Complex engineered systems are often difficult to analyze and design due to the tangled interdependencies among their subsystems and components. Conventional design methods often need exact modeling or accurate struct...Complex engineered systems are often difficult to analyze and design due to the tangled interdependencies among their subsystems and components. Conventional design methods often need exact modeling or accurate structure decomposition, which limits their practical application. The rapid expansion of data makes utilizing data to guide and improve system design indispensable in practical engineering. In this paper, a data driven uncertainty evaluation approach is proposed to support the design of complex engineered systems. The core of the approach is a data-mining based uncertainty evaluation method that predicts the uncertainty level of a specific system design by means of analyzing association relations along different system attributes and synthesizing the information entropy of the covered attribute areas, and a quantitative measure of system uncertainty can be obtained accordingly. Monte Carlo simulation is introduced to get the uncertainty extrema, and the possible data distributions under different situations is discussed in detail The uncertainty values can be normalized using the simulation results and the values can be used to evaluate different system designs. A prototype system is established, and two case studies have been carded out. The case of an inverted pendulum system validates the effectiveness of the proposed method, and the case of an oil sump design shows the practicability when two or more design plans need to be compared. This research can be used to evaluate the uncertainty of complex engineered systems completely relying on data, and is ideally suited for plan selection and performance analysis in system design.展开更多
With the development of science and technology as well as the diversification and individualization of market demand,modern products update more and more rapidly.e rapid development of new products to satisfy the incr...With the development of science and technology as well as the diversification and individualization of market demand,modern products update more and more rapidly.e rapid development of new products to satisfy the increasingly improved and personalized customer demands greatly depends on the progress in the innovative design theory and performance optimization展开更多
In the conceptual design stage of complex products, CBR(Case-Based Reasoning) tool is useful to offer a feasible set of schemes. Then the most adaptive scheme can be generated through a procedure of comparison and e...In the conceptual design stage of complex products, CBR(Case-Based Reasoning) tool is useful to offer a feasible set of schemes. Then the most adaptive scheme can be generated through a procedure of comparison and evaluation. The procedure is essentially a multiple criteria decision-making problem. The traditional multiple criteria programming is not flexible enough in executing the system evaluation algorithm due to both the limited experimental data and the lack of human experiences. To make the CBR tool to be more efficient, a new method for the best choice among the feasible schemes based on the Fuzzy AHP using Fuzzy numbers (FFAHP) is proposed. Since the final results become a problem of ranking the mean of fuzzy numbers by the optimism of decision-maker using the FFAHP, its execution is much more intuitive and effective than with the traditional method.展开更多
In this paper, the method based on uniform design and neural network is proposed to model the complex system. In order to express the system characteristics all round, uniform design method is used to choose the model...In this paper, the method based on uniform design and neural network is proposed to model the complex system. In order to express the system characteristics all round, uniform design method is used to choose the modeling samples and obtain the overall information of the system;for the purpose of modeling the system or its characteristics, the artificial neural network is used to construct the model. Experiment indicates that this method can model the complex system effectively.展开更多
To design approximately linear-phase complex coefficient finite impulse response (FIR) digital filters with arbitrary magnitude and group delay responses, a novel neural network approach is studied. The approach is ...To design approximately linear-phase complex coefficient finite impulse response (FIR) digital filters with arbitrary magnitude and group delay responses, a novel neural network approach is studied. The approach is based on a batch back-propagation neural network algorithm by directly minimizing the real magnitude error and phase error from the linear-phase to obtain the filter's coefficients. The approach can deal with both the real and complex coefficient FIR digital filters design problems. The main advantage of the proposed design method is the significant reduction in the group delay error. The effectiveness of the proposed method is illustrated with two optimal design examples.展开更多
