t The excited states of the doubly-odd 120^Ⅰ have been investigated via the 110^Pd（14^N, 4n） and the 114^Cd（10^B, 4n） reactions at beam energies of 64 MeV and 48 MeV, re-spectively. The previously known bands are...t The excited states of the doubly-odd 120^Ⅰ have been investigated via the 110^Pd（14^N, 4n） and the 114^Cd（10^B, 4n） reactions at beam energies of 64 MeV and 48 MeV, re-spectively. The previously known bands are extended, and a new band structure is established. The yrast band is assigned to the πrh11/2 vh11/2 configuration instead of the previously as- signed πg7/2 vh11/2 configuration. Possible configurations of the other observed bands are also discussed.展开更多
A novel malonamide-linked zinc bisporphyrinate[Zn_(2)-1]has been designed and synthesized.UV-vis and NMR spectroscopic studies suggest the molecule aggregates in solution.Such zinc bisporphyrinate is very CD-sensitive...A novel malonamide-linked zinc bisporphyrinate[Zn_(2)-1]has been designed and synthesized.UV-vis and NMR spectroscopic studies suggest the molecule aggregates in solution.Such zinc bisporphyrinate is very CD-sensitive when it is mixed with amino acid ethyl esters.The amplitude value of the induced circular dichroism(ICD)is up to ca.1500 L•mol^(−1)•cm^(−1).Further studies by ^(1)H NMR and UV-vis spectroscopies reveal amino acid esters function as monodentate ligands,and[Zn_(2)-1]interacts with amino acid ethyl esters through coordination and hydrogen bonding interactions.展开更多
基金supported by National Natural Science Foundation of China (No.10675053)National Basic Research Program of China(No.2007CB815005)
文摘t The excited states of the doubly-odd 120^Ⅰ have been investigated via the 110^Pd（14^N, 4n） and the 114^Cd（10^B, 4n） reactions at beam energies of 64 MeV and 48 MeV, re-spectively. The previously known bands are extended, and a new band structure is established. The yrast band is assigned to the πrh11/2 vh11/2 configuration instead of the previously as- signed πg7/2 vh11/2 configuration. Possible configurations of the other observed bands are also discussed.
基金This work was supported by the Natural Science Foundation of China(No.21271133)the Priority Academic Program Development of Jiangsu Higher Education Institutions.
文摘A novel malonamide-linked zinc bisporphyrinate[Zn_(2)-1]has been designed and synthesized.UV-vis and NMR spectroscopic studies suggest the molecule aggregates in solution.Such zinc bisporphyrinate is very CD-sensitive when it is mixed with amino acid ethyl esters.The amplitude value of the induced circular dichroism(ICD)is up to ca.1500 L•mol^(−1)•cm^(−1).Further studies by ^(1)H NMR and UV-vis spectroscopies reveal amino acid esters function as monodentate ligands,and[Zn_(2)-1]interacts with amino acid ethyl esters through coordination and hydrogen bonding interactions.
