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Biodegradation behavior of polymethyl methacrylate−bioactive glass 45S5 composite coated magnesium in simulated body fluid 被引量:1
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作者 Zanko ROUEIN Hassan JAFARI +2 位作者 Fatemehsadat PISHBIN Rahim MOHAMMADI Abdolreza SIMCHI 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2022年第7期2216-2228,共13页
The biodegradation behavior of Mg,coated by polymethyl methacrylate as well as polymethyl methacrylate(PMMA)−bioactive glass(BG)composite was investigated.Electrophoretic deposition and dip coating techniques were ado... The biodegradation behavior of Mg,coated by polymethyl methacrylate as well as polymethyl methacrylate(PMMA)−bioactive glass(BG)composite was investigated.Electrophoretic deposition and dip coating techniques were adopted to prepare composite coating using a suspension of different percentages of the above two chemical materials.The deposited coatings were characterized using SEM,EDS,FTIR,and water contact angle measurements.Biodegradation behavior study of the coated Mg was performed using linear polarization,impedance spectroscopy,and immersion tests in simulated body fluid.The compact and homogeneous composite coating was developed as evidenced by electron microscopy results.The water contact angle measurement showed a 44°increase in the contact angle of the composite coated Mg compared to the uncoated one.The composite coating was covered by a bone-like hydroxyapatite layer after 336 h,indicating that the coating has an excellent in vitro bioactivity.The electrochemical testing results confirmed a significant reduction,96.9%,in the biodegradation rate of Mg coated with the composite prepared from 45 g/L PMMA+3.5 g/L 45S5 GB suspension compared to that of the uncoated one.Therefore,the composite coated Mg can be proposed as a promising material for biodegradable implant application. 展开更多
关键词 magnesium alloy polymethyl methacrylate bioactive glass composite coating electrophoretic deposition BIODEGRADATION
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The development of advanced Cr-free organic composite coated electrogalvanized steel sheet with excellent grounding property
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作者 ZHANG Jianping Research Institute,Baoshan Iron & Steel Co.,Ltd.,Shanghai 201900,China 《Baosteel Technical Research》 CAS 2010年第S1期43-,共1页
In recent years,the concern about environmental protection is increasing on a world scale.Major manufacturers of home appliances and OA equipment have introduced so-called 'green procurement schemes' for reduc... In recent years,the concern about environmental protection is increasing on a world scale.Major manufacturers of home appliances and OA equipment have introduced so-called 'green procurement schemes' for reducing environmentally harmful substances in manufacturing process and end products. Under such background,a new type of chromate-free organic composite coated electro-galvanized steel sheet with high conductivity was developed by Baosteel,which meets the EU RoHS Directive(Restriction of the Hazardous Substances) and other related laws and regulations on environmental safety.It also provides excellent surface electrical conductivity,corrosion resistance,fingerprint resistance,solvent resistance,coating adhesion, heat resistance,formability and other special properties to meet the demand of manufacture's process of OA machine. Compared with previously developed anti-fingerprinting coated electro-galvanized steel sheet,this newly developed product has a good balance between high corrosion resistance(time to 5%white rust in salt spray test is 120 h for flat panel and 72 h for worked potion) and conductivity(surface electro-resistivity in accordance with LOREAST is less than 0.1 milliohm ) due to the special design of coating's structure.Besides,It also provides the properties of grounding and shielding against electromagnetic waves.The evaluation of surface performances of new product showed that it is comparable or even better than the similar products. Currently,the newly developed product has been commercialized. In this paper,the major properties are discussed,such as corrosion resistance,surface electrical conductivity, fingerprint resistance,solvent resistance,coating adhesion(ink/melamine alkyd paint),heat resistance and formability.Furthermore,the application is also briefly described. 展开更多
关键词 chromate-free thin organic composite coating conductivity corrosion resistance elecro-galvanized steel sheet
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Co-electrodeposition and properties evaluation of functionally gradient nickel coated ZrO_2 composite coating 被引量:1
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作者 B.BOSTANI N.PARVINI AHMADI +1 位作者 S.YAZDANI R.ARGHAVANIAN 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2018年第1期66-76,共11页
