Electromagnetic logging while drilling(LWD)is one of the key technologies of the geosteering and formation evaluation for high-angle and horizontal wells.In this paper,we solve the dipole source-generated magnetic/ele...Electromagnetic logging while drilling(LWD)is one of the key technologies of the geosteering and formation evaluation for high-angle and horizontal wells.In this paper,we solve the dipole source-generated magnetic/electric fields in 2D formations efficiently by the 2.5D finite diff erence method.Particularly,by leveraging the field’s rapid attenuation in spectral domain,we propose truncated Gauss–Hermite quadrature,which is several tens of times faster than traditional inverse fast Fourier transform.By applying the algorithm to the LWD modeling under complex formations,e.g.,folds,fault and sandstone pinch-outs,we analyze the feasibility of the dimension reduction from 2D to 1D.For the formations with smooth lateral changes,like folds,the simplified 1D model’s results agree well with the true responses,which indicate that the 1D simplification with sliding window is feasible.However,for the formation structures with drastic rock properties changes and sharp boundaries,for instance,faults and sandstone pinch-outs,the simplified 1D model will lead to large errors and,therefore,2.5D algorithms should be applied to ensure the accuracy.展开更多
The main purpose of this note is to construct almost complex or complex structures on certain isoparametric hypersurfaces in unit spheres.As a consequence,complex structures on S^(1)×S^(7)×S^(6),and on S^(10...The main purpose of this note is to construct almost complex or complex structures on certain isoparametric hypersurfaces in unit spheres.As a consequence,complex structures on S^(1)×S^(7)×S^(6),and on S^(10)×S^(3)×S(2)with vanishing first Chern class,are built.展开更多
This paper presents the relations between spinors and dual characteristic pairs, and gives a way to get the dual characteristic pairs of Dirac structure associated to a generalized complex structure.
Electrochemical micromachining (EMM) technology for fabricating micro structures is presented in this article. By applying ultra short pulses, dissolution of a workpiece can be restricted to the region very close to...Electrochemical micromachining (EMM) technology for fabricating micro structures is presented in this article. By applying ultra short pulses, dissolution of a workpiece can be restricted to the region very close to the electrode. First, an EMM system for meeting the requirements of the EMM process is established. Second, sets of experiments is carried out to investigate the influence of some of the predominant electrochemical process parameters such as electrical parameters, feed rate, electrode geometry features and electrolyte composition on machining quality, especially the influences of pulse on time on shape precision and working end shape of electrode on machined surface quality. Finally, after the preliminary experiments, a complex microstructure with good shape precision and surface quality is successfully obtained.展开更多
Simulation for stochastic wind field is very important in analyzing dynamic responses of large complex structures due to strong wind.The typical simulation method is the spectrum representation method (SRM),but the SR...Simulation for stochastic wind field is very important in analyzing dynamic responses of large complex structures due to strong wind.The typical simulation method is the spectrum representation method (SRM),but the SRM has drawbacks of inferior precision in lower frequency and slow calculating speed.In view of this,the modified Fourier spectrum method (MFSM) is introduced into the simulation of stochastic wind field in this paper.In this method,phase information of wind velocity time history is determined by cross power spectral density (CPSD) between adjacent points,and the wind velocity time history with time and space correlation is generated by iterative modification for CPSD considering auto power spectral density (APSD).Simulation of the wind field for a long-span bridge is undertaken to verify the effectiveness of the MFSM.Simulation results of the SRM and the MFSM are compared.It can be concluded that the MFSM is more accurate and has higher calculation speed than the SRM.展开更多
In this paper,we introduce the notion of a product structure on a 3-Bihom-Lie algebra,which is a Nijenhuis operator with some conditions.We prove that a 3-Bihom-Lie algebra has a product structure if and only if it is...In this paper,we introduce the notion of a product structure on a 3-Bihom-Lie algebra,which is a Nijenhuis operator with some conditions.We prove that a 3-Bihom-Lie algebra has a product structure if and only if it is the direct sum of two vector spaces which are also Bihom-subalgebras.Then we give four special conditions under each of which a 3-Bihom-Lie algebra has a special decomposition.Similarly,we introduce a complex structure on a 3-Bihom-Lie algebra and there are also four types of special complex structures.Finally,we establish the relation between a complex structure and a product structure.展开更多
We calculate the dimensions of Bott–Chern and Aeppli cohomologies associated to a complex structure on S^(3)×S^(3).We express them in terms mainly of Hogde numbers.
