Validation of the Relationship between Precipitable Water and Surface Vapor Pressure by Means of Reanalysis Data

By means of ERA-40, JRA-25, NCEP/NCAR and NCEP/DOE reanalysis data, empirical relations between precipitable water and surface vapor pressure in spatial and temporal scale were calculated. The reliabilities of precipitable water from reanalysis data were validated based on comparing different W-e empirical relations of various reanalysis data, in order to provide basis and reference for reasonable application. The results showed that W-e empirical relation of ERA-40 was closest to that of sounding data in China, and precipitable water from ERA-40 was the most credible. The worldwide comparison among W-e empirical relations of four reanalysis data showed that there was little difference in annual mean W-e empirical relations in the middle latitudes and great differences in low and high latitudes. Seasonal mean W-e empirical relations in the middle latitudes of the northern Hemisphere had little difference in spring, autumn and winter, but great difference in summer. Therefore, the reliabilities of precipitable water from reanalysis data in spring, autumn and winter in the middle latitudes of the northern hemisphere were higher than other areas and seasons. W-e empirical relations of NCEP/NCAR and NCEP/DOE had good stability in different years, while there was poor stability in ERA-40 and JRA-25.

Quantitative relationship between surface sedimentary diatoms and water depth in North-Central Bohai Bay,China

To study the quantitative relationship between surface sedimentary diatoms and water depth,67 surface samples were collected for diatom analysis on eight profiles with water depth variation from the muddy intertidal zone to the shallow sea area in North-Central Bohai Bay,China.The results showed that the distribution of diatoms changed significantly in response to the change in water depth.Furthermore,the quantitative relationship between the distribution of dominant diatom species,their assemblages,and the water depth was established.The water depth optima for seven dominant species such as Cyclotella striata/stylorum,Paralia sulcata,and Coscinodiscus perforatus and the water depth indication range of seven diatom assemblages were obtained in the study area above the water depth(elevation)of-10 m.The quantitative relationship between surface sedimentary diatoms and water depth provides a proxy index for diatom-paleo-water depth reconstruction in the strata in Bohai Bay,China.

The new multistage water adsorption model of Longmaxi Formation shale considering the spatial configuration relationship between organic matter and clay minerals

The water adsorption by shale significantly affects shale gas content and its seepage capacity.However,the mechanism of water adsorption by shale is still unclear due to its strong heterogeneity and complicated pore structure.The relationship between the adsorbed water content at different relative humidities(RHs)and shale compositions,as well as shale pore structure and the spatial configuration relationship between organic matter(OM)and clay minerals,was investigated to clarify the controlling factors and mechanisms of water adsorption by Longmaxi Formation shale from the Southern Sichuan Basin in China.Consequently,the water adsorption process could be generally divided into three different stages from 0%RH to 99%RH.Furthermore,the Johnston’s clay mine ral interlayer pore structure model(JCM),the Freundlich model(FM)and the Dubinin-Astakhov model(DAM)were tested to fit the three water adsorption stages from low RH to high RH,respectively.The fitting results of the JCM and FM at lower RHs were far from good,while the fitting results of DAM at higher RHs were acceptable.Accordingly,two revised models(LRHM and MRHM)considering the spatial configuration relationship between OM and clay minerals were proposed for the two stages with lower RHs,and performed better fitting results indicating the pronounced effect of the spatial configuration relationship between OM and clay minerals on the water adsorption process of Longmaxi Formation shale.The outcomes of this study will contribute to clarifying the water distribution characteristics in the pore network of shale samples with variable water contents.

Relationship between the Water Body Chlorophylla and Water Quality Factors of Wetlands Baiguishan Reservoir

[Objective] The aim was to explore the relationship between water body Chlorophyll-a and water quality factors of wetlands Baiguishan reservoir.[Method] Chlorophyll-a and water quality factors of water quality of Wetlands BaiGuishan Reservoir was studied,the analysis of the relationship on water quality of Wetlands Baiguishan Reservoir was made by use of trophic status indices and SPSS17.0 statistical analysis.[Result] Total phosphorus was an important factor of influence Chlorophyll-a in reservoir,water body had slight eutrophication phenomenon in reservoir of July to October in 2010.[Conclusion] Comprehensive management should be strengthened so as to improve the water quality of Baiguishan wetland.

Relative Abundance and the Relationships between Aniline,Phenol and Catechol Degraders in Fresh Water

Relative abundance and relationships between aniline, phenol and catechol degraders were investigated in unpolluted and polluted fresh waters in Osaka prefecture, Japan. Phenol and catechol degraders were found more frequently compared to aniline degraders. The results indicate that these degraders were more abundant in polluted waters than in unpolluted waters. Aniline degraders isolated from the Ina River water showed a higher capability of degrading catechol than phenol. Analysis on sequence homology among these three kinds of degraders indicated a possible relationship between aniline degraders and certain strains of both catechol and phenol degraders.

