Groundwater Pollution from Underground Coal Gasification

In situ coal gasification poses a potential environmental risk to groundwater pollution although it depends mainly on local hydrogeological conditions. In our investigation,the possible processes of groundwater pollution origi-nating from underground coal gasification (UCG) were analyzed. Typical pollutants were identified and pollution con-trol measures are proposed. Groundwater pollution is caused by the diffusion and penetration of contaminants generated by underground gasification processes towards surrounding strata and the possible leaching of underground residue by natural groundwater flow after gasification. Typical organic pollutants include phenols,benzene,minor components such as PAHs and heterocyclics. Inorganic pollutants involve cations and anions. The natural groundwater flow after gasification through the seam is attributable to the migration of contaminants,which can be predicted by mathematical modeling. The extent and concentration of the groundwater pollution plume depend primarily on groundwater flow ve-locity,the degree of dispersion and the adsorption and reactions of the various contaminants. The adsorption function of coal and surrounding strata make a big contribution to the decrease of the contaminants over time and with the distance from the burn cavity. Possible pollution control measures regarding UCG include identifying a permanently,unsuitable zone,setting a hydraulic barrier and pumping contaminated water out for surface disposal. Mitigation measures during gasification processes and groundwater remediation after gasification are also proposed.

Appraisal of pollution and health risks associated with coal mine contaminated soil using multimodal statistical and Fuzzy-TOPSIS approaches

The present study assesses the concentration,probabilistic risk,source classification,and dietary risk arising from heavy metal(HMs)pollution in agricultural soils affected by coal mining in eastern part of India.Analyses of soil and rice plant indicated significantly elevated levels of HMs beyond the permissible limit in the contaminated zones(zone 1:PbSoil:108.24±72.97,CuSoil:57.26±23.91,CdSoil:8.44±2.76,CrSoil:180.05±46.90,NiSoil:70.79±25.06 mg/kg;PbGrain:0.96±0.8,CuGrain:8.6±5.1,CdGrain:0.65±0.42,CrGrain:4.78±1.89,NiGrain:11.74±4.38 mg/kg.zone 2:PbSoil:139.56±69.46,CuSoil:69.89±19.86,CdSoil:8.95±2.57,CrSoil:245.46±70.66,NiSoil:95.46±22.89 mg/kg;PbGrain:1.27±0.84,CuGrain:7.9±4.57,CdGrain:0.76±0.43,CrGrain:8.6±1.58,NiGrain:11.50±2.46 mg/kg)compared to the uncontaminated zone(zone 3).Carcinogenic and non-carcinogenic health risks were computed based on the HMs concentration in the soil and rice grain,with Pb,Cr,and Ni identified as posing a high risk to human health.Monte Carlo simulation,the solubility-free ion activity model(FIAM),and severity adjusted margin of exposure(SAMOE)were employed to predict health risk.FIAM hazard quotient(HQ)values for Ni,Cr,Cd,and Pb were>1,indicating a significant non-carcinogenic risk.SAMOE(risk thermometer)results for contaminated zones ranged from low to moderate risk(CrSAMOE:0.05,and NiSAMOE:0.03).Fuzzy-TOPSIS and variable importance plots(from random forest)showed that Ni and Cr were mostly responsible for the toxicity in the rice plant,respectively.A self-organizing map for source classification revealed common origin for the studied HMs with zone 2 exhibiting the highest contamination.The positive matrix factorization model for the source apportionment identified coal mining and transportation as the predominant sources of HMs.Spatial distribution analysis indicated higher contamination near mining sites as compared to distant sampling sites.Consequently,this study will aid environmental scientists and policymakers controlling HM pollution in agricultural soils near coal mines.

溶胶-凝胶水热合成法制备纳米CoAl_2O_4粉体

以仲丁醇铝和硝酸钴为原料,用溶胶-凝胶水热合成法制备了纳米CoAl2O4粉体,探讨了水热合成中前驱体的制备工艺条件,并用X射线衍射和扫描电镜等手段分析了水热系统中反应温度、反应时间对纳米CoAl2O4粉体的形成以及形貌的影响。结果表明:前驱体在250℃的水热系统中反应24h,能制备出较纯净、结晶完整、粒度均匀、粒径小、尖晶石结构的纳米CoAl2O4粉体,其平均粒度约为50～60nm。

