Analysis of organic compounds in coal gasification wastewater

A procedure for analysis of organic pollutants in coal gasification wastewater was developed, including a series extraction steps at different pH, followed by LC separation or resin adsorption, then analyzed by GC or GC/MS. More than 200 organic pollutants in 22 categories were determined. CH2CL2 extraction at NaHCO3 presence was used to separate carboxylic acids with phenolic compounds in aqueous. Derivatization with acetic anhydride was used for analyses of mono-, di-, poly-hydroxyl phenolic compounds. 21 mono-hydroxyl phenols and 13 di-hydroxyl phenols were determined from the coai gasification wastewater samples. Derivatization with BF3-CH3OH was used for analysis of carboxylic acid. 17 mono-carboxyl, 4 di-carboxyl acids and 6 aromatic acids were determined from coal gasification wastewater samples.

Feasibility analysis of gob-side entry retaining on a working face in a steep coal seam

Based on the decline in exploitation of coal resources, steep coal seam mining and mining face tensions continue to explore the feasibility analysis of steeply inclined faces in the gob. One of the key factors in utilizing the technology of gob-side entry retaining in steep coal seams is to safely and effectively prevent caving rock blocks from rushing into the gob-side entry by sliding downwards along levels. Using theoretical analysis and field methods, we numerically simulated the mining process on a fully-mechanized face in a steep coal seam. The stress and deformation process of roof strata has been analyzed, and the difficulty of utilizing the technology is considered and combined with practice in a steep working face in Lvshuidong mine. The feasibility of utilizing the technology of gob-side entry retaining in a steep coal seam has been recognised. We propose that roadways along the left lane offshoot body use a speciallymade reinforced steel dense net to build a dense rock face at the lower head. The results show that the lane offshoot branch creates effective roof control, safe conditions for roadway construction workers, and practical application of steeply inclined gob.

Regression analysis of major parameters affecting the intensity of coal and gas outbursts in laboratory

Estimating the intensity of outbursts of coal and gas is important as the intensity and frequency of outbursts of coal and gas tend to increase in deep mining. Fully understanding the major factors contributing to coal and gas outbursts is significant in the evaluation of the intensity of the outburst. In this paper, we discuss the correlation between these major factors and the intensity of the outburst using Analysis of Variance(ANOVA) and Contingency Table Analysis(CTA). Regression analysis is used to evaluate the impact of these major factors on the intensity of outbursts based on physical experiments. Based on the evaluation, two simple models in terms of multiple linear and nonlinear regression were constructed for the prediction of the intensity of the outburst. The results show that the gas pressure and initial moisture in the coal mass could be the most significant factors compared to the weakest factor-porosity. The P values from Fisher's exact test in CTA are: moisture(0.019), geostress(0.290), porosity(0.650), and gas pressure(0.031). P values from ANOVA are moisture(0.094), geostress(0.077), porosity(0.420), and gas pressure(0.051). Furthermore, the multiple nonlinear regression model(RMSE: 3.870) is more accurate than the linear regression model(RMSE: 4.091).

Theoretical analysis on the deformation characteristics of coal wall in a longwall top coal caving face

Against the background of analyzing coal wall stability in 14101 fully mechanized longwall top coal caving face in Majialiang coal mine,based on the torque equilibrium of the coal wall,shield support and the roof strata,an elastic mechanics model was established to calculate the stress applied on the coal wall.The displacement method was used to obtain the stress and deformation distributions of the coal wall.This study also researched the influence of support resistance,protective pressure to the coal wall,fracture position of the main roof and mining height on the coal wall deformation.The following conclusions are drawn:(1) The shorter the distance from the longwall face,the greater the vertical compressive stress and horizontal tensile stress borne by the coal wall.The coal wall is prone to failure in the form of compressive-shear and tension;(2) With increasing support resistance,the revolution angle of the main roof decreases linearly.As the support resistance and protective force supplied by the face guard increases,the maximum deformation of the coal wall decreases linearly;(3) As the face approaches the fracture position of the main roof,coal wall horizontal deformation increases significantly,and the coal wall is prone to instability;and(4) The best mining height of 14101 longwall face is 3.0 m.