Analysis of Coupling between Soil and Water Conservation and Economic-social Development

The coupling relation exists in water and soil conser-vation and economic-social development. The article analyses the relation of soil and water conservation and economic-social development stages as well as the coupling analytical method. Then calculates the expecting income by dispersing Markov decision and calculates the correlation coefficient and the re-lationship degree. The article obtains the relationship of soil and water conservation investments and all kinds of incomes. Finally, it analyzes the important meaning in socio-economic development of water and soil conservation.

A New Class of Simple,General and Efficient Finite Volume Schemes for Overdetermined Thermodynamically Compatible Hyperbolic Systems

In this paper,a new efficient,and at the same time,very simple and general class of thermodynamically compatiblefinite volume schemes is introduced for the discretization of nonlinear,overdetermined,and thermodynamically compatiblefirst-order hyperbolic systems.By construction,the proposed semi-discrete method satisfies an entropy inequality and is nonlinearly stable in the energy norm.A very peculiar feature of our approach is that entropy is discretized directly,while total energy conservation is achieved as a mere consequence of the thermodynamically compatible discretization.The new schemes can be applied to a very general class of nonlinear systems of hyperbolic PDEs,including both,conservative and non-conservative products,as well as potentially stiff algebraic relaxation source terms,provided that the underlying system is overdetermined and therefore satisfies an additional extra conservation law,such as the conservation of total energy density.The proposed family offinite volume schemes is based on the seminal work of Abgrall[1],where for thefirst time a completely general methodology for the design of thermodynamically compatible numerical methods for overdetermined hyperbolic PDE was presented.We apply our new approach to three particular thermodynamically compatible systems:the equations of ideal magnetohydrodynamics(MHD)with thermodynamically compatible generalized Lagrangian multiplier(GLM)divergence cleaning,the unifiedfirst-order hyperbolic model of continuum mechanics proposed by Godunov,Peshkov,and Romenski(GPR model)and thefirst-order hyperbolic model for turbulent shallow waterflows of Gavrilyuk et al.In addition to formal mathematical proofs of the properties of our newfinite volume schemes,we also present a large set of numerical results in order to show their potential,efficiency,and practical applicability.

QSRR Study on the Relationship between the Chromatographic Capacity Factor and Lipophilicity and Structure Parameters of Halogenated Thiophenols

The capacity factors （k＇） of fourteen types ofhalogenated thiophenols in different phases of methanol-water eluent were determined by reversed phased high-performance liquid chromatography （RP-HPLC） and the relationships between the logarithm of capacity factor lgK＇ and methanol ratio ψ were analyzed. A fair linear relationship is found between lgK＇ and ψ, and the correlation coefficients R2 of the constructed linear equations are all greater than 0.990. Relationship between the chromatographic data lgKw＇ when extrapolated to pure water and n-octanol/water partition coefficient lgKow obtained by the group contribution method has shown a good linear correlation with R2= 0.956. The structure parameters of fourteen halogenated thiophenols were calculated by using DFT, and the correlation equation of lgKw＇ and structure parameters was obtained by using SPSS, lgKw＇ = -0.409 ＋ 0.039a and R2 = 0.981, meaning that lgKw＇ is mainly determined by the polarizability α.

Change of Annual Extreme Water Levels and Correlation with River Discharges in the Middle-lower Yangtze River: Characteristics and Possible Affecting Factors

As one of the fastest developing regions in China, the middle-lower Yangtze River （MLYR） is vulnerable to floods and droughts. With obtained time series of annual highest water level （HWL）, annual lowest water level （LWL） and the corresponding fiver discharges from three gauging stations in MLYR that covering the period 1987-2011, the current study evaluated the change character- istics of annual extreme water levels and the correlation with fiver discharges by using the methods of Vend test, Mann-Whitney-Pettitt （MWP） test and double mass analysis. Major result indicated a decreasing/increasing trend for annual HWL/LWL of all stations in MLYR during the study period. A change point in 1999 was identified for annual HWL at the Hankou and Datong stations. The year 2006 was found to be the critical year that the relationship between annual extreme water levels and fiver discharges changed in the MLYR. With contrast to annual LWL in MLYR, further investigation revealed that the change characteristics of annual HWL were highly consistent with regional precipitation in the Yangtze River Basin, while the linkage with Three Gorges Dam （TGD） operation is not strong. Our observation also pointed out that the effect of serious down cutting of the riverbed and the enlargement of the cross-section area during the initial period of TGD operation caused the downward trend of the relationship between annual LWL and river discharge. Whereas, the relatively raised river water level before the flood season due to TGD regulation since 2006 explained for the changing upward trend of the relationship between annual HWL and river discharge.

