Influence of Bayer Red Mud on the Operational and Mechanical Characteristics of Composite Cement Mortar

The aim of this study is to enhance the value and utilization of red mud generated in the Bayer process by preparing composite cement mortars.The effects of two different types of Bayer red mud with varying physical and chemical characteristics on the fluidity,mechanical strength,mineral composition,and microstructure of the composite cement mortar were systematically evaluated.The results showed that the optimal addition of red mud A was 10 wt%,while it was 20 wt% for red mud B.The mechanical properties of the composite cement mortar met the standards for P·O42.5 cement.Furthermore,the composite mortar with the addition of red mud B showed higher flexural and compressive strengths compared to the composite mortar with red mud A.This improvement is attributed to the smaller particle size of red mud B,which filled the micro-pores and increased the compactness of the cement stone,as well as its higher content of Na_(2)O,K_(2)O,and other free alkalis,which resulted in more obvious alkali activation,accelerating the hydration of the active minerals in the slurry.

Preparation of Super Composite Cement with a Lower Clinker Content and a Larger Amount of Industrial Wastes

The effects of the grinding mode,fineness,gypsum kinds and dosage,mix proportions on properties of the composite cements consisting of slag,fly ash,limestone and a lower content clinker were investigated,respectively.The results show that when the proportions among slag,fly ash and limestone are appropriate,the grinding technology and system are reasonable,the optimized gypsums and additives are effective,the 52.5R grade cement (52.5R grade cement means a higher strength than 52.5 at early age) can be prepared by clinker dosage of 50% in weight,the 42.5R or 42.5,32.5 grade composite cement containing 40% and 30% clinker also may be made, respectively.Moreover,the high performance concrete prepared from the above composite cements was studied experimentally.

Beneficial use of stainless steel EAF slag as composite cement admixture and its heavy metals leaching risk analysis

This study analyzes the feasibility of using stainless steel electric arc furnace （EAF） slag as composite cement admixture and the risk of leaching-out of heavy metals. The results show that the stainless steel EAF slag, mainly made up of Ca2 SiO4, Ca3 Mg （ SiO4 ） 2, some Cr-containing minerals and in small particle size, is easily ground and has cementitious activity. EAF slag, when used as cement admixture, can be added with a maximum percentage of 32%. It can meet the strength requirements of the standard P · C 32.5 cement. When the mixing percentage is decreased to 25 % , the strength of the cement can be increased to that of P · C 42.5 cement. Other main quality indexes of composite cement, such as the setting time and stability, also satisfy standard requirements. The results also show that most of the heavy metals in the stainless steel EAF slag exist in a stable speciation. The concentration of heavy metals that leach out from the stainless steel EAF slag and the composite cement products is far lower than the standard limit of hazardous wastes. The main heavy metal, chromium, exists as less hazardous trivalent chromium. Therefore, the risk of heavy metals leaching out from the stainless steel EAF slag is low. The internal exposure index （IRa） and the external exposure index （Iγ） of the stainless steel EAF slag are both lower than 1.0, satisfying the standard requirements of the state for the radionuclides of building materials. Therefore, stainless steel EAF slag can be safely used as admixture to produce composite cement.

DEVELOPING A NEW GENERATION OF HIGH PERFORMANCE COMPOSITE CEMENT

This paper proposed a new generation of high performance composite cement which is designed according to the optimization of composition and structure of cement paste and is manufactured by blending the differ ent components with special composite techniques. Each of these components has its different special property, and should be compatible with each other and match each other, and the properties of them are complementary mutually. At present, such kind of high performance composite cement can be manufactured with high reactivity cement clinker, ground granulated blast - furnace slag, high grade fly ash, silica fume etc..

Development and application of novel high‐efficiency composite ultrafine cement grouts for roadway in fractured surrounding rocks

The fractured surrounding rocks of roadways pose major challenges to safe mining.Grouting has often been used to reinforce the surrounding rocks to mitigate the safety risks associated with fractured rocks.The aim of this study is to develop highly efficient composite ultrafine cement(CUC)grouts to reinforce the roadway in fractured surrounding rocks.The materials used are ultrafine cement(UC),ultrafine fly ash(UF),ultrafine slag(US),and additives(superplasticizer[SUP],aluminate ultrafine expansion agent[AUA],gypsum,and retarder).The fluidity,bleeding,shrinkage,setting time,chemical composition,microstructure,degree of hydration,and mechanical property of grouting materials were evaluated in this study.Also,a suitable and effective CUC grout mixture was used to reinforce the roadway in the fractured surrounding rock.The results have shown that the addition of UF and US reduces the plastic viscosity of CUC,and the best fluidity can be obtained by adding 40%UF and 10%US.Since UC and UF particles are small,the pozzolanic effect of UF promotes the hydration reaction,which is conductive to the stability of CUC grouts.In addition,fine particles of UC,UF,and US can effectively fill the pores,while the volumetric expansion of AUA and gypsum decreases the pores and thus affects the microstructure of the solidified grout.The compressive test results have shown that the addition of specific amounts of UF and US can ameliorate the mechanical properties of CUC grouts.Finally,the CUC22‐8 grout was used to reinforce the No.20322 belt roadway.The results of numerical simulation and field monitoring have indicated that grouting can efficaciously reinforce the surrounding rock of the roadway.In this research,high‐performance CUC grouts were developed for surrounding rock reinforcement of underground engineering by utilizing UC and some additives.