A back analysis of the temperature field in the combustion volume space during underground coal gasification

The exact shape and size of the gasification channel during underground coal gasification(UGC) are of vital importance for the safety and stability of the upper parts of the geological formation.In practice existing geological measurements are insufficient to obtain such information because the coal seam is typically deeply buried and the geological conditions are often complex.This paper introduces a cylindrical model for the gasification channel.The rock and soil masses are assumed to be homogeneous and isotropic and the effect of seepage on the temperature field was neglected.The theory of heat conduction was used to write the equation predicting the temperature field around the gasification channel.The idea of an excess temperature was introduced to solve the equations.Applying this model to UCG in the field for an influence radius,r,of 70 m gave the model parameters,u1,2,3...,of 2.4,5.5,8.7...By adjusting the radius(2,4,or 6 m) reasonable temperatures of the gasification channel were found for 4 m.The temperature distribution in the vertical direction,and the combustion volume,were also calculated.Comparison to field measurements shows that the results obtained from the proposed model are very close to practice.

Comparative Experimental Analysis on Coal Spontaneous Combustion

The goal of this study was to investigate coal quality features and their relationship to coal spontaneous combustion characteristics in multi-seam coal mines to better predict when coal spontaneous combustion is likely to occur.To that end,coal samples of various particle sizes were obtained from five coal seams(Nos.6,8,9,12 and 20)in the Shuangyashan City Xin’an Coal Mine.The samples were then respectively heated using a temperature programming system to observe and compare similarities and differences in the sponta-neous combustion process of different particle sizes in response to rising temperature.The experimental results show,that in all five coal seams,the concentration of CO,C_(2)H_(4),and C_(2)H_(6) increased with a certain degree of regularity as a function of rising temperature.However,of these three gasses,only CO and C_(2)H_(4) can be used as indicators to predict coal mine spontaneous combustion.The critical temperature for samples from all five coal seams ranged from 50–85℃,while the dry cracking temperature of coal seams 8 and 12(80–100℃)were lower than those of 6,9,and 20(100–120℃).Furthermore,the production rate of CO,C_(2)H_(4),and C_(2)H_(6) is related to both coal particle size and temperature.The smaller the particle size,the faster the production rate;and the higher the temperature,the more gas that gets produced.All five coal seems are mainly com-posed of long flame coal.However,they differ in that the No.12 coal seam contains weak cohesive coal;the No.8 coal seam contains lean and gas coal;and the Nos.6,9,and 20 coal seams contain a certain amount of anthracite.During the programmed coal heating,the CO,C_(2)H_(4),and C_(2)H_(6) release trend for the coal seams was No.12>No.8>Nos.6,9,and 20.These results demonstrate that the presence of weak cohesive coal and anthracite highly influence the concentration of CO,C_(2)H_(4),and C_(2)H_(6) released during coal spontaneous combustion.

A rapid analysis of coal with furnace under controlled multiple temperature areas

A novel thermogravimetric analyzer system of furnace with multiple temperature controller was described,which mainly decreased the analysis cycle duration down to 20 min.Furthermore,the present C591 rapid analyzer system under software can monitor and control some coal physical and chemical properties like change of coal,control com- bustion regulation,operation of coal mixture,and improvement of the turnover rate of the transportation facilities as well.

Coal petrology,sedimentology and depositional environment of the Parvadeh coais in the Upper Triassic,Tabas Block of Central-East Iran

