Research progress on protective coatings against molten nitrate salts for thermal energy storage in concentrating solar power plants

Concentrating solar power(CSP) has garnered considerable global attention as a reliable means of generating bulk electricity, effectively addressing the intermittent nature of solar resources.The integration of molten salt technology for thermal energy storage(TES) has further contributed to the growth of CSP plants;however, the corrosive nature of molten salts poses challenges to the durability of container materials, necessitating innovative corrosion mitigation strategies.This review summarizes scientific advancements in high-temperature anticorrosion coatings for molten nitrate salts, highlighting the key challenges and future trends.It also explores various coating types, including metallic, ceramic, and carbon-based coatings, and compares different coating deposition methods.This review emphasizes the need for durable coatings that meet long-term performance requirements and regulatory limitations, with an emphasis on carbon-based coatings and emerging nanomaterials.A combination of multiple coatings is required to achieve desirable anticorrosion properties while addressing material compatibility and cost considerations.The overall goal is to advance the manufacturing, assembly, and performance of CSP systems for increased efficiency, reliability, and durability in various applications.

Cascade utilization of full spectrum solar energy for achieving simultaneous hydrogen production and all-day thermoelectric conversion

Solar-driven photocatalytic water/seawater splitting holds great potential for green hydrogen production.However,the practical application is hindered by the relatively low conversion efficiency resulting from the inadequate utilization of solar spectrum with significant waste in the form of heat.Moreover,current equipment struggles to maintain all-day operation subjected to the lack of light during nighttime.Herein,a novel hybrid system integrating photothermal catalytic(PTC)reactor,thermoelectric generator(TEG),and phase change materials(PCM)was proposed and designed(named as PTC-TEG-PCM)to address these challenges and enable simultaneous overall seawater splitting and 24-hour power generation.The PTC system effectively maintains in an optimal temperature range to maximize photothermal-assisted photocatalytic hydrogen production.The TEG component recycles the low-grade waste heat for power generation,complementing the shortcoming of photocatalytic conversion and achieving cascade utilization of full-spectrum solar energy.Furthermore,exceptional thermal storage capability of PCM allow for the conversion of released heat into electricity during nighttime,contributing significantly to the overall power output and enabling PTC-TEG-PCM to operate for more than 12 h under the actual condition.Compared to traditional PTC system,the overall energy conversion efficiency of the PTC-TEG-PCM system can be increased by∼500%,while maintaining the solar-to-hydrogen efficiency.The advancement of this novel system demonstrated that recycling waste heat from the PTC system and utilizing heat absorption/release capability of PCM for thermoelectric application are effective strategies to improve solar energy conversion.With flexible parameter designing,PTC-TEG-PCM can be applied in various scenarios,offering high efficiency,stability,and sustainability.

Analysis of Current Research and Future Development Trends of Applying Solar Energy in Street Lighting

In the context of promoting green energy transition and addressing climate change globally,solar energy,as a clean and renewable energy source,has gradually become a hot topic for research.Solar streetlight systems realize energy self-sufficiency and environment-friendly lighting by integrating photovoltaic power generation technology and efficient LED lighting technology.By comprehensively analyzing the current status of the application of solar streetlights at home and abroad,this paper discusses its technical advantages,market penetration,and challenges in its development.In terms of technical characteristics,this paper focuses on analyzing the key technologies such as energy conversion efficiency and intelligent control systems of solar streetlights.

Progress in Research and Development of Molten Chloride Salt Technology for Next Generation Concentrated Solar Power Plants

Concentrated solar power(CSP)plants with thermal energy storage(TES)system are emerging as one kind of the most promising power plants in the future renewable energy system,since they can supply dispatchable and low-cost electricity with abundant but intermittent solar energy.In order to significantly reduce the levelized cost of electricity(LCOE)of the present commercial CSP plants,the next generation CSP technology with higher process temperature and energy efficiency is being developed.The TES system in the next generation CSP plants works with new TES materials at higher temperatures(>565℃)compared to that with the commercial nitrate salt mixtures.This paper reviews recent progressin research and development of the next generation CSP and TES technology.Emphasis is given on theadvanced'TES technology based on molten chloride salt mixtures such as MgCl_(2)/NaCl/KCl which hassimilar thermo-physical properties as the commercial nitrate salt mixtures,higher thermal stability(>800℃),and lower costs(<0.35USD·kg^(-1)).Recent progress in the selection/optimization of chloridesalts,determination of molten chloride salt properties,and corrosion control of construction materials(eg.,alloys)in molten chlorides is reviewed.

