展开更多
This work investigates the influence of pH variation on coag-flocculation kinetics and performance of Chitin Derived Coag-flocculant (CDC) in removal of Suspended and Dissolved Particles (SDP) from Coal washery efflue...This work investigates the influence of pH variation on coag-flocculation kinetics and performance of Chitin Derived Coag-flocculant (CDC) in removal of Suspended and Dissolved Particles (SDP) from Coal washery effluent (CWE) medium. Key parameters such as rate constant Km, half life t1/2,, and pH etc. were investigated. The best coag-flocculation performance is recorded at Km, of 0.007 l/mg.min, t1/2, of 0.0362min, pH of 8, dosage of 100mg/l and efficiency E(%) of 99.933. Minimum efficiency (%) > 94.00 was achieved at 30 minutes of coagflocculation, establishing CDC as an effective water treatment agent at the conditions of the experiment.展开更多
The highly efficient inorganic polymer flocculants (IPFs) of the ferric-silica system is a new and promising coagulant. Interactions between ferric species and silica play a large part in the coagulation of suspensi...The highly efficient inorganic polymer flocculants (IPFs) of the ferric-silica system is a new and promising coagulant. Interactions between ferric species and silica play a large part in the coagulation of suspensions. These effects are quite distinct from those associated with polymeric or colloid silica. However, although these species are key to coagulation efficiency, they have not been comprehensively discussed. A new type of coagulant, poly-silica-ferric-chloride (PFSC), was synthesized by co-polymerization and characterized by time complexation spectroscopy and photon correlation spectroscopy. Compared with traditional ferric salt, the results indicated that PFSC had a higher molecular weight, lesser positive charge, lower Feb and higher Fec. The higher the Si/Fe ratio, the higher the silica and lower the silicac found. The PFSC with appropriate polysilica acid not only obtained better coagulation/flocculation efficiency in turbidity removal, enhanced the flocculation index (FI) and provided less residual ferric, it also lowered water treatment costs compared to traditional ferric salt. Results showed that PFSC could remove colloid particles in water by charge neutralization and sweeping, adsorption bridging mechanism.展开更多
In this study,a high-efficiency cationic flocculant,P(DAC-MAPTAC-AM),was successfully prepared using UV-induced polymerization technology.The monomer Acrylamide(AM):Acryloxyethyl Trimethyl ammonium chloride(DAC):metha...In this study,a high-efficiency cationic flocculant,P(DAC-MAPTAC-AM),was successfully prepared using UV-induced polymerization technology.The monomer Acrylamide(AM):Acryloxyethyl Trimethyl ammonium chloride(DAC):methacrylamido propyl trimethyl ammonium chloride(MAPTAC)ratio,monomer concentration,photoinitiator concentration,urea content,and cationic monomer DAC:MAPTAC ratio,light time,and power of highpressure mercury lamp were studied.The characteristic groups,characteristic diffraction peaks,and characteristic proton peaks of P(DAC-MAPTAC-AM)were confirmed by fourier transform infrared spectroscopy(FTIR),X-Ray diffraction(XRD),1H nuclear magnetic resonance spectrometer(1H NMR),and scanning electron microscopy(SEM).The effects of dosage,pH value,and velocity gradient(G)value on the removal efficiencies of turbidity,COD,ammonia nitrogen,and total phenol by poly aluminum ferric chloride(PAFC),P(DACMAPTAC-AM),and PAFC/P(DAC-MAPTAC-AM)in the flocculation treatment of coal chemical wastewater were investigated.Results showed that the optimal conditions for the flocculation of coal chemical wastewater using P(DAC-MAPTAC-AM)alone are as follows:dosage of 8-12 mg/L,G value of 100-250 s^-1,and pH value of 4-8.The optimal dosage of PAFC is 90-150 mg/L with a pH of 2-12.The optimal dosage for PAFC/P(DAC-MAPTAC-AM)is as follows:PAFC dosage of 90-150 mg/L,P(DAC-MAPTAC-AM)dosage of 8-12 mg/L,and pH range of 2-6.When P(DAC-MAPTAC-AM)was used alone,the optimal removal efficiencies of turbidity,COD,ammonia nitrogen,and total phenol were 81.0%,35.0%,75.0%,and 80.3%,respectively.PAFC has good tolerance to wastewater pH and good pH buffering.Thus,the flocculation treatment of coal chemical wastewater using the PAFC/P(DAC-MAPTAC-AM)compound also exhibits excellent resistance and buffering capacity.展开更多
文摘The electrokinetic characteristics and coagulation behaviors of polyaluminum silicate chloride (PASiC) and polyaluminum chloride (PAC) were studied and compared by streaming current (SC) measurement and jar test method. The experimental results showed that the interaction between polysilicic acid characterized negative charge and hydrolyzed aluminum species result in a decrease of the charge neutralizing ability of PASiC, compared to PAC. The decrease has a close relationship with the basicity ( B ) and Al/Si molar ratio in PASiC. The less the B value and the Al/Si molar ratio, the lower the charge neutralizing ability of PASiC is. In contrast, the preparation technique for PASiC affects the charge-neutralization of PASiC to a smaller extent. In addition, compared with PAC, PASiC may enhance aggregating efficiency and give better coagulating effects.