Peat forming environment strongly influences the economic value of any coal seam and coal-bearing strata.Hence,pal-aeoenvironmental studies provide important information for coal resource exploration.In this context,detailed studies on selected coals from the Parvadeh Area,Iran,were conducted using sedimentology,coal petrology,X-ray diffraction(XRD),scanning electron microscopy-energy dispersive X-ray analyzer(SEM-EDX),and proximate analysis.The sedi-mentary facies above and below the coal seams are mainly marine or marine-influenced facies,supporting that the coal-forming mires in the Parvadeh Area developed in a paralic environment,where the base level must be closely related to sea level.Sulfur contents are moderate to high and mark the influence of brackish/marine water,especially during transgres-sion after peat growth in a lower delta plain environment.The peat-forming mires extended on coastal/delta plain lobes.The lower delta plain/coastal plain coals are characterized by lateral continuity and substantial thickness,whereas few coals possibly representing the upper delta plain are thin and more discontinuous.The detrital nature and composition of the numerous partings and the overall high ash yield in the coal seams indicate an active tectonic area with high rates of creation of accommodation space over peat growth.Coal petrology and coal facies analysis exhibits a permanently high water table within a forest swamp and mostly rheotrophic conditions,sometimes with connection to the seawater.Accord-ing to paleoenvironmental reconstructions,it seems that coal layers may be thicker,with less sulfur(pyrite),but more clastic minerals and partings toward the western part of the area.Although these coal seams presently have low economic potential for the mining operation,partly due to great depth,this humic,high-volatile to medium-volatile bituminous coal may be suitable for exploration of coal bed methane resources.

Analysis of Contradiction Between Coal and Power Industry

At the beginning of 2008, the Central, East and South China suffered a rare snow and ice disaster. After the disaster, power generation and power grid enterprises faced a big problem of power coal supply.

APPLICATION OF THERMAL ANALYSIS TO THE QUICK DETERMINATION OF THE PROXIMATE ANALYSIS ITEMS AND CALORIC VALUE FOR COAL

A research on the application of a TG-DTA(thermal gravimetry aifferential thermal analysis)to the quick determination of moisture,organic volatile fixed carbon,ash and caloric value for coal is described.

Ultrasonic vibrations and coal permeability: Laboratory experimental investigations and numerical simulations

Ultrasonic vibrations in coal lead to cavitation bubble oscillation, growth, shrinkage, and collapse, and the strong vibration of cavitation bubbles not only makes coal pores break and cracks propagate, but plays an important role in enhancing the permeability of coal. In this paper, the influence of ultrasonic cavitation on coal and the effects of the sonic waves on crack generation, propagation, connection, as well as the effect of cracks on the coal permeability, are studied. The experimental results show that cracks in coal are generated even connected rapidly after ultrasonic cavitation. Under the effect of ultrasonic cavitation,the permeability increases between 30% and 60%, and the number of cracks in coal also significantly increased. Numerical experiments show that the effective sound pressure is beneficial to fracture propagation and connection, and it is closely related to the permeability. Moreover, the numerical simulations and physical experiments provide a guide for the coal permeability improvement.

Pico–nano bubble column flotation using static mixer-venturi tube for Pittsburgh No.8 coal seam

The flotation process is a particle-hydrophobic surface-based separation technique. To improve the essential flotation steps of collision and attachment probabilities, and reduce the step of detachment probabilities between air bubbles and hydrophobic particles, a selectively designed cavitation venturi tube combined with a static mixer can be used to generate very high numbers of pico and nano bubbles in a flotation column. Fully embraced by those high numbers of tiny bubbles, hydrophobic particles readily attract the tiny bubbles to their surfaces. The results of column flotation of Pittsburgh No. 8 seam coal are obtained in a 5.08 cm ID and 162 cm height flotation column equipped with a static mixer and cavitation venturi tube, using kerosene as collector and MIBC as frother. Design of the experimental procedure is combined with a statistical two-stepwise analysis to determine the optimal operating conditions for maximum recovery at a specified grade. The effect of independent variables on the responses has been explained. Combustible material recovery of 85–90% at clean coal product of 10–11% ash is obtained from feed of 29.6% ash, with a much-reduced amount of frother and collector than that used in conventional column flotation. The column flotation process utilizing pico and nano bubbles can also be extended to the lower limit and upper limit of particle size ranges, minus 75 lm and 300–600 lm, respectively, for better recovery.