High-temperature Thermal Properties and Wear Behavior of Basalt as Heat Storage Material for Concentrated Solar Power Plants

The microstructures,components,thermal stability,specific heat capacity and thermal conductivity of basalt sample were studied.Besides,as a comprehensive result of thermal expansion and contraction process,both the friction coefficient and wear rate of the basalt sample were also characterized.Our results indicate that basalt is an excellent candidate to be used as thermal energy storage material for concentrated solar power plants,and also provide a strategy for solar energy utilization in volcanic area with excellent geographical environment.

Preparation and Characterization of Andalusite Ceramic Used for Solar Thermal Power Generation

High-temperature thermal storage material is one of the critical materials of solar thermal power generation system. Andalusite, kaolin, talc, γ-Al2O3 and partially stabilized zireonia were used as the raw materials, and in-situ synthesis of cordierite was adopted to fabricate thermal storage material for solar thermal power generation via pressureless sintering. The phase compositions, microstructures and thermal shock resistances of the sintered samples were analyzed by XRD, SEM and EDS, and the corresponding mechanical properties were measured. The results show that the major phases of the samples are mullite and zirconium silicate, and the pores distribute uniformly. After being sintered at 1 460℃C, A4 sample exhibits a better mechanical performance and thermal shock resistance, its loss rate of bending strength after 30 cycles thermal shock is 3.04%, the bulk density and bending strength are 2.86 g.cm^-3 and 139.66 MPa, respectively. The better thermal shock resistance of the sample is closely related to the effect of zirconium silicate, such as its uniform distribution, nested growth with mullite, low thermal expansion coefficient, high thermal conductivity, etc. This ceramic can be widely used as one of potential thermal storage materials of solar thermal power generation system.

Application of Model Predictive Control Based on Kalman Filter in Solar Collector Field of Solar Thermal Power Generation

There are two prominent features in the process of temperature control in solar collector field.Firstly,the dynamic model of solar collector field is nonlinear and complex,which needs to be simplified.Secondly,there are a lot of random and uncontrollable,measurable and unmeasurable disturbances in solar collector field.This paper uses Taylor formula and difference approximation method to design a dynamic matrix predictive control(DMC)by linearizing and discretizing the dynamic model of the solar collector field.In addition,the purpose of controlling the stability of the outlet solar field salt temperature is achieved by adjusting the mass flow of molten salt.In order to further improve the ability of the system to suppress unmeasured disturbances,a steady-state Kalman filter is designed to estimate state variables,so that the system has better stability and robustness.The simulation verification results show that the DMC control system based on Kamlan filtering has better control effect than the traditional DMC control system.In the case of large fluctuations in solar radiation intensity and consideration of undetectable interference,the overshoot of the system is reduced by 4%and the rise time remains unchanged.

Hyperparameter Optimization Based Deep Belief Network for Clean Buses Using Solar Energy Model

Renewable energy has become a solution to the world’s energy concerns in recent years.Photovoltaic(PV)technology is the fastest technique to convert solar radiation into electricity.Solar-powered buses,metros,and cars use PV technology.Such technologies are always evolving.Included in the parameters that need to be analysed and examined include PV capabilities,vehicle power requirements,utility patterns,acceleration and deceleration rates,and storage module type and capacity,among others.PVPG is intermit-tent and weather-dependent.Accurate forecasting and modelling of PV sys-tem output power are key to managing storage,delivery,and smart grids.With unparalleled data granularity,a data-driven system could better anticipate solar generation.Deep learning(DL)models have gained popularity due to their capacity to handle complex datasets and increase computing power.This article introduces the Galactic Swarm Optimization with Deep Belief Network(GSODBN-PPGF)model.The GSODBN-PPGF model predicts PV power production.The GSODBN-PPGF model normalises data using data scaling.DBN is used to forecast PV power output.The GSO algorithm boosts the DBN model’s predicted output.GSODBN-PPGF projected 0.002 after 40 h but observed 0.063.The GSODBN-PPGF model validation is compared to existing approaches.Simulations showed that the GSODBN-PPGF model outperformed recent techniques.It shows that the proposed model is better at forecasting than other models and can be used to predict the PV power output for the next day.