For the first time,functionally electroless nickel plated ZrO2(NCZ)graded Ni-NCZ composite coating has been successfully co-electrodeposited from a bath with gradually increasing of stirring rate.Studies showed that c... For the first time,functionally electroless nickel plated ZrO2(NCZ)graded Ni-NCZ composite coating has been successfully co-electrodeposited from a bath with gradually increasing of stirring rate.Studies showed that co-electrodeposition in a bath with stirring rate of250r/min results in the maximum co-electrodeposited particle content and the best particle distribution.To produce NCZ graded Ni-NCZ composite coating,the stirring rate was continuously increased from0to250r/min.The electroplated coating had a continuous gradient increasing of co-electrodeposited NCZ content from substrate towards the surface.The results showed that with increasing the co-electrodeposited NCZ particles content in Ni matrix,microhardness increases from interface towards the surface of the coating.Little crystallite size of Ni matrix and higher co-electrodeposited hard particles content were recognized as the reasons of microhardness increasing.Bend test revealed that the functionally graded composite coating shows more excellent adhesion to the substrate compared with the ordinary distributed Ni-NCZ on the same substrate.This result is attributed to lower mechanical mismatch between coating and substrate in the functionally graded composite coating with respect to the uniformly distributed one.The results of wear resistance measurements reveal that wear resistance of functionally graded Ni-NCZ is higher than that of ordinary distributed composite coating. 展开更多
关键词 co-electrodeposition functionally graded composite coating MICROHARDNESS wear resistance adhesion
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Effective AC response of a nonlinear spherical coated composite 被引量:1
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作者 郝艳花 陈小刚 +1 位作者 侯睿 王瑞 《Chinese Physics B》 SCIE EI CAS CSCD 2010年第6期471-476,共6页
An effective nonlinear response of a nonlinear composite with spherical coated inclusions randomly embedded in a host medium under the action of an external AC electric field, Ea= E1 sin(wt) + E3 sin(3wt), is inv... An effective nonlinear response of a nonlinear composite with spherical coated inclusions randomly embedded in a host medium under the action of an external AC electric field, Ea= E1 sin(wt) + E3 sin(3wt), is investigated using a perturbation method. The local potentials of the composite at higher harmonics are given both in the region of local inclusion particles and in the local host region under the external AC electric field. All effective nonlinear responses of the composite and the relationship between the effective nonlinear responses at the fundamental frequency and third harmonics are also studied for spherical coated inclusion in a dilute limit. 展开更多
关键词 nonlinear composite effective nonlinear response coated composite AC electric field
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Corrosion resistance and anti-soiling performance of micro-arc oxidation/graphene oxide/stearic acid superhydrophobic composite coating on magnesium alloys 被引量:7
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作者 Dong Wang Chen Ma +4 位作者 Jinyu Liu Weidong Li Wei Shang Ning Peng Yuqing Wen 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第6期1128-1139,共12页
Magnesium(Mg)alloys,the lightest metal construction material used in industry,play a vital role in future development.However,the poor corrosion resistance of Mg alloys in corrosion environments largely limits their p... Magnesium(Mg)alloys,the lightest metal construction material used in industry,play a vital role in future development.However,the poor corrosion resistance of Mg alloys in corrosion environments largely limits their potential wide applications.Therefore,a micro-arc oxidation/graphene oxide/stearic acid(MAO/GO/SA)superhydrophobic composite coating with superior corrosion resistance was fabricated on a Mg alloy AZ91D through micro-arc oxidation(MAO)technology,electrodeposition technique,and self-assembly technology.The composition and microstructure of the coating were characterized by scanning electron microscopy,X-ray diffraction,energy dispersive spectroscopy,and Raman spectroscopy.The effective protection of the MAO/GO/SA composite coating applied to a substrate was evaluated using potentiodynamic polarization,electrochemical impedance spectroscopy tests,and salt spray tests.The results showed that the MAO/GO/SA composite coating with a petal spherical structure had the best superhydrophobicity,and it attained a contact angle of 159.53°±2°.The MAO/GO/SA composite coating exhibited high resistance to corrosion,according to electrochemical and salt spray tests. 展开更多