This paper presents a complex design of frequency modulated interrupted continuous wave (FMICW) and frequency-coded pulses (FCP) for detection of aircraft and ship targets. Here, FMICW is used to satisfy requirements ...This paper presents a complex design of frequency modulated interrupted continuous wave (FMICW) and frequency-coded pulses (FCP) for detection of aircraft and ship targets. Here, FMICW is used to satisfy requirements of aircraft detection and FCP is used to satisfy requirements of ship detection for the differences in maneuverability and scatter characteristics of targets and interference background. The design of such a complex waveform for detection of aircraft and ship targets by a HF radar is discussed in detail with different considerations for better performance.展开更多
The engineering problems today become more and more complex particularly in the area of new product development. It requires the multi-disciplinary design method to solve complex problems. This paper presents an integ...The engineering problems today become more and more complex particularly in the area of new product development. It requires the multi-disciplinary design method to solve complex problems. This paper presents an integrated design system for solving complexity during multi-disciplinary design. Complexity could be solved if the design problems, given by any individuals who are concerned, are structured. The design system uses the multi-viewpoint concept to allow experts to share their information and knowledge in common views. Knowledge modules are used to store semantics from the experts of different disciplines. Then the system agent acts as an internal designer to help support the individuals to translate any semantics provided from one discipline and then propagate to other related disciplines. With these tools, the integrated design system can structure and solve the complexity of design problems.展开更多
With the acceleration of urbanization, city complex as an intensive urban organization form has gradually grown up in China. By consulting relevant documents of city complex, emergence background and related concepts ...With the acceleration of urbanization, city complex as an intensive urban organization form has gradually grown up in China. By consulting relevant documents of city complex, emergence background and related concepts of city complex were introduced, landscape design of Chenglong-International was analyzed to propose landscape design principles and concepts of city complex under the compound development model, landscape processing techniques of outdoor functional subareas and transitional areas were introduced to provide useful reference for the landscape design of city complex.展开更多
The current research of complex nonlinear system robust optimization mainly focuses on the features of design parameters, such as probability density functions, boundary conditions, etc. After parameters study, high-d...The current research of complex nonlinear system robust optimization mainly focuses on the features of design parameters, such as probability density functions, boundary conditions, etc. After parameters study, high-dimensional curve or robust control design is used to find an accurate robust solution. However, there may exist complex interaction between parameters and practical engineering system. With the increase of the number of parameters, it is getting hard to determine high-dimensional curves and robust control methods, thus it's difficult to get the robust design solutions. In this paper, a method of global sensitivity analysis based on divided variables in groups is proposed. By making relevant variables in one group and keeping each other independent among sets of variables, global sensitivity analysis is conducted in grouped variables and the importance of parameters is evaluated by calculating the contribution value of each parameter to the total variance of system response. By ranking the importance of input parameters, relatively important parameters are chosen to conduct robust design analysis of the system. By applying this method to the robust optimization design of a real complex nonlinear system-a vehicle occupant restraint system with multi-parameter, good solution is gained and the response variance of the objective function is reduced to 0.01, which indicates that the robustness of the occupant restraint system is improved in a great degree and the method is effective and valuable for the robust design of complex nonlinear system. This research proposes a new method which can be used to obtain solutions for complex nonlinear system robust design.展开更多