In-Situ Preparation and Thermal Shock Resistance of Mullite-Cordierite Heat Tube Material for Solar Thermal Power

In order to improve the thermal shock resistance of solar thermal heat transfer tube material, the mullite-cordierite composite ceramic as solar thermal heat transfer tube material were fabricated by pressureless sintering using a-Al203, Suzhou kaolin, talc, and feldspar as starting materials. The important parameter for solar thermal transfer tube such as water absorption （W）, bulk density （Db）, and the mechanical properties were investigated. The phase composition and microstructure of the composite ceramics were analyzed by XRD and SEM. The experimental results show that the B3 sintered at 1 300 ℃ and holding for 3 h has an optimum thermal shock resistance. The bending strength loss rate of B3 is only 2% at 1 100℃ by air quenching-strength test and the sample can endure 30 times thermal shock cycling, and the water absorption, the bulk density and the bending strength are 0.32%, 2.58 g·cm-3, and 125.59 MPa respectively. The XRD analysis indicated that the phase compositions of the sample were mullite, cordierite, corundum, and spinel. The SEM images illustrate that the cordierite is prismatic grain and the mullite is nano rod, showing a good thermal shock resistance for composite ceramics as potential solar thermal power material.

Development modes analysis of renewable energy power generation in North Africa

North African countries generally have strategic demands for energy transformation and sustainable development.Renewable energy development is important to achieve this goal.Considering three typical types of renewable energies—wind,photovoltaic(PV),and concentrating solar power(CSP)—an optimal planning model is established to minimize construction costs and power curtailment losses.The levelized cost of electricity is used as an index for assessing economic feasibility.In this study,wind and PV,wind/PV/CSP,and transnational interconnection modes are designed for Morocco,Egypt,and Tunisia.The installed capacities of renewable energy power generation are planned through the time sequence production simulation method for each country.The results show that renewable energy combined with power generation,including the CSP mode,can improve reliability of the power supply and reduce the power curtailment rate.The transnational interconnection mode can help realize mutual benefits of renewable energy power,while the apportionment of electricity prices and trading mechanisms are very important and are related to economic feasibility;thus,this mode is important for the future development of renewable energy in North Africa.

Natural gas pyrolysis in double-walled reactor tubes using thermal plasma or concentrated solar radiation as external heating source

The thermal pyrolysis of natural gas as a clean hydrogen production route is examined. The concept of a double-walled reactor tube is proposed and implemented. Preliminary experiments using an external plasma heating source are carried out to validate this concept. The results point out the efficient CH4 dissociation above 1850 K （CH4 conversion over 90%） and the key influence of the gas residence time. Simulations are performed to predict the conversion rate of CH4 at the reactor outlet, and are consistent with experimental tendencies. A solar reactor prototype featuring four independent double-walled tubes is then developed. The heat in high temperature process required for the endothermic reaction of natural gas pyrolysis is supplied by concentrated solar energy. The tubes are heated uniformly by radiation using the blackbody effect of a cavity-receiver absorbing the concentrated solar irradiation through a quartz window. The gas composition at the reactor outlet, the chemical conversion of CH4, and the yield to H2 are determined with respect to reaction temperature, inlet gas flow-rates, and feed gas composition. The longer the gas residence time, the higher the CH4 conversion and H2 yield, whereas the lower the amount of acetylene. A CH4 conversion of 99% and H2 yield of about 85% are measured at 1880 K with 30% CH4 in the feed gas （6 L/min injected and residence time of 18 ms）, A temperature increase from 1870 K to 1970 K does not improve the H2 yield.

Optimization of solar thermal power station LCOE based on NSGA-Ⅱ algorithm

In view of the high cost of solar thermal power generation in China,it is difficult to realize large-scale production in engineering and industrialization.Non-dominated sorting genetic algorithm II(NSGA-II)is applied to optimize the levelling cost of energy(LCOE)of the solar thermal power generation system in this paper.Firstly,the capacity and generation cost of the solar thermal power generation system are modeled according to the data of several sets of solar thermal power stations which have been put into production abroad.Secondly,the NSGA-II genetic algorithm and particle swarm algorithm are applied to the optimization of the solar thermal power station LCOE respectively.Finally,for the linear Fresnel solar thermal power system,the simulation experiments are conducted to analyze the effects of different solar energy generation capacities,different heat transfer mediums and loan interest rates on the generation price.The results show that due to the existence of scale effect,the greater the capacity of the power station,the lower the cost of leveling and electricity,and the influence of the types of heat storage medium and the loan on the cost of leveling electricity are relatively high.