关键词 magnesium alloy composite coating SUPERHYDROPHOBIC corrosion resistance anti-soiling performance
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ZIF-8-based micro-arc oxidation composite coatings enhanced the corrosion resistance and superhydrophobicity of a Mg alloy 被引量:6
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作者 Shiquan Jiang Zhiyuan Zhang +3 位作者 Dong Wang Yuqing Wen Ning Peng Wei Shang 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2023年第4期1367-1380,共14页
Mg alloys are considered the most promising engineering materials because of their unique properties.However,the uncontrolled corrosion rate of these alloys limits their applications.Therefore,in this study,a micro-ar... Mg alloys are considered the most promising engineering materials because of their unique properties.However,the uncontrolled corrosion rate of these alloys limits their applications.Therefore,in this study,a micro-arc oxidation layer was used as a transition layer to“directly”grow a zinc-based metal-organic framework(MOF)composite coating on the surface of a Mg alloy(AZ91D).Herein,the two zeolitic imidazolate framework(ZIF-8)coatings with different morphologies were separately prepared by homologous metal oxide induction and a one-step in-situ growth method.The superhydrophobic composite coating showed strong hydrophobicity and self-cleaning properties,which could prevent the penetration of water and corrosive ions(Cl^(−))into the surface of AZ91D.Electrochemical tests demonstrated that the super-hydrophobic composite coatings greatly enhanced the corrosion resistance of AZ91D,and the corrosion current density decreased from 10^(−5)to 10^(−9)A/cm^(2).These results indicate that the ZIF-8 coatings are beneficial for improving the hydrophobicity and enhancing the corrosion resistance of Mg alloys.Therefore,MOF composite coatings provide a new strategy that can be used to prepare multifunctional anticorrosion coatings on metal substrates. 展开更多
关键词 Mg alloy composite coating Metal-organic framework Corrosion resistance SUPERHYDROPHOBICITY
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Microstructure and properties of induction brazing nickel base/WC composite coating 被引量:2
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作者 秦建 杨骄 +4 位作者 刘攀 刘大双 卢洪波 廖清泉 常云峰 《China Welding》 CAS 2023年第1期27-34,共8页
BNi-2/WC composite wear-resisting coating was prepared on carbon steel by the method of induction brazing.The microstructure and phase composition of the composite coating were analyzed,and the bonding strength and we... BNi-2/WC composite wear-resisting coating was prepared on carbon steel by the method of induction brazing.The microstructure and phase composition of the composite coating were analyzed,and the bonding strength and wear-resisting performance of the coating were tested.During the process of induction brazing,the tungsten carbide partially dissolves and reacts with the filler metal alloy to form NiW compound phase,which realizes the metallurgical combination of tungsten carbide and filler metal alloy.The matrix of the filler metal alloy consists of Ni solid solution and Ni_(3)B/Ni_(3)Si eutectic phase,and the metallurgical diffusion reaction occurs between the filler metal alloy and the steel matrix.The mechanical analysis results show that the self-strength of the composite coating reaches 140 MPa and the bonding strength of the filler metal alloy to the steel matrix reaches 360 MPa.The dry sand rubber wheel wear testing machine showed that the coating weight loss was only 0.2824 g,which was only 1/5 of the weight loss of 65 Mn matrix under the same conditions. 展开更多
关键词 composite coating induction brazing tungsten carbide BNI-2 wear resistance
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New superhydrophobic composite coatings on Mg-Mn-Ce magnesium alloy 被引量:1
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作者 K.V.Nadaraia S.N.Suchkov +5 位作者 I.M.Imshinetskiy D.V.Mashtalyar D.Yu.Kosianov E.A.Belov S.L.Sinebryukhov S.V.Gnedenkov 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2023年第5期1721-1739,共19页
A novel combined method for the formation of composite coatings on the Mg-Mn-Ce alloy is developed.Ceramic like matrix was formed on the Mg alloy surface by the plasma electrolytic oxidation.Then the samples were subs... A novel combined method for the formation of composite coatings on the Mg-Mn-Ce alloy is developed.Ceramic like matrix was formed on the Mg alloy surface by the plasma electrolytic oxidation.Then the samples were subsequently processed by dip-coating in an alcohol suspension of superdispersed polytetrafluoroethylene and spraying with the tetrafluoroethylene telomers solution.SEM,OSP,and SPM was used to study structure of formed surfaces.It was established by measurements of CA and CAH,as well as surface free energy calculations