A CFD Model to Evaluate Near-Surface Oil Spill from a Broken Loading Pipe in Shallow Coastal Waters

Oil spills continue to generate various issues and concerns regarding their effect and behavior in the marine environment,owing to the related potential for detrimental environmental,economic and social implications.It is essential to have a solid understanding of the ways in which oil interacts with the water and the coastal ecosystems that are located nearby.This study proposes a simplified model for predicting the plume-like transport behavior of heavy Bunker C fuel oil discharging downward from an acutely-angled broken pipeline located on the water surface.The results show that the spill overall profile is articulated in three major flow areas.The first,is the source field,i.e.,a region near the origin of the initial jet,followed by the intermediate or transport field,namely,the region where the jet oil flow transitions into an underwater oil plume flow and starts to move horizontally,and finally,the far-field,where the oil re-surface and spreads onto the shore at a significant distance from the spill site.The behavior of the oil in the intermediate field is investigated using a simplified injection-type oil spill model capable of mimicking the undersea trapping and lateral migration of an oil plume originating from a negatively buoyant jet spill.A rectangular domain with proper boundary conditions is used to implement the model.The Projection approach is used to discretize a modified version of the Navier-Stokes equations in two dimensions.A benchmark fluid flow issue is used to verify the model and the results indicate a reasonable relationship between specific gravity and depth as well as agreement with the aerial data and a vertical temperature profile plot.

First record of abnormal body coloration in a rockfish Sebastes koreanus(Scorpaenoidei:Sebastidae)from coastal water of China based on morphological characteristics and DNA barcoding

The first record of abnormal body coloration in Sebastes koreanus Kim and Lee,1994,from the Yellow Sea of China,was documented based on morphological characteristics and DNA barcoding.The two rockfish specimens were collected from the coastal waters of Qingdao,China,and the whole body and all fins of them were red.Of the two red-colored rockfish,there were tiny deep red spots on each fin,2 red radial stripes behind and below the eyes and 1 large deep red blotch on the opercula,while the similar stripe and spot patterns are also present in the S.koreanus specimens with normal body coloration.The countable characteristics of the two specimens are in the range of the morphometry of S.koreanus.To further clarify the species identity and taxonomic status of the two specimens,DNA barcode analysis was carried out.The genetic distance between the red-colored rockfish and S.koreanus was 0,and the minimum net genetic distances between the red-colored rockfish and other Sebastes species except for S.koreanus were 3.0%,which exceeds the threshold of species delimitation.The phylogenetic analysis showed that the DNA barcoding sequences of the two red-colored rockfish clustered with the S.koreanus sequences.The above results of DNA barcode analysis also support that the two red-colored rockfish could be identified as the species of S.koreanus.The mechanism of color variation in S.koreanus is desirable for further research and the species could be an ideal model to study the color-driven speciation of the rockfishes.

DNA barcoding of fishes from Zhoushan coastal waters using mitochondrial COI and 12S rRNA genes

Accurate species identification is a key component of biodiversity research.DNA barcoding is an effective molecular method used for fish species identification.We aimed to study the DNA barcoding of fish in Zhoushan coastal waters,explore the differences and applicability of two gene fragments(12S rRNA and COI)of DNA barcoding in fish species identification,and established a comprehensive fish barcoding reference database.Two hundred and eighty-seven captured fish samples from Zhoushan coastal waters were identified using morphological characteristics and DNA barcoding.A total of 26412S rRNA sequences(belonging to eight orders,31 families,55 genera,and 66 species)and 188 COI sequences(belonging to seven orders,30 families,48 genera,and 58 species)were obtained.The lengths of the 12S rRNA sequences ranged from 165 to 178 bp,and the guanine-cytosine(GC)content was 45.37%.The average 12S rRNA interspecific and intraspecific genetic distances(K2P)were 0.10%and 26.66%,respectively.The length of the COI sequence ranged 574–655 bp,and the content of GC was 45.97%.The average 12S rRNA interspecific and intraspecific genetic distances(K2P)were 0.16%and 27.45%,respectively.The minimum interspecific genetic distances of 12S rRNA and COI(1.23%and 1.86%)were both greater than their maximum intraspecific genetic distances(2.42%and 8.66%).Three molecular analyses(NJ tree,ABGD,and GMYC)were performed to accurately identify and delineate species.Clustering errors occurred when the 12S rRNA sequences were delimited using the NJ tree method,and the delimitation results of ABGD and GMYC are consistent with the final species identification results.Our results demonstrate that DNA barcoding based on 12S rRNA and COI can be used as an effective tool for fish species identification,and 12S rRNA has good application prospects in the environmental DNA(eDNA)metabarcoding of marine fish.