As a matter of fact,most natural structures are complex topology structures with intricate holes or irregular surface morphology.These structures can be used as lightweight infill,porous scaffold,energy absorber or mi...As a matter of fact,most natural structures are complex topology structures with intricate holes or irregular surface morphology.These structures can be used as lightweight infill,porous scaffold,energy absorber or micro-reactor.With the rapid advancement of 3D printing,the complex topology structures can now be efficiently and accurately fabricated by stacking layered materials.The novel manufacturing technology and application background put forward new demands and challenges to the current design methodologies of complex topology structures.In this paper,a brief review on the development of recent complex topology structure design methods was provided;meanwhile,the limitations of existing methods and future work are also discussed in the end.展开更多
The two complexes [HgI_2L](DMF)(1) and [AgL_2](ClO_4)(CH_3CN)(2) were synthesized from the reaction of Schiff base ligand(2-acetylpyridine-p-aminobenzoylhydrazone)(L) with HgI_2 or AgClO_4 respectively. ...The two complexes [HgI_2L](DMF)(1) and [AgL_2](ClO_4)(CH_3CN)(2) were synthesized from the reaction of Schiff base ligand(2-acetylpyridine-p-aminobenzoylhydrazone)(L) with HgI_2 or AgClO_4 respectively. The compounds are characterized by ^1H NMR,FTIR and elemental analysis. The structures of the ligand and two complexes are measured via single-crystal X-ray diffraction. In these two complexes,the structures are both distorted triangular bipyramids with five-coordinated centers.展开更多
A new kind of Schiff base HL(HL= 1-phenyl-3-methyl-4-(p-methylbenzoyl)-5-pyrazolone with L-Leucine methyl ester) and complexes Ni L′_2·0.75C_2H_5OH·0.25H_2O,Cu L′′2(L′ = 1-phenyl-3-methyl-4-(p-meth...A new kind of Schiff base HL(HL= 1-phenyl-3-methyl-4-(p-methylbenzoyl)-5-pyrazolone with L-Leucine methyl ester) and complexes Ni L′_2·0.75C_2H_5OH·0.25H_2O,Cu L′′2(L′ = 1-phenyl-3-methyl-4-(p-methylbenzoyl)-5-pyrazolone with L-leucine ethyl,L′′ = 1-phenyl-3-methyl-4-(p-methylbenzoyl)-5-pyrazolone with L-leucine) have been synthesized and structurally determined by X-ray diffraction. For HL: crystal structure determination indicates that there are two independent HLs with different conformations in one asymmetric unit. For complex 1: the Ni(Ⅱ) ion is six-coordinated by two carbonyl oxygen atoms from pyrazolone ring,two nitrogen atoms from different HL′ and two oxygen atoms from L-Leucine ethyl ester to form a distorted octahedral geometry. For complex 2: the Cu(Ⅱ) ion is four-coordinated by one carbonyl oxygen atom from the pyrazolone ring,one nitrogen atom from HL′′,and two different carboxylic oxygen atoms from L-leucine with the same conformation to form a distorted quadrilateral geometry.展开更多
The mononuclear radical anionic complex [1-N-methyl-1,10-phenanthrolium][Ni(dmit)2](dmit = 1,3-dithiole-2-thione-4,5-dithiolate) with a new countercation has been prepared and its crystal structure was determined ...The mononuclear radical anionic complex [1-N-methyl-1,10-phenanthrolium][Ni(dmit)2](dmit = 1,3-dithiole-2-thione-4,5-dithiolate) with a new countercation has been prepared and its crystal structure was determined by X-ray crystallography at 298 and 80 K. In the mononuclear radical anionic complex, the nickel ion assumes a slightly distorted square-planar geometry. There are two and three kinds of intermolecular interactions between adjacent mononuclear radical anionic complexes in the crystal at 298 and 80 K, respectively(i.e., Models A and B at 298 K; and Models C, D and E at 80 K). The variable-temperature magnetic moments indicate a strong antiferromagnetic interaction between the adjacent mononuclear radical anionic complexes, and the theoretical calculations reveal that the stronger antiferromagnetic coupling strength at lower temperature should be contributed to the larger overlap integrals between the short contact atoms. This study is the first to reveal the mechanism of stronger magnetic coupling strength at lower temperature for a mononuclear radical anionic nickel complex with dmit as the ligand.展开更多
