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On fractional discrete financial system:Bifurcation,chaos,and control
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作者 Louiza Diabi Adel Ouannas +2 位作者 Amel Hioual Shaher Momani Abderrahmane Abbes 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第10期129-140,共12页
The dynamic analysis of financial systems is a developing field that combines mathematics and economics to understand and explain fluctuations in financial markets.This paper introduces a new three-dimensional(3D)frac... The dynamic analysis of financial systems is a developing field that combines mathematics and economics to understand and explain fluctuations in financial markets.This paper introduces a new three-dimensional(3D)fractional financial map and we dissect its nonlinear dynamics system under commensurate and incommensurate orders.As such,we evaluate when the equilibrium points are stable or unstable at various fractional orders.We use many numerical methods,phase plots in 2D and 3D projections,bifurcation diagrams and the maximum Lyapunov exponent.These techniques reveal that financial maps exhibit chaotic attractor behavior.This study is grounded on the Caputo-like discrete operator,which is specifically influenced by the variance of the commensurate and incommensurate orders.Furthermore,we confirm the presence and measure the complexity of chaos in financial maps by the 0-1 test and the approximate entropy algorithm.Additionally,we offer nonlinear-type controllers to stabilize the fractional financial map.The numerical results of this study are obtained using MATLAB. 展开更多
关键词 financial model stability CHAOS commensurate and incommensurate orders COMPLEXITY
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The National Interest and Global Justice:Contradictory Terms,Incomparable and Non-commensurable Goods,Yet Compatible?
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作者 Ariel Colonomos 《Fudan Journal of the Humanities and Social Sciences》 2019年第2期233-253,共21页
Prima facie,the pursuit of national interest stands in contradiction with the rules of global justice.Indeed,the former relies upon selfishness and the maximization of national utility,while the latter presupposes dis... Prima facie,the pursuit of national interest stands in contradiction with the rules of global justice.Indeed,the former relies upon selfishness and the maximization of national utility,while the latter presupposes distributive measures at the global level that exercise some constrain on state behavior.However,these two notions are open to interpretation and,sometimes,even lack clarity.This paper will look for clarification and will ask whether it is possible to go beyond the radical difference between those two logics.I will start by underlining the reasons why the national interest and global justice are in contradiction with each other.Although they are not commensurable,the paper will then argue the two can be compatible in specific equilibriums of international politics,I will refer to as the“rationalist”and the“revolutionist”modes.Finally,the paper will discuss whether,in the best of all possible worlds,we should strive for this compatibility. 展开更多
关键词 INTERNATIONAL POLITICS INTERNATIONAL relations theory Global JUSTICE National interest COMMENSURABILITY REALISM
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Commensurate and incommensurate Haldane phases for a spin-1 bilinear-biquadratic model
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作者 代艳伟 陈爱民 +1 位作者 刘希婧 苏耀恒 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第9期157-162,共6页
Commensurate and incommensurate Haldane phases for a spin-1 bilinear-biquadratic model are investigated using an infinite matrix product state algorithm.The bipartite entanglement entropy can detect a transition point... Commensurate and incommensurate Haldane phases for a spin-1 bilinear-biquadratic model are investigated using an infinite matrix product state algorithm.The bipartite entanglement entropy can detect a transition point between the two phases.In both phases,the entanglement spectrum shows double degeneracy.We calculate the nonlocal order parameter of the bond-centered inversion in both phases,which rapidly approaches a saturation value of-1 as the segment length increases.The nonlocal order parameter of the bond-centered inversion with a saturation value-1 and the nonzero value string order indicate that the Haldane phase is a symmetry-protected topological phase.To distinguish the commensurate and incommensurate Haldane phases,the transversal spin correlation and corresponding momentum distribution of the structure factor are analyzed.As a result,the transversal spin correlations exhibit different decay forms in both phases. 展开更多
关键词 commensurate and incommensurate phases symmetry-protected topological phase transversal spin correlation
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Prediction of the Hualian Earthquakes in Taiwan and an Extended Discussion on the Method of Commensurability 被引量:4
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作者 胡辉 韩延本 《Applied Geophysics》 SCIE CSCD 2005年第3期194-196,F0003,共4页