that formed coatings demonstrate superhydrophobic properties due to the presence of an irregular hierarchical surface structure and low surface free energy of fluoropolymers.The coating preserves its hydrophobic properties after exposure to high and low temperatures,for a long time as well as being in corrosive environments.EDS and XRD data analysis confirmed the presence of organofluorine compounds in the composite layers,including in the form of crystalline polytetrafluoroethylene.Using potentiodynamic polarization test and EIS,it was found that the resulting coatings significantly increase the corrosion resistance of Mg material.These data are also confirmed by salt spray tests for 40 days.Incorporation of fluoropolymers additionally decrease coatings coefficient of friction. 展开更多
关键词 Magnesium alloy Plasma electrolytic oxidation SUPERHYDROPHOBICITY FLUOROPOLYMERS composite coatings
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Compositing Soft Coated Ti-Fiber Reinforced Ti-Al Matrix Composites
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作者 何贵玉 储双杰 +2 位作者 胡世平 张太贤 蔡学章 《Rare Metals》 SCIE EI CAS CSCD 1997年第3期41-46,共6页
It is showed that there are Ti 3Al, Ti 2Cu and β phase in the interface of Ti/Ti Al composites reinforced with Y 2O 3 Cr composite soft coated Ti fiber, and that interface bonding is intact. Bending strength ... It is showed that there are Ti 3Al, Ti 2Cu and β phase in the interface of Ti/Ti Al composites reinforced with Y 2O 3 Cr composite soft coated Ti fiber, and that interface bonding is intact. Bending strength of the composites can be increased by 26%, to 709 MPa, and bending deflection increased slightly compared with the Ti/Ti Al composites reinforced by Ti fibers coated with Y 2O 3. 展开更多
关键词 Ti Al matrix composite Ti fiber composite soft coating Mechanical property
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Effective response in nonlinear spherical coated composites under external AC and DC electric fields
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作者 包曙红 陈小刚 +2 位作者 李倩倩 郭军明 翟丽丽 《Chinese Physics B》 SCIE EI CAS CSCD 2012年第8期428-434,共7页
By using the perturbation method, effective nonlinear direct current (DC) and alternating current (AC) responses of nonlinear composites with spherical coated inclusions randomly embedded in a host medium are stud... By using the perturbation method, effective nonlinear direct current (DC) and alternating current (AC) responses of nonlinear composites with spherical coated inclusions randomly embedded in a host medium are studied under the action of an external electric field Ea = E0 + E1 sinωt + E3 sin 3ωt with different amplitudes and frequencies. The local potentials of composites at all harmonics are given in the inclusion particles and the host regions. All effective nonlinear responses to composites and the relationship between the effective nonlinear responses at all harmonics are also deduced for the spherical coated inclusions in a dilute limit. 展开更多
关键词 nonlinear spherical coated composites effective nonlinear response the external AC andDC electric field
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One-step hydrothermal synthesis of 2,5-PDCA-containing MgAl-LDHs three-layer composite coating with high corrosion resistance on AZ31
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作者 Fan Shi Jingmao Zhao +3 位作者 Mohammad Tabish Jingbao Wang Pu Liu Jiayu Chang 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2023年第7期2541-2557,共17页
The addition of 2,5-pyridinedicarboxylic acid(2,5-PDCA)to the Mg-Al LDH coating,which was prepared by one-step hydrothermal synthesis,had extremely enhanced the corrosion protection of AZ31 Mg alloy,although the 2,5-P... The addition of 2,5-pyridinedicarboxylic acid(2,5-PDCA)to the Mg-Al LDH coating,which was prepared by one-step hydrothermal synthesis,had extremely enhanced the corrosion protection of AZ31 Mg alloy,although the 2,5-PDCA could not be intercalated into the interlayer spacing.The corrosion current density of 0.05 mol L^(−1)2,5-PDCA LDH containing LDH coating is 3.18 nA cm^(−2),reduced by two orders of magnitude compared to the LDH coating without inhibitor,and the corrosion inhibition efficiency of the coating is 98.05%.The coating formed on the surface of AZ31 was peeled off from the substrate by using a mechanical method and SEM observation of the cross-section showed that the coating consisted of three different layers.The innermost layer is a thick layer that consists of Mg(OH)_(2)and the intermediate layer is LDH,which is vertical to the substrate and the outmost layer is a thin but very dense deposit layer of LDH agglomerates with complexes of 2,5-PDCA and Mg.This kind of sediment/LDH/Mg(OH)_(2)three-layer composite structure was accountable for the increase in the corrosion resistance of AZ31 Mg alloy. 展开更多