An Assessment of Saltwater Intrusion in Coastal Regions of Lagos, Nigeria

This paper explains various factors that contribute to saltwater intrusion, including overexploitation of freshwater resources and climate change as well as the different techniques essential for effective saltwater intrusion management. The impact of saltwater intrusion along coastal regions and its impact on the environment, hydrogeology and groundwater contamination. It suggests potential solutions to mitigate the impact of saltwater intrusion, including effective water management and techniques for managing SWI. The application of A.I (assessment index) serves as a guideline to correctly identify wells with SWI ranging from no intrusion, slight intrusion and strong intrusion. The challenges of saltwater intrusion in Lagos and the salinization of wells were investigated using the hydro-chemical parameters. The study identifies four wells (“AA”, “CMS”, “OBA” and “VIL”) as having high electric conductivities, indicating saline water intrusion, while other wells (“EBM”, “IKJ, and “IKO”) with lower electric conductivities, indicate little or no salt-water intrusion, and “AJ” well shows slight intrusion. The elevation of the wells also played a vital role in the SWI across coastal regions of Lagos. The study recommends continuous monitoring of coastal wells to help sustain and reduce saline intrusion. The findings of the study are important for policymakers, researchers, and practitioners who are interested in addressing the challenges of saltwater intrusion along coastal regions. We assessed the SWI across the eight (8) wells using the Assessment Index to identify wells with SWI. Wells in “CMS” and “VIL” has strong intrusions. A proposed classification system based on specific ion ratios categorizes water quality from good (+) to highly (-) contaminated (refer to Table 4). These findings underscore the need for attention and effective management strategies to address groundwater unsuitability for various purposes.

A Regional Ocean Reanalysis System for Coastal Waters of China and Adjacent Seas

A regional ocean reanalysis system for the coastal waters of China and adjacent seas has been developed by the National Marine Data and Information Service（NMDIS）.It produces a dataset package called CORA （China ocean reanalysis）.The regional ocean model used is based on the Princeton Ocean Model with a generalized coordinate system（POMgcs）.The model is parallelized by NMDIS with the addition of the wave breaking and tidal mixing processes into model parameterizations.Data assimilation is a sequential three-dimensional variational（3D-Var） scheme implemented within a multigrid framework.Observations include satellite remote sensing sea surface temperature（SST）,altimetry sea level anomaly（SLA）,and temperature/salinity profiles.The reanalysis fields of sea surface height,temperature,salinity,and currents begin with January 1986 and are currently updated every year. Error statistics and error distributions of temperature,salinity and currents are presented as a primary evaluation of the reanalysis fields using sea level data from tidal gauges,temperature profiles,as well as the trajectories of Argo floats.Some case studies offer the opportunity to verify the evolution of certain local circulations.These evaluations show that the reanalysis data produced provide a good representation of the ocean processes and phenomena in the coastal waters of China and adjacent seas.

Three-Dimensional Tidal Model and Its Application to Numerical Simulation of Water Quality in Coastal Waters

The turbulence mechanism plays an important part in the mixing process and momentum transfer of turbulence. A three-dimensional Prandtl mixing length tidal model has been developed to simulate tidal flows and water quality. The eddy viscosities and diffusivities are computed from the Prandtl mixing length model. In order to model the water quality of an estuary or coastal area many interdependent processes need to be simulated. These may be conveniently separated into three main groups: transport and mixing processes, biochemical interaction of water quality variables and the utilization and re-cycling of nutrients by living matter. The model simulates full oxygen and nutrient balance, primary productivity and the transport, reaction mechanism and fate of pollutants over tidal time-scales. The model is applied to numerical simulation of tidal flows and water quality in Dalian Bay. The model has been calibrated against a limited data set of historical water quality observations and in general demonstrates excellent agreement with all available data.