Parameters analysis of shearer drum loading performance

Three drums with different helical angles （15°, 20°, and 25°） were developed to investigate improved loading performance of the shearer drum. Nine trials were performed at different drum rotation speeds （80, 100, and 120 r/min） and different haulage speeds （1.5, 2.0, and 2.5 m/min） in an orthogonal test design. Loaded coal quantity and cutting power of the drum were the responses measured under the dif- ferent conditions. The effect of the parameters was determined by means of the extreme difference method. The significance of the effects was determined by analysis of variance. The results indicate that the effect from changes in the helical vane on loading performance of the drum is the largest in magnitude. The haulage speed has the least affect on loading performance. The helical angle has the least affect on cutting power of the drum. Haulage speed has the largest affect on the cutting power of the drum. 2011 Published by Elsevier B.V. on behalf of China University of Mining ＆ Technology.

Gas diffusion in a cylindrical coal sample – A general solution,approximation and error analyses

The analytical mathematical solutions of gas concentration and fractional gas loss for the diffusion of gas in a cylindrical coal sample were given with detailed mathematical derivations by assuming that the diffusion of gas through the coal matrix is concentration gradient-driven and obeys the Fick’s Second Law of Diffusion.The analytical solutions were approximated in case of small values of time and the error analyses associated with the approximation were also undertaken.The results indicate that the square root relationship of gas release in the early stage of desorption,which is widely used to provide a simple and fast estimation of the lost gas,is the first term of the approximation,and care must be taken in using the square root relationship as a significant error might be introduced with increase in the lost time and decrease in effective diameter of a cylindrical coal sample.

Coal pillar mechanics of violent failure in U.S. Mines

This paper seeks to enhance the understanding that the horizontal stresses build up and release during coal pillar loading and unloading(post-failure) drawing upon three decades of observations, geomechanical monitoring and numerical modeling in bump-prone U.S. mines. The focus is on induced horizontal stress in mine pillars and surrounding strata as highly stressed pillars punch into the roof and floor, causing shear failure and buckling of strata; under stiff stratigraphic units of some western US mines, these events could be accompanied by violent failure of pillar cores. Pillar punching eventually results in tensile stresses at the base of the pillar, facilitating transition into the post-failure regime; this transition will be nonviolent if certain conditions are met, notably the presence of interbedded mudstones with low shear strength properties and proper mine designs for controlling seismicity and dynamic loads. The study clearly shows high confining stress build-up in coal pillars resulting in up to twice higher peak vertical stress and high strain energy accumulations in some western US mines in comparison with peak stresses predicted using common empirical pillar design methods. It is the unstable release of this strain energy that can cause significant damage resulting from pillar dilation and ground movements. These forces are much greater than the capacity of most common internal support systems, resulting in horizontal stressinduced roof falls locally, in mines under unremarkable far-field horizontal stress. Attention should be placed on pillar designs as increasing support density may prove to be ineffective. This mechanism is analyzed using field measurements and generic finite-difference stress analyses. The study confirms the higher load carrying capacity of confinement-controlled coal seams in comparison with structurally controlled coal seams. Such significant differences in confining stresses are not taken into account when estimating peak pillar strength using most common empirical techniques such as those proposed by Bieniawski and Salamon. While using lower pillar strength estimates may be considered conservative,it underestimates the actual capacity of pillars in accumulating much higher stress and strain energies,misleading the designer and inadvertently diminishing mine safety. The role of induced horizontal stress in mine pillars and surrounding strata is emphasized in coal pillar mechanics of violent failure. The triggering mechanism for the violent events is sudden loss of pillar confinement due to dynamic loading resulting from failure of overlying stiff and strong strata. Evidence of such mechanism is noted in the field by observed red-dust at the coal-rock interfaces at the location of coal bumps and irregular, periodic caving in room-and-pillar mines quantified through direct pressure measurements in the gob.

An analytic solution describing the visco-elastic deformation of coal pillars in room and pillar mine

Coal pillar deformation is typically nonlinear and time-dependent. The accurate prediction of this defor- mation has a vital importance for the successful implementation of mining techniques. These methods have proven very important as a way to excavate coal resources from under buildings, railways, or water bodies. Elastic and visco-elastic theory are employed with a Maxwell model to formulate an analytic solution for displacement of coal pillars in room and pillar mine. These results show that the visco-elastic solution adequately predicts the coal pillar deformation over time. We conclude that the visco-elastic solution can predict the coal pillar and roadway displacement from the measured geological parameters of the conditions in situ. Furthermore, this method would be useful for mine design, coal pillar support optimization, ground subsidence prediction, and coal pillar stability analysis.