Hemolysis of PM_(10) on RBCs in vitro:An indoor air study in a coal-burning lung cancer epidemic area

Epidemiological studies have suggested that inhalation exposure to indoor ambient air from coal-burning environments is causally associated with respiratory health risks.In order to explore the toxicological mechanisms behind the adverse health effects,the hemolytic activity of PM_(10)(particulate matter with an aerodynamic diameter of 10 um or less)samples collected from homes burning coal in the recognized China"cancer village"Xuanwei were evaluated and matched against their trace elemental contents.The results demonstrated that the hemolytic activity of indoor PM_(10) in coal-burning environments ranged from 4.28%to 5.24%,with a clear positive dose-response relationship.Although low dose samples exhibited a reduced hemolytic activity,PM_(10) could have a toxic effect upon people in a coal-burning indoor environment for extended time periods.The concentrations of analyzed trace elements in PM_(10) samples ranged from 6966 to 12,958 ppm.Among the analyzed elements,Zn,Ti,Ni,Cu,Pb,Ba,Mn,Cr and V were found at higher concentrations and accounted for over 95%of the total elements.The concentrations of total analyzed elements in the PM_(10) samples revealed a significant positive correlation with PM_(10) hemolytic activity.Of the analyzed elements,Zn,Pb and Cs positively correlated with hemolysis,while Li,U and V negatively correlated with the hemolysis of human red blood cells(RBCs).Therefore,the heavy metal elements could be one of the main factors responsible for the hemolytic capacity of indoor PM_(10) in coal-burning environments.

Household air pollution and lung cancer in China:a review of studies in Xuanwei

Over half of the world's population is exposed to household air pollution from the burning of solid fuels at home. Household air pollution from solid fuel use is a leading risk factor for global disease and remains a major public health problem, especially in low- and mid-income countries. This is a particularly serious problem in China, where many people in rural areas still use coal for household heating and cooking. This review focuses on several decades of research carried out in Xuanwei County, Yunnan Province, where household coal use is a major source of household air pollution and where studies have linked household air pollution exposure to high rates of lung cancer. We conducted a series of case-control and cohort studies in Xuanwei to characterize the lung cancer risk in this population and the factors associated with it. We found lung cancer risk to vary substantially between different coal types, with a higher risk associated with smoky(i.e., bituminous) coal use compared to smokeless(i.e., anthracite) coal use. The installation of a chimney in homes resulted in a substantial reduction in lung cancer incidence and mortality. Overall, our research underscores the need among existing coal users to improve ventilation, use the least toxic fuel, and eventually move toward the use of cleaner fuels, such as gas and electricity.

Application of High-pressure Flat Membranes in Coal Chemical Wastewater Treatment

In the process of using high-pressure flat membranes to treat coal chemical wastewater,the effects of high-pressure flat membranes on the concentration of salt ions and the removal of pollutants were studied under the conditions of different concentrations of influent TDS,COD and silicon dioxide.The results showed that when the concentration of influent TDS was 35 000-55 000 mg/L,the economic benefit of high-pressure flat membrane operation was the best,and the concentration ratio of high-pressure flat membranes was stable,varying from 3.3 to 3.6.As the concentration of influent organic matter ranged from 100 to 1 800 mg/L,the removal rate of organic matter ranged from 60% to 79%.In addition,the retention rate of high-pressure flat membranes to silicon dioxide was more than 90%.

淄博洪山-寨里煤矿地下水串层污染治理区水化学和硫同位素特征

在明确淄博洪山-寨里煤矿地下水串层污染治理区内水文地质状况、地下水流场特征等基础上,通过对矿井水、采空区水、矿排水、奥灰水、雨水、地表水的取样分析,掌握治理区的地下水水化学、硫同位素特征。选择接受大气降雨补给的区域、煤矿水聚集区、奥灰水聚集区以及奥灰水与煤矿水交叉混合区,分区对地下水水质现状及煤矿水和奥灰水之间水力联系情况进行分析判断。通过对比分析治理前后研究区水质情况,发现治理后奥灰水仍呈现高SO_(4)^(2-)浓度、高硬度、高TDS特征,且硫酸盐主要来源于煤矿水,治理后洪山、寨里煤矿地下水串层通道依然存在,串层污染情况持续进行,且污染较治理前有加重趋势。则今后治理工作应进一步查清、控制导水通道,控制矿坑水水位,避免其污染奥灰水。