A three-dimensional prediction system for water quality polluction in coastal waters

The hydrodynamics and water quality in Hakata Bay, Japan are strongly affected by the seasonal variations in both the gravitational circulation and the stratification in the bay. The three\|dimensional hydrodynamics and water quality model has been developed to simulate the long\|term transport and fate of pollutants in the system. The model is unique in that it completely integrates the refined modelling of the hydrodynamics, biochemical reactions and the ecosystem in the coastal waters. It is a 3\|dimensional segmented model which is capable of resolving mean daily variations in all the parameters relevant to pollution control. It predicts daily fluctuations in the oxygen content at different depths in water throughout the year. It takes into account transport and settling of pollutant particles. It predicts light penetration from computed turbidity variations. It includes interactions between the ecosystem and water quality through nutrient cycling and photosynthesis. The model has been calibrated well against the data set of historical water quality observations in Hakata Bay.

Detection of 36 antibiotics in coastal waters using high performance liquid chromatography-tandem mass spectrometry

Among pharmaceuticals and personal care products released into the aquatic environment, antibiotics are of particular concern, because of their ubiquity and health effects. Although scientists have recently paid more attention to the threat of antibiotics to coastal ecosystems, researchers have often focused on relatively few antibiotics, because of the absence of suitable analytical methods. We have therefore developed a method for the rapid detection of 36 antibiotic residues in coastal waters, including tetracyclines （TCs）, sulfanilamides （SAs）, and quinolones （QLs）. The method consists of solid-phase extraction （SPE） and liquid chromatography-tandem mass spectrometry （LC-MS/MS） analysis, using electrospray ionization （ESI） in positive mode. The SPE was performed with Oasis HLB and Oasis MCX cartridges. Chromatographic separation on a Cr8 column was achieved using a binary eluent containing methanol and water with 0.1% formic acid. Typical recoveries of the analytes ranged from 67.4% to 109.3% at a fortification level of 100 ng/L. The precision of the method, calculated as relative standard deviation （RSD）, was below 14.6% for all the compounds. The limits of detection （LODs） varied from 0.45 pg to 7.97 pg. The method was applied to detemaine the target analytes in coastal waters of the Yellow Sea in Liaoning, China. Among the tested antibiotics, 31 were found in coastal ＇waters, with their concentrations between the LOD and 212.5 ng/L. These data indicate that this method is valid for analysis of antibiotics in coastal waters. The study first reports such a large number of antibiotics along the Yellow Sea coast of Liaoning, and should facilitate future comprehensive evaluation of antibiotics in coastal ecosystems

Seasonal variations of phytoplankton diversity in the Coleroon coastal waters,southeast coast of India

The results of an investigation carried out during June 2005 to May 2007 on physico-chemical parameters,species composition and community structure of phytoplankton including Chlorophyll a（Chl-a） at the Coleroon coastal waters（Southeast coast of India） are reported.Air and surface water temperatures（℃） varied from 25.1 to 30.1 and from 24.5 to 28.5 respectively.Salinity values varied from 6 to 28.5 and the pH ranged between 7.0 and 8.3.Variation in dissolved oxygen content was from 3.1 to 7.5 mg/dm^3 while the light extinction coefficient values（LEC） ranged between 3.1 and 10.1 cm.The ranges of inorganic nutrients（μmol/dm^3） viz.,nitrate,nitrite,phosphate and silicate were 10.1-23.4,1.2-8.9,0.2-3.1 and 55-125,respectively.The ranges of Chlorophyll a（μg/dm-3） values was 2.0-7.5.Presently,124 phytoplankton species representing different classes viz：Bacillariophyceae（77）,Dinophyceae（19）,Cyanophyceae（15）,Chlorophyceae（10） and Chrysophyceae（3） were recorded.The phytoplankton cell abundance varied from 0.290 to 111.662 cells/cm-3,with peak diversity（3.38 bits/ind.） during summer season.The maximum abundance was found during summer season coinciding with the stable hydrographical conditions.The seasonal distribution and abundance of phytoplankton are discussed in relation to hydrographical parameters.Canonical Correspondence Analysis（CCA） was applied in this paper for discriminating environmental factors having effect on phytoplankton community at species level.Coleroon coastal water is subjected to long term fluctuations in physico-chemical parameters depending upon the seasonal tidal amplitude and freshwater influx resulting in a continuous exchange of organic,inorganic,plant and animal matters.