The two title complexes, [Cd{3,5-(NO2)2sal}(2,2′-bipy)]n 1 and [Mn{3,5- (NO2)2sal}(2,2′-bipy)]n 2 (3,5-(NO2)2sal = 3,5-dinitrosalicylate, 2,2'-bipy = 2,2′-bipyridine), were synthesized by the hydrother...The two title complexes, [Cd{3,5-(NO2)2sal}(2,2′-bipy)]n 1 and [Mn{3,5- (NO2)2sal}(2,2′-bipy)]n 2 (3,5-(NO2)2sal = 3,5-dinitrosalicylate, 2,2'-bipy = 2,2′-bipyridine), were synthesized by the hydrothermal reaction and structurally characterized. Complex 1 crystallizes in triclinic, space group P1, a = 5.581(4), b = 12.071(8), c = 12.88(1)A, α= 92.10(3),β= 96.73(3), γ = 102.02(2)°, C17H10N407Cd, Mr = 494.69, V= 841(1)A3, Z = 2, Dc = 1.954 g/cm3, F(000) = 488, μ= 1.353 mm^-1, R = 0.0248 and wR = 0.0761. Complex 2 crystallizes in monoclinic with space group P21/c, a = 8.604(3), b = 23.88(1), c = 8.894(3) A, β = 102.45(1)°, C17H10N407Mn, Mr = 437.23, V= 1785(1) A3, Z=.4, Dc = 1.627 g/cm3, F(000) = 884, μ = 0.791 mm^-1, R = 0.0471 and wR = 0.1250. Complex 1 possesses an infinite 1D polymeric chain structure consisting of the repeated basic four-membered ring units (Cd2O2) and eight-membered ring units (CdOCO)2. Compound 2displays a linear 1D chain through Mn(Ⅱ) atoms and bridging carboxylate groups of 3,5-dinitrosalicylic acid ligands with the Mn…Mn separation of 4.472(2)A. The fluorescence properties and cyclic voltammetric behaviors of the complexes are also reported.展开更多
Eight new ZnⅡ-yⅢ and ZnⅡ-LnⅢ heterometallic Schiff base complexes: MZnL2(NO3)3 (M = Y (1), La (2), Pr (3), Nd (4), Eu (5), Gd (6), Dy (7), Er (8); L = 2-(((2- (imidazo[1,5-a]pyridin-3-yl)p...Eight new ZnⅡ-yⅢ and ZnⅡ-LnⅢ heterometallic Schiff base complexes: MZnL2(NO3)3 (M = Y (1), La (2), Pr (3), Nd (4), Eu (5), Gd (6), Dy (7), Er (8); L = 2-(((2- (imidazo[1,5-a]pyridin-3-yl)phenyl)imino)methyl)-6-methoxyphenol), have been rationally synthesized under solvothermal conditions and characterized by IR, elemental analyses (EA), single-crystal X-ray diffraction, and powder XRD. Furthermore, luminescence in the visible region for solids 1-8 suggested zine/ligand-centered emission at room temperature.展开更多
The reaction of Co^II ions with 1,4-bis(imidazol)butane(bimb) or 1,4-bis(triazol)butane(bitb) in the presence of ClO4^-, respectively affords two CoII coordination complexes, namely {[Co(bimb)3]·2ClO4}n...The reaction of Co^II ions with 1,4-bis(imidazol)butane(bimb) or 1,4-bis(triazol)butane(bitb) in the presence of ClO4^-, respectively affords two CoII coordination complexes, namely {[Co(bimb)3]·2ClO4}n(I) and {[Co(bitb)3]·2ClO4}n(II). Single-crystal X-ray analysis indicates that both complexes I and II show the same α-Po topological structures. However, complex I exhibits a 2-fold interpenetrating network, while complex II features a 3-fold interpenetrating network. In addition, solid-state properties such as thermal stabilities and magnetic properties of two complexes were also investigated.展开更多
The crystal structure of the title complex salt has been determined by single-crystal X-ray structure analysis. The crystal data are as follows; Monoclinic, P21/c, a=15.6480(10)A,b=16.7870(10)A, c=10.347(2)A, β=90.79...The crystal structure of the title complex salt has been determined by single-crystal X-ray structure analysis. The crystal data are as follows; Monoclinic, P21/c, a=15.6480(10)A,b=16.7870(10)A, c=10.347(2)A, β=90.790(10), V=2717.7(6)A3, Z=3, and R=0.0333 for 4789 unique reflections. The complex anion has a pseudo-octahedral structure distorted more than the CrⅢand CoⅢ analogs, in which cach iminodiacetato ligand (ida2-) is coordinated in a facial fashion with the two N atoms in a cis configuration, resulting in an unsyin-fac structure.展开更多
The reactivity of carbonyl iron cluster with alkynes has been studied by the thermal reaction of Fe_3(CO)_(12) with R-C≡C-R'(R = Fc(Ferrocenyl); R′ = Ph(Phenyl), Fc, H). The hexacarbonyldiiron cluster wit...The reactivity of carbonyl iron cluster with alkynes has been studied by the thermal reaction of Fe_3(CO)_(12) with R-C≡C-R'(R = Fc(Ferrocenyl); R′ = Ph(Phenyl), Fc, H). The hexacarbonyldiiron cluster with ferracyclopentadiene ring(μ_2, η~4-C_4Ph_4)Fe_2(CO)_6(1) and one tetraphenyl substituted cyclopentadienone(Ph_4C_4CO)(2) were simultaneously obtained by the reaction of Fe_3(CO)_(12) with alkyne(Ph-C≡C-Ph). Only one ferrole cluster(μ_2, η~4-C_4Fc_2H_2)Fe_2(CO)_6(3) was separated by using Fc-C≡C-H as alkyne. One tri-carbonyl iron complex(η~4-C_4Fc_4CO)Fe(CO)_3(4) and an unexpected new cyclic ketone compound 2,2,4,5-tetraferrocenylcyclopenta-4-en-1,3-di-one [Fc_4C_3(CO)_2](5) were obtained by using Fc-C≡C-Fc as alkyne. A new complex(η4-2,4-diphenyl-3,5-diferrocenylcyclopenta-2,4-dien-1-one)-tricarbonyl iron(η~4-C_4Ph_2Fc_2CO)Fe(CO)_3(6) was synthesized by the reaction of Fe_3(CO)_(12) with Fc-C≡C-Ph. The structures of compounds 1~6 were determined by X-ray single-crystal diffraction and spectroscopic characterization. The crystal structures of two new compounds 5 and 6 were analyzed. Our experimental results reveal the structural models of the reaction products are affected by the kinds of substituents from alkynes R-C≡C-R′.展开更多