Minimizing the impact of the mixed uncertainties(i.e.,the aleatory uncertainty and the epistemic uncertainty) for a complex product of compliant mechanism(CPCM) quality improvement signifies a fascinating research top...Minimizing the impact of the mixed uncertainties(i.e.,the aleatory uncertainty and the epistemic uncertainty) for a complex product of compliant mechanism(CPCM) quality improvement signifies a fascinating research topic to enhance the robustness.However, most of the existing works in the CPCM robust design optimization neglect the mixed uncertainties, which might result in an unstable design or even an infeasible design. To solve this issue, a response surface methodology-based hybrid robust design optimization(RSM-based HRDO) approach is proposed to improve the robustness of the quality characteristic for the CPCM via considering the mixed uncertainties in the robust design optimization. A bridge-type amplification mechanism is used to manifest the effectiveness of the proposed approach. The comparison results prove that the proposed approach can not only keep its superiority in the robustness, but also provide a robust scheme for optimizing the design parameters.展开更多
Innovation design for complex products is a difficult issue in the military manufacturing industry. Ontology may provide a feasible way to rebuild the design process for complex products via sharing and reusing of des...Innovation design for complex products is a difficult issue in the military manufacturing industry. Ontology may provide a feasible way to rebuild the design process for complex products via sharing and reusing of design knowledge. In this paper, a design method used in the innovation design process of the complex products with knowledge modeling is proposed. Knowledge modeling is realized through ontology construction by combining the cycling evolutional theory of constructing ontology and OWL (Ontology Web Language)-based knowledge representation. As a case study, the satellite is selected as one of the complex products. The application domain of the satellite ontology is analyzed. According to the analysis result, the knowledge structure of satellite ontology is put forward based on OWL. The application of satellite product design shows that the method can effectively organize and reuse the knowledge resources in the innovation design of complex product and help companies to create more competitive products based on the existing knowledge and experience.展开更多
The number of products used as agro-chemicals, food additives, flavors, aromas, pharmaceuticals and nutraceuticals which are made by fermentation or extraction from plants has increased significantly. Despite this gro...The number of products used as agro-chemicals, food additives, flavors, aromas, pharmaceuticals and nutraceuticals which are made by fermentation or extraction from plants has increased significantly. Despite this growth, initial predictions for a potential product purification process for these complex mixtures remains entirely experimentally based. The present work represents an initial study to demonstrate the benefits of a systematic approach. For process development of chemically well-studied systems model based process design methods are already available. Therefore the proposed approach focuses on a method for the efficient characterization of the physical properties of the key components. Once this is adequately defined, unit operations and their potential to separate the feed components can be modeled. The current state of research is discussed. Based on this evaluation the most efficient method for conceptual process development has been identified and further developed. The resulting methodology consists of model-based cost accounting accompanied by experimental model-parameter determination. The latter is carried out at in miniaturized laboratory-scale measurement cells for each unit operation using the complete original feed. The model-based modelparameter determination from these experiments is accompanied by a comprehensive error analysis. The experimental plan currently includes the determination of thermodynamic equilibrium conditions in the mixture directly from the raw material mixture. Transport kinetics and fluid dynamic parameters are first estimated from known correlations or preexisting knowledge. Later on these parameters are determined exactly in mini-plant experiments. Furthermore, biological and botanical-based guidelines are developed to identify thermodynamically favored basic operations. Finally, the developed approaches are successfully validated using two plant extracts. Firstly, it could be proven that the botanical pre-selection can reduce the experimental plan significantly. Secondly, it was shown that the experimental equilibrium data of the kinetics and fluid dynamics can have a significant impact on the separation costs. Therefore, detailed rigorous modeling approaches have to be chosen instead of short-cut methods in order to make any valid process development conclusions or to further optimize the system.展开更多