Assimilation of surface currents into a regional model over Qingdao coastal waters of China

Surface currents measured by high frequency （HF） radar arrays are assimilated into a regional ocean model over Qingdao coastal waters based on Kalman filter method. A series of numerical experiments are per- formed to evaluate the performance of the data assimilation schemes. In order to optimize the analysis pro- cedure in the traditional ensemble Kalman filter （ENKF）, a different analysis scheme called quasiensemble Kaman filter （QENKF） is proposed. The comparisons between the ENKF and the QENKF suggest that both them can improve the simulated error and the spatial structure. The estimations of the background error covariance （BEC） are also assessed by comparing three different methods： Monte Carlo method; Canadian quick covariance （CQC） method and data uncertainty engine （DUE） method. A significant reduction of the root-mean-square （RMS） errors between model results and the observations shows that the CQC method is able to better reproduce the error statistics for this coastal ocean model and the corresponding external forcing. In addition, the sensibility of the data assimilation system to the ensemble size is also analyzed by means of different scales of the ensemble size used in the experiments. It is found that given the balance of the computational cost and the forecasting accuracy, the ensemble size of 50 will be an appropriate choice in the Qingdao coastal waters.

Atmospheric Correction of SeaWiFS Data for the Retrieval of SuspendedSediment in East China Coastal Waters

The data of SeaWiFS (Sea-Viewing Wide Field-of-View Sensor), installed on SeaStar, has been used to generate SSC (suspended sediment concentration) of complex and turbid coastal waters in China. In view of the problems of the SeaDAS (SeaWiFS Data Analysis System) algorithm applied to China coastal waters, a new atmospheric correction algorithm is discussed, developed, and used for the SSC of East China coastal waters. The advantages of the new algorithm are described through the comparison of the results from different algorithms.

Eranno carrerai sp. nov., a new polychaete worm (Lumbrineridae) from coastal waters of China

In this paper, a new polychaete species, Eranno carrerai sp. nov. from coastal areas of China, is described based on specimens deposited in the Marine Biological Museum of the Chinese Academy of Sciences, Qingdao, collected during 1957 to 1976 from the Yellow Sea, East China Sea and South China Sea at depths of 9–210 m.

Occurrence and distribution of vibrios in fishes and shellfishes in coastal waters of Hong Kong

The summer occurrence and distribution of vibrios in the fishes and shellfishes in the coasal waters of Hong Kong were investigaed. A total of 69 strains of vibrios were isolated from all samples examined. The strains, along with 10 reference strains were classified with the technique of numerical taxonomy bared on 54 characters and 62 of the 69 strains fell into 5 major phena, identified as V. paraheamolyticus (30 strains), V. alginoloticus (23 strains), V. choloerae (3 strains), V. harveyi (2 strains) and V. fluinalis (4 strains). Among them, V.paraheamolyticus and V. alginolyticus were the predominant species in the fishes, shellfishes and the coastal waters of Hong Kong and comprised 43. 5 % and 33. 3 % of the total Vibrio spp. isolates respectively. Meanwhile, 3 strains of non-Ol V. cholerae were isolated from oyster and it was the first time to record V. cholerae non-Ol in seawater or from shellfishes in Hong Kong. These results highlighted the potential risks of food poisoning associated with raw or undercooked seafood.