Two complexes, [Cd(nphth)(2,2'-bipy)(H20)]2.2H20 (1) and [Cd(nphth)(4,4'- bipy)(H20)], (2) (nphth = 3-nitrophthalate, 2,2'-bipy = 2,2'-bipyridine, 4,4'-bipy = 4,4'-bipyridine), were synthesized...Two complexes, [Cd(nphth)(2,2'-bipy)(H20)]2.2H20 (1) and [Cd(nphth)(4,4'- bipy)(H20)], (2) (nphth = 3-nitrophthalate, 2,2'-bipy = 2,2'-bipyridine, 4,4'-bipy = 4,4'-bipyridine), were synthesized by hydrothermal reactions and structurally characterized. Complex 1 crystallizes in triclinic with space group Pi, a = 0.7599(4), b = 1.0551(6), c = 1.2448(6) nm, α = 88.96(2), β = 75.40(2), γ= 76.76(2)°, V= 0.9393(9) nm3, Z = 1, Dc = 1.816 Mg/m3, F(000) = 512, μ = 1.217 mm-1, S = 0.946, the final R = 0.0238 and wR = 0.0631, Complex 2 crystallizes in monoclinic, space group P21/c, a = 0.737(5), b = 2.338(1), c = 1.0030(6) nm, β = 96:359(9)°, V= 1.803(2) nm3, Z = 4, Dc = 1.826 Mg/m3, F (000) = 984,μ = 1.260 mm-1, S = 1.016, the final R = 0.0455 and wR = 0.1007. Complex 1 exhibits a discrete cyclic binuclear structure and complex 2 possesses a 2D layer structure with cyclic binuclear unit. The fluorescent spectrum study shows that complex 1 exhibits fluorescent emission in the solid state at room temperature.展开更多
Two new mononuclear complexes, namely [Co(L)2](1) and [Mn(L)2](2)(HL = N-(3-methylsalicylidene)tryptamine), have been synthesized by the reactions of the ligand with cobalt acetate or manganese acetate in ...Two new mononuclear complexes, namely [Co(L)2](1) and [Mn(L)2](2)(HL = N-(3-methylsalicylidene)tryptamine), have been synthesized by the reactions of the ligand with cobalt acetate or manganese acetate in anhydrous ethanol. The crystal structures of the complexes were characterized by IR spectrum, elemental analysis, PXRD and single-crystal X-ray diffraction analysis. Complex 1 crystallizes in monoclinic, space group C2/c, with a = 23.146(2), b = 9.4864(10), c = 13.9261(15)A, β = 102.898(2)°, V = 2980.6(5) ?3, Z = 4, Dc = 1.367 g/cm3, F(000) = 1284 and μ = 0.616 mm^-1. Complex 2 crystallizes in monoclinic, space group P21/n, with a = 14.807(11), b = 13.118(10), c = 16.663(13) A, β = 111.237(14)°, V = 3017(4) A^3, Z = 4, Dc = 1.342 g/cm^3, F(000) = 1276 and μ = 0.477 mm-1. The units of complex 1 are linked by intermolecular N–H…π hydrogen bonds into infinite 1D chains, which are further extended into a 3D supramolecular structure by a series of π···π stacking interactions. The units of complex 2 are linked by intermolecular N–H…π hydrogen bonds and C–H…π hydrogen bonds into an infinite 3D supramolecular structure. Meanwhile, the antibacterial activities of the ligand and its complexes have been tested against four kinds of bacteria. The results show that the three compounds all have excellent antibacterial activities and that 1 and 2 possess stronger inhibiting effects against the bacteria than the Schiff base.展开更多
Consider the real, simply-connected, connected, s-step nilpotent Lie group G endowed with a left-invariant, integrable almost complex structure J, which is nilpotent. Consider the simply-connected, connected nilpotent...Consider the real, simply-connected, connected, s-step nilpotent Lie group G endowed with a left-invariant, integrable almost complex structure J, which is nilpotent. Consider the simply-connected, connected nilpotent Lie group Gk, defined by the nilpotent Lie algebra g/ak, where g is the Lie algebra of G, and ak is an ideal of g. Then, J gives rise to an almost complex structure Jk on Gk. The main conclusion obtained is as follows: if the almost complex structure J of a nilpotent Lie group G is nilpotent, then J can give rise to a left-invariant integrable almost complex structure Jk on the nilpotent Lie group Gk, and Jk is also nilpotent.展开更多
Large-scale 3D physical models of complex structures can be used to simulate hydrocarbon exploration areas. The high-fidelity simulation of actual structures poses challenges to model building and quality control. Suc...Large-scale 3D physical models of complex structures can be used to simulate hydrocarbon exploration areas. The high-fidelity simulation of actual structures poses challenges to model building and quality control. Such models can be used to collect wideazimuth, multi-azimuth, and full-azimuth seismic data that can be used to verify various 3D processing and interpretation methods. Faced with nonideal imaging problems owing to the extensive complex surface conditions and subsurface structures in the oil-rich foreland basins of western China, we designed and built the KS physical model based on the complex subsurface structure. This is the largest and most complex 3D physical model built to date. The physical modeling technology advancements mainly involve 1) the model design method, 2) the model casting flow, and 3) data acquisition. A 3D velocity model of the physical model was obtained for the first time, and the model building precision was quantitatively analyzed. The absolute error was less than 3 mm, which satisfies the experimental requirements. The 3D velocity model obtained from 3D measurements of the model layers is the basis for testing various imaging methods. Furthermore, the model is considered a standard in seismic physical modeling technology.展开更多