Effect of Polyaniline/manganese Dioxide Composite on the Thermoelectric Effect of Cement-based Materials

To enhance the thermoelectric effect of cement-based materials,conductive polyaniline(PANI)modified MnO_(2)powder was synthesized and used as a thermoelectric component in the cement composites.The nanostructured PANI was deposited on the surface of the nanorod-shapedα-MnO_(2)particle and the weight ratio of PANI to MnO_(2)was 22.3:77.7 in the composite.The synthesized PANI/MnO_(2)composite was nanostructured according to the SEM image.The test results of the thermoelectric properties proved that the PANI/MnO_(2)composite was effective as the Seebeck coefficient and electrical conductivity values of the cement composites with PANI/MnO_(2)inside were 3-4 orders of magnitude higher than those of pure cement paste and the thermal conductivity values of these cement samples were similar.The obtained maximum figure of merit(ZT)value(2.75×10^(-3))was much larger than that of conductive materials reinforced cement-based composites.The thermoelectric effect of cement composites is mainly enhanced by the increased Seebeck coefficient and electrical conductivity in this work.

Microstructure of a Planting Material Consisting of Nutrition-Expansive Perlitic-Cement Composites

An ecotypic revetment material consisting of nutrition-expansive perlitic-cement composites is introduced. This planting material can combine vegetation recovery with slope protection. The XRD, SEM and image analysis techniques were used to study its composition and microstructure. Its strength was measured by an electro-hydraulic servo-controlled testing machine. The results show the unconfined compressive strength is about 393.6 kPa, and the average elastic modulus is about 47.0 MPa. The quartz, felspar, chlorite and calcite are the main non-clay minerals in the planting material. Its particles are mainly spherical,and the range of the equivalent diameter is 1.83 to 15.96 μm. The results also show the planting material contains a large amount of micro non-capillary and capillary pores, and has a microstructure characteristic of honeycomb and coralline. CSH gel produced by hydration of cement increases the strength and water stability of the particles. The anisotropy and slight orientation of the particles increase the void cross-section area,providing an explanation of the high permeability for the planting material.The better porosity of the planting material is apt tokeep moisture and nutriment, provides oxygen for plant root breathing, and aids to exhaust the carbon dioxide by means of exchanging with atmosphere, hence it can facilitate vegetation.

The Smart Behavior of Cement-based Composite Containing Carbon Fibers under Three-point-bending Load

The influences of the fiber volume fraction on the electrical conductivity and the fraction change of electrical resistance under three-point-bending test were discussed.It is found that the relationship beween the electrical conductivity of composites and the fiber volume fraction can be explained by the percolation theory and the change of electrical resistance of specimens reflects to the process of loading.The sensitivity and the response of the change of electrical resistance to the load for specimens with different fiber volume fractions are quite different.which provide an important guide for the manufacture of conductive and intrinsically smart carbon fiber composite.

Effects of Fiber Distribution and Content on Performance of Engineered Cementitious Composite (ECC)

The 21 dog-bone specimens with different fiber contents and fiber distribution (random chopped fiber or directional continuous filament fiber bundles) were designed and tested under uniaxial tension using domestic PVA (polyvinyl alcohol) fiber.High fiber content exerted positive influences on cracking stress,peak stress and deformation capacity of specimens with random chopped fiber,compared with the decrease shown in cracking stress of specimens containing directional fiber bundles.There were multiple cracks in specimens containing directional fiber bundles,while only 1-2 typical cracks could be shown in chopped fiber specimens after being broken.Random chopped fiber connected more closely with matrix compared with that only part of fiber bundles could contact with matrix.Double-fold line model and parabolic model could be used simultaneously to fit well with the uniaxial tension constitutive relations of engineered cementitious composite (ECC).Although the performance of PVA produced in China can not reach to the same level of those from Japan,there exists certain practical value in engineering according to its contribution to deformability of structure.

Improvement of Water Sensitivity of Macro-defect-free Cement Based Composites with Cross Coupling Agent

The enhancement of interface bonding between cement and polymerand the structural reticula- tion of the water-soluble polymer areproposed to minimize the shortening of the mechanical properties ofmacro-de- fect-free(MDF)cement based composites at high relativehumidity. The MDF composites incorporated with vari- ouscross-coupling agents studied experimentally. The results show thatthe MDF composites modified with small amounts of cross-couplingagent had raised mechanical properties, but it is more important thatthe modified MDF composites had a significant increase in waterresistance compared to the original one.

INTERFACE AND PROPERTIES OF ALKALI-TREATED CARBON FIBRE REINFORCED CEMENT COMPOSITES

The surface of carbon fibre is studied which has been treated with heated sodium hydrate solution (NaOH) . It is found that the surface of carbon fibre is not corroded during the treatment. But at the same time, it is also found that after this treatment, a certain number of carbonyl groups (C O) and (-COOH or ?COONa) are produced on the treated surface of carbon fibre. When carbon fiber is mixed with cement paste, the above reactive groups will link with Ca+2 in the paste, which will result in an early stage hydration of cement in inter facial areas. In addition, the experiments show that the rheological properties of cement paste reinforced with alkali-treated carbon fibre differ greatly from that of untreated carbon fibre reinforced cement paste.

THE EFFECT OF POLYMER IN STEEL FIBER REINFORCED CEMENT COMPOSITES

Three kinds of polymers, polymethyl acrylate emulsion (POLYVINYLformal solution (PV- FO), styrene acrylate copolymer emulsion (SA)are chosen To study the effect of polymer in steel fiber rein forcedce- Ment composites (SFRCC). The experimental results show That thebonding properties in SFRCC are remarkably im- Proved after theaddition of three kinds of polymer.

Energy Consumption and Erosion Mechanism of Polyester Fiber Reinforced Cement Composite in Wind-blown Sand Environments

Considering the economic and environmental benefits associated with the recycling of polyester(PET)fibres,it is vital to study the application of fibre-reinforced cement composites.According to the characteristics of the wind-blown sand environment in Inner Mongolia,the erosion resistance of the polyester fibre-reinforced cement composites(PETFRCC)with different PET fibre contents to various erosion angles,velocities and sand particle flows was investigated by the gas-blast method.Based on the actual conditions of sandstorms in Inner Mongolia,the sand erosion parameters required for testing were calculated by the similarity theory.The elastic-plastic model and rigid plastic model of PETFRCC and cement mortar were established,and the energy consumption mechanism of the model under particle impact was analyzed.The experimental results indicate that the microstructure of PETFRCC rafter hydration causes a spring-like buffering effect,and the deformation of PETFRCC under the same impact load is slightly smaller than that of cement mortar,and the damage mechanism of PETFRCC is mainly characterized by fiber deformation and slight brittle spalling of matrix.And under the most unfavorable conditions of the erosion,the erosion rate of 0.5PETFRCC is about 57.69%lower than that of cement mortar,showing better erosion resistance.

Performance of the Cement Matrix Composite Material With Rubber Powder

The effect of the deferent rubber content substituted for fine aggregate on the mortar performance was studied.The effects of the rubber coated with the coating materials on the mortar compressive strength,bending strength and impact work were discussed.The optimum rubber powder content and the suitable coating material were found.Through the electrical probe test-BEI,SEI and calcium ion distribution,and the slight crack and the interface between the rubber and cement matrix are analyzed.The results show that the rubber powder coated with the surface treatment materials A,B and C has the capability of absorbing a large amount of energy under the compressive and flexural load and the slight cracks of R-C were controlled and restrained.

Microstructure and Mechanical Properties of CaCO_3 Whisker-reinforced Cement

Composite Portland cement （PC） played an important role in various kinds of construction engineering owing to low hydration heat,low-cost,and application of solid industrial waste,but its brittleness and low strength limited its use in stress-bearing locations.The aim of this study is to improve the toughness and fracture resistance by incorporating CaCO3 whisker in cement matrix.Effect of different content of calcium carbonate whiskers on the mechanical properties of PC was investigated.The results showed that the flexural strength,impact strength and split tensile strength were increased by 39.7%,39.25% and 36.34% at maximum,respectively.Microstructure and elements of the whiskers in hardened cement were observed and analyzed by SEM/EDS.The mechanisms of the reinforcement of CaCO3 whisker on cement were also discussed,and the conclusion was that the improvement could be correlated to energy-dissipating processes owing to crack bridging,crack deflection,and whisker pull-out at the crack tips.

Multifunctional, Sustainable, and Biological Non-Ureolytic Self-Healing Systems for Cement-Based Materials

Microbially induced calcium carbonate(CaCO_(3))precipitation(MICP)has been investigated as a sustain-able alternative to conventional concrete remediation methods for improving the mechanical properties and durability of concrete structures.To date,urea-dependent MICP is the most widely employed MICP pathway in biological self-healing concrete research as its use has resulted in efficient CaCO_(3) precipita-tion rates.NH_(3) is a byproduct of ureolysis,and can be hazardous to cementitious structures and the health of various species.Accordingly,non-ureolytic bacterial concrete self-healing systems have been developed as eco-friendly alternatives to urea-dependent self-healing systems.Non-ureolytic pathways can improve the physical properties of concrete samples and incorporate the use of waste materials;they have the potential to be cost-effective and sustainable.Moreover,they can be applied in terrestrial and marine environments.To date,research on non-ureolytic concrete self-healing systems has been scarce compared to that on ureolytic systems.This article discusses the advances and challenges in non-ureolytic bacterial concrete self-healing studies and highlights the directions for future research.

A Simple Cement Hydration Model Considering the Influences ofWater-to-Cement Ratio and Mineral Composition

A simple hydration model is used here by taking the composition of the cement and the initial water: cementratio (w/c) into account explicitly. Its conceptual basis is a combination of the Avrami equation and Bentz’s modelbased on simple spatial considerations. In this model, the Avrami equation determines the initial reaction, andBentz’s model describes the following hydration stage. The model favors engineers for it relies on one experimentalparameter and has a reliable approximation in the practice.

Behavior of High Performance PVA Fiber Reinforced Cement Composites in Triaxial Compression

Based on an extensive experimental program,the paper studies the behavior of HPFRCC under triaxial compression. The experimental parameters are lateral confining pressure and PVA fiber content by volume. The test results indicate that ultimate strength and peak strain are significantly improved with the increases of confining pressure. The confining effect introduced by the fibers becomes minor in triaxial compression tests,where there is relatively high external confining pressure. The axial stress-strain curves with different confining pressure and different PVA fiber content by volume are obtained. Lateral confining pressure constraints the lateral expansion of HPFRCC,so there is a big plastic deformation with its ultimate strength improved. At lower confining pressure,PVA fiber content by volume has some effect on the decreased section of stress-strain curve. According to test results,the paper establishes formula of confining pressure with ultimate strength and axial peak strain respectively.

Review of recent developments in cement composites reinforced with fibers and nanomaterials

The quest for high-performance construction materials is led by the development and application of new reinforcement materials for cement composites.Concrete reinforcement with fibers has a long history.Nowadays,many new fibers associated with high performance and possessing eco-environmental characteristics,such as basalt fibers and plant fibers,have received much attention from researchers.In addition,nanomaterials are considered as a core material in the modification of cement composites,specifically in the enhancement of the strength and durability of composites.This paper provides an overview of the recent research progress on cement composites reinforced with fibers and nanomaterials.The influences of fibers and nanomaterials on the fresh and hardened properties of cement composites are summarized.Moreover,future trends in the application of these fibers or of nanomaterial-reinforced cement composites are proposed.

Loading necrostatin-1 composite bone cement inhibits necroptosis of bone tissue in rabbit

Bone necrosis after injecting of polymethylmethacrylate(PMMA)bone cement will lead to re-fracture of bone tissue.As a new type of necrosis,there is little research related to the necroptosis of surrounding bone tissue near the bone cement.The purpose of our study was to(i)investigate the presence of necroptosis in vivo and,(ii)established as a new type of bone cement containing PMMA,calcium phosphate cement(CPC)and Necrostatin-1(Nec-1)to inhibit necroptosis of bone tissue.A total of 12 Japanese rabbits were used to establish the animal model and randomly divided into 4 groups signed as a control group,PMMA group,PMMA–CPC group and PMMA–CPC–Nec-1 group,respectively.We used scanning electron microscope to observe the structure of the samples,used HE staining to detect the necrosis,and used western blotting as well as ELISA test to examine the iconic molecule receptor interacting protein kinase-3(RIP 3)protein and tumor necrosis factor a(TNF-a).After analyzing the results of our study,we found that the structure in both PMMA bone cement group and composite bone cement group was damaged and there was an evidence of necrosis,but it was absent in control group.Through molecule detection,the RIP 3 protein expression was decreased in PMMA–CPC–Nec-1(P<0.05).TNF-a expression was increased in bone cement groups with and without CPC(P<0.05),but was inhibited in PMMA–CPC–Nec-1 group.We have concluded that the necroptosis could be confirmed in bone tissue necrosis induced by TNF-a after bone cement injection and also could be inhibited by composite bone cement with Nec-1.