Mercury Emission From Coal-fired Power Plants in China

燃煤是最大的人为汞排放源之一，燃煤电厂的汞排放控制问题也越来越为人们所关注。该文将目前公布的中国电厂的汞排放数据进行筛选汇总，得到18个电厂的汞排放数据，通过对比和分析，总结出了符合我国燃煤电厂特点的一般性汞排放规律。结果表明：与美国煤种相比，我国的燃煤具有低氯、高灰的特性，这不利于汞的排放控制；循环流化床燃烧可能会因燃尽率的不同而较煤粉炉燃烧易获得较高的Hgp；空气污染控制设备的使用能够有效地减少汞排放，选择性催化还原＋静电除尘器／布袋除尘器＋石灰石-石膏湿法脱硫（SCR＋ESP／FF＋WFGD）组合的平均脱汞率可达71．48％；SCR的大规模应用可能会将汞大量转移到飞灰和脱硫石膏中，带来二次污染的问题。

Non-isothermal oxidation of coal with Ce(NO3)3 and Cu(NO3)2 additives

Non-isothermal oxidation of brown coal with 5 wt% of Cu(NO3)2, 5 wt% of Ce(NO3)3 and {2.5 wt% Cu(NO3)2 + 2.5 wt% Ce(NO3)3} additives was studied. The introduction of additives was carried out by an incipient wet impregnation method to ensure uniform distribution of cerium and copper nitrates within the structure of coal powdery samples (according to SEM and EDX mapping). The samples reactivity was studied in an isothermal oxidation regime at 200 °C (1 h) and by DSC/TGA at 2.5 °C/min heating rate. The additives implementation was found to reduce significantly the oxidation onset temperature (△Ti = 20-55 °C), the samples oxidation delay time (△ti= 2-22 min) and overall duration of the oxidation process (△tc = 8-16 min). The additives efficiency could be graded in accordance with the activation on the coal oxidation in the following row: Cu(NO3)2 >{Cu(NO3)2 + Ce(NO3)3}> Ce(NO3)3. According to the mass spectroscopy, the obtained row of activation correlates well with the initial temperature of the studied nitrate's decomposition (from 190 to 223 °C). A presence of nitrates was found to change significantly the trend of heat release taking place during the oxidation of coal samples (according to DSC/TGA data). The influence of coal morphology and volatiles concern in initial sample on the parameters of the oxidation process was studied as well. Activation energy (Ea) of the coal oxidation was calculated using Coats-Redfern method. Maximum decrease in Ea from 69 to 58 kJ/mol was observed for the samples with Cu(NO3)2. Graphical abstract.

Association of TNF-α-238G/A and 308 G/A Gene Polymorphisms with Pulmonary Tuberculosis among Patients with Coal Worker’s Pneumoconiosis

Objectives Tumor necrosis factor-α （TNF-α） may play an important role in host＇s immune response to mycobacterium tuberculosis （M. tuberculosis） infection. This study was to investigate the association of TNF-α gene polymorphism with pulmonary tuberculosis （TB） among patients with coal worker＇s pneumoconiosis （CWP）. Methods A case-control study was conducted in 113 patients with confirmed CWP complicated with pulmonary TB and 113 non-TB controls with CWP. They were matched in gender, age, job, and stage of pneumoconiosis. All participants were interviewed with questionnaires and their blood specimens were collected for genetic determination with informed consent. The TNF-α gene polymorphism was determined with polymerase chain reaction of restriction fragment length polymorphism （PCR-RFLP）. Frequency of genotypes was assessed for Hardy-Weinberg equilibrium by chi-square test or Fisher＇s exact probability. Factors influencing the association of individual susceptibility with pulmonary TB were evaluated with logistic regression analysis. Gene-environment interaction was evaluated by a multiplieative model with combined OR. All data were analyzed using SAS version 8.2 software. Results No significant difference in frequency of the TNF-α-308 genotype was found between CWP complicated with pulmonary TB and non-TB controls （2,2=5.44, P=-0.07）. But difference in frequency of the TNF-α-308 A allele was identified between them （2,2-5.14, P=0.02）. No significant difference in frequencies of the TNF-α-238 genotype and allele （P=0.23 and P=0.09, respectively） was found between cases and controls either, with combined （GG and AA） OR of 3.96 （95% confidence interval of 1.30-12.09） at the -308 locus of the TNF-α gene, as compared to combination of the TNF-α-238 GG and TNF-α-308 GG genotypes. Multivariate-adjusted odds ratio of the TNF-α-238 GG and TNF-α-308 GA genotypes was 1.98 （95% CI of 1.06-3.71） for risk for pulmonary TB in patients with CWP. There was a synergic interaction between the TNF-a-308 GG genotype and body mass index （OR=4.92）, as well as an interaction between the TNF-α-308 GG genotype and history of BCG immunization or history of TB exposure. And, the interaction of the TNF-α-238 GG genotype and history of BCG immunization or TB exposure with risk for pulmonary TB in them was also indicated. Conclusions TNF-α-308 A allele is associated with an elevated risk for pulmonary TB, whereas TNF-α-238 A allele was otherwise.