Structural Characterization and Octanol/water Partition Coefficients(LogP) Prediction for Oxygen-containing Organic Compounds

New descriptors were constructed and structures of some oxygen-containing organic compounds were parameterized. The multiple linear regression（MLR） and partial least squares regression（PLS） methods were employed to build two relationship models between the structures and octanol/water partition coefficients（LogP） of the compounds. The modeling correlation coefficients（R） were 0.976 and 0.922, and the ＂leave one out＂ cross validation correlation coefficients（R（CV）） were 0.973 and 0.909, respectively. The results showed that the structural descriptors could well characterize the molecular structures of the compounds; the stability and predictive power of the models were good.

Experimental and QSPR Studies on n-Octanol/water Partition Coefficient (lgK_(ow)) of Substituted Aniline

The n-octanol/water partition coefficients （lgKow） of 18 substituted anilines were determined at 25 ℃ by shake-flask method. The geometrical optimization of substituted anilines has been performed at B3LYP/6-311G^＊＊ level with Gaussian98 program, and the molecular surface areas of substituted anilines were calculated using ChemOffice 2004 program. The calculated structural parameters of substituted anilines were used as theoretical descriptors and the two-parameter （molecular surface area （MA） and the energy of the highest occupied molecular orbital （EaoMo）） quantitative structure-property relationship （QSPR） model of lgKow for substituted aniline with molecular structural parameters was developed by multi-linear regression method. The regression coefficient square （r^2） is 0.990 and the standard deviation SE 0.109. The model was validated by variance inflation factors （VIF） and t-test, and the results show that there exists small self-correlation between variables of the model with perfect stability. The model gives results in good qualitative agreement with experimental data. At last, the model was applied to predict lgKow values of five substituted anilines whose lgKow values have not been determined experimentally.

Morphological Characteristics of Cambodia Mekong Delta and Tonle Sap Lake and Its Response to River-Lake Water Exchange Pattern

Tonle Sap Lake is the largest river-connected lake, buffer area and ecological zone of Mekong River, which plays a huge role in dispelling flood peak and compensating water, and the conservation of biological diversity. The river-lake relationship between Mekong River and Tonle Sap Lake is unique and has always been a major focus in the international community. The land terrain and under-water topography were used to analyze the morphological characteristics of Cambodia Mekong Delta and Tonle Sap Lake. Long series of hydrological data of river-lake controlling stations were used to analyze the water level variation characteristics and water volume exchange pattern between Mekong River and Tonle Sap Lake, and the response relationship to river-lake morphological characteristics were also researched. The results show that: Cambodia Mekong Delta and Tonle Sap Lake Area is low-lying and flat with gentle channel gradient and water surface gradient, making the relationship between water level and area (or volume) smooth. The channel storage capacity of Mekong River and Tonle Sap River is not enough compared to the inflow, so vast flooding plain is extremely prone to be inundated, making the flood relationships between the left and right banks become very complicated. Tonle Sap Lake is a seasonal freshwater lake with water flowing in and flowing out, and the timing and intensity of water exchange with Mekong River are closely related to the water flow resistance at the exit section of Tonle Sap Lake and the cross-sectional area of Tonle Sap River, which can be reflected by the river-lake water level difference and the water level of Tonle Sap River. Affected by the river-lake morphological characteristics, the water exchange intensity between Mekong River and Tonle Sap Lake is great. Tonle Sap Lake not only stores 14.4% of flood volume (39.7 billion m3) from the Mekong River every year, but also supplies 29.7% of dry water (69.4 billion m3) to the Mekong River. Influenced by the adjustment of the floodplain, the water level fluctuation of Mekong River and Tonle Sap Lake is slow, and the rising and droop rates of water level are positively correlated with the floodplain storage area. The research results will help to understand the relationship mechanism between Mekong River and Tonle Sap Lake and provide a scientific basis for the comprehensive governance of Cambodia Mekong Delta and Tonle Sap Lake Area.