基金the National Natural Science Foundation of China (41674131,41574118,41974146,41904109)the Fundamental Research Funds for the Central Universities (17CX06041,17CX06044)the China National Science and Technology Major Project (2016ZX05007-004,2017ZX05072-002)
文摘Electromagnetic logging while drilling(LWD)is one of the key technologies of the geosteering and formation evaluation for high-angle and horizontal wells.In this paper,we solve the dipole source-generated magnetic/electric fields in 2D formations efficiently by the 2.5D finite diff erence method.Particularly,by leveraging the field’s rapid attenuation in spectral domain,we propose truncated Gauss–Hermite quadrature,which is several tens of times faster than traditional inverse fast Fourier transform.By applying the algorithm to the LWD modeling under complex formations,e.g.,folds,fault and sandstone pinch-outs,we analyze the feasibility of the dimension reduction from 2D to 1D.For the formations with smooth lateral changes,like folds,the simplified 1D model’s results agree well with the true responses,which indicate that the 1D simplification with sliding window is feasible.However,for the formation structures with drastic rock properties changes and sharp boundaries,for instance,faults and sandstone pinch-outs,the simplified 1D model will lead to large errors and,therefore,2.5D algorithms should be applied to ensure the accuracy.
基金The project is partially supported by the NSFC(11871282,11931007)BNSF(Z190003)Nankai Zhide Foundation.
文摘The main purpose of this note is to construct almost complex or complex structures on certain isoparametric hypersurfaces in unit spheres.As a consequence,complex structures on S^(1)×S^(7)×S^(6),and on S^(10)×S^(3)×S(2)with vanishing first Chern class,are built.
基金Supported by the Science and Technology Project of Beijing Municipal Commission of Education(SQKM201211232017) Supported by the National Science Foundation of China(Ill26152)
文摘This paper presents the relations between spinors and dual characteristic pairs, and gives a way to get the dual characteristic pairs of Dirac structure associated to a generalized complex structure.
基金National Natural Science Foundation of China (50635040)National High-tech Research and Development Program (2009AA04Z302)Jiangsu Provincial Natural Science Foundation (BK2008043)
文摘Electrochemical micromachining (EMM) technology for fabricating micro structures is presented in this article. By applying ultra short pulses, dissolution of a workpiece can be restricted to the region very close to the electrode. First, an EMM system for meeting the requirements of the EMM process is established. Second, sets of experiments is carried out to investigate the influence of some of the predominant electrochemical process parameters such as electrical parameters, feed rate, electrode geometry features and electrolyte composition on machining quality, especially the influences of pulse on time on shape precision and working end shape of electrode on machined surface quality. Finally, after the preliminary experiments, a complex microstructure with good shape precision and surface quality is successfully obtained.
基金Project supported by the National Natural Science Foundation of China (No.90915004)the Six Talents Peak in Jiangsu Province(No.2008178)the 333 High-Level Talent Training Project of Jiangsu Province,China
文摘Simulation for stochastic wind field is very important in analyzing dynamic responses of large complex structures due to strong wind.The typical simulation method is the spectrum representation method (SRM),but the SRM has drawbacks of inferior precision in lower frequency and slow calculating speed.In view of this,the modified Fourier spectrum method (MFSM) is introduced into the simulation of stochastic wind field in this paper.In this method,phase information of wind velocity time history is determined by cross power spectral density (CPSD) between adjacent points,and the wind velocity time history with time and space correlation is generated by iterative modification for CPSD considering auto power spectral density (APSD).Simulation of the wind field for a long-span bridge is undertaken to verify the effectiveness of the MFSM.Simulation results of the SRM and the MFSM are compared.It can be concluded that the MFSM is more accurate and has higher calculation speed than the SRM.
基金Supported by NNSF of China(No.12271085 and No.12071405)supported by Sichuan Science and Technology Program(No.2023NSFSC1287).