关键词 Three-layer composite coating Hydrothermal synthesis 2 5-PDCA MgAl-LDHs PEELING
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Corrosion behavior of composite coatings containing hydroxyapatite particles on Mg alloys by plasma electrolytic oxidation: A review
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作者 Arash Fattah-alhosseini Razieh Chaharmahali +1 位作者 Sajad Alizad Mosab Kaseem 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2023年第9期2999-3011,共13页
Mg and its alloys have been introduced as promising biodegradable materials for biomedical implant applications due to their excellent biocompatibility, mechanical behavior, and biodegradability. However, their suscep... Mg and its alloys have been introduced as promising biodegradable materials for biomedical implant applications due to their excellent biocompatibility, mechanical behavior, and biodegradability. However, their susceptibility to rapid corrosion within the body poses a significant challenge and restricts their applications. To overcome this issue, various surface modification techniques have been developed to enhance the corrosion resistance and bioactivity of Mg-based implants. PEO is a potent technique for producing an oxide film on a surface that significantly minimizes the tendency to corrode. However, the inevitable defects due to discharges and poor biological activity during the coating process remain a concern. Therefore, adding suitable particles during the coating process is a suitable solution. Hydroxyapatite(HAp)has attracted much attention in the development of biomedical applications in the scientific community. HAp shows excellent biocompatibility due to its similarity in chemical composition to the mineral portion of bone. Therefore, its combination with Mg-based implants through PEO has shown significant improvements in their corrosion resistance and bioactivity. This review paper provides a comprehensive overview of the recent advances in the preparation, characterization, corrosion behavior and bioactivity applications of HAp particles on Mg-based implants by PEO. 展开更多
关键词 Mg and its alloys HYDROXYAPATITE Corrosion behavior composite coatings Plasma electrolytic oxidation(peo)
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Oxidation and Electrical Properties of Cu-Mn_(3)O_(4)Composite Coating Obtained by Electrodeposition on SOFC Interconnects
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作者 吕烨 LUO Shengyun 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2023年第1期72-78,共7页
Cu-Mn_(3)O_(4)composite coating was prepared on the SUS 430 ferritic stainless steel by electrodeposition and then exposed in air at 800℃corresponding to the cathode atmosphere of solid oxide fuel cell(SOFC).A dual-l... Cu-Mn_(3)O_(4)composite coating was prepared on the SUS 430 ferritic stainless steel by electrodeposition and then exposed in air at 800℃corresponding to the cathode atmosphere of solid oxide fuel cell(SOFC).A dual-layer oxide structure mainly comprising an external layer of CuO followed by(Cu,Mn,Fe)_(3)O_(4)spinel and an internal layer of Cr-rich oxide was thermally developed on the coated steel.The scale area-specific resistances(ASRs)of the coated steels were lower than the scale ASR of the uncoated steel after identical thermal exposure.The external layer of CuO/(Cu,Mn,Fe)_(3)O_(4)spinel not only served as a barrier to reduce the growth rate of Cr-rich oxide internal layer and to suppress the outward diffusion of Cr,but also lowered the surface scale ASRs considerably. 展开更多
关键词 solid oxide fuel cell steel interconnect Cu-Mn_(3)O_(4)composite coating area specific resistance
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Preparation and blood-compatibility properties of PTFE coated with soybean Iecithin composite membrane
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作者 Tang Shunqing Zhou Changren and Xiao Daqin(Biomedical Engineering Institute, Jinan University, Guangzhou, 510632, China) 《Chinese Journal of Biomedical Engineering(English Edition)》 1999年第3期22-23,共2页
关键词 PTFE Preparation and blood-compatibility properties of PTFE coated with soybean Iecithin composite membrane
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Tribological properties of nanostructured Al_2O_3-40%TiO_2 multiphase ceramic particles reinforced Ni-based alloy composite coatings 被引量:9
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作者 何龙 谭业发 +2 位作者 谭华 周春华 高立 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2013年第9期2618-2627,共10页