Influence of Fouling Assemblage on the Corrosion Behaviour of Mild Steel in the Coastal Waters of The Gulf of Mannar, India

Corrosion behaviour and biofouling characteristics of mild steel in three different coastal locations in the Gulf of Mannar,India have been studied over a period of 24 months.Oyster fouling was predominant at Open sea-Tuticorin,while barnacle fouling was dominant at both Mandapam and Harbour-Tuticorin.The rate of corrosion for 24 months exposure period was highest at Mandapam,where fouling was minimal.The surface of the mild steel was characterized by etchings&crevices beneath the hard foulers attached on it,at all the test locations.The depth of crevice caused by hard foulers was higher at Open sea-Tuticorin followed by Harbour-Tuticorin and Mandapam.The loss in ultimate tensile strength was more in Open sea-Tuticorin than the other two locations.Corrosion behaviour of mild steel is discussed based on the variation in the biofouling assemblage at the three test locations.

Fouling community characteristics in subtropical coastal waters of the southwestern East China Sea

A fouling study was conducted in coastal waters southwest of the East China Sea between December 2013 and November 2014. A total of 84 species of fouling organisms belonging to 69 genera, 49 families, and 10 phyla were recorded over the entire year. The community composition was dominated by coastal warm-water species belonging to typical subtropical inner bay communities. The prosperous stage of settlement lasted from April to September, and the adhesion strength of the fouling organisms was the highest in summer. Sessile suspension feeders constituted the main core of settlement for the fouling community. Amphibalanus reticulatus was the most dominant and representative species of fouling organism, and other dominant species included Caprella equilibra, Ectopleura crocea, Anthopleura nigrescens, Stylochus ijimai, Spirobranchus kraussii, Crassostrea angulata, Perna viridis, Jassa falcata, Stenothoe valida, Sphaerozius nitidus, and Biflustra grandicella. The individuals in the fouling community showed a mutual dependence or constraint relationship due to competition for settlement space and food, and they exhibited a particular spatiotemporal distribution in accordance with adaptation to environmental factors. Temperature was the most important environmental factor determining the geographic distribution of fouling organisms. The temperature characteristics of species essentially reflect the differences in the fouling community composition in various climate zones. The species number, settlement stage, and settlement rate of fouling organisms are closely related to water temperature. Local natural environmental conditions（salinity, water currents, light, etc.） as well as human activity（such as aquaculture production） are all important factors affecting the settlement of fouling organisms.

Provenance analysis of surface sediments in the Holocene mud area of the southern coastal waters off Shandong Peninsula,China

The sedimentary record of mud areas is an important carrier of information on the Holocene evolution of marine environments. Based on fine interpretations of the shallow stratigraphic section data, a small mud deposit area has been found in the southern coastal waters off Shandong Peninsula. This mud area is mainly distributed in coastal waters north of Laoshantou to the vicinity of Rushan Estuary. Overall, it is parallel to the coastline and spreads in a banded pattern, gradually thinning from offshore to the sea. The isopach map of depth distribution is parallel with the shoreline, and the depocenter lies in coastal waters of the Aoshan Bay where the maximum thickness is up to 22.5 m. Accelerator mass spectrometry（AMS） ^（14）C dating shows that the mud area was formed in the Holocene. The test data of surface sediments from the mud area, including particle size, mineral characteristics, and rare earth element contents, are used in comparisons with the composition of materials from the major surrounding medium and small rivers flowing into the sea and the Huanghe（Yellow） River. In this paper, the sedimentary characteristics and provenance of the mud deposit area are discussed. The results show that the formation of this mud area resulted from the joint action of the Huanghe River and surrounding rivers flowing into the sea.