Full scale experimental study of a small natural draft dry cooling tower for concentrating solar thermal power plant

Concentrating solar thermal power system can provide low carbon,renewable energy resources in countries or regions with strong solar irradiation.For this kind of power plant which is likely to be located in the arid area,natural draft dry cooling tower is a promising choice.To develop the experimental studies on small cooling tower,a 20 m high natural draft dry cooling tower with fully instrumented measurement system was established by the Queensland Geothermal Energy Centre of Excellence.The performance of this cooling tower was measured with the constant heat input of 600 kW and 840 kW and with ambient temperature ranging from 20 ℃ to 32 ℃.The cooling tower numerical model was refined and validated with the experimental data.The model of 1 MW concentrating solar thermal supercritical CO2 power cycle was developed and integrated with the cooling tower model.The influences of changing ambient temperature and the performance of the cooling tower on efficiency of the power system were simulated.The differences of the mechanism of the ambient temperature effect on Rankine cycle and supercritical CO2 Brayton cycle were analysed and discussed.

Figure of Merit Analysis of a Hybrid Solar-geothermal Power Plant

Figure of merit analysis is a general methodology used to evaluate whether a hybrid power plant could produce more power than two stand-alone power plants. In this paper, the assessment methodology using figure of merit analysis was re-examined for a hybrid solar-geothermal power plant. A new definition of the figure of merit was introduced specifically for a solar boosted geothermal plant to include both the technical and economic factors. The new definition was then applied in a case study of a hypothetical demonstration hybrid solar-geothermal power plant in Australia. The power plant was considered to have a typical net power output of 2.2 MW with a solar energy fraction of 27%. The analysis was performed to compare the power output and capital cost of the hybrid plant with the state-of-the-art (SoA) and existing stand-alone solar and geothermal plants. Based on the new definition, the hybrid plant was found to generally outperform the two existing stand-alone plants. Moreover, at an ambient temperature of 5 °C, the hybrid plant was found to outperform the SoA stand-alone plants when the geothermal temperature was greater than 150 °C. For geothermal temperature of 180 °C on the other hand, the hybrid plant outperformed the SoA stand-alone plants at ambient temperatures lower than 33 °C.

A survey of geothermal power generation combined with renewable energy for low carbon emissions

At present,industrial development is heavily dependent on traditional fossil energy,which has had an increasingly serious impact on the environment.Clean and renewable energy has received extensive attention and its proportion in daily life has gradually increased.As a clean and renewable energy source that is not affected by changes in weather and seasons,geothermal energy has developed rapidly in recent years and has received increasing attention.According to reports,the total installed capacity of geothermal power generation in the world in 2020 was 15950 MW-an increase of~27%over 2015.At the end of 2019,the total installed capacity for global geothermal direct use was 107727 MW-an increase of 52.0%compared with 2015;the total annual energy use was 1020887 TJ(283580 GWh)-an increase of 72.3%over 2015.Through the investigation of geothermal power generation technology in recent years,the characteristics and shortcomings of various power generation methods are analysed.At the same time,this review analyzes the characteristics of geothermal energy and other renewable-energy(solar energy,water energy)coupling power generation,and analyzes the principles and characteristics of geothermal energy and various new-energy coupling power generation methods.Through investigation and analysis,this review provides a complete understanding of various geothermal power generation technologies and provides insights into the future development direction.

Energy and Exergy Analysis of a New Small Concentrating Solar Power Plant

A new small concentrating solar power plant which is suitable for urban area is presented, and a theoretical framework for the energy and exergy analysis in the overall power plant is also constructed. The framework can be used to evaluate the energy and exergy losses in each component. Furthermore, the energy and exergy efficiencies have also been computed and compared for the individual components as well as for the overall plant.

Proposal of a Solar Thermal Power Plant at Low Temperature Using Solar Thermal Collectors

To this day, only two types of solar power plants have been proposed and built: high temperature thermal solar one and photovoltaic one. It is here proposed a new type of solar thermal plant using glass-top flat surface solar collectors, so working at low temperature (i.e., below 100°C). This power plant is aimed at warm countries, i.e., the ones mainly located between -40° and 40° latitude, having available space along their coast. This land based plant, to install on the seashore, is technologically similar to the one used for OTEC (Ocean Thermal Energy Conversion). This plant, apart from supplying electricity with a much better thermodynamic efficiency than OTEC plants, has the main advantage of providing desalinated water for drinking and irrigation. This plant is designed to generate electricity (and desalinated water) night and day and all year round, by means of hot water storage, with just a variation of the power delivered depending on the season.