The Ni-based alloy composite coatings reinforced by nanostructured Al2O3-40%TiO2 multiphase ceramic particles were prepared on the surface of 7005 aluminum alloy by plasma spray technology. The microstructure and trib... The Ni-based alloy composite coatings reinforced by nanostructured Al2O3-40%TiO2 multiphase ceramic particles were prepared on the surface of 7005 aluminum alloy by plasma spray technology. The microstructure and tribological properties of the composite coatings were researched. The results show that the composite coatings mainly consist of γ-Ni, α-Al2O3, γ-Al2O3 and rutile-TiO2 etc, and exhibit lower friction coefficients and wear losses than the Ni-based alloy coatings at different loads and speeds. The composite coating bears low contact stress at 3 N and its wear mechanism is micro-cutting wear. As loads increase to 6-12 N, the contact stress is higher than the elastic limit stress of worn surface, and the wear mechanisms change into multi-plastic deformation wear, micro-brittle fracture wear and abrasive wear. With the increase of speeds, the contact temperature of worn surface increases. The composite coating experiences multi-plastic deformation wear, fatigue wear and adhesive wear. 展开更多
关键词 nanostructured A1203-TiO2 multiphase ceramic particles Ni-based alloy composite coating plasma spray friction wear
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Tribological properties of Ni-base alloy composite coating modified by both graphite and TiC particles 被引量:7
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作者 蔡滨 谭业发 +2 位作者 屠义强 王小龙 谭华 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2011年第11期2426-2432,共7页
In order to reduce the friction coefficient of Ni-base alloy coating and further improve its wear resistance,Ni-base alloy composite coatings modified by both graphite and TiC particles were prepared by plasma spray t... In order to reduce the friction coefficient of Ni-base alloy coating and further improve its wear resistance,Ni-base alloy composite coatings modified by both graphite and TiC particles were prepared by plasma spray technology on the surface of 45 carbon steel.The results show that friction coefficient of the composite coating is 47.45% lower than that of the Ni-base alloy coating,and the wear mass loss is reduced by 59.1%.Slip lines and severe adhesive plastic deformation are observed on the worn surface of the Ni-base alloy coating,indicating that the wear mechanisms of the Ni-base alloy coating are multi-plastic deformation wear and adhesive wear.A soft transferred layer abundant in graphite and ferric oxide is developed on the worn surface of the composite coating,which reduces the friction coefficient and wear loss in a great deal.The main wear mechanism of the composite coating is fatigue delamination of the transferred layer. 展开更多
关键词 Ni-base alloy plasma spraying composite coating GRAPHITE TiC TRIBOLOGY
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Preparation and tribological performances of Ni-P-multi-walled carbon nanotubes composite coatings 被引量:7
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作者 孟振强 李溪滨 +1 位作者 熊拥军 湛菁 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第11期2719-2725,共7页
Multi-walled carbon nanotubes (MWNTs) were wet-milled in the presence of ammonia and cationic surfactant and then used as reinforcements to prepare Ni-P-MWNTs composite coatings by electroless plating. The tribologi... Multi-walled carbon nanotubes (MWNTs) were wet-milled in the presence of ammonia and cationic surfactant and then used as reinforcements to prepare Ni-P-MWNTs composite coatings by electroless plating. The tribological performances of the composite coatings under dry condition were investigated in comparison with 45 steel and conventional Ni-P coating, Micrographs show that short MWNTs with uniform length and open tips were obtained through the wet-milling process. The results of wear test reveal that the Ni-P-MWNTs composite coatings posses much better friction reduction and anti-wear performances when compared with 45 steel and Ni-P coating. Within the MWNTs content range of 0.74%-1.97%, the friction coefficient and the volume wear rate of the composite coatings decrease gradually and reach the minimum values of 0.08 and 6.22x10-15 m3/(N.m), respectively. The excellent tribological performances of the composite coatings can be attributed to the introduction of MWNTs, which play both roles of reinforcements and solid lubricant during the wear process. 展开更多
关键词 Ni-P coating carbon nanotubes composite coating ball milling electroless plating SELF-LUBRICATION tribologicalperformance friction coefficient volume wear rate
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Reactive HVOF sprayed TiN-matrix composite coating and its corrosion and wear resistance properties 被引量:7
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作者 马静 闫冬青 +2 位作者 胡建文 张欣 李扬 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2013年第4期1011-1018,共8页