Synergistic effects of phosphoric acid modified hydrochar and coal gangue-based zeolite on bioavailability and accumulation of cadmium and lead in contaminated soil

In this paper,a novel compound was developed by mixing H_(3)PO_(4)-modified cauliflower leaves hydrochar(CLH)and coal gangue-based Na-X zeolite(ZL).An alkaline soil contaminated with cadmium(Cd)and lead(Pb)was amended through the individual and synergistic application of CLH and ZL(1%CLH,2%CLH,1%ZL,2%ZL and 1%CLH+1%ZL),and Chinese cabbage was grown on it.Individual application of CLH was superior to ZL on decreasing the pH of alkaline soil and increasing soil available phosphorus(Olsen-P)and soil organic matter(SOM).In contrast,their combined application significantly improved the soil cation exchange capacity(CEC).Besides,the 1%CLH+1%ZL was the most efficient treatment in decreasing diethylenetriamine pentaacetate(DTPA)-extractable Cd/Pb and concentrations of these two metals in cabbage root and shoot.Their synergistic application could better increase Cd and Pb immobilization and cabbage yield than their alone application.Furthermore,the immobilization of Pb for all treatments was higher than that of Cd.The synergistic immobilization mechanism of CLH and ZL reflected that the CLH precipitated and complexed with these two metals,which may block the pores of hydrochar or wrap on the surface of hydrochar.So the continuous adsorption and complexation were prevented.Nevertheless,ZL could probably alleviate this obstacle.This finding provides helpful information about using CLH combined with ZL as a soil stabilizer to immobilize heavy metals in contaminated alkaline soil.

Effects of a proline solution cover on the geochemical and mineralogical characteristics of high-sulfur coal gangue

Batch experiments were conducted to comparatively evaluate the inhibition effects and mechanisms of a low-concentration(1%) proline solution cover on the release of pollutants from high-sulfur coal gangue. Highsulfur coal gangue was continuously immersed in a proline solution and in deionized water(as a control treatment) for540 days. The results showed that the coal gangue in the control treatment was oxidized and generated leachate with poor water qualities, i.e., the leachate exhibited lower p H values, higher redox potential values, higher pollutant concentrations(SO_4^(2-), Fe, Mn, Cu, and Zn), and high levels of acidophilic sulfur-oxidizing bacteria. However,compared to the control treatment, the addition of the proline solution(1%) significantly improved the water quality of the leachate by significantly reducing the Eh values, the pollutant concentrations(SO_4^(2-), Fe^(2+), Fe, Mn,Cu, and Zn), and the activity of acidophilic sulfur-oxidizing bacteria and by significantly increasing the pH value to neutral. The proline treatment significantly inhibited the oxidation of coal gangue and the release of pollutants,mainly by inhibiting the activity of acidophilic sulfur-oxidizing bacteria and by altering the heavy metal fractions and the mineralogical characteristics. Therefore, in engineering practice, workers should consider using an environmental friendly aqueous proline solution cover toachieve the in-situ control of pollutant releases from coal gangue dumps.