The method of commensurability was used by the authors to predict the great earthquake of magnitude 7.5 that occurred on March 31,2002 in Taiwan 70km away from Hualian. Analyzing the earthquakes of magnitude≥7.0 whic... The method of commensurability was used by the authors to predict the great earthquake of magnitude 7.5 that occurred on March 31,2002 in Taiwan 70km away from Hualian. Analyzing the earthquakes of magnitude≥7.0 which occurred in the Hualian area of Taiwan within the 20th century, the authors discovered that the occurrences of the earthquakes are commensurable. The earthquakes of magnitude 7.6 which occurred in Hualian of Taiwan, on September 20th, 1999 and of magnitude 7.5 which occurred 70 km away from Hualian, on March 31th, 2002 appeared at the commensurable point of K=2 and the period times the golden section, respectively. An extended discussion is carried out on the method of commensurability and its implied physical significance, especially on the contribution of the commensurable periodic extension made by Prof. Weng Wenbo. 展开更多
关键词 information determinacy COMMENSURABILITY and extension of periodicity
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Generation and Propagation of Ultrasonic Waves in Piezoelectric Graphene Nanoribbon
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作者 Musah Rabiu Samuel Y. Mensah +3 位作者 Sulemana S. Abukari Matthew Amekpewu Baah Sefa-Ntiri Anthony Twum 《Open Journal of Acoustics》 2013年第3期38-42,共5页
Generation and propagation of ultrasonic waves in single layer Graphene Nanoribbon is studied using semi-classical approach. When piezoelectric Graphene Nanoribbon (GNR) is exposed to time varying light beam, ultrason... Generation and propagation of ultrasonic waves in single layer Graphene Nanoribbon is studied using semi-classical approach. When piezoelectric Graphene Nanoribbon (GNR) is exposed to time varying light beam, ultrasonic waves are produced which propagate in the medium. At low frequencies, we observed oscillations of the ultrasonic observables, velocity change and attenuation which are characteristics of massless Dirac fermions in graphene. Exploiting this oscillatory behavior, we estimate graphene’s electronic mobility to be around . Propagating ultrasonic waves can be amplified, depending on the electric field amplitude. Specifically, amplification occurs when drift velocity exceeds sound velocity. This scheme can be employed for efficient ultrasonic amplifier device operation. 展开更多
关键词 Current DENSITY NEGATIVE DIFFERENTIAL CONDUCTIVITY commensurable Frequencies
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Symmetry and tendency judgment of Ms≥8. 0 strong earthquakes in Chile 被引量:12
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作者 Jin Junfang Yin Shuyan Yan Junping 《Geodesy and Geodynamics》 2014年第1期34-40,共7页
The Ms ≥ 8.0 strong earthquakes occurring in Chile since 1800 were analyzed using the ternary, quaternary, and quinary commensurability methods and the butterfly structure diagram, and it was believed that the earthq... The Ms ≥ 8.0 strong earthquakes occurring in Chile since 1800 were analyzed using the ternary, quaternary, and quinary commensurability methods and the butterfly structure diagram, and it was believed that the earthquake signal in Chile in 2014 is relatively strong, a large earthquake is likely to occur in Chile in 2014. An analysis of spatial epicenter migrations showed that the longitudinal and latitudinal epicenter migra- tions have symmetry and synchronism, and there were five obvious northward migrations and four southward migrations. The symmetry axis of the longitudinal migrations is at about 71.7°W and that of the latitudinal mi- grations is at about 30°S; these spatial symmetry axes are located at the subduction zone on the western margin of South America, where two major plates (the Nazca Plate and the South American Plate) converge. 展开更多
关键词 SYMMETRY tendency judgment COMMENSURABILITY butterfly structure Chile
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Multiscale mechanics of noncovalent interface in graphene oxide layered nanocomposites 被引量:2
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作者 ZeZhou He YinBo Zhu HengAn Wu 《Theoretical & Applied Mechanics Letters》 CSCD 2022年第1期3-9,共7页
Noncovalent interfaces play a vital role in inelastic deformation and toughening mechanisms in layered nanocomposites due to their dynamical recoverability. When interfacial engineering is applied to design layered na... Noncovalent interfaces play a vital role in inelastic deformation and toughening mechanisms in layered nanocomposites due to their dynamical recoverability. When interfacial engineering is applied to design layered nanocomposites, shear-lag analysis is usually implemented to evaluate the capability of interfacial loading transfer. Here, we introduce a multiscale shear-lag model that correlates macroscale mechanical properties with the molecular mechanisms to quantify the effects of interfacial configuration in graphene oxide(GO) layered nanocomposites. By investigating the mechanical responses of commensurate and incommensurate interfaces, we identify that the commensurate interface exhibits a pronounced size effect due to the nucleation and propagation of interfacial defects, whereas the incommensurate interface displays uniform deformation. Our predictions are further validated through large-scale molecular dynamics simulations for GO layered nanocomposites. This work demonstrates how size effects and interfacial configurations can be exploited to fabricate layered nanocomposites with superior mechanical properties despite relying on weak noncovalent interfaces. 展开更多
关键词 Multiscale mechanics Noncovalent interface Commensurate and incommensurate Shear-lag model Layered nanocomposites
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微波集成公度线FET放大器的简化实频技术设计法
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作者 伍霆杰 吴咏诗 《微波学报》 1987年第1期12-20,共9页
将简化实频技术发展用于具有公度线匹配网络的微波集成FET多级放大器的设计。勿需FFT的数学模型,勿需设定匹配网络的拓扑,按照通带内的噪声系数与传输增益指标要求可直接求得最佳的网络散射矩阵,据此即可综合公度线匹配网络。设计的实... 将简化实频技术发展用于具有公度线匹配网络的微波集成FET多级放大器的设计。勿需FFT的数学模型,勿需设定匹配网络的拓扑,按照通带内的噪声系数与传输增益指标要求可直接求得最佳的网络散射矩阵,据此即可综合公度线匹配网络。设计的实践证明此方法是适用于工程实际的。 展开更多
关键词 Microwave amplifier CAD Commensurate Line
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On Fundamentals Predicting Floods-Landslides
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作者 Yan Tongzhen Li Yun ’an Wang Hongxing Faculty of Engineering, China University of Geosciences, Wuhan 430074 Yi Shunmin State Key Hydraulics Laboratory of High Speed Flows, Sichuan Union University, Chengdu 610065 《Journal of Earth Science》 SCIE CAS CSCD 1998年第3期64-67,共4页
Based on the floods landslides commensurability system, the paper presents and discusses the disasters/hazards with comprehensive interaction and erosional processes. However, people are not enough to get their possi... Based on the floods landslides commensurability system, the paper presents and discusses the disasters/hazards with comprehensive interaction and erosional processes. However, people are not enough to get their possibility for the sustainability. They have had so many disasters to meet and to control continuously. Finally, the fundamentals should be built up with nonlinear solutions of landsliding problems; the events of geomagnetism anomaly should be considered. 展开更多
关键词 FUNDAMENTALS floods landslides COMMENSURABILITY geomagnetism anomaly astronomy.
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Gas Source Molecular Beam Epitaxy Growth of Si_(1-x)Ge_x/Si Alloys
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作者 刘学锋 李建平 孙殿照 《Rare Metals》 SCIE EI CAS CSCD 1997年第2期43-48,共6页
Strained SiGe alloys are successfully grown on Si(100) substrate in gas source molecular beam epitaxy system using disilane (Si 2H 6) and germane (GeH 4). The surface reconstructions are monitored by in situ r... Strained SiGe alloys are successfully grown on Si(100) substrate in gas source molecular beam epitaxy system using disilane (Si 2H 6) and germane (GeH 4). The surface reconstructions are monitored by in situ reflection high energy electron diffraction during epitaxy. At a fixed substrate temperature, the Ge composition in the alloys increase with GeH 4/(GeH 4+2Si 2H 6) gas flow rate ratio. Surface morphologies of the grown samples show a strong dependence on the Ge composition, substrate temperature and SiGe epilayer thickness. Results indicate that high substrate temperature and large Ge composition are favorable for the growth mode transition from two dimensional to three dimensional growth. 展开更多
关键词 SiGe alloys GSMBE Commensurate growth Lattice mismatch
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Spatiotemporal characteristics and trend assessment of Ms≥5.6 earthquakes in the Tianshan area of China based on co-occurrence analysis and commensurability
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作者 Wan Jia Yan Jun-Ping +3 位作者 Liu Zi-Qiang Wang Xiao-Meng Zhang Yu-Feng Wang Cheng-Bo 《Applied Geophysics》 SCIE CSCD 2021年第3期396-407,434,共13页
Based on the complete seismic data of the Tianshan area in the past 118 years,the co-occurrence rate of earthquakes in different fault zones is calculated,the fault zone with the highest associative degree in the Tian... Based on the complete seismic data of the Tianshan area in the past 118 years,the co-occurrence rate of earthquakes in different fault zones is calculated,the fault zone with the highest associative degree in the Tianshan area is determined as the research object,extracted the earthquake time series information of the strong associative fault zone and the commensurability method is used to obtain the commensurability expression,the year of strongest earthquake signal is calculated and predicted,then the butterfly structure diagram and commensurability structure system are drawn.Combined the butterfly structure diagram and commensurability structure system to analyze the seismic spatiotemporal structure characteristics of the Tianshan area,judge the trend of future earthquakes,and predict the time of future earthquakes.The results demonstrate that Ms≥5.6 earthquake signals are strong in 2020 and 2021.In order to determine the location of future earthquakes,the historical epicenter migration law of the strongly correlated fault zone in the Tianshan area is analyzed.It is revealed that the epicenter distribution is symmetric in both the longitude and latitude directions.Analyzing the spatial distribution of epicenters,the five successive earthquakes in the strong associative fault zone in the Tianshan area present a pentagonal symmetrical structure in space.It is judged that the next earthquake will migrate toward the northeast.Additionally,the sunspot has a strong seismic correlation with the strong associative fault zone in the Tianshan area.Specifi cally,on the 11-year cycle scale of sunspot activity,64.71% of earthquakes occurred in the fluctuation descending range;on the monthly scale of sunspot activity.Hence,it has been verified that the proposed disaster prediction method based on commensurability theory is scientifi c and has a broad application prospect. 展开更多
关键词 Tianshan area EARTHQUAKE associative degree COMMENSURABILITY
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Amplitude Oscillations of the Resonant Phenomena in a Frenkel-Kontorova Model with an Incommensurate Structure
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作者 YAN Yan-Zong WANG Cang-Long +1 位作者 SHAO Zhi-Gang YANG Lei 《Chinese Physics Letters》 SCIE CAS CSCD 2012年第6期68-71,共4页
Dynamical mode locking phenomena in incommensurate structures of the dc- and ac-driven overdamped FrenkelKontorova model are studied by molecular-dynamics simulations.It is found that the Shapiro steps exhibit signifi... Dynamical mode locking phenomena in incommensurate structures of the dc- and ac-driven overdamped FrenkelKontorova model are studied by molecular-dynamics simulations.It is found that the Shapiro steps exhibit significantly different amplitude and frequency dependences from the ones observed in the commensurate structures.The step widths still oscillate with the amplitude,but the form is no longer Bessel-like,i.e.,the anomaly appears in our simulations.The same type of anomalies is also exhibited by the critical depinning force.The oscillatory behavior and the anomalies are also revealed in the ((F),Fac) phase diagram where three phases are observed.These oscillations are directly correlated with the existence and the stability of interference phenomena in real systems. 展开更多
关键词 FORCE STEPS COMMENSURATE
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The identification algorithm for commensurate order linear time-invariant fractional systems
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作者 王振滨 曹广益 朱新坚 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2005年第5期576-580,共5页
An efficient identification algorithm is given for commensurate order linear time-invariant fractional systems. This algorithm can identify not only model coefficients of the system, but also its differential order at... An efficient identification algorithm is given for commensurate order linear time-invariant fractional systems. This algorithm can identify not only model coefficients of the system, but also its differential order at the same time. The basic idea is to change the system matrix into a diagonal one through basis transformation. This makes it possible to turn the system’s input-output relationships into the summation of several simple subsystems, and after the identification of these subsystems, the whole identification system is obtained which is algebraically equivalent to the former system. Finally an identification example verifies the effectiveness of the method previously mentioned. 展开更多
关键词 fractional systems COMMENSURATE linear time-invariant state-space representation system identification
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INCOMMENSURATE AND COMMENSURATE PHASE TRANSITIONS IN Ti-Ni-Fe ALLOY
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作者 RAO Jianxi Naval Academy of Engineering,Wuhan,China MA Ruzhang University of Science and Technology Beijing,Beijing,China HE Yusheng Tsinghua University,Beijing,China MA Ruzhang Professor,Department of Metal Physics,University of Science and Technology Beijing 100083,Beijing,China 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 1990年第2期89-92,共4页
Measurements by using the ultrasonic technique together for electric resistance verified that the first sound velocity valley on cooling is mainly due to the soft-mode of driving the com- mensurate phase transition,an... Measurements by using the ultrasonic technique together for electric resistance verified that the first sound velocity valley on cooling is mainly due to the soft-mode of driving the com- mensurate phase transition,and the second one due to the soft-mode of driving the martensitic transformation.The starting point,R_s,and finishing point,R_f,of the commensurate phase transition of the alloy have been determined. 展开更多
关键词 incommensurate phase transition commensurate phase transition Ti-Ni-Fe alloy
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Application of Commensurability in Earthquake Prediction
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作者 Youjin Su Hui Hu 《International Journal of Geosciences》 2015年第6期619-624,共6页
This article introduces application of the expanding commensurability in earthquake prediction. The results show that most of the world’s major earthquake occurred at their commensurable points of time axis. An EQ 7.... This article introduces application of the expanding commensurability in earthquake prediction. The results show that most of the world’s major earthquake occurred at their commensurable points of time axis. An EQ 7.0 occurred in Lushan of China on 2013-04-20 and an EQ 8.2 occurred in Iquique of northern Chile on 2014-04-01 all occurred at their commensurable points of time axis. This once again proves that the commensurability provides an important scientific basis for the prediction of major earthquakes, which will occur in the area in future. 展开更多
关键词 COMMENSURABILITY ORDERS in the NATURAL World EARTHQUAKE PREDICTION
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How to bridge China and Africa culturally?—New clues from the commensurability of Asiancentricity and Afrocentricity
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作者 Ma Xiaofen 《Journalism and Mass Communication》 2021年第1期14-25,共12页
With the frequent economic cooperation and the cultural communication from China to Africa focusing on foreign policies and economic efforts is insufficient.Because culture-oriented investigations make more contributi... With the frequent economic cooperation and the cultural communication from China to Africa focusing on foreign policies and economic efforts is insufficient.Because culture-oriented investigations make more contributions to the development of the pan-cultural exchange,and they complement general culture inquiries.Chinese philosophies are very representative for Asiancentricity.The reason why is that a common key of the Asian values,beliefs,and worldviews which exceed many philosophies and religions,like Confucianism,Buddhism,Taoism.Secondly,the aspects of ontology,epistemology and axiology of Asiancentricity and Afrocentricity are quite similar.This can also be understood as commensurability existing in Chinese and African philosophies in some ways.In Chinese philosophy,everything and everyone can become valuable in relationships with others,and the myriad becomes perceivable and meaningful.In the meantime,conforming to the fundamental principles of the Asiancentricity perspectives,all of the elements in the universe,including animals,human beings,natural phenomena and inanimate objects,are connected with each other.Both of two philosophies emphasise the importance of being communal and harmony,rather than emphasising the characteristics of ego and individualism.Although,Asiancentricity and Afrocentricity are not totally common and universal,they do have enumerable commensurable factors and are embedded in the communicative and cultural particularities. 展开更多
关键词 Chinese philosophies Asiancentricity Afrocentricity COMMENSURABILITY
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Quantization of Particle Energy in the Analysis of the Boltzmann Distribution and Entropy
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作者 V.P. Malyshev Yu.S. Zubrina A.M. Makasheva 《Journal of Mathematics and System Science》 2017年第10期278-288,共11页
The Boltzmann equilibrium distribution is an important rigorous tool for determining entropy, since this function cannot be measured, but only calculated in accordance with Boltzmann's law. On the basis of the commen... The Boltzmann equilibrium distribution is an important rigorous tool for determining entropy, since this function cannot be measured, but only calculated in accordance with Boltzmann's law. On the basis of the commensuration coefficient of discrete and continuous similarly-named distributions developed by the authors, the article analyses the statistical sum in the Boltzmann distribution to the commensuration with the improper integral of the similarly-named function in the full range of the term of series of the statistical sum at the different combination of the temperature and the step of variation (quantum) of the particle energy. The convergence of series based on the Cauchy, Maclaurin criteria and the equal commensuration of series and improper integral of the similarly-named function in each unit interval of variation of series and similarly-named function were estab- lished. The obtained formulas for the commensuration coefficient and statistical sum were analyzed, and a general expres- sion for the total and residual statistical sums, which can be calculated with any given accuracy, is found. Given a direct calculation formula for the Boltzmann distribution, taking into account the values of the improper integral and commensuration coefficient. To determine the entropy from the new expression for the Boltzmann distribution in the form of a series, the conver- gence of the similarly-named improper integral is established. However, the commensuration coefficient of integral and series in each unit interval turns out to be dependent on the number of the term of series and therefore cannot be used to determine the sum of series through the improper integral. In this case, the entropy can be calculated with a given accuracy with a corresponding quantity of the term of series n at a fixed value of the statistical sum. The given accuracy of the statistical sum turns out to be mathematically identical to the fraction of particles with an energy exceeding a given level of the energy barrier equal to the activation energy in the Arrhenius equation. The prospect of development of the proposed method for expressing the Boltzmann distribution and entropy is to establish the relationship between the magnitude of the energy quantum Ae and the properties of the system-forming particles. 展开更多
关键词 distribution ENTROPY SEQUENCE commensuration statistical sum convergent series analysis.
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Predicting the 2019 M7 Strong Earthquake in California
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作者 Guangmeng Guo Yongtao Jiang 《International Journal of Geosciences》 2021年第10期941-948,共8页
The U.S. Geological Survey has estimated a 99% chance of a magnitude 6.7 earthquake in California in the next 30 years from 2008. In this paper, Fourier transform, mode analysis and commensurability analysis are used ... The U.S. Geological Survey has estimated a 99% chance of a magnitude 6.7 earthquake in California in the next 30 years from 2008. In this paper, Fourier transform, mode analysis and commensurability analysis are used to study the earthquake cycle in California and predict </span><span style="font-family:Verdana;">the</span><span style="font-family:Verdana;"> future strong earthquake. The analysis shows that the strong earthquake in California is most likely to occur in 2019, and the prediction was sent to the relevant institutions of United States in 2018. In July 2019 a</span><span style="font-family:Verdana;">n</span><span style="font-family:Verdana;"> M7.1 earthquake occurred in California, which proved our prediction to be correct. 展开更多
关键词 California Earthquake Prediction The Fourier Transform COMMENSURABILITY
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On Confucious Human Rights Discourse
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作者 孟庆涛 LIU Haile(译) 《The Journal of Human Rights》 2020年第5期675-693,共19页
As to the contents of Confucian discourse of human rights there are four topics which are being or not-being,history,relationship and constructivism on Confucian-human right.According to the different criteria of bein... As to the contents of Confucian discourse of human rights there are four topics which are being or not-being,history,relationship and constructivism on Confucian-human right.According to the different criteria of being or not being on Confucian-human right there are three points:not being in ancient times,being in ancient times,not being originally and being later.There are three points too on relationship of Confucian-human right:exclusion,integration and conversion.what is sometimes overlooked on the history of Confucian-human right is eastern studies introduced to the west.The traditional Chinese thoughts had an important effect on western human right idea and normative text.Du Gangjian,a well-known expert on Chaoshan new Confucianism in construction of Confucian-human right,constructs a theory system of Confucian human rights by Confucius’ideas.Taken together,Confucian discourse of human rights is at the cross-section when China mingled with the western countries and the modern replaced the ancient.The commensurability of human rights is just made at this point. 展开更多
关键词 confucian discourse of human rights eastern studies introduced to the west COMMENSURABILITY
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Commensurate stacking within confined ultramicropores boosting acetylene storage capacity and separation efficiency 被引量:1
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作者 Zhenghui Huang Kungang Chai +2 位作者 Chengjun Kang Rajamani Krishna Zhaoqiang Zhang 《Nano Research》 SCIE EI CSCD 2023年第5期7742-7748,共7页
Developing advanced porous materials possessing both a high storage capacity and selectivity for acetylene(C_(2)H_(2))remains challenging but a sought-after endeavor.Herein we show a strategy involving synergic combin... Developing advanced porous materials possessing both a high storage capacity and selectivity for acetylene(C_(2)H_(2))remains challenging but a sought-after endeavor.Herein we show a strategy involving synergic combination of spatial confinement and commensurate stacking for enhanced C_(2)H_(2)storage and capture via maximizing the host–guest and guest–guest interactions.Two ultramicroporous metal-organic frameworks(MOFs),MIL-160 and MOF-303 are elaborately constructed to exhibit ultrahigh C_(2)H_(2)uptakes of 235 and 195 cm^(3)·g^(−1),respectively,due to the confinement effect of the suitable pore sizes and periodically dispersed molecular recognition sites.Specially,C_(2)H_(2)capacity of MIL-160 sets a new benchmark for C_(2)H_(2)storage.The exceptional separation performances of two materials for C_(2)H_(2)over both CO_(2)and ethylene(C_(2)H_(4)),which is rarely observed,outperform most of the benchmark materials for C_(2)H_(2)capture.We scrutinized the origins of ultrahigh C_(2)H_(2)loading in the confined channels via theoretical investigations.The superior separation efficiency for C_(2)H_(2)/CO_(2)and C_(2)H_(2)/C_(2)H_(4)mixtures with unprecedented C_(2)H_(2)trapping capacity(>200 L·kg^(−1))was further demonstrated by dynamic breakthrough experiments. 展开更多
关键词 adsorption and separation acetylene storage commensurate stacking gas cluster metal-organic frameworks
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