TiN-matrix composite coating was prepared on 45# steel by reactive high-velocity oxy-fuel (HVOF) spraying. Its microstructure, phase composition, micro-hardness, corrosion resistance in 3.5% NaC1 solution and wear r... TiN-matrix composite coating was prepared on 45# steel by reactive high-velocity oxy-fuel (HVOF) spraying. Its microstructure, phase composition, micro-hardness, corrosion resistance in 3.5% NaC1 solution and wear resistance were analyzed. The results suggest that the TiN-matrix composite coating is well bonded with the substrate. The micro-hardness measured decreases with the increase of applied test loads. And the micro-hardness of the coating under heavy loads is relatively high. The TiN-matrix composite coating exhibits an excellent corrosion resistance in 3.5% NaC1 solution. The corrosion potential of coating is positive and the passivation zone is broad, which indicates that the TiN-matrix composite coating is stable in the electrolyte and provides excellent protection to the substrate. The wear coefficient of the coating under all loads maintains at 0.49-0.50. The wear mechanism of the coating is revealed to be three-body abrasive wear. Yet the failure forms of TiN-matrix composite coating under different loads have an obvious difference. The failure form of coating under light loads is particle spallation due to the stress concentration while that of coating under heavy loads is crackin~ between inter-lamellae. 展开更多
关键词 reactive HVOF spraying TiN-matrix composite coating corrosion resistance wear resistance
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Electrodeposition and corrosion resistance of Ni-P-TiN composite coating on AZ91D magnesium alloy 被引量:5
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作者 周亚茹 张珊 +4 位作者 聂林林 朱泽洁 张鉴清 曹发和 张俊喜 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2016年第11期2976-2987,共12页
In order to improve the corrosion resistance and microhardness of AZ91D magnesium alloy, TiN nanoparticles were addedto fabricate Ni-P-TiN composite coating by electrodeposition. The surface, cross-section morphology ... In order to improve the corrosion resistance and microhardness of AZ91D magnesium alloy, TiN nanoparticles were addedto fabricate Ni-P-TiN composite coating by electrodeposition. The surface, cross-section morphology and composition wereexamined using SEM, EDS and XRD, and the corrosion resistance was checked by electrochemical technology. The results indicatethat TiN nanoparticles were doped successfully in the Ni-P matrix after a series of complex pretreatments including activation, zincimmersion and pre-electroplating, which enhances the stability of magnesium alloy in electrolyte and the adhesion betweenmagnesium alloy and composite coating. The microhardness of the Ni-P coating increases dramatically by adding TiN nanoparticlesand subsequent heat treatment. The corrosion experimental results indicate that the corrosion resistance of Ni-P-TiN compositecoating is much higher than that of uncoated AZ91D magnesium alloy and similar with Ni-P coating in short immersion time.However, TiN nanoparticles play a significant role in long-term corrosion resistance of composite coatings. 展开更多
关键词 AZ91D composite coating TiN nanoparticle ELECTRODEPOSITION corrosion resistance
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Tribological behavior and mechanisms of graphite/CaF_2/TiC/Ni-base alloy composite coatings 被引量:3
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作者 蔡滨 谭业发 +2 位作者 何龙 谭华 王小龙 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2013年第2期392-399,共8页
In order to reduce the friction coefficients and improve the wear resistance of mechanical parts, which work in the severe friction and wear conditions at heavy loads, the graphite/CaFg/TiC/Ni-base alloy composite coa... In order to reduce the friction coefficients and improve the wear resistance of mechanical parts, which work in the severe friction and wear conditions at heavy loads, the graphite/CaFg/TiC/Ni-base alloy composite coatings were prepared by plasma spray and their tribological behavior and mechanisms were investigated. The results show that the friction coefficients of the composite coatings are in the range of 0.22-0.288, which are reduced by 25.9% to 53% compared with those of the pure Ni-base alloy coatings, and the wear rates of the former are 18.6%-70.1% less than those of the latter. When wear against GCr15 steel balls, a transferred layer mainly composed of ferric oxides, graphite and CaF2 may gradually develop on the worn surface of the composite coatings, which made the friction and wear between GCr15 steel ball and the composite coatings change into that between the former and the transferred layer. So the friction coefficients and the wear lubrication effect of the transferred layer. The main wear layer in friction process. rates of the composite coatings are greatly reduced because of the solid mechanism of the composite coatings is delamination of the transferred 展开更多
关键词 plasma spray composite coatings Ni-base alloy GRAPHITE TIC CAF2 TRIBOLOGY
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