Phase synchronization on small-world networks with community structure

In this paper, we propose a simple model that can generate small-world network with community structure. The network is introduced as a tunable community organization with parameter r, which is directly measured by the ratio of inter- to intra-community connectivity, and a smaller r corresponds to a stronger community structure. The structure properties, including the degree distribution, clustering, the communication efficiency and modularity are also analysed for the network. In addition, by using the Kuramoto model, we investigated the phase synchronization on this network, and found that increasing the fuzziness of community structure will markedly enhance the network synchronizability; however, in an abnormal region （r ≤ 0.001）, the network has even worse synchronizability than the case of isolated communities （r = 0）. Furthermore, this network exhibits a remarkable synchronization behaviour in topological scales： the oscillators of high densely interconnected communities synchronize more easily, and more rapidly than the whole network.

ClO_4^--directed Assembly of Two Co^ⅡComplexes Based on Flexible N-donor Ligands:Syntheses,Crystal Structures and Magnetic Properties

The reaction of Co^II ions with 1,4-bis（imidazol）butane（bimb） or 1,4-bis（triazol）butane（bitb） in the presence of ClO4^-, respectively affords two CoII coordination complexes, namely {[Co（bimb）3]·2ClO4}n（I） and {[Co（bitb）3]·2ClO4}n（II）. Single-crystal X-ray analysis indicates that both complexes I and II show the same α-Po topological structures. However, complex I exhibits a 2-fold interpenetrating network, while complex II features a 3-fold interpenetrating network. In addition, solid-state properties such as thermal stabilities and magnetic properties of two complexes were also investigated.

Adaptive evolvement of information age C^4ISR structure

Command, control, communication, computing, intel- ligence, surveillance and reconnaissance （C^4ISR） in information age is a complex system whose structure always changes ac- tively or passively during the warfare. Therefore, it is important to optimize the structure, especially in ambiguous and quick-tempo modern warfare. This paper proposes an adaptive evolvement mechanism for the C^4ISR structure to survive the changeable warfare. Firstly, the information age C^4ISR structure is defined and modeled based on the complex network theory. Secondly, taking the observe, orient, decide and act （OODA） model into consideration, four kinds of loops in the C^4ISR structure are pro- posed and their coefficient of networked effects （CNE） is further defined. Then, the adaptive evolvement mechanisms of the four kinds of loops are presented respectively. Finally, taking the joint air-defense C^4ISR as an example, simulation experiments are im- plemented, which validate the evolvement mechanism and show that the information age C41SR structure has some characteristics of small-world network and scale-free network.

Synthesis and Crystal Structure of a New Diamine Complex CuCl_4(H_2tn)

In an attempt to synthesize a new pyrimidine complex of copper(II) in a solution reaction of CuBr2 with 2,2'-bis(hexahydropyrimidine) and hydro-chloric acid, we unexpectedly obtained a bright yellow chip-like crystal of CuCl4(H2tn) [H2tn=(H3NCH2CH2CH2NH3)2+]. Its structure was determined by single-crystal X-ray diffraction analysis. The crystal belongs to orthorhombic system, space group Pnma, with cell parameters: a=0.7216(2) nm, b=1.8308(6) nm, c=0.7553(3) nm, V=0.9953(6) nm3, Z=4, F(000)=564, Mr=281.49, Dc=1.879 g/cm3. (Mo Ka)=3.204 mm-1, R1=0.0248, wR2=0.0575. The analysis of the crystal structure indicates that the complex has a three-dimensional network structure, which is formed by hydrogen bonds and electrostatic interaction.