文摘In this paper,we introduce the notion of a product structure on a 3-Bihom-Lie algebra,which is a Nijenhuis operator with some conditions.We prove that a 3-Bihom-Lie algebra has a product structure if and only if it is the direct sum of two vector spaces which are also Bihom-subalgebras.Then we give four special conditions under each of which a 3-Bihom-Lie algebra has a special decomposition.Similarly,we introduce a complex structure on a 3-Bihom-Lie algebra and there are also four types of special complex structures.Finally,we establish the relation between a complex structure and a product structure.
文摘We calculate the dimensions of Bott–Chern and Aeppli cohomologies associated to a complex structure on S^(3)×S^(3).We express them in terms mainly of Hogde numbers.
基金supported by Science Fund for Creative Research Groups of National Natural Science Foundation of China(No.51521064)the National Nature Science Foundation of China(No.51575483).
文摘As a matter of fact,most natural structures are complex topology structures with intricate holes or irregular surface morphology.These structures can be used as lightweight infill,porous scaffold,energy absorber or micro-reactor.With the rapid advancement of 3D printing,the complex topology structures can now be efficiently and accurately fabricated by stacking layered materials.The novel manufacturing technology and application background put forward new demands and challenges to the current design methodologies of complex topology structures.In this paper,a brief review on the development of recent complex topology structure design methods was provided;meanwhile,the limitations of existing methods and future work are also discussed in the end.
基金Supported by the National Natural Science Foundation of China(No.21061003)
文摘The two complexes [HgI_2L](DMF)(1) and [AgL_2](ClO_4)(CH_3CN)(2) were synthesized from the reaction of Schiff base ligand(2-acetylpyridine-p-aminobenzoylhydrazone)(L) with HgI_2 or AgClO_4 respectively. The compounds are characterized by ^1H NMR,FTIR and elemental analysis. The structures of the ligand and two complexes are measured via single-crystal X-ray diffraction. In these two complexes,the structures are both distorted triangular bipyramids with five-coordinated centers.
文摘A new kind of Schiff base HL(HL= 1-phenyl-3-methyl-4-(p-methylbenzoyl)-5-pyrazolone with L-Leucine methyl ester) and complexes Ni L′_2·0.75C_2H_5OH·0.25H_2O,Cu L′′2(L′ = 1-phenyl-3-methyl-4-(p-methylbenzoyl)-5-pyrazolone with L-leucine ethyl,L′′ = 1-phenyl-3-methyl-4-(p-methylbenzoyl)-5-pyrazolone with L-leucine) have been synthesized and structurally determined by X-ray diffraction. For HL: crystal structure determination indicates that there are two independent HLs with different conformations in one asymmetric unit. For complex 1: the Ni(Ⅱ) ion is six-coordinated by two carbonyl oxygen atoms from pyrazolone ring,two nitrogen atoms from different HL′ and two oxygen atoms from L-Leucine ethyl ester to form a distorted octahedral geometry. For complex 2: the Cu(Ⅱ) ion is four-coordinated by one carbonyl oxygen atom from the pyrazolone ring,one nitrogen atom from HL′′,and two different carboxylic oxygen atoms from L-leucine with the same conformation to form a distorted quadrilateral geometry.
基金supported by the National Natural Science Foundation of China(No.20971080)the Natural Science Foundation of Shandong Province(No.ZR2013BM009)
文摘The mononuclear radical anionic complex [1-N-methyl-1,10-phenanthrolium][Ni(dmit)2](dmit = 1,3-dithiole-2-thione-4,5-dithiolate) with a new countercation has been prepared and its crystal structure was determined by X-ray crystallography at 298 and 80 K. In the mononuclear radical anionic complex, the nickel ion assumes a slightly distorted square-planar geometry. There are two and three kinds of intermolecular interactions between adjacent mononuclear radical anionic complexes in the crystal at 298 and 80 K, respectively(i.e., Models A and B at 298 K; and Models C, D and E at 80 K). The variable-temperature magnetic moments indicate a strong antiferromagnetic interaction between the adjacent mononuclear radical anionic complexes, and the theoretical calculations reveal that the stronger antiferromagnetic coupling strength at lower temperature should be contributed to the larger overlap integrals between the short contact atoms. This study is the first to reveal the mechanism of stronger magnetic coupling strength at lower temperature for a mononuclear radical anionic nickel complex with dmit as the ligand.