Self-organization theory informs an analysis on the evolution of labor self-organizations (LSOs), but lacks technical analysis on the evolution of their organizational structures. Fortunately, complex network technolo...Self-organization theory informs an analysis on the evolution of labor self-organizations (LSOs), but lacks technical analysis on the evolution of their organizational structures. Fortunately, complex network technology offers a new approach to analyzing these structures. Built on an extension of the Barabási-Albert (BA) model, we can simulate the evolution of LSOs by analyzing indicators including the clustering coefficient, degree distribution (DD) and average path length (APL) of workers, thereby demonstrating the evolving patterns of LSOs. Accordingly, governmental mechanism designs based on such patterns may not only stimulate energy growth and functional realization of LSOs, but also reduce the social percussions of abrupt evolutions. A comparative analysis of the evolutionary trajectories of LSOs in China and the U.S. finds that the U.S. government’s mechanism designs for protecting capitalism not only prevented the effective gathering of workers, but also prolonged the history of industrial conflicts. Such mechanism designs also led to the early dispersion and decline of LSOs and hindered the evolution of the working class. In contrast, the Chinese government established a socialist system that allowed workers to become the underlying force of socialist productivity. This design reduced labor strife while accelerating the evolution of workers towards higher stages.展开更多
Two cyanide bridged trinuclear compounds [Fe(bpy)2(CN)2]·[Cu(Cyclam)]2(ClO4)4·DMF 1 and [Fe(Phen)2(CN)2]·[Cu(Cyclam)]2(ClO4)4·2CH3CN·4H2O 2 (Bpy = 2,2'- bipyridine, Phen = 1,...Two cyanide bridged trinuclear compounds [Fe(bpy)2(CN)2]·[Cu(Cyclam)]2(ClO4)4·DMF 1 and [Fe(Phen)2(CN)2]·[Cu(Cyclam)]2(ClO4)4·2CH3CN·4H2O 2 (Bpy = 2,2'- bipyridine, Phen = 1,10-phenanthroline, Cyclam = 1,4,8,11-tetraaza-cyclotetradecane, and DMF = N,N-dimethylformamide) have been synthesized by using mononuclear [Fe(Phen)2(CN)2]·2H2O and [Fe(bpy)2(CN)2]·3H2O as precursors. These two complexes crystallize in monoclinic space groups P21/c and C2/c, respectively. For 1, a = 25.164(2), b = 12.0405(11), c = 20.4433(15) A, β = 91.948(3)°, V = 6190.5(9) A^3, Z = 4, Mr = 1418.90, Dc = 1.522 g/cm^3, F(000) = 2936, μ = 1.161 mm^-1, the final R = 0.0722 and wR = 0.2011 for 10779 observed reflections (I 〉 2σ(I)). For 2, a = 43.5945(0), b = 11.8447(0), c = 29.5637(2)A, β = 120.430(11)o, V = 13162.76(9) A^3, Z = 8, Mr = 1518.48, Dc = 1.533 g/cm^3, F(000) = 6288, μ = 1.101 mm^-1, the final R = 0.0711 and wR = 0.1783 for 11262 observed reflections (I 〉 2σ(I)).展开更多
Studies on the electronic structure,molecular design,syntheses of some novel series of tetranuclear rare earth complexes in our laboratory have been reviewed.Spin-unrestricted localized INDO method was used to calcula...Studies on the electronic structure,molecular design,syntheses of some novel series of tetranuclear rare earth complexes in our laboratory have been reviewed.Spin-unrestricted localized INDO method was used to calculate the electronic structure and the chemical bonding in the typical rare earth cluster Sc[Sc_6Cl_(12)Co]was discussed.展开更多
基金Supported by National Hi-tech Research and Development Program of China(863 Program,Grant No.2015AA042101)
文摘Complex engineered systems are often difficult to analyze and design due to the tangled interdependencies among their subsystems and components. Conventional design methods often need exact modeling or accurate structure decomposition, which limits their practical application. The rapid expansion of data makes utilizing data to guide and improve system design indispensable in practical engineering. In this paper, a data driven uncertainty evaluation approach is proposed to support the design of complex engineered systems. The core of the approach is a data-mining based uncertainty evaluation method that predicts the uncertainty level of a specific system design by means of analyzing association relations along different system attributes and synthesizing the information entropy of the covered attribute areas, and a quantitative measure of system uncertainty can be obtained accordingly. Monte Carlo simulation is introduced to get the uncertainty extrema, and the possible data distributions under different situations is discussed in detail The uncertainty values can be normalized using the simulation results and the values can be used to evaluate different system designs. A prototype system is established, and two case studies have been carded out. The case of an inverted pendulum system validates the effectiveness of the proposed method, and the case of an oil sump design shows the practicability when two or more design plans need to be compared. This research can be used to evaluate the uncertainty of complex engineered systems completely relying on data, and is ideally suited for plan selection and performance analysis in system design.
文摘With the development of science and technology as well as the diversification and individualization of market demand,modern products update more and more rapidly.e rapid development of new products to satisfy the increasingly improved and personalized customer demands greatly depends on the progress in the innovative design theory and performance optimization
基金This project was partly supported bythe Key Programof the National Natural Science Foundation of China (79990580) .