Effect of Mild-calcined Coal Gangue Additionon Hot Strength and Refractoriness Under Loadof Ultra Low Cement Castablesin Al_2O_3-SiO_2 System

This work explored the way to improve hot modulus q/＇ rupture （HMOR） and refractoriness under load （RUL） by adding mild-calcined coal gangue （MCG） in Al2O3 -SiO2 ultra low cement （ULC） castables, making use of the in-situ effect of the MCG during heating-up. The influence of respective additions of 5%, 10% and 1.5% of the MCG powders calcined at 700℃ was investigated on HMOR at 1400 ℃ and RUL of the castables. With increased addition of the MCG, HMOR and RUL become significantly enhanced. At 10% of the MCG addition, HMOR reaches 3 MPa, as compared to 0. 3 MPa in the case of no MCG addition. RUL of the specimens dried at 110 ℃for 24 h can be increased by some 270 ℃ with 10% of the MCG addition. RUL 0.11 the specimens preheated at 1 500℃ for 3 h maintains the growth trend with the MCG addition increasing. The microstructure of the heated castable samples was investigated by means of SEM. The in-situ formed needle-like and interlaced mullite in the matrix is contributive to the tmprovement.

Current Situation and Application in Coal-Generated Hydrocarbons

The characteristics and research methods of terrigenous organic hydrocarbon-generated source rock in coal measures are studied in this thesis. After abundance of organic matters, pyrolysis parameter of rocks and hydrocarbon generated capacity of macerals are basically discussed in coal measures of the Cretaceous Muleng-Chengzihe formation in Suibin depression in Sanjang basin, the hydrocarbon generated grade in coal-genera^ted source rock is ascertained in this depression. At last, we think that it is a main attack prospect in coal-genera^ted hydrocarbons study in the future to research the macerals of coal measures organic source rock and to build a criterion to classify the coal-generated hydrocarbons in Northeast region.

Mercury pollution in the Chongqing part of the Three Gorges Reservoir area and its remediation and prevention

Mercury pollution in the Three Gorges Reservoir area of P.R.China merits special attention.We investigated into the current situation in the Chongqing part of the Reservoir area,identified the pollution sources and proposed some suggestions for the remediation and prevention of mercury pollution in this area.Atmospheric mercury in Chongqing was mainly from coal burning and releases of mercury-containing products such as various types of lights and fever thermometers.Urban drainage in Chongqing and Changshou,and runoffs from the high mercury background area in the lower reaches of the Wujiang River contributed most of the mercury in the water of the Yangtze River.A majority of the blame should be laid on mercury and gold mining in the Wujiang valley.We suggested foresting sloping lands to relieve soil erosion and prevent mercury-bearing soil from running into rivers,educational activities to discourage use of mercury-containing products and improved infrastructure to collect mercury-containing wastes for reducing mercury releases,more facilities for treating wastewater and solid waste to accommodate increased requirements of discharge,and growing selected perennial plants in mercury-contaminated land to absorb the mercury in soil.We also suggested concerted operation of a dedicated water-quality monitoring system,reinforced legislation and an effective administrative mechanism to ensure lasting efforts are invested in curbing mercury releases and restoring mercury contaminated land and water in the Reservoir area.

MILD粉体燃烧技术研究进展与关键问题分析

MILD燃烧是一种在中度或极度低氧环境下发生的温和燃烧模式,兼具高燃烧热利用率和极低NOx排放的优势,国际燃烧领域认为它是拥有巨大应用潜力的清洁燃烧技术之一。自1990年左右开展相关研究以来,对于实现气体燃料的MILD燃烧的相关技术已相对成熟,而关于煤粉和生物质等固体燃料的MILD燃烧机制和实现条件的研究仍相对缺乏。基于高动量氧化剂射流来实现内部再循环,不再需要外部高温预热来建立MILD燃烧,极大拓宽了MILD燃烧的应用范围。从颗粒弥散、受热、着火、燃烧、污染物等方面概述了MILD粉体燃料燃烧的基础特性,由于颗粒的不均匀弥散和反应,煤粉等碳基固体燃料的MILD燃烧进程较气体燃料更复杂。高速射流MILD燃烧在增加点火延迟的同时也扩展了点火区和反应区,需要对燃烧各阶段的特征和机理开展系统研究。介绍了固体燃料MILD燃烧理论设计和装备研发领域所取得的研究成果,建议通过高精度数值模拟,改进现有燃煤锅炉燃烧器、调节工艺参数以匹配MILD燃烧模式,增加焦炭颗粒的停留时间以提高燃烬率,提高燃烧稳定性并抑制包括细颗粒物在内的各类污染物排放。基于互联能源系统的整体方法,推进MILD燃烧与各类新型燃烧技术的耦合研究,尤其加强煤粉、生物质与氢、氨等可燃气体共燃特性研究,助力能源转型。探究粉体MILD燃烧中的湍流两相流特征、湍流相间传热作用以及湍流-化学耦合作用是加深对粉体MILD燃烧理解的关键,涉及多变量分析和高精度模拟,是未来研究的重点和难点。