基金the National Natural Science Foundation of China (No. 20431010)
文摘The two title complexes, [Cd{3,5-(NO2)2sal}(2,2′-bipy)]n 1 and [Mn{3,5- (NO2)2sal}(2,2′-bipy)]n 2 (3,5-(NO2)2sal = 3,5-dinitrosalicylate, 2,2'-bipy = 2,2′-bipyridine), were synthesized by the hydrothermal reaction and structurally characterized. Complex 1 crystallizes in triclinic, space group P1, a = 5.581(4), b = 12.071(8), c = 12.88(1)A, α= 92.10(3),β= 96.73(3), γ = 102.02(2)°, C17H10N407Cd, Mr = 494.69, V= 841(1)A3, Z = 2, Dc = 1.954 g/cm3, F(000) = 488, μ= 1.353 mm^-1, R = 0.0248 and wR = 0.0761. Complex 2 crystallizes in monoclinic with space group P21/c, a = 8.604(3), b = 23.88(1), c = 8.894(3) A, β = 102.45(1)°, C17H10N407Mn, Mr = 437.23, V= 1785(1) A3, Z=.4, Dc = 1.627 g/cm3, F(000) = 884, μ = 0.791 mm^-1, R = 0.0471 and wR = 0.1250. Complex 1 possesses an infinite 1D polymeric chain structure consisting of the repeated basic four-membered ring units (Cd2O2) and eight-membered ring units (CdOCO)2. Compound 2displays a linear 1D chain through Mn(Ⅱ) atoms and bridging carboxylate groups of 3,5-dinitrosalicylic acid ligands with the Mn…Mn separation of 4.472(2)A. The fluorescence properties and cyclic voltammetric behaviors of the complexes are also reported.
基金supported by the National Natural Science Foundation of China(21272167 and 21201127)Starting-up Foundation(Q410900111 and Q410900211)+1 种基金Scientific Research Foundation of Soochow University(SDY2012A07)the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)
文摘Eight new ZnⅡ-yⅢ and ZnⅡ-LnⅢ heterometallic Schiff base complexes: MZnL2(NO3)3 (M = Y (1), La (2), Pr (3), Nd (4), Eu (5), Gd (6), Dy (7), Er (8); L = 2-(((2- (imidazo[1,5-a]pyridin-3-yl)phenyl)imino)methyl)-6-methoxyphenol), have been rationally synthesized under solvothermal conditions and characterized by IR, elemental analyses (EA), single-crystal X-ray diffraction, and powder XRD. Furthermore, luminescence in the visible region for solids 1-8 suggested zine/ligand-centered emission at room temperature.
基金Supported by the National Natural Science Foundation of China(Nos.21301106,21201109 and 21373122)
文摘The reaction of Co^II ions with 1,4-bis(imidazol)butane(bimb) or 1,4-bis(triazol)butane(bitb) in the presence of ClO4^-, respectively affords two CoII coordination complexes, namely {[Co(bimb)3]·2ClO4}n(I) and {[Co(bitb)3]·2ClO4}n(II). Single-crystal X-ray analysis indicates that both complexes I and II show the same α-Po topological structures. However, complex I exhibits a 2-fold interpenetrating network, while complex II features a 3-fold interpenetrating network. In addition, solid-state properties such as thermal stabilities and magnetic properties of two complexes were also investigated.
文摘The crystal structure of the title complex salt has been determined by single-crystal X-ray structure analysis. The crystal data are as follows; Monoclinic, P21/c, a=15.6480(10)A,b=16.7870(10)A, c=10.347(2)A, β=90.790(10), V=2717.7(6)A3, Z=3, and R=0.0333 for 4789 unique reflections. The complex anion has a pseudo-octahedral structure distorted more than the CrⅢand CoⅢ analogs, in which cach iminodiacetato ligand (ida2-) is coordinated in a facial fashion with the two N atoms in a cis configuration, resulting in an unsyin-fac structure.
基金supported by the National Natural Science Foundation of China(Nos.21266019,21062011 and 21462029)Inner Mongolia Autonomous Region Higher Scientific Research Project(NJZY14060)
文摘The reactivity of carbonyl iron cluster with alkynes has been studied by the thermal reaction of Fe_3(CO)_(12) with R-C≡C-R'(R = Fc(Ferrocenyl); R′ = Ph(Phenyl), Fc, H). The hexacarbonyldiiron cluster with ferracyclopentadiene ring(μ_2, η~4-C_4Ph_4)Fe_2(CO)_6(1) and one tetraphenyl substituted cyclopentadienone(Ph_4C_4CO)(2) were simultaneously obtained by the reaction of Fe_3(CO)_(12) with alkyne(Ph-C≡C-Ph). Only one ferrole cluster(μ_2, η~4-C_4Fc_2H_2)Fe_2(CO)_6(3) was separated by using Fc-C≡C-H as alkyne. One tri-carbonyl iron complex(η~4-C_4Fc_4CO)Fe(CO)_3(4) and an unexpected new cyclic ketone compound 2,2,4,5-tetraferrocenylcyclopenta-4-en-1,3-di-one [Fc_4C_3(CO)_2](5) were obtained by using Fc-C≡C-Fc as alkyne. A new complex(η4-2,4-diphenyl-3,5-diferrocenylcyclopenta-2,4-dien-1-one)-tricarbonyl iron(η~4-C_4Ph_2Fc_2CO)Fe(CO)_3(6) was synthesized by the reaction of Fe_3(CO)_(12) with Fc-C≡C-Ph. The structures of compounds 1~6 were determined by X-ray single-crystal diffraction and spectroscopic characterization. The crystal structures of two new compounds 5 and 6 were analyzed. Our experimental results reveal the structural models of the reaction products are affected by the kinds of substituents from alkynes R-C≡C-R′.