基金Sponsored by the Sino-Dutch Research Program(Grant No.SDRP-WRZ)the State Key Laboratory of Urban Water Resource and Environment,Harbin Institute of Technology(Grant No.2013DX10)
文摘A N 2 flotation tank combined with coagulation was developed as a pretreatment equipment of biological process to remove oil and other pollutants in coal gasification wastewater( CGW). With optimal PAC dosage of 20 mg / L,the sole coagulation process achieves removal efficiencies of 29. 34% and 26. 83% for oil and COD,respectively. For the sole N 2 floatation process,the optimal N 2 flux and HRT are 20 m3/ h and 20 min. Meanwhile,the oil and COD removal efficiencies are 35. 41% and 14. 26%,respectively. For the combined system of coagulation and N 2 floatation,the optimal parameter values are the same as the ones of separate processes. Correspondingly,the removal efficiencies are 46. 28% and 31. 89% for oil and COD, respectively. Besides,BOD 5 / COD of the effluent is improved. In contrast with conventional dissolved air floatation,the inert gas- N 2 prevents the formation of cyclopentenone, pyridine derivatives, and other heterocyclic aromatic hydrocarbons,thus improving the biodegradability of influent for the subsequent biological processes.
基金Funded by the Natural Science Foundation of Chongqing(No.2006BB6183)
文摘Pulse electro-coagulation flotation was used to treat oil wastewater of high oil content.Different operational conditions were examined,including current density,reactive time,electrode distance,pH and pole switching time.Orthogonal tests were carried out to identify the optimal operational conditions for this technique.Considering the treatment cost and efficiency together,the optimal operational conditions were an electrode distance of 3.3 cm,pH of 4,current density of 49.38 mA/cm2,reaction time of 15 min and pole switching time of 10 s.The removal efficiency of oil wastewater under normal conditions reached up to 96.21%.The influences of different factors on removal efficiency were in the following decreasing sequence:pH> current density > pole switching time > reactive time > board distance.
文摘Water supply and sanitation demands are foreseen to face enormous challenges over the coming decades to meet the fast growing needs in a global perspective. Significant growth in the industry is predicted and membrane separation technologies have been identified as one of the possible solutions to meet future demands. Application and implementation of membrane technology is expected both in production of potable water as well as in treatment of wastewater. In potable water production membranes are substituting conventional separation technologies due to the superior performance, potential for less chemical use and sludge production, as well as the potential to fulfill hygienic barrier requirements. Membrane bio-reactor (MBR) technology is probably the membrane process which has had most success and has the best prospects for the future in wastewater treatment. Trends and developments indicate that this technology is becoming accepted and is rapidly becoming the best available technology for many wastewater treatment applications. A major drawback of MBR systems is membrane fouling. Studies have shown that fouling mitigation in MBR systems can potentially be done by coupling coagulation and flocculation to the process.
文摘The effluent from the pulping of E. urophylla by alkali sodium sulfite chemi mechanical process(AS-CMP) was characterized for its biodegradability by photosynthetic bacteria (PSB). Chemical coagulation post treatment of biotreated wastewater was also studied. One month continuous treatment in the laboratory indicated that the COD Cr , BOD 5 and SS removals in biotreatment stages reached 56%, 83% and 89% respectively, and the CH 2Cl 2 extractives decreased from 10.7 mg/L to 7.7 mg/L. In chemical coagulation post treatment stage, the effects of process conditions, such as coagulant dosage, pH value and the coordinated coagulation flocculation treatment of three kinds of coagulants on coagulation effectiveness were discussed. The optimum operating conditions were given.
文摘In order to extract gold fines from pyrite slag, the hydrophobic flocculation flotation (HFF) was studied and compared with conventional flotation. The main parameters of HFF such as flotation reagent, surfactant dosage. the duration of agitation and the amount of non-polar oil were investigated, and the effect of non-polar oil was analyzed particularly. It is demonstrated that the HFF is better for gold extraction from pyrite slag than the conventional flotation, and the non-polar oil and the intensive agitation are the key to improve the Au contents and recovery in the concentrate. HFF was used to treat the pyrite slag from the west of Jiangxi province, whose gold contentsare 2.949/t and the size of which are smaller than 10μm. The gold concentrate with gold grade 126.3 g/t and 51 .35% recovery was obtained. Thus, a new method of extracting gold fines from pyrite slag is developed using HFF.
