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Sputtered nano-cobalt on H-USY zeolite for selectively converting syngas to gasoline 被引量:2
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作者 Peng Lu Jian Sun +5 位作者 Pengfei Zhu Takayuki Abe Ruiqin Yang Akira Taguchi Tharapong Vitidsant Noritatsu Tsubaki 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2015年第5期637-641,共5页
Selectively converting CO and H2 to gasoline product (isoparaffin and olefin) in one step still remains a great challenge. We demonstrate effective H-USY zeolite supported nano-cobalt bifunctional catalysts for this... Selectively converting CO and H2 to gasoline product (isoparaffin and olefin) in one step still remains a great challenge. We demonstrate effective H-USY zeolite supported nano-cobalt bifunctional catalysts for this catalytic reaction, which are prepared by the novel physical sputtering process. Particles of the sputtered cobalt exist in nano-level and are well-dispersed on acid USY zeolite. Easy activation of the loaded nano-cobalt is also achieved in a low-temperature hydrogen reduction atmosphere. In the tandem catalytic reaction, the sputtered bifunctional Co/USY catalyst exhibits a much higher CO conversion and higher isoparaffin selectiv- ity than the conventional impregnated one. Compared with H-Mor, H-Beta and other zeolites supported catalysts, H-USY zeolite supported cobalt catalyst shows the clearest promotional effect on the activity of FischerTropsch synthesis. The described synthesis herein provides a new pathway to solve the problem caused by the strong metal-support interaction (MSI) in heterogeneous catalysis. 展开更多
关键词 cobalt usy zeolite fischer-tropsch synthesis hydrocarbon
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Correlation between hydrocarbon distribution and water-hydrocarbon ratio in Fischer-Tropsch synthesis
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作者 Xiaofeng Zhou Qingling Chen +1 位作者 Yuewu Yao Huixin Weng 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2011年第5期525-530,共6页
In order to shorten the evaluation cycle of cobalt catalyst before the optimized catalyst is fixed on, a mathematical method is proposed to calculate weight percentage of C5+ hydrocarbons. Based on the carbide polyme... In order to shorten the evaluation cycle of cobalt catalyst before the optimized catalyst is fixed on, a mathematical method is proposed to calculate weight percentage of C5+ hydrocarbons. Based on the carbide polymerization mechanism and the main hydrocarbons being linear alkanes and α-olefins, the correlation between hydrocarbon distribution and the molecular mass ratio of water to hydrocarbons is discussed. The result shows the ratio was within the range of 1.125-1.286 and the lower the ratio, the more gaseous hydrocarbons were obtained. Moreover, a linear equation between the weight percentage of C5+ hydrocarbons and the weight ratio of C5+ hydrocarbons to the total water is established. These results are validated by corresponding experiments. The weight percentage of C5+ hydrocarbons could be immediately calculated by this linear equation without detailed gas chromatography (GC) analysis of them. 展开更多
关键词 fischer-tropsch synthesis cobalt catalyst water-hydrocarbon weight ratio hydrocarbon distribution
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分子筛改性Co/SiO2催化剂对Fischer-Tropsch合成汽油类烃的影响 被引量:4
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作者 李宇萍 王铁军 +2 位作者 吴创之 吕永兴 李海滨 《石油化工》 CAS CSCD 北大核心 2008年第5期445-449,共5页
在中孔SiO2中添加USY,HZSM-5,β分子筛组成双功能载体,并采用初湿浸渍法在载体上浸渍钴盐,制备了一系列分子筛改性的Co/SiO2催化剂,考察了分子筛的类型、HZSM-5分子筛的骨架硅铝比、HZSM-5分子筛在载体中的含量对Fischer-Tropsch... 在中孔SiO2中添加USY,HZSM-5,β分子筛组成双功能载体,并采用初湿浸渍法在载体上浸渍钴盐,制备了一系列分子筛改性的Co/SiO2催化剂,考察了分子筛的类型、HZSM-5分子筛的骨架硅铝比、HZSM-5分子筛在载体中的含量对Fischer-Tropsch合成汽油类烃(C5-12)的影响。实验结果表明,载体中SiO2和分子筛共同作用,提高了催化剂的活性,并使产物分布向汽油类烃偏移,其中,以HZSM-5分子筛改性的Co/SiO2催化剂的催化性能最好。HZSM-5分子筛改性催化剂对催化性能的影响受其骨架硅铝比的影响。当骨架硅铝比n(SiO2):n(Al2O3)=38、HZSM-5分子筛在载体中的质量分数为20%时,CO转化率达到80%以上,汽油类烃的选择性高达55%,其中异构烷烃的选择性在10%以上。 展开更多
关键词 fischer-tropsch合成 钴/二氧化硅催化剂 分子筛 汽油类烃
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