Study on the Evaporation Kinetics of Zinc and Lead in Zn-Pb-Bearing Dust Pellets Mixed with Coal Powder

The study on the evaporation kinetics of zinc and lead in the pellets made of ZnPbbearing dust mixed with carbon ,in nitrogen atmosphere at the temperature range between 1 100 and 1 300 , shows that the reduction temperature has a significant effect on the evaporation rates of zinc and lead and that both the particle size of coal powder and the extra carbon content have no effect on the evaporation rates . The obtained activation energies for the evaporation of zinc and lead are 7942 kJ/mol and 8874kJ/mol respectively. The evaporation rate of zinc is controlled by the reaction between zinc oxide and CO while that of lead is controlled by lead volatilization and the diffusion of gaseous lead through gas boundary layer covering the surface of liquid lead.

Adsorption Behavior of Methyl Orange onto Modified Ultrafine Coal Powder

甲基橘子的吸附被学习到极其细小的煤粉末(UCP ) 和从水的答案的修改的极其细小的煤粉末(MUCP ) 上，在哪个接触时间，剂量，温度， pH，和甲基橘子的影响在答案的集中被调查。由 UCP 和 MUCP 的甲基橘子的吸附动力学能被 Lagergren 一阶、假的秒顺序描述运动模型分别地。甲基橘子的吸附等温线跟随 Freundlich 和兰米尔等温线方程到在 303， 313 和 323 K 的 MUCP 上。Δ 的价值；为甲基橘子吸附的 G 0 是 − 到 MUCP 上； 22.55， −； 23.10 并且 −； 23.79 kJ·；在 303， 313，和 323 K 的摩尔 −1 分别地。Δ 的价值； H 0 和 Δ； S 0 是 −； 3.74 kJ·；摩尔 −1 和 61.99 J·；摩尔 −1, 分别地。吸附过程自发、发热。

Reduction of Pyrite Cinder Pellets Mixed with Coal Powder

Direct reduction of pyrite cinder in a rotary hearth furnace （RHF） was studied under the condition of labo ratory simulation. Effects of reduction temperature, reduction time, molar ratio of carbon to oxygen, .and CaO addition on metallization rate as well as compressive strength of the pellets after reduction were discussed. The results showed that the metallization rate and compressive strength were 93.9% and 2 160 N per pellet respectively under the conditions of the reduction temperature of 1 200 ℃, the reduction time of 16 min, and the molar ratio of carbon to oxygen （xc/xo） of 1. 0; adding 2.5% CaO was beneficial to sulfur enrichment in slag phase of pellet, and metal- lization rate increased slightly while compressive strength decreased.

Combustion Characteristics of Polyethylene and Coal Powder at High Temperature

To study the combustion characteristics of the polyethylene（PE）particle and coal powder at blast temperature of the blast furnace,the contents of CO and CO2 of off-gas during the combustion of PE particle and coal powder at the 1 200 ℃ and 1 250 ℃ were measured using carbon monoxide and carbon dioxide infrared analyzer,and then the corresponding combustion ratio was calculated.The results showed that when the temperature is high,the combustion speed of PE and coal powder is high and the corresponding combustion ratio is high.Whereas,the combustion speed and ratio of PE are much higher than those of coal powder.

Fundamental research on the size and velocity measurements of coal powder by trajectory imaging

A trajectory imaging based method for measuring the velocity and diameter of coal particles was presented.By using an industrial charge-coupled device(CCD)camera and a low power semiconductor laser,the images of coal particles under relatively long exposure time were recorded and then processed to yield both the velocities and sizes.Fundamental research on this method with special attention to recording parameters,e.g.,magnification factor and exposure time,was carried out.For most of the test cases,the results agree with those obtained by particle image velocimetry(PIV)and shadow imaging method.Measurements with good accuracy can be obtained when the imaging magnification factor and exposure time are set appropriately,making N be larger than 3.5,and R between 5-7,where N and R are the number of pixels occupied by the average width and the ratio of length to width of particle trajectory on the image,respectively.The work indicates the feasibility and potential application of the present measurement method for online measurement of coal powder in pipes in industrial power plants.