文摘This paper reports an approach to estimate the sludge density in a physicochemical treatment of municipal wastewater, experiments considered 4 coagulants (aluminum sulfate SAl, iron sulfate SFe, aluminum polychloride PAX, iron polychloride PIX), and 2 flocculant products (cationic CP and anionic AP polymers). Experimental approach is based on running a set of jar tests at different coagulant concentrations. After the stirring and resting times took place, pH and conductivity were registered finding that SAl and SFe either with or without polymers are the coagulants producing the higher pH drop. Conductivity measures also establish two kind of data since higher conductivity (about 2000 ) was observed for SAl, and PIX, PIX + CP, PIX + AP;otherwise a conductivity about 1300 was observed for SAl + PC, SFe and PAX alone and with CP or AP. Settleable solids (SST) determined with an Imhoff cone were similar for sulfates and polychlorides, but dry sludge (DS) clearly set up two groups the one with higher sludge content corresponds to sulfates group. The quotient of DS divided by the SST provided an estimation of the apparent sludge density, in this way it was observed that higher densities were obtained for sludge from sulfates at lower coagulant concentrations;also sludge from SFe was heavier than the one from SAl. Otherwise, polychlorides produced a lighter sludge in respect to the one obtained with sulfates, and between them the PIX coagulant provided a heavier sludge than the PAX coagulant.
文摘For the wastewater containing high-concentration Hg,the feasibility of high-concentration Hg in wastewater treated by coagulation sedimentation,adsorption and the combined process was studied. Research results showed that if using the single coagulation sedimentation process,when FeSO_4·7H_2O dosage was 1. 39 g / L,and NaOH dosage was 0. 40 g / L,it could meet discharge requirement,but the reagent cost was 13. 1yuan / t,which was high. Because that there was subsequent adsorption process,it was selected 0. 28 g / L of FeSO_4·7H_2O and 0. 36 g / L of NaOH,and the estimated reagent cost was 2. 62 yuan / t. In selection process of adsorption materials,powdered activated carbon,granular activated carbon and diatomite all could effectively adsorb Hg,and the technology was feasible. When using the combined process of coagulation sedimentation + adsorption to treat the wastewater containing high-concentration Hg( 800 μg / L),removal rate could reach 99%,and operation cost was 2. 71 yuan. It could meet the requirement of sewage discharged into sewer( 20 μg / L) at the technology,and was acceptable at the economy.Therefore,treatment of wastewater containing high-concentration Hg by the combined process was feasible at the aspects of technology and economy.
文摘Characterization of water, waste water and natural organic matter are involved in this paper, and as well as the features of flocculation and coagulation for removing natural organic matter from water and waste water Novel flocculant and coagualant is strongly asked for improving removal efficiency and environment friendly. Enhanced coagulation is introduced to meet the experimental and practical requirement.
文摘Flotation mechanism of kaolinite was investigated through flotation test, SEM analysis and quantum chemical simulation calculation. It is shown that the (001) face of kaolinite easily adsorb cationic collector to exhibit hydrophobicity; the (001) face is easily interacted with the reagent carrying the group of high electronegativity (-O-, -N-, F-) to show hydrophilicity. The cationic and anionic polyacrylamide are adsorbed onto the (001) face of kaolinite and the flocculation of kaolinite particles may take place; the (001) faces are exposed to interact with cationic collector to be rendered hydrophobicity. Thus, the macromolecules can evidently enhance the flotation of kaolinite in alkaline media.
基金Supported by Water Pollution Control and Treatment National Science and Technology Major Project(2012ZX07404-003)Major Projects of Science and Technology of Jinan City(201201133)
文摘[Objective] The study aimed to discover the effects of powder active carbon( PAC) /flotation /micro-flocculation /ultrafiltration combined process on the treatment of reservoir water. [Method]Taken the water from a mountainous reservoir for the initial samples,the parameters such as turbidity,COD Mn,chlorophyll-a and methylisobormeol( MIB) of water samples were monitored before and after treated with combined processes of micro-flocculation /ultrafiltration, flotation /micro-flocculation /ultrafiltration, PAC /flotation /micro-flocculation /ultrafiltration. [Result] The results showed that the removal rates of turbidity of water samples by the above three processes were 97. 5%,98. 0% and 98. 6%,respectively. The removal rates of COD Mn were 30. 9%,35. 0% and 52. 0%. The removal rates of chlorophyll-a were 80. 6%,91. 0% and 99. 0%. The removal rates of MIB were 17. 0%,34. 2% and 97. 0%. [Conclusion]The PAC /flotation /micro-flocculation ultrafiltration combined process can be flexibly combined based on the characteristics of algae and odor in water,and is suitable for water plant construction or reconstruction.