^(226)Ra and ^(228)Ra tracer study on nutrient transport in east coastal waters of Hainan Island,China

Material fluxes （e.g., nutrients） from coastal waters to offshore areas play an important role in controlling the water quality of the adjacent sea areas not only by increasing nutrient concentration hut also by changing nutrient structures. In this study, naturally occurring isotopes, ^226Ra and ^228Ra, were measured with the alpha spectrometry in the Wenjiao-Wenchang and Wanquan estuaries and adjacent sea areas along the east coast of Hainan Island. The excess ^226Ra and ^228Ra activities were observed by comparison with the values derived from the conservative mixing of freshwater and seawater end-members in both estuaries. Using a one-dimensional diffusion model, the horizontal eddy diffusion coefficient of 3.1 6 × 10^5 cm^2/s, for nutrients diffusing from their sources, was derived from 228Ra activities. Consequently, the corresponding nutrient fluxes flowing into the coastal waters were assessed. The results can provide useful information for the study of the mixing and exchange processes of coastal waters as well as dissoluble pollutant transport in this sea area.

Hard Foulers Induced Crevice Corrosion of HSLA Steel in the Coastal Waters of the Gulf of Mannar (Bay of Bengal), India

In the present study an attempt has been made to investigate the relationship between the variations in the fouling assemblage and corrosion behaviour of HSLA steel at three coastal locations in the Gulf of Mannar, India, over a period of 24 months. Oyster fouling was dominant in the Tuticorin open sea, while barnacles were the major foulants in the Tuticorin harbour and Mandapam. The fouling load in the Tuticorin waters was higher when compared to the Mandapam waters. The corrosion rates decreased progressively with the immersion time at all three test locations. In the Tuticorin open sea, the corrosion rates were higher when compared to the other two locations throughout the study period. The surface of the coupons was characterized by crevices beneath the hard foulers in the Tuticorin harbour and Mandapam, whereas in the Tuticorin open sea, the coupons experienced crevices of a tunneling nature. The percentage of the loss of the tensile strength increased with time at all the test locations.

Simulation of the Fate of Faecal Bacteria in Estuarine and Coastal Waters Based on A Fractionated Sediment Transport Model

A two-dimensional depth-integrated numerical model is refined in this paper to simulate the hydrodynamics, graded sediment transport process and the fate of faecal bacteria in estuarine and coastal waters. The sediment mixture is divided into several fractions according to the grain size. A bed evolution model is adopted to simulate the processes of the bed elevation change and sediment grain size sorting. The faecal bacteria transport equation includes enhanced source and sink terms to represent bacterial kinetic transformation and disappearance or reappearance due to sediment deposition or re-suspension. A novel partition ratio and dynamic decay rates of faecal bacteria are adopted in the numerical model. The model has been applied to the turbid water environment in the Bristol Channel and Severn estuary, UK. The predictions by the present model are compared with field data and those by non-fractionated model.

Survey of cyanomyovirus abundance in Shantou coastal waters by g20

To understand the genetic diversity and population changes in cyanophages in the coastal waters of Shantou, northeast South China Sea, we used the capsid assembly protein gene g20 as a marker of the abundance and phylogeny of natural cyanomyovirus communities. The abundance of total viruses, heterotrophic bacteria, and picophytoplankton in the coastal waters was monitored with flow cytometry. Hydrological parameters （NO3^-, NO2^-, NH3, soluble reactive phosphorus, total dissolved nitrogen, total dissolved phosphorus, dissolved oxygen, chemical oxygen demand, temperature, salinity, and chlorophyll a concentration） and microbial abundance （total viruses, total bacteria, Prochlorococcus, Synechococcus, and eukaryotes） were measured in the upper and lower layers at four sampling sites in the research area. In the direct viral counts, cyanomyoviruses accounted for 1.92% to 〉10% of the total viral community. A phylogenetic analysis showed that the g20 sequences in the Shantou coastal waters were very diverse, distributed in eight distinct operational taxonomic units, including the newly formed Cluster W. The g20 gene copies inferred from real time PCR assay indicated that cyanomyovimses were correlated significantly with the heterotrophic bacteria numbers and the nitrate and chlorophyll a concentrations. These results suggest that cyanomyoviruses are ubiquitous and are an abundant component of the virioplankton in Shantou coastal waters.