DFT and Position of Cl Substitution (PCS) Methods Studies on n-Octanol/water Partition Coefficients (lgK_(ow)) and Aqueous Solubility (–lgS_w) of All PCDD Congeners

Optimized calculations of 75 PCDDs and their parent DD were carded out at the B3LYP/6-31G＊ level by density functional theory （DFT） method. The structural parameters were obtained and significant correlation between the C1 substitution position and some structural parameters was found. Consequently, the number of C1 substitution positions was taken as theoretical descriptors to establish two novel QSPR models for predicting lgKow and -lgSw of all PCDD congeners. The two models achieved in this work contain two variables （Na and Nβ）, of which r = 0.9312, 0.9965 and SD = 0.27, 0.12 respectively, and t values are all large. The variation inflation factors （VIF） of variables in the two models herein are both less than 5.0, suggesting high accuracy of the lgKow and -lgSw predicting models, and the results of cross-validation test also show that the two models exhibit optimum stability and good predictive power. By comparison, the correlation and predictive ability of the present work are more advantageous than those obtained using semi-empirical AM1 and GC-RI methods.

Combined effect of bicarbonate and water in photosynthetic oxygen evolution and carbon neutrality

Carbon neutrality is widely concerned and highly valued by many countries.Biosphere has always maintained the balance between oxidized organic substances and assimilated organic matter,resulting in netzero carbon dioxide(CO_(2)) emissions and maintaining its own carbon neutrality.Nature has set a good example for human beings to coordinate oxygen(O_(2)) balance and CO_(2)balance,and achieve carbon neutrality.How does photosynthetic oxygen evolution initiate carbon and water neutrality?My synthesis shows that photo system Ⅱ functions as carbonic anhydrase to catalyze the reaction of CO_(2)hydration under physiological conditions,and CO_(2)hydration coupled with chemical equilibrium,H^(+)+HCO_(3)^(-)→1/2O_(2)+2e^(-)+2H^(+)+CO_(2),occurs in a photosystem Ⅱ corecomplex.Meanwhile,I focused on the revisiting of four classical heavy oxygen(O^(18)) labeling experiments and found that bicarbonate can promote photo synthetic oxygen evolution,and that photo synthetic oxygen evolution can alternately come from bicarbonate and water,not only water.Bicarbonate photolysis and water photolysis account for half of the photo synthetic oxygen evolution respectively,which can well explain the bicarbonate effect,Dole effect and plants’ environmental adaptability.Photosynthetic oxygen evolution initiated the journey of water metabolism and carbon metabolism in nature,which led to the coupling as 1:1(mol/mol) stoichiometric relationship between the reduction of CO_(2)and oxidation of organic carbon,coordinated the evolution of the atmosphere,hydrosphere,lithosphere and biosphere,and realized "carbon neutrality" in the whole Earth system.

Mechanism of Photothermal Energy on the Growth and Yield of Rice under Water Level Regulation

The flooding caused by heavy rainfall in rice irrigation area and the drought caused by the drop of groundwater level are the research focus in the field of irrigation and drainage.Based on the comparative experiment and farmland water level control technology,this paper studied the average soil temperature under different soil layers(TM),the daily temperature change(TDC),the photosynthetic accumulation of single leaf and canopy in rice,and response of photothermal energy to rice root characteristics and growth factors in the paddy field under drought conditions.The results showed that the peak soil temperature under drought treatment was basically synchronous with the conventional irrigation,and the it was delayed by 2–6 h under flooding treatment compared to the drought treatment.Under different water gradients,the temperature decreased according to T_(L)>T_(CK)>T_(H)(L,H and CK represented water flooding,drought and control treatments),and the TDC was opposite.In addition to milky stage,the daily photosynthetic(Pn)accumulation of single leaf and canopy in the flooding and drought treated paddy fields were lower than conventional irrigation,and had a negative impact on leaf area index(LAI)and yield(YR),but did not form fatal damage.The root characteristic factors,RL(root length),RW(root weight),R-CR(root-canopy ratio)were promoted with drought,and YR under light drought was slightly higher than that under heavy drought.There was a strong positive correlation between TM and R-CR in all rice growth stages,while TDC-5 was negatively correlated with effective panicle number,TDC and R-CR in 20 cm soil layer were positively correlated.The correlation between daily Pn accumulation and YR was low,and the correlation between Pn and YR factors was negative or weak positive or negative.The total Pn was positively correlated with yield factors,and the correlation coefficient was higher than that of daily Pn.