文摘In the conceptual design stage of complex products, CBR(Case-Based Reasoning) tool is useful to offer a feasible set of schemes. Then the most adaptive scheme can be generated through a procedure of comparison and evaluation. The procedure is essentially a multiple criteria decision-making problem. The traditional multiple criteria programming is not flexible enough in executing the system evaluation algorithm due to both the limited experimental data and the lack of human experiences. To make the CBR tool to be more efficient, a new method for the best choice among the feasible schemes based on the Fuzzy AHP using Fuzzy numbers (FFAHP) is proposed. Since the final results become a problem of ranking the mean of fuzzy numbers by the optimism of decision-maker using the FFAHP, its execution is much more intuitive and effective than with the traditional method.
文摘In this paper, the method based on uniform design and neural network is proposed to model the complex system. In order to express the system characteristics all round, uniform design method is used to choose the modeling samples and obtain the overall information of the system;for the purpose of modeling the system or its characteristics, the artificial neural network is used to construct the model. Experiment indicates that this method can model the complex system effectively.
基金supported by the National Natural Science Foundation of China(6087602250677014)+2 种基金the High-Tech Research and Development Program of China(2006AA04A104)the Hunan Provincial Natural Science Foundation of China (06JJ202407JJ5076).
文摘To design approximately linear-phase complex coefficient finite impulse response (FIR) digital filters with arbitrary magnitude and group delay responses, a novel neural network approach is studied. The approach is based on a batch back-propagation neural network algorithm by directly minimizing the real magnitude error and phase error from the linear-phase to obtain the filter's coefficients. The approach can deal with both the real and complex coefficient FIR digital filters design problems. The main advantage of the proposed design method is the significant reduction in the group delay error. The effectiveness of the proposed method is illustrated with two optimal design examples.
文摘This paper presents a complex design of frequency modulated interrupted continuous wave (FMICW) and frequency-coded pulses (FCP) for detection of aircraft and ship targets. Here, FMICW is used to satisfy requirements of aircraft detection and FCP is used to satisfy requirements of ship detection for the differences in maneuverability and scatter characteristics of targets and interference background. The design of such a complex waveform for detection of aircraft and ship targets by a HF radar is discussed in detail with different considerations for better performance.
文摘The engineering problems today become more and more complex particularly in the area of new product development. It requires the multi-disciplinary design method to solve complex problems. This paper presents an integrated design system for solving complexity during multi-disciplinary design. Complexity could be solved if the design problems, given by any individuals who are concerned, are structured. The design system uses the multi-viewpoint concept to allow experts to share their information and knowledge in common views. Knowledge modules are used to store semantics from the experts of different disciplines. Then the system agent acts as an internal designer to help support the individuals to translate any semantics provided from one discipline and then propagate to other related disciplines. With these tools, the integrated design system can structure and solve the complexity of design problems.
文摘With the acceleration of urbanization, city complex as an intensive urban organization form has gradually grown up in China. By consulting relevant documents of city complex, emergence background and related concepts of city complex were introduced, landscape design of Chenglong-International was analyzed to propose landscape design principles and concepts of city complex under the compound development model, landscape processing techniques of outdoor functional subareas and transitional areas were introduced to provide useful reference for the landscape design of city complex.
基金Supported by National Natural Science Foundation of China(Grant No.51275164)
文摘The current research of complex nonlinear system robust optimization mainly focuses on the features of design parameters, such as probability density functions, boundary conditions, etc. After parameters study, high-dimensional curve or robust control design is used to find an accurate robust solution. However, there may exist complex interaction between parameters and practical engineering system. With the increase of the number of parameters, it is getting hard to determine high-dimensional curves and robust control methods, thus it's difficult to get the robust design solutions. In this paper, a method of global sensitivity analysis based on divided variables in groups is proposed. By making relevant variables in one group and keeping each other independent among sets of variables, global sensitivity analysis is conducted in grouped variables and the importance of parameters is evaluated by calculating the contribution value of each parameter to the total variance of system response. By ranking the importance of input parameters, relatively important parameters are chosen to conduct robust design analysis of the system. By applying this method to the robust optimization design of a real complex nonlinear system-a vehicle occupant restraint system with multi-parameter, good solution is gained and the response variance of the objective function is reduced to 0.01, which indicates that the robustness of the occupant restraint system is improved in a great degree and the method is effective and valuable for the robust design of complex nonlinear system. This research proposes a new method which can be used to obtain solutions for complex nonlinear system robust design.
基金supported by the National Natural Science Foundation of China(71702072 71811540414+2 种基金 71573115)the Natural Science Foundation for Jiangsu Institutions(BK20170810)the Ministry of Education of Humanities and Social Science Planning Fund(18YJA630008)
文摘Minimizing the impact of the mixed uncertainties(i.e.,the aleatory uncertainty and the epistemic uncertainty) for a complex product of compliant mechanism(CPCM) quality improvement signifies a fascinating research topic to enhance the robustness.However, most of the existing works in the CPCM robust design optimization neglect the mixed uncertainties, which might result in an unstable design or even an infeasible design. To solve this issue, a response surface methodology-based hybrid robust design optimization(RSM-based HRDO) approach is proposed to improve the robustness of the quality characteristic for the CPCM via considering the mixed uncertainties in the robust design optimization. A bridge-type amplification mechanism is used to manifest the effectiveness of the proposed approach. The comparison results prove that the proposed approach can not only keep its superiority in the robustness, but also provide a robust scheme for optimizing the design parameters.
文摘Innovation design for complex products is a difficult issue in the military manufacturing industry. Ontology may provide a feasible way to rebuild the design process for complex products via sharing and reusing of design knowledge. In this paper, a design method used in the innovation design process of the complex products with knowledge modeling is proposed. Knowledge modeling is realized through ontology construction by combining the cycling evolutional theory of constructing ontology and OWL (Ontology Web Language)-based knowledge representation. As a case study, the satellite is selected as one of the complex products. The application domain of the satellite ontology is analyzed. According to the analysis result, the knowledge structure of satellite ontology is put forward based on OWL. The application of satellite product design shows that the method can effectively organize and reuse the knowledge resources in the innovation design of complex product and help companies to create more competitive products based on the existing knowledge and experience.
文摘The number of products used as agro-chemicals, food additives, flavors, aromas, pharmaceuticals and nutraceuticals which are made by fermentation or extraction from plants has increased significantly. Despite this growth, initial predictions for a potential product purification process for these complex mixtures remains entirely experimentally based. The present work represents an initial study to demonstrate the benefits of a systematic approach. For process development of chemically well-studied systems model based process design methods are already available. Therefore the proposed approach focuses on a method for the efficient characterization of the physical properties of the key components. Once this is adequately defined, unit operations and their potential to separate the feed components can be modeled. The current state of research is discussed. Based on this evaluation the most efficient method for conceptual process development has been identified and further developed. The resulting methodology consists of model-based cost accounting accompanied by experimental model-parameter determination. The latter is carried out at in miniaturized laboratory-scale measurement cells for each unit operation using the complete original feed. The model-based modelparameter determination from these experiments is accompanied by a comprehensive error analysis. The experimental plan currently includes the determination of thermodynamic equilibrium conditions in the mixture directly from the raw material mixture. Transport kinetics and fluid dynamic parameters are first estimated from known correlations or preexisting knowledge. Later on these parameters are determined exactly in mini-plant experiments. Furthermore, biological and botanical-based guidelines are developed to identify thermodynamically favored basic operations. Finally, the developed approaches are successfully validated using two plant extracts. Firstly, it could be proven that the botanical pre-selection can reduce the experimental plan significantly. Secondly, it was shown that the experimental equilibrium data of the kinetics and fluid dynamics can have a significant impact on the separation costs. Therefore, detailed rigorous modeling approaches have to be chosen instead of short-cut methods in order to make any valid process development conclusions or to further optimize the system.
基金a deliverable of the “Research on the Accounting of ‘Trade in Value-added’ in Chinese Services Sector and its Place in the Global Value Chain,” a project funded by the National Social Science Foundation of China(15BGJ036)“The Impacts of Economic Globalization on Entrepreneurship in China—Theoretical Research and Empirical Analysis,” a youth project funded by the National Natural Science Foundation of China(NSFC)(71603142)+3 种基金“Research on Approaches to Labor-Management Cooperation with Chinese Characteristics—A Labor Relations Evolutionary Perspective,” a Ministry of Education humanities and social sciences research youth project(16YJC790115)“Research on the Evolution of Labor Relations with Chinese Characteristics Since the 18th CPC National Congress,” a Shandong planned social sciences research project(16CZLJ05)“Research on the Evolution Mechanisms and Paths of the Marxist Labor System from a Complex Network Perspective,” a project funded by the China Postdoctoral Science Foundation(CPSF)(2017M612180)“Research on Mechanism Design of the Spatial Structure of Labor-Management Cooperation with Chinese Characteristics,” a Qingdao postdoctoral applied research project
文摘Self-organization theory informs an analysis on the evolution of labor self-organizations (LSOs), but lacks technical analysis on the evolution of their organizational structures. Fortunately, complex network technology offers a new approach to analyzing these structures. Built on an extension of the Barabási-Albert (BA) model, we can simulate the evolution of LSOs by analyzing indicators including the clustering coefficient, degree distribution (DD) and average path length (APL) of workers, thereby demonstrating the evolving patterns of LSOs. Accordingly, governmental mechanism designs based on such patterns may not only stimulate energy growth and functional realization of LSOs, but also reduce the social percussions of abrupt evolutions. A comparative analysis of the evolutionary trajectories of LSOs in China and the U.S. finds that the U.S. government’s mechanism designs for protecting capitalism not only prevented the effective gathering of workers, but also prolonged the history of industrial conflicts. Such mechanism designs also led to the early dispersion and decline of LSOs and hindered the evolution of the working class. In contrast, the Chinese government established a socialist system that allowed workers to become the underlying force of socialist productivity. This design reduced labor strife while accelerating the evolution of workers towards higher stages.
基金Supported by the 973 Program (2007CB815301 and 2006CB932904)the National Natural Science Foundation of China (20333070, 20871114 and 20673118)+1 种基金the Science Foundation of CAS (KJCX2-YW-M05)Fujian Province (2006F3132 and 2007J0171)
文摘Two cyanide bridged trinuclear compounds [Fe(bpy)2(CN)2]·[Cu(Cyclam)]2(ClO4)4·DMF 1 and [Fe(Phen)2(CN)2]·[Cu(Cyclam)]2(ClO4)4·2CH3CN·4H2O 2 (Bpy = 2,2'- bipyridine, Phen = 1,10-phenanthroline, Cyclam = 1,4,8,11-tetraaza-cyclotetradecane, and DMF = N,N-dimethylformamide) have been synthesized by using mononuclear [Fe(Phen)2(CN)2]·2H2O and [Fe(bpy)2(CN)2]·3H2O as precursors. These two complexes crystallize in monoclinic space groups P21/c and C2/c, respectively. For 1, a = 25.164(2), b = 12.0405(11), c = 20.4433(15) A, β = 91.948(3)°, V = 6190.5(9) A^3, Z = 4, Mr = 1418.90, Dc = 1.522 g/cm^3, F(000) = 2936, μ = 1.161 mm^-1, the final R = 0.0722 and wR = 0.2011 for 10779 observed reflections (I 〉 2σ(I)). For 2, a = 43.5945(0), b = 11.8447(0), c = 29.5637(2)A, β = 120.430(11)o, V = 13162.76(9) A^3, Z = 8, Mr = 1518.48, Dc = 1.533 g/cm^3, F(000) = 6288, μ = 1.101 mm^-1, the final R = 0.0711 and wR = 0.1783 for 11262 observed reflections (I 〉 2σ(I)).
基金Project supported by The National Natural Science Foundation of China and Science and Technology Foundation of State Education Commision of China
文摘Studies on the electronic structure,molecular design,syntheses of some novel series of tetranuclear rare earth complexes in our laboratory have been reviewed.Spin-unrestricted localized INDO method was used to calculate the electronic structure and the chemical bonding in the typical rare earth cluster Sc[Sc_6Cl_(12)Co]was discussed.