Thermal oxidation of SiAlON powders synthesized from coal gangue

The oxidation behavior of different SiAlON phases（β-SiAlON,X-phase SiAlON and 12H powders） synthesized from coal gangue in air atmosphere was investigated using isothermal thermogravimetry（TG） and field-emission scanning electron microscopy（FE-SEM）.The effect of ferric oxide impurities in coal gangue was studied.The results show that ferric oxide contributes to the growth of SiAlON crystalline during the synthesis process.In the oxidation experiment,the existence of ferric oxide decreases the oxidation resistance of SiAlON.The reason is that the impurity causes the formation of a liquid phase at a higher temperature.At 1423-1623 K,the oxidation of SiAlON powders is diffusion controlled and it can be described by Chou＇s model.A fair agreement is found between theoretical calculations and the experimental data.

Purification process of coal-based coke powder as anode for Li-ion batteries

A process of purification of coal-based coke powder as anode for Li-ion batteries was attempted. The process started with the treatment of coke powder with dilute hydrofluoric acid solution, followed by united-acid-leaching using sulfuric acid and hydrochloric acid. The effects of altering the hydrofluoric acid addition, hydrofluoric acid concentration, contact time, temperature and acid type were investigated. A minimum ash content of 0.35% was obtained when proper conditions were applied. The electrochemical performance of purified coke powder shows greatly improved electrochemical performance. The as-purified coke powder presented an initial reversible capacity of 257.4 mAh/g and a retention rate of 95% after 50 cycles. The proposed purification process paves a way to prepare a promising anode material with good performance with low cost of coke powder for Li-ion batteries.

Study on Inorganic Flocculant Prepared from Powdered Coal Ashes

The feasibility of preparing flocculant from powdered coal ashes is studied in detail. By means of orthogonal tests, the influence of various factors, such as the activation temperature, the activation time, the ratio of CaO to Al2O3, the hydrochloric acid concentration, the reaction time and the reaction temperature, on preparation is investigated, and the hest operating condition is determined.

Carbothermal Reduction Synthesis of Al_2O_3-SiC Powders from Coal Gangue

The Al2O3 -SiC composite powders were prepared in argon atmosphere rising coal gangue and carbonaceous materials （ carbon black, active carbon and antbravite） as starting materials by carbothermal reduction. Effects of excessive carbon addition, carbon types. temperature, soaking time. shaping pressure, types and amount of additives on phase composition and micro-structure of the Al2O3 - SiC composite powders were investigated. The re.suits indicate that： temperature, soaking time and chloride additi＇ve have significant influence on the synthesized Al2O3 -SiC composite powders. Based on the results, the optimized Al2O3 -SiC composite powders , Al2O3 58 mass% and SiC 42 mass%, with particle size d50 ≤5μm were prepared using coal gangue and carbon black as starting materials after 3 h firing at 1550 ℃. and proper additive addition could reduce the temperattlre by 50 ℃.

STUDY ON THE FUNCTION OF REINFORCED RUBBER OF MODIFIED POWDERED COAL ASH

The powdered coal ash (PCA) was classified, then the ash particle (- 45μm) was modified by a surface active agent and obtained modified powder coal ash (MPCA). The character of the MPC was investigated, when it was used as a new type reinforced filler of rubber.The results show that MPCA can replace or party replace carbon black or silica as reinforced fillers of rubbers.

Study on the removal of Hg^0 from flue gas by coal dry powder gasification coarse slag

The prevention and treatment of mercury in coal-fired power plants has always been the focus and difficulty.How to control the pollution of mercury to human body and ecological environment quickly and effectively is a hot research topic nowadays.As a low cost and potential adsorbent,there is a huge space for the development of coal dry powder gasification coarse slag.In this paper,Mercury osmotic tubes are heated by water bath tank as mercury source,and the scavenging effect of adsorbent on Mercury monomer under different influence conditions is explored.The adsorbent plays an important role in adsorption of mercury monomer because of its special active sites on the surface.The reason is that the adsorbent surface is rich in carboxyl group,hydroxyl functional group,combined with mercury to form complexes.This shows that chemical adsorption facilitates the adsorption process.