Water-cut rising mechanism and optimized water injection technology for deepwater turbidite sandstone oilfield: A case study of AKPO Oilfield in Niger Delta Basin, West Africa

Through the analysis of the reservoir connection relationship and the water-cut rising rules after water breakthrough in the highly volatile oil AKPO oilfield, a new model of water-cut rising was established, and the timing and strategy of water injection were put forward. The water-cut rising shapes of producers after water breakthrough can be divided into three types, and their water-cut rising mechanism is mainly controlled by reservoir connectivity. For the producers which directly connect with injectors in the single-phase sand body of the single-phase channel or lobe with good reservoir connectivity, the water-cut rising curve is "sub-convex". For the producers which connect with injectors through sand bodies developed in multi-phases with good inner sand connectivity but poorer physical property and connectivity at the overlapping parts of sands, the response to water injection is slow and the water-cut rising curve is "sub-concave". For the producers which connect with injectors through multi-phase sand bodies with reservoir physical properties, connectivity in between the former two and characteristics of both direct connection and overlapping connection, the response to water injection is slightly slower and the water-cut rising curve is "sub-S". Based on ratio relationship of oil and water relative permeability, a new model of water cut rising was established. Through the fitting analysis of actual production data, the optimal timing and corresponding technology for water injection after water breakthrough were put forward. Composite channel and lobe reservoirs can adopt water injection strategies concentrating on improving the vertical sweep efficiency and areal sweep efficiency respectively. This technology has worked well in the AKPO oilfield and can guide the development of similar oilfields.

Cash gifts,perception of social sphere and distribution of water resources for rural farmers in a typical oasis area in Northwest China

Face-to-face interviews(n=860) were conducted to determine cash-gift behavior, cognition and complexity of social relations, and family water consumption for agricultural production in a typical oasis area in Northwest China. The survey results revealed cash gifts to be the second-largest expenditure(1,330 Yuan) for rural households, far beyond the average spending on health(854.1 Yuan) or education(890.8 Yuan). The amount of cash-gift expenditures indirectly reflects a family's social relations level, and our developed Social Relations Extent Coefficient—based on cash-gift and food expenditures—can directly reflect the extent or level of these relationships. Different types of farmers or farming families have different coefficients. The coefficient also shows how social station affects a family's water resource utilization, and how water is distributed among different types of farmers. Despite the current inequities, however, promotion of better agricultural techniques and large-scale cultivation in this area could help distribute water resources more equitably and effectively.

THE SLUMP RETENTION OF N-2000 HIGH-RANGE WATER-REDUCING AND RETARDING ADMIXTURE

N-2000 is an admixture for concrete, with a low slump loss, high range water-reducing ratio and long-time retarding. The N-2000 is made up of naphthalene-sulfonic-maldehyde polycondensation (NSMP) and ATMP. Its characteristic results from the synergistic effects of NSMP and ATMP. The results show that when 0.7%-1.2% of N-2000 is added to concrete (by mass of cement), the water reducing ratio is up to 20%-30%, and the slump of fresh concrete can be retained for 2 hours without significant loss. N-2000 can not only improve the workability of fresh concrete but also increase the strength of the hardened concrete, especially early strength. It is also proved to have a good compatibility with various cements.

PRELIMINARY STUDIES ON STRUCTURES AND PROPERTIES OF WATER-RETENTIVE, FLAME-RETARDANT ACRYLIC FIBERS

The blend fibers of acrylonitrile-vinylidene chloride-sodium methallysulfonate copolymer(AN-VDC-SMAS) and cellulose acetate (CA) with various blend ratios were investigated bymeans of SEM, DDV, WAXD, etc. The results show that AN-VDC-SMAS and CA areincompatibale; the numerous microvoids in the blend fiber resulted from the phase seperationcan remarkably improve the water absorbability and the dyeing behavior but hardly influencethe mechanical properties. On the other hand, the crystal structure of the continuous phaseAN-VDC-SMAS is not influnced by the dispersed phase CA.

Study on copper complexing ligand concentrations in several China's coastal waters

Copper complexing ligand concentrations in the Daya Bay, Qingdao coast, Jiaozhou Bay, South China Sea and Huanghe Estuary waters were determined by the anodic stripping voltammetry technique. The distribution regularity and the relationship with other parameters were discussed. The results were as follows： Copper complexing ligand concentrations of the South China Sea were a little higher than those of other sea areas, and they were apparently higher than those of the ocean. Compared with the subsurface layer （SSL） in the sea surface microlayer copper complexing ligand concentrations showed an enrichment phenomenon, of which the mechanism is similar to dissolved organic matter. The metal complexing ligand concentration profiles of the South China Sea showed that the value in the sea surface was the highest, then it decreased with depth accruing, and a higher value appeared at the bottom. Copper complex- ing ligand concentrations were higher than those of cadmium and lead. Ligands in each sea area exhibited a complicated property. In short, the distribution regularity of copper complexing ligand concentrations in China＇s coastal waters was consistent with that of other regions in the world. Meanwhile, the positive relationship between the copper complexing ligand concentrations and biological oxygen demand, chemical oxygen demand, dissolved organic carbon, and viscosity were found clearly.