Separation of arenols from a high-temperature coal tar

A high-temperature coal tar collected from Xuzhou Coking Plant, Saint-Gobain Pipelines （Xuzhou） Co., Ltd. was exhaustively extracted with petroleum ether （PE）. The extract was sequentially eluted through silica gel with PE and PE/ethyl acetate （EA） mixed solvents （volume ratio 2：1 ） to afford two eluted frac- tions. The extract and eluted fractions were analyzed with gas chromatography/mass spectrometry. In total, 14 arenols were detected, including phenol, cresols, xylenols, fluorenols, phenanthren-3-ol and pyren-l-ol.

Applicable conditions for a classification system of aquifer-protective mining in hallow coal seams

Based on the conclusions of domestic and foreign research, we have analyzed the collapse-fall characteristics of overlying strata and the mechanism of aquifer-protective mining in shallow coal seam working faces at the Shendong Mine. We have selected the height of the water-conducting fracture zone in overlying strata as a composite index and established the applicable conditions of aquifer-protective mining in shallow coal seams with a multi-factor synthetic-index classification method. From our calculations and analyses of variance, we used factors such as the overlying strata strength, mining disturbing factors and rock integrity as related factors of the composite index. We have classified the applicable conditions of aquifer-protective mining in shallow coal seams into seven types by comparing the result of the height of water-conducting fractured zones of long-wall and short-wall working faces with the thickness of the bedrock, the thickness of the weathered zone and the size of safety coal-rock pillars. As a result, we propose the preliminary classification system of aquifer-protective mining in shallow coal seams. It can provide a theoretical guidance for safe applications of aquifer-protective mining technology in shallow coal seams under similar conditions.

One-piece coal mine mobile refuge chamber with safety structure and less sealing risk based on FEA

In order to reduce the risk of sealing and improve the structural strength for a coal mine mobile refuge chamber,a new type of one-piece model was designed.Mechanical and mathematical calculation performed an important role.Calculated according to statics and relevant contents,the structure had the same total volume as the traditional segmented structure,but had shorter length,wider width and greater height.Those prevented the structure from stress or deformation failure.Some reinforcing ribs with enough moments of inertia were welded in the external shell.Because of the one-piece structure,this refuge chamber reduced the risk of sealing which was a serious problem of segmented structure.Impact load with 300 ms duration and0.6 MPa over-pressure was settled.Explicit nonlinear dynamic analysis program was used to simulate the response of the refuge chamber.The maximum stress and the maximum displacement were obtained.The refuge chamber including blast airtight doors could meet the rigidity requirement.Weak parts of the chamber were the front and back end shell where bigger displacement values occurred than others.Thus,the calculation indicated that the refuge chamber could meet structural safety requirements.Based on the numerical analysis,suggestions were put forward for further resistance ability improvement.Only large inclined shaft with larger wellhead was suitable for this one-piece coal mine mobile refuge chamber.

An experiment-library least-squares method on on-line coal element contents analysis

A new experiment-library least-squares(experiment-LLs) method used in the neutron inelastic-scattering and thermal-capture analysis(NITA) technique for on-line coal analysis was developed,which has significantly decreased the non-linear radiation effects.In this method,sixty samples with preset elemental contents were made,from whose experimental spectra twenty single-element spectrum libraries corresponding to twenty kinds of coal were built using the least-squares method.The spectrum of the unknown sample was analyzed based on these twenty libraries to estimate its element contents.With the initial estimated result,the procedure of developing library and analysis was iterated to build a new library with the closest element contents to the unknown sample.Hence the experiment-LLs method can reduce non-linear radiation effects.The experiment-LLs method was performed on an improved coal analysis system which was equipped with a long-life 14 MeV pulsed-neutron generator,a bulk BGO detector with a temperature controller,a moisture meter and coal-smoothing device.The precisions of this system for ash content,water content,volatile content and calorific value have reached 1.0wt%,0.5wt%,1.0wt%,350 kJ/kg,respectively.