文摘This work investigates the influence of pH variation on coag-flocculation kinetics and performance of Chitin Derived Coag-flocculant (CDC) in removal of Suspended and Dissolved Particles (SDP) from Coal washery effluent (CWE) medium. Key parameters such as rate constant Km, half life t1/2,, and pH etc. were investigated. The best coag-flocculation performance is recorded at Km, of 0.007 l/mg.min, t1/2, of 0.0362min, pH of 8, dosage of 100mg/l and efficiency E(%) of 99.933. Minimum efficiency (%) > 94.00 was achieved at 30 minutes of coagflocculation, establishing CDC as an effective water treatment agent at the conditions of the experiment.
基金supported by the Main Programme of the Province Natural Science Foundation of Jiangsu (No.BK2010034)the Social Development Projects of Nantong(No. S2009018)the Science Foundation of Nantong University (No. 9zy004)
文摘The highly efficient inorganic polymer flocculants (IPFs) of the ferric-silica system is a new and promising coagulant. Interactions between ferric species and silica play a large part in the coagulation of suspensions. These effects are quite distinct from those associated with polymeric or colloid silica. However, although these species are key to coagulation efficiency, they have not been comprehensively discussed. A new type of coagulant, poly-silica-ferric-chloride (PFSC), was synthesized by co-polymerization and characterized by time complexation spectroscopy and photon correlation spectroscopy. Compared with traditional ferric salt, the results indicated that PFSC had a higher molecular weight, lesser positive charge, lower Feb and higher Fec. The higher the Si/Fe ratio, the higher the silica and lower the silicac found. The PFSC with appropriate polysilica acid not only obtained better coagulation/flocculation efficiency in turbidity removal, enhanced the flocculation index (FI) and provided less residual ferric, it also lowered water treatment costs compared to traditional ferric salt. Results showed that PFSC could remove colloid particles in water by charge neutralization and sweeping, adsorption bridging mechanism.
基金National Key Research and Development Program of China(No.2017YFB0602500)2018 Six Talent Peaks Project of Jiangsu Province(No.JNHB-038)。
文摘In this study,a high-efficiency cationic flocculant,P(DAC-MAPTAC-AM),was successfully prepared using UV-induced polymerization technology.The monomer Acrylamide(AM):Acryloxyethyl Trimethyl ammonium chloride(DAC):methacrylamido propyl trimethyl ammonium chloride(MAPTAC)ratio,monomer concentration,photoinitiator concentration,urea content,and cationic monomer DAC:MAPTAC ratio,light time,and power of highpressure mercury lamp were studied.The characteristic groups,characteristic diffraction peaks,and characteristic proton peaks of P(DAC-MAPTAC-AM)were confirmed by fourier transform infrared spectroscopy(FTIR),X-Ray diffraction(XRD),1H nuclear magnetic resonance spectrometer(1H NMR),and scanning electron microscopy(SEM).The effects of dosage,pH value,and velocity gradient(G)value on the removal efficiencies of turbidity,COD,ammonia nitrogen,and total phenol by poly aluminum ferric chloride(PAFC),P(DACMAPTAC-AM),and PAFC/P(DAC-MAPTAC-AM)in the flocculation treatment of coal chemical wastewater were investigated.Results showed that the optimal conditions for the flocculation of coal chemical wastewater using P(DAC-MAPTAC-AM)alone are as follows:dosage of 8-12 mg/L,G value of 100-250 s^-1,and pH value of 4-8.The optimal dosage of PAFC is 90-150 mg/L with a pH of 2-12.The optimal dosage for PAFC/P(DAC-MAPTAC-AM)is as follows:PAFC dosage of 90-150 mg/L,P(DAC-MAPTAC-AM)dosage of 8-12 mg/L,and pH range of 2-6.When P(DAC-MAPTAC-AM)was used alone,the optimal removal efficiencies of turbidity,COD,ammonia nitrogen,and total phenol were 81.0%,35.0%,75.0%,and 80.3%,respectively.PAFC has good tolerance to wastewater pH and good pH buffering.Thus,the flocculation treatment of coal chemical wastewater using the PAFC/P(DAC-MAPTAC-AM)compound also exhibits excellent resistance and buffering capacity.