Demonstration of Pilot Scale Large Aperture Parabolic Trough Organic Rankine Cycle Solar Thermal Power Plant in Louisiana

During the calendar year of 2012 the University of Louisiana at Lafayette in conjunction with CLECO Power LLC (CLECO) has constructed and commissioned a pilot scale parabolic trough solar thermal power plant for the first time in Louisiana. The large aperture trough (LAT) solar collectors were provided by Gossamer Space Frames and are coupled with an organic Rankine cycle (ORC) power block provided by ElectraTherm, Inc. for study of the feasibility of cost-effective commercial scale solar thermal power production in Louisiana. Supported by CLECO and providing power to the existing CLECO grid, the implementation of state-of-the-industry collector frames, mirrors, trackers, and ORC power block is studied under various local weather conditions which present varied operating regimes from existing solar thermal installations. The solar collectors provide a design output of 650 kWth and preliminary actual performance data from the system level is presented. The optimal size, configuration and location for such a plant in the given solar resource region are being studied in conjunction with CLECO’s search for optimal renewable energy solutions for the region. The pilot scale size of the facility and implementation of the simpler ORC allow remote operation of the facility and flexibility in operating parameters for optimization studies. The construction of the facility was supported by the Louisiana Department of Natural Resources, the U.S. Department of Energy, and CLECO. The continued operation of the plant is supported by CLECO Power LLC and the University of Louisiana at Lafayette.

Determination of Suitable Sites for Establishment of Large-Scale Concentrated Solar Power Plants in Kenya

The demand for energy in Kenya, especially for electricity, is increasing rapidly due to population growth, decentralization of governance, and technological and industrial development. Hydroelectricity, the core source of power, has proved unreliable due to the rapid climate change. In response, the country has ventured into other renewable sources to counter the issues posed by the alternative nonrenewable sources such as unreliability, high costs, and environmental degradation as seen with the use of diesel and kerosene. The purpose of this research is to determine the viability of setting up a large-scale concentrated solar power plantation in Kenya that will assist in stabilizing Kenya’s energy demand and supply as well as increase its affordability. The project is divided into three phases. The first phase conducts an overlay analysis to determine the Kenya’s solar energy potential. The results show that the northern region has the highest potential. The second step involves the creation of an exclusion mask which eliminates the unsuitable land forms and Land Use Land Cover. Based on the results, the best ten sites are situated in Turkana and Marsabit counties. The final phase involves the evaluation of the potential capacity of power that could be generated per square kilometer. The study finds out that the potential varies based on the technologies: parabolic trough, linear Fresnel reflector, or dish systems.

Potential Map for the Installation of Concentrated Solar Power in Northeast of Brazil Using Analytic Hierarchy Process (AHP)

Brazil has a predominantly renewable energy matrix, with large participation of water resource in domestic supply of energy. Data from 2019 National Energy Balance show that renewable sources (water, biomass, wind and solar photovoltaic) together represented 83% of domestic electric supply in 2018, where the remaining percentage (16.7%) represented non-renewable sources. The generation of electricity through thermal solar technology was not representative. However, it is known that Brazil presents high potential for the installation of solar thermal plants, especially in the Northeastern Region, where direct normal solar irradiation values are high. It is observed that the (high) costs of the projects associated to the absence of a specific incentive program make Concentrating Solar Power (CSP) plants installation more and more time consuming. As a way to contribute to the insertion of solar thermal energy in Brazil, this article presents a methodology for the location of parabolic trough solar thermal plants of 80 MW for the State of Bahia, located in the Northeastern Region of Brazil. Such methodology was based on the application the Analytic Hierarchy Process (AHP) method and the Geoprocessing Technologies to define potentially available sites for the implementation of the projects. For the analysis, parameters related to energy production in the solar power plant, electric, roadways and water infrastructure of the plant were taken into account, as well as the occupation, slopes and land use. Considering the analyses performed, it was confirmed that Bahia disposes of many sites with great generation potential, especially in the western region of the State (at Barreiras), where favorable conditions were found for the development of the technology. Localities situated in other region of the State were also confirmed as suitable, however with less site availability for the insertion of plants. Methodology validations were also carried out and indicated that the model reached the proposed objective, faithfully representing the real-world simplifications that were made.