Four new rod-coil diblock molecules, which had well-defined para-phenylene oligomers (PPP, from biphenyl to quinquephenyl) as rigid segments and poly(ethylene oxide) (PEO, M-w ca. 750) as flexible segments, were synth...Four new rod-coil diblock molecules, which had well-defined para-phenylene oligomers (PPP, from biphenyl to quinquephenyl) as rigid segments and poly(ethylene oxide) (PEO, M-w ca. 750) as flexible segments, were synthesized. The chemical structure and the number of repeating unit in PEO coil and PPP rod were characterized by H-1-NMR and MALDI-TOF mass spectrometry. The diblock oligomers showed good solubility in common organic solvents and aggregated in water as characterized by a blue shift in UV-vis absorption spectra, a red shift in emission spectra, quenching of the fluorescence and formation of the microfibrilla and fractal-like structures. The formation of different supramolecular structures meant that this effort might lead to commercial important highly organized functional materials.展开更多
The self-assembly of five narrowly distributed novel rod-coil diblock copolymers, poly(styrene-block-(2, 5-bis[4-methoxy-phenyl]oxycarbonyl) styrene) (PS-b-PMPCS), in p-xylene, a selective solvent at room temperature,...The self-assembly of five narrowly distributed novel rod-coil diblock copolymers, poly(styrene-block-(2, 5-bis[4-methoxy-phenyl]oxycarbonyl) styrene) (PS-b-PMPCS), in p-xylene, a selective solvent at room temperature, was studied. Therod-coil copolymers, which have the same PS length but different PMPCS length, were synthesized by 2,2,6,6-tetramethyl-I-piperidinyloxy (TEMPO) mediated living free radical polymerization. The influence of the rod length on the self-assemblymorphology was studied by transmission electron microscopy (TEM). At a concentration of 2.0 mg/mL, those copolymerswith relatively shorter PMPCS length (copolymers 1 and 2) form individual spherical micelles; those with relatively longerPMPCS length (copolymer 3 and 4) form 'pearl chains' coexisting with individual spherical micelles; the ones with longestPMPCS length form 'pearl chains' coexisting with occasionally formed nanofibers. The diameter of all the morphologieswas controlled by the rod length. This gives us a way to govern the self-assembly morphology by altering the length of oneblock in the block copolymer.展开更多
Due to the influence of material characteristics and winding power, single output electromagnet has limited ability to improve the dynamic characteristic of electro-hydraulic valve. Therefore, an electromechanical con...Due to the influence of material characteristics and winding power, single output electromagnet has limited ability to improve the dynamic characteristic of electro-hydraulic valve. Therefore, an electromechanical converter with double push rods is proposed in this paper, which can simultaneously output two electromagnetic forces, can push or pull the valve core and sleeve according to the current direction and realize rapid operation of load. According to the electromagnetic principle and the magnetic circuit analysis method, the mathematical model and equivalent circuit of the electromechanical converter with double push rods are established. Through the finite element simulation model of the electromechanical converter with double push rods with the same magnetization directions, the changing rules of its magnetic field distribution and force–displacement behaviors are studied and analyzed. According to the analysis results, the electromagnetic mechanical parameters and mechanical structure of the electromechanical converter with double push rods are determined, and the prototype is made. The test platform for the push-pull characteristics of the electromechanical converter with double push rods is built, and its static and dynamic characteristics are tested and analyzed. The results show that the thrust and pull output characteristics of the internal and external push rods are basically consistent with the simulation output, and proportional to the current density of the coil;the push-pull hysteresis of internal and external push rods output force is less than 5%;and the dynamic time response characteristics of the displacement and force are obtained. The hysteresis e ect of output force is improved e ectively through the H bridge drive control circuit modulated by PWM. Compared with the displacement response of a singlewinding electromagnet with a similar volume, it can e ectively improve the dynamic displacement response. Followup work will further optimize the structure of the electromechanical converter and test the corresponding pilot valve. The research results provide a new theory for improving the output characteristics of electro-hydraulic pilot valve and have an extremely high engineering application value and broad application prospect.展开更多
An optically active rod coil rod triblock copolymer containing poly(ethylene oxide)(PEO) as the flexible segment and poly{(+) 2,5 bis[4′ ((s) 2 methyl butoxy) phenyl]styrene} (PMBPS) as the rigid segment,PMBPS b PEO ...An optically active rod coil rod triblock copolymer containing poly(ethylene oxide)(PEO) as the flexible segment and poly{(+) 2,5 bis[4′ ((s) 2 methyl butoxy) phenyl]styrene} (PMBPS) as the rigid segment,PMBPS b PEO b PMBPS,was synthesized via atom transfer radical polymerization.The PMBPS block had a stable helical conformation with an excess of screw sense in solution.The self assembly behavior of the triblock copolymer in dioxane/water mixed solvents was examined by means of TEM and turbidity measurements.The triblock copolymer molecules aggregated when water content in the system was about 2wt%. The higher the initial polymer concentrations,the lower the critical water content.They formed vesicles with highly dispersed outside diameters,but they had a relatively uniform wall thickness of (27±3) nm.展开更多
基金This work has been supported by the National Natural Science Foundation of China (Grants 29874003 and 29992590-4), the Research Fund for Doctoral Program of Higher Education (Grant 99000136) and the Teaching and Research Award Fund for Outstanding Young
文摘Four new rod-coil diblock molecules, which had well-defined para-phenylene oligomers (PPP, from biphenyl to quinquephenyl) as rigid segments and poly(ethylene oxide) (PEO, M-w ca. 750) as flexible segments, were synthesized. The chemical structure and the number of repeating unit in PEO coil and PPP rod were characterized by H-1-NMR and MALDI-TOF mass spectrometry. The diblock oligomers showed good solubility in common organic solvents and aggregated in water as characterized by a blue shift in UV-vis absorption spectra, a red shift in emission spectra, quenching of the fluorescence and formation of the microfibrilla and fractal-like structures. The formation of different supramolecular structures meant that this effort might lead to commercial important highly organized functional materials.