基金supported by the National Natural Science Foundation of China(21371088)the Education Department of Fujian Province(No.JK2012048,JA12310,JB12207)
文摘Two complexes, [Cd(nphth)(2,2'-bipy)(H20)]2.2H20 (1) and [Cd(nphth)(4,4'- bipy)(H20)], (2) (nphth = 3-nitrophthalate, 2,2'-bipy = 2,2'-bipyridine, 4,4'-bipy = 4,4'-bipyridine), were synthesized by hydrothermal reactions and structurally characterized. Complex 1 crystallizes in triclinic with space group Pi, a = 0.7599(4), b = 1.0551(6), c = 1.2448(6) nm, α = 88.96(2), β = 75.40(2), γ= 76.76(2)°, V= 0.9393(9) nm3, Z = 1, Dc = 1.816 Mg/m3, F(000) = 512, μ = 1.217 mm-1, S = 0.946, the final R = 0.0238 and wR = 0.0631, Complex 2 crystallizes in monoclinic, space group P21/c, a = 0.737(5), b = 2.338(1), c = 1.0030(6) nm, β = 96:359(9)°, V= 1.803(2) nm3, Z = 4, Dc = 1.826 Mg/m3, F (000) = 984,μ = 1.260 mm-1, S = 1.016, the final R = 0.0455 and wR = 0.1007. Complex 1 exhibits a discrete cyclic binuclear structure and complex 2 possesses a 2D layer structure with cyclic binuclear unit. The fluorescent spectrum study shows that complex 1 exhibits fluorescent emission in the solid state at room temperature.
基金supported by the National Natural Science Foundation of China(No.21272008)the Natural Science Industry-University-Research Foundation of Suzhou University(2015hx014)
文摘Two new mononuclear complexes, namely [Co(L)2](1) and [Mn(L)2](2)(HL = N-(3-methylsalicylidene)tryptamine), have been synthesized by the reactions of the ligand with cobalt acetate or manganese acetate in anhydrous ethanol. The crystal structures of the complexes were characterized by IR spectrum, elemental analysis, PXRD and single-crystal X-ray diffraction analysis. Complex 1 crystallizes in monoclinic, space group C2/c, with a = 23.146(2), b = 9.4864(10), c = 13.9261(15)A, β = 102.898(2)°, V = 2980.6(5) ?3, Z = 4, Dc = 1.367 g/cm3, F(000) = 1284 and μ = 0.616 mm^-1. Complex 2 crystallizes in monoclinic, space group P21/n, with a = 14.807(11), b = 13.118(10), c = 16.663(13) A, β = 111.237(14)°, V = 3017(4) A^3, Z = 4, Dc = 1.342 g/cm^3, F(000) = 1276 and μ = 0.477 mm-1. The units of complex 1 are linked by intermolecular N–H…π hydrogen bonds into infinite 1D chains, which are further extended into a 3D supramolecular structure by a series of π···π stacking interactions. The units of complex 2 are linked by intermolecular N–H…π hydrogen bonds and C–H…π hydrogen bonds into an infinite 3D supramolecular structure. Meanwhile, the antibacterial activities of the ligand and its complexes have been tested against four kinds of bacteria. The results show that the three compounds all have excellent antibacterial activities and that 1 and 2 possess stronger inhibiting effects against the bacteria than the Schiff base.
文摘Consider the real, simply-connected, connected, s-step nilpotent Lie group G endowed with a left-invariant, integrable almost complex structure J, which is nilpotent. Consider the simply-connected, connected nilpotent Lie group Gk, defined by the nilpotent Lie algebra g/ak, where g is the Lie algebra of G, and ak is an ideal of g. Then, J gives rise to an almost complex structure Jk on Gk. The main conclusion obtained is as follows: if the almost complex structure J of a nilpotent Lie group G is nilpotent, then J can give rise to a left-invariant integrable almost complex structure Jk on the nilpotent Lie group Gk, and Jk is also nilpotent.
基金sponsored by National Science and Technology Major Project(2011ZX05046-001)
文摘Large-scale 3D physical models of complex structures can be used to simulate hydrocarbon exploration areas. The high-fidelity simulation of actual structures poses challenges to model building and quality control. Such models can be used to collect wideazimuth, multi-azimuth, and full-azimuth seismic data that can be used to verify various 3D processing and interpretation methods. Faced with nonideal imaging problems owing to the extensive complex surface conditions and subsurface structures in the oil-rich foreland basins of western China, we designed and built the KS physical model based on the complex subsurface structure. This is the largest and most complex 3D physical model built to date. The physical modeling technology advancements mainly involve 1) the model design method, 2) the model casting flow, and 3) data acquisition. A 3D velocity model of the physical model was obtained for the first time, and the model building precision was quantitatively analyzed. The absolute error was less than 3 mm, which satisfies the experimental requirements. The 3D velocity model obtained from 3D measurements of the model layers is the basis for testing various imaging methods. Furthermore, the model is considered a standard in seismic physical modeling technology.