A ZA 27 alloy reinforced with Mn containing intermetallic compounds was prepared and its tribological behaviors were investigated. By adding Mn, RE, Ti and B into ZA 27 alloy, the test alloy (ZMJ) was fabricated by sa...A ZA 27 alloy reinforced with Mn containing intermetallic compounds was prepared and its tribological behaviors were investigated. By adding Mn, RE, Ti and B into ZA 27 alloy, the test alloy (ZMJ) was fabricated by sand casting. Microstructural analysis shows that considerable amount of Mn containing intermetallic compounds such as Al 5MnZn, Al 9(MnZn) 2 and Al 65 Mn(RE) 6Ti 4Zn 36 are formed. Compared to ZA 27, ZMJ shows better wear resistance, lower friction coefficient and lower temperature rise of worn surface under lubricated sliding condition. ZMJ also shows the lowest steady friction coefficient under dry friction condition. The wear resistance improvement of ZMJ is mainly attributed to the high hardness and good dispersion of these Mn containing intermetallic compounds. It is indicated that the intermetallic compounds play a dominant role in reducing the sever adhesive and abrasive wear of the ZA 27 alloy.展开更多
Gas nitridation of TiAl based alloys in an ammonia atmosphere was carried out. The evaluation of the surface wear resistance was performed to compare with those of the non nitrided alloys. It is concluded that high te...Gas nitridation of TiAl based alloys in an ammonia atmosphere was carried out. The evaluation of the surface wear resistance was performed to compare with those of the non nitrided alloys. It is concluded that high temperature nitridation raised wear resistance of TiAl based alloys markedly. The tribological behaviors of the nitrided alloys were also discussed. The oxidation kinetics of the nitrided TiAl based alloys were investigated at 800～1?000?℃ in hot air. It is concluded that nitridation is detrimental to the oxidation resistance of TiAl based alloys under the present conditions. The nitrided alloys exhibit increased oxidizing rate with the prolongation of nitridation time at 800?℃. However, alloys nitrided at 940?℃ for 50?h display a sign of better oxidation resistance than the other nitrided alloys at more severe oxidizing conditions. The parabolic rate law is considered as the basis of the data processing and interpretation of the mass gain vs time data. As a comparison with it, attempts were made to fit the data with the power law. The oxidation kinetic parameter k n, k p and n were measured and the trends were discussed.展开更多
A kind of novel compound containing S and Mo elements was synthesized. Its chemical structure was characterized by elemental analysis, IR and 3MR. hs anti-wear property and the load-carrying capacity, as an extreme pr...A kind of novel compound containing S and Mo elements was synthesized. Its chemical structure was characterized by elemental analysis, IR and 3MR. hs anti-wear property and the load-carrying capacity, as an extreme pressure （EP） additive of lubricating oil, were investigated using a four-bull tester. The experimentul results show that the additive exhibits a superior anti-wear property and a high load-carrying capacity . The presence of other additives does not interfere with the anti-wear prnperty of the extreme pressure additive. The influences of load and temperature on the propert） of the additive were examined. The possible mechanism uas investigated by means of sufface analysis of the tested steel ball specimen , using XPS. The lubricatian films formed on the rubbing surface are mainly composed of MoS2, MoO3 and MoO2.展开更多
The effects of rare earths(RE)-Mg-Ti compound modification on the structures and properties of high-carbon high speed steel(HSS) were researched.The impact toughness(α_k),the fracture toughness(K_(1c))and threshold o...The effects of rare earths(RE)-Mg-Ti compound modification on the structures and properties of high-carbon high speed steel(HSS) were researched.The impact toughness(α_k),the fracture toughness(K_(1c))and threshold of fatigue crack growth(ΔK_(th))are tested.The thermal fatigue test is done on a self-straining thermal fatigue tester,the wear test is done on a high temperature wear test machine.The results show that the matrix can be refined by the RE-Mg-Ti compound modification,the eutectic carbides are inclined to spheroidicize and are distributed evenly,the morphology and distribution of eutectic carbides are improved by appropriate RE-Mg-Ti complex modification.After RE-Mg-Ti compound modification,a little effects can be found on the strength,hardness and red hardness,but the fracture toughness(K_(1c)) and threshold of fatigue crack growth(△K_(th)) are improved in the meantime,the impact toughness (α_k) is increased by over one time,and the resistance to thermal fatigue and wear resistance at an elevated temperature are remarkably improved.展开更多