基金The financial support of the National Natural Science Foundation of China (Grants. 29992590-4 and 20134010)
文摘The self-assembly of five narrowly distributed novel rod-coil diblock copolymers, poly(styrene-block-(2, 5-bis[4-methoxy-phenyl]oxycarbonyl) styrene) (PS-b-PMPCS), in p-xylene, a selective solvent at room temperature, was studied. Therod-coil copolymers, which have the same PS length but different PMPCS length, were synthesized by 2,2,6,6-tetramethyl-I-piperidinyloxy (TEMPO) mediated living free radical polymerization. The influence of the rod length on the self-assemblymorphology was studied by transmission electron microscopy (TEM). At a concentration of 2.0 mg/mL, those copolymerswith relatively shorter PMPCS length (copolymers 1 and 2) form individual spherical micelles; those with relatively longerPMPCS length (copolymer 3 and 4) form 'pearl chains' coexisting with individual spherical micelles; the ones with longestPMPCS length form 'pearl chains' coexisting with occasionally formed nanofibers. The diameter of all the morphologieswas controlled by the rod length. This gives us a way to govern the self-assembly morphology by altering the length of oneblock in the block copolymer.
基金Supported by National Natural Science Foundation for Young Scientists of China(Grant No.51505317)Shanxi Provincial Natural Science Foundation of China(Grant No.201601D102039)
文摘Due to the influence of material characteristics and winding power, single output electromagnet has limited ability to improve the dynamic characteristic of electro-hydraulic valve. Therefore, an electromechanical converter with double push rods is proposed in this paper, which can simultaneously output two electromagnetic forces, can push or pull the valve core and sleeve according to the current direction and realize rapid operation of load. According to the electromagnetic principle and the magnetic circuit analysis method, the mathematical model and equivalent circuit of the electromechanical converter with double push rods are established. Through the finite element simulation model of the electromechanical converter with double push rods with the same magnetization directions, the changing rules of its magnetic field distribution and force–displacement behaviors are studied and analyzed. According to the analysis results, the electromagnetic mechanical parameters and mechanical structure of the electromechanical converter with double push rods are determined, and the prototype is made. The test platform for the push-pull characteristics of the electromechanical converter with double push rods is built, and its static and dynamic characteristics are tested and analyzed. The results show that the thrust and pull output characteristics of the internal and external push rods are basically consistent with the simulation output, and proportional to the current density of the coil;the push-pull hysteresis of internal and external push rods output force is less than 5%;and the dynamic time response characteristics of the displacement and force are obtained. The hysteresis e ect of output force is improved e ectively through the H bridge drive control circuit modulated by PWM. Compared with the displacement response of a singlewinding electromagnet with a similar volume, it can e ectively improve the dynamic displacement response. Followup work will further optimize the structure of the electromechanical converter and test the corresponding pilot valve. The research results provide a new theory for improving the output characteristics of electro-hydraulic pilot valve and have an extremely high engineering application value and broad application prospect.
文摘An optically active rod coil rod triblock copolymer containing poly(ethylene oxide)(PEO) as the flexible segment and poly{(+) 2,5 bis[4′ ((s) 2 methyl butoxy) phenyl]styrene} (PMBPS) as the rigid segment,PMBPS b PEO b PMBPS,was synthesized via atom transfer radical polymerization.The PMBPS block had a stable helical conformation with an excess of screw sense in solution.The self assembly behavior of the triblock copolymer in dioxane/water mixed solvents was examined by means of TEM and turbidity measurements.The triblock copolymer molecules aggregated when water content in the system was about 2wt%. The higher the initial polymer concentrations,the lower the critical water content.They formed vesicles with highly dispersed outside diameters,but they had a relatively uniform wall thickness of (27±3) nm.