煤炭洗选过程中的能源消耗与污染控制

随着中国经济的快速发展,煤炭作为主要能源,其洗选过程中的能源消耗与污染问题日益凸显。煤炭洗选过程中,能源消耗较高,不仅导致资源浪费,还加重了环境污染。因此,研究煤炭洗选过程中的能源消耗与污染控制问题具有重要的现实意义和理论价值。分析了煤炭洗选过程中的能源消耗,深入剖析了煤炭洗选过程中的污染来源及控制,并进一步提出了煤炭洗选过程中能源消耗与污染控制策略。旨在为煤炭洗选行业的绿色、高效、可持续发展提供一定的参考。

煤矿生产区周边水体环境重金属污染分析与治理技术

水体环境受污染会严重影响生态平衡,利用物理化学技术与生物治理技术相结合的方式,治理煤矿生产区水体环境重金属污染。在分析重金属污染情况后,考虑到重金属污染物进入水体后会出现降解、沉淀、氧化以及吸附反应,根据水体环境实时变化特征,利用物理与化学治理技术实施过滤、物理吸附、土壤淋漓以及化学固化操作。同时,利用水中微生物种群,通过生物治理的方式,消纳、转移重金属污染物。实验结果表明,该技术对水中的锰、铁以及铬等重金属元素均能高效地治理、去除。

煤矸石规模化生态利用原理与关键技术

煤炭是我国主要能源,是能源安全的压舱石。煤矸石作为采煤和洗煤加工过程中的必然产物,每年产出量达7亿t以上,亟需规模化、生态化利用技术,以破解煤矸石作为企业发展绊脚石的难题。在分析煤矸石大规模利用中的生态损伤机理的基础上,提出煤矸石规模化生态利用原理,从技术视角探讨了环境安全的规模化生态利用具体解决途径,提出了酸性煤矸石山原位污染控制与生态修复和煤矸石地面充填造地两大规模化生态利用方式关键技术。结果表明:(1)煤矸石规模化生态利用的关键是环境污染的防控,通过对矸石的可利用性和经济性评价,结合风险管控手段,可实现煤矸石规模化生态利用。(2)对已堆积的矸石山采用原位污染控制基础上的植被恢复以实现生态化利用,提出了污染源头诊断-防灭火与污染阻隔-植被恢复一体化的生态利用技术。基于矸石氧化产酸产热导致污染的机理分析,采用热红外与测绘技术相耦合进行煤矸石山深部燃点(氧化点)定位;研发了杀菌剂与还原菌耦合的氧化抑制剂并结合惰性材料覆盖碾压进行抑氧隔氧污染阻隔;对自燃区采用喷浆控火与注浆灭火结合的安全灭火技术;氧化抑制剂结合惰性材料覆盖碾压的长效防火技术;提出以乡土草灌为主的防燃型植被恢复技术,可实现酸性煤矸石山的原位污染控制与生态修复。(3)通过地面充填生态化利用可行性分析、充填生态化利用技术和维护管理长期监测,可实现煤矸石地面充填造地的生态化利用。其关键是矸石材料筛选的污染风险分析、地面充填场地选择的可行性分析以及充填全过程的环保措施,包括充填前的场地底部防渗阻隔、渗滤液导排等安全环保措施,充填中的分层充填技术、防火控酸的污染防控和土壤剖面重构技术,充填后的侵蚀控制、植被恢复等技术。煤矸石规模化生态利用不仅解决了矿区固废堆存带来的生态环境问题,还通过对新、旧矸石的科学合理利用,打造矿区生态修复的新模式。

裂解气相色谱-质谱法分离鉴定聚氨酯防水涂料中的煤焦油

建立了采用闪蒸裂解气相色谱-质谱测定固化后的聚氨酯防水涂料中的煤焦油的新方法。该方法方便快捷,无需对样品进行前处理,而且测定结果不受聚氨酯组分的干扰。该方法在建筑材料中有毒有害组分的分析检测方面有一定的应用价值。