文摘A ZA 27 alloy reinforced with Mn containing intermetallic compounds was prepared and its tribological behaviors were investigated. By adding Mn, RE, Ti and B into ZA 27 alloy, the test alloy (ZMJ) was fabricated by sand casting. Microstructural analysis shows that considerable amount of Mn containing intermetallic compounds such as Al 5MnZn, Al 9(MnZn) 2 and Al 65 Mn(RE) 6Ti 4Zn 36 are formed. Compared to ZA 27, ZMJ shows better wear resistance, lower friction coefficient and lower temperature rise of worn surface under lubricated sliding condition. ZMJ also shows the lowest steady friction coefficient under dry friction condition. The wear resistance improvement of ZMJ is mainly attributed to the high hardness and good dispersion of these Mn containing intermetallic compounds. It is indicated that the intermetallic compounds play a dominant role in reducing the sever adhesive and abrasive wear of the ZA 27 alloy.
文摘Gas nitridation of TiAl based alloys in an ammonia atmosphere was carried out. The evaluation of the surface wear resistance was performed to compare with those of the non nitrided alloys. It is concluded that high temperature nitridation raised wear resistance of TiAl based alloys markedly. The tribological behaviors of the nitrided alloys were also discussed. The oxidation kinetics of the nitrided TiAl based alloys were investigated at 800～1?000?℃ in hot air. It is concluded that nitridation is detrimental to the oxidation resistance of TiAl based alloys under the present conditions. The nitrided alloys exhibit increased oxidizing rate with the prolongation of nitridation time at 800?℃. However, alloys nitrided at 940?℃ for 50?h display a sign of better oxidation resistance than the other nitrided alloys at more severe oxidizing conditions. The parabolic rate law is considered as the basis of the data processing and interpretation of the mass gain vs time data. As a comparison with it, attempts were made to fit the data with the power law. The oxidation kinetic parameter k n, k p and n were measured and the trends were discussed.
文摘A kind of novel compound containing S and Mo elements was synthesized. Its chemical structure was characterized by elemental analysis, IR and 3MR. hs anti-wear property and the load-carrying capacity, as an extreme pressure （EP） additive of lubricating oil, were investigated using a four-bull tester. The experimentul results show that the additive exhibits a superior anti-wear property and a high load-carrying capacity . The presence of other additives does not interfere with the anti-wear prnperty of the extreme pressure additive. The influences of load and temperature on the propert） of the additive were examined. The possible mechanism uas investigated by means of sufface analysis of the tested steel ball specimen , using XPS. The lubricatian films formed on the rubbing surface are mainly composed of MoS2, MoO3 and MoO2.
文摘The effects of rare earths(RE)-Mg-Ti compound modification on the structures and properties of high-carbon high speed steel(HSS) were researched.The impact toughness(α_k),the fracture toughness(K_(1c))and threshold of fatigue crack growth(ΔK_(th))are tested.The thermal fatigue test is done on a self-straining thermal fatigue tester,the wear test is done on a high temperature wear test machine.The results show that the matrix can be refined by the RE-Mg-Ti compound modification,the eutectic carbides are inclined to spheroidicize and are distributed evenly,the morphology and distribution of eutectic carbides are improved by appropriate RE-Mg-Ti complex modification.After RE-Mg-Ti compound modification,a little effects can be found on the strength,hardness and red hardness,but the fracture toughness(K_(1c)) and threshold of fatigue crack growth(△K_(th)) are improved in the meantime,the impact toughness (α_k) is increased by over one time,and the resistance to thermal fatigue and wear resistance at an elevated temperature are remarkably improved.
