Jet dispersion and deposition of charged particles in confined chambers

Dispersion and surface deposition of charged particles by gas-solids jets in confined chambers are constantly encountered in many industrial applications such as in electrostatic precipitation and dry powder coating processes. Understanding and control of flow patterns and trajectories of charged particles are important to the optimal design and operation of such devices. In this study, modeling of flow fields and particle trajectories of dilute gas-solid two-phase flows with charged particles in confined chambers is performed. The dilute gas-solid two-phase flows are simulated by use of a hybrid Eulerian-Lagrangian approach with the one-way coupling between the gaseous phase and particle phase. The space charge distribution is included as a source term in equations of motion or Lagrangian equation of charged particles, which in turn depends on the particle trajectories that determine the space charge distribution. Our modeling predictions suggested that the electrostatic charge plays a significant role in particle radial dispersion. Effect of voltage has limited influence on particle trajectories however it can have a big impact on the residence time. Cone angle has a significant effect on the structure of flow field. For cone with a larger cone angle （typically over 15°）, there will be a flow separation along the side wall near the flow entrance region. By comparing with the conical chamber, the cylindrical chamber has a big vortex and three smaller vortexes in the lower part of the chamber, which would complicate the particle dispersion with or without the coupling of charging.

Facile pathway to generate agrochemical nanosuspensions integrating super-high load, eco-friendly excipients, intensified preparation process, and enhanced potency

An aqueous nanosuspension of agrochemicals unlike pharmaceutics has to achieve massive production in an effective way,capable to ensure sufficient profits in commercialization.This work implements the flash nanoprecipitation(FNP)technique to effectively generate agrochemical nanosuspension,anticipatedly overcoming such an obstacle.Azoxystrobin,a broad spectrum fungicide,in either acetone or ethanol is used herein as a mode agrochemical.To ensure a green and practical utilization,three kinds of commercially available and eco-friendly surfactants,i.e.,poly(ethylene glycol)-block-poly(lactic-co-glycolic acid)(PEG-b-PLGA),Tween 80 and alkyl polyglucosides(APGs),are employed for stabilizing the nanoparticles.The results show that the polymeric stabilizer,PEG-b-PLGA,has the best stabilization efficiency,and can maintain the particles below 100 nm for at least three weeks.The azoxystrobin load of the nanoparticles reaