The construction and performance characteristics of a novel (diphenhydramine) DPH CC-sensor based on DZCE were reported in this work. The CC-membrane was prepared by incorporating of (diazacrown ether) DZCE and/or (te...The construction and performance characteristics of a novel (diphenhydramine) DPH CC-sensor based on DZCE were reported in this work. The CC-membrane was prepared by incorporating of (diazacrown ether) DZCE and/or (tetraflorophenyl borate) TFPB into a plasticized poly(vinyl chloride) membrane. The CC-sensor revealed a Nernstian behavior over a DPH-concentration range (9.1 × 10<sup>-3</sup> - 6.3 × 10<sup>-7</sup> mol ·L<sup>-1</sup>), and relatively low detection limit (1 × 10<sup>-7</sup> mol ·L<sup>-1</sup>). The potentiometric response was independent on the pH of the solution in the range of 7 - 10. The DPH-CC showed a very short response time (<5 s). It showed good selectivity towards different cations and pharmaceutical compounds. The relative selectivity coefficient was applied for evaluation of the selectivity properties of the DPH-CC. The DPH-CC was used successfully for determination of DPH in its samples. The found recovery range was 95% - 98.5%, and the standard deviation value ranged between 0.13 - 0.42. The DPH-CC facilitates the analysis of DPH directly without pretreatment and it can be built-in as a detector in chromatographic apparatus. It can be used as a tool for on-line monitoring of the drug levels.展开更多
This paper presents the fundamental technique of phase generated carrier （PGC） and its realization on compact reconfigurable input and output （RIO） which adopts real-time and field programmable grate array （FPGA...This paper presents the fundamental technique of phase generated carrier （PGC） and its realization on compact reconfigurable input and output （RIO） which adopts real-time and field programmable grate array （FPGA） techniques. Improvement of the PGC technique is also introduced by using peak-to-peak value detection method to reduce the influence of variation of the light intensity. A four-element fibre Bragg gratings （FBG） laser sensor system is conducted in the experiment and the demodulated results demonstrate correlation coefficient as high as 0.995 with the reference signal and the dynamic range to be 120dB@63Hz.展开更多
针对目前基于圆锥指数的土壤紧实度测量中,无法消除土壤摩擦力对紧实度测量的影响,要求检测传感器匀速贯入土壤,因此存在使用不便、精度不高的难题。为了提高土壤紧实度实时测量方法的精度及可操作性,在圆锥指数方法基础上,设计了土壤...针对目前基于圆锥指数的土壤紧实度测量中,无法消除土壤摩擦力对紧实度测量的影响,要求检测传感器匀速贯入土壤,因此存在使用不便、精度不高的难题。为了提高土壤紧实度实时测量方法的精度及可操作性,在圆锥指数方法基础上,设计了土壤紧实度实时检测传感器,并加入了加速度的同步测量,消除了使用过程中金属杆插入速度不均造成的误差,提高了土壤紧实度测量精度。通过大量试验验证了自制传感器具有较好的静态性能和动态性能,其测量范围为0~900 k Pa,灵敏度为0.041 896,稳定性测量标准差为5 k Pa,测量精度为±0.02%FS,超调量为7.81%,过渡时间为0.632 s。与美国SC-900型土壤紧实度仪对比其准确性的线性拟合决定系数均达到0.96以上,结果表明设计的土壤紧实度传感器与SC-900型土壤紧实度仪在实际测量中性能相当,且使用更方便、价格更低廉。为农林生产、环境保护及生态监测提供了一种具有自主知识产权、精准获取土壤紧实度的有效手段。展开更多
文摘The construction and performance characteristics of a novel (diphenhydramine) DPH CC-sensor based on DZCE were reported in this work. The CC-membrane was prepared by incorporating of (diazacrown ether) DZCE and/or (tetraflorophenyl borate) TFPB into a plasticized poly(vinyl chloride) membrane. The CC-sensor revealed a Nernstian behavior over a DPH-concentration range (9.1 × 10<sup>-3</sup> - 6.3 × 10<sup>-7</sup> mol ·L<sup>-1</sup>), and relatively low detection limit (1 × 10<sup>-7</sup> mol ·L<sup>-1</sup>). The potentiometric response was independent on the pH of the solution in the range of 7 - 10. The DPH-CC showed a very short response time (<5 s). It showed good selectivity towards different cations and pharmaceutical compounds. The relative selectivity coefficient was applied for evaluation of the selectivity properties of the DPH-CC. The DPH-CC was used successfully for determination of DPH in its samples. The found recovery range was 95% - 98.5%, and the standard deviation value ranged between 0.13 - 0.42. The DPH-CC facilitates the analysis of DPH directly without pretreatment and it can be built-in as a detector in chromatographic apparatus. It can be used as a tool for on-line monitoring of the drug levels.
基金supported by the National 863 Program under Grant No 2007AA03Z415.
文摘This paper presents the fundamental technique of phase generated carrier （PGC） and its realization on compact reconfigurable input and output （RIO） which adopts real-time and field programmable grate array （FPGA） techniques. Improvement of the PGC technique is also introduced by using peak-to-peak value detection method to reduce the influence of variation of the light intensity. A four-element fibre Bragg gratings （FBG） laser sensor system is conducted in the experiment and the demodulated results demonstrate correlation coefficient as high as 0.995 with the reference signal and the dynamic range to be 120dB@63Hz.
文摘针对目前基于圆锥指数的土壤紧实度测量中,无法消除土壤摩擦力对紧实度测量的影响,要求检测传感器匀速贯入土壤,因此存在使用不便、精度不高的难题。为了提高土壤紧实度实时测量方法的精度及可操作性,在圆锥指数方法基础上,设计了土壤紧实度实时检测传感器,并加入了加速度的同步测量,消除了使用过程中金属杆插入速度不均造成的误差,提高了土壤紧实度测量精度。通过大量试验验证了自制传感器具有较好的静态性能和动态性能,其测量范围为0~900 k Pa,灵敏度为0.041 896,稳定性测量标准差为5 k Pa,测量精度为±0.02%FS,超调量为7.81%,过渡时间为0.632 s。与美国SC-900型土壤紧实度仪对比其准确性的线性拟合决定系数均达到0.96以上,结果表明设计的土壤紧实度传感器与SC-900型土壤紧实度仪在实际测量中性能相当,且使用更方便、价格更低廉。为农林生产、环境保护及生态监测提供了一种具有自主知识产权、精准获取土壤紧实度的有效手段。