未燃煤粉对高炉炉渣流动性的影响

高炉喷吹煤粉技术是降低炼铁生产成本、优化高炉操作的主要技术手段,在高喷煤比条件下未能在风口回旋区燃尽的残炭颗粒以未燃煤粉形式进入料柱,过多的未燃煤粉会对炉渣性能产生不利影响。为了研究未燃煤粉对高炉炉渣流动性的影响,通过X射线衍射分析、扫描电子显微镜和能谱分析仪等分析手段研究了未燃煤粉在炉渣中的存在状态及对炉渣性能的影响。结果表明,未燃煤粉颗粒呈均匀状分布于炉渣中,添加未燃煤粉前后炉渣黏度与温度的关系均满足阿伦尼乌斯方程,并且黏度值随着温度降低均呈现出增大趋势。随着未燃煤粉固体颗粒质量分数增加,炉渣黏度呈线性增大趋势,并且炉渣中未燃煤粉含量越多,转速对非均相熔体黏度的影响越明显。

旋转爆轰发动机内煤粉-氢气两相爆轰流场数值研究

旋转爆轰发动机因其较高的热循环效率在航空航天领域备受关注。为了研究气固混合燃料在空气氛围中的旋转爆轰特性,在圆柱坐标系中建立了气固混合相燃料爆轰理论模型,并基于三维守恒元与求解元方法,对圆盘形燃烧室内的爆轰过程进行三维数值模拟。计算获得了气固混合相旋转爆轰波稳定传播时的流场结构,分析了爆轰流场的热力学参数分布特征、化学反应区分布以及旋转爆轰波后的波系分布特点。研究结果表明,微米级煤粉在氢气辅助作用下可快速反应并支持旋转爆轰波的稳定传播,但因盘形燃烧室的扁平结构特征和非预混喷注方式,导致爆轰波波阵面呈现为不规则的曲面。煤粉和氢气射流穿透空气层的能力差异导致气固混合燃料的化学反应区发生分离,最终以双反应区的爆轰组织形式支持旋转爆轰波稳定传播。旋转爆轰波不规则的曲面结构使其在扁平的燃烧室中发生多次反射,进而在爆轰波后有规律地出现多道反射激波。

矸石基混凝土轴心受压声发射特性与损伤本构模型

为研究不同水泥取代率、不同水胶比下矸石基混凝土轴心受压时的力学性能,及推广应用矸石基混凝土这一绿色建筑材料,通过轴心受压试验和声发射试验,研究了轴心受压时不同煤矸石粉掺量、不同水胶比下矸石基混凝土的应力-应变曲线、声发射振铃计数和声发射累积能量随煤矸石粉掺量和水胶比的变化规律,提出了矸石基混凝土轴心受压时的本构关系。结果表明:相比普通混凝土,矸石基混凝土的力学性能有一定程度的改善,主要表现为其峰值应力和峰值应变增加;矸石基混凝土轴心受压应力-应变全曲线与普通混凝土基本一致,煤矸石粉掺量为20%时峰值应力达到最大值;声发射振铃计数可以有效描述矸石基混凝土的损伤演化规律,随着煤矸石粉取代率的增大,振铃计数先减少后增加。考虑煤矸石粉和水胶比对矸石基混凝土轴心受压时的影响,提出了具有较高精度的矸石基混凝土轴心受压本构关系,这为矸石基混凝土力学性能的进一步研究提供了参考,也对推广应用的结构计算有一定参考价值。

粉煤成型过程的数值模拟

为明确摩擦系数和成型压力对煤粉成型过程的影响,利用MSC.Marc软件定量化分析了粉煤在成型过程中非均质变化的特点,获得成型过程中的应力、密度和位移等分布参数。结果显示,随着摩擦系数的增加,最大位移逐渐变小,相对密度的均匀性减小,最大应力由6.013 MPa急剧增长到71.22MPa,极易导致型煤发生开裂。随着成型压力的增加,最大位移不断增加,相对密度略有增加,而最大应力却呈现急剧增长的趋势。因此,煤粉成型过程中应适当降低摩擦系数且不可盲目增加成型压力。

三元矿物掺和料胶砂试件性能研究

为解决煤矸石及钢渣作为单一掺和料强度不足的问题,以煤矸石、钢渣和矿粉为原材料制备复合掺和料水泥砂浆。研究不同配合比下掺和料对水泥砂浆抗压强度的影响,并利用X射线衍射(XRD)、热重-差热分析(TG-DTA)、扫描电镜(SEM)等手段分析不同体系试块的水化机理和微观结构。结果表明,单掺煤矸石、钢渣均表现出较低的活性,而矿粉具有良好的反应活性;三元掺和料中煤矸石-矿粉-钢渣复掺比例为1∶7∶2时,试块的抗压强度最高,28 d抗压强度可以达55.26 MPa。在三元掺和料体系中,煤矸石、矿粉和钢渣可以相互促进水化,增多水化产物,加深水化程度,三者具有一定的耦合作用,具有制备三元矿物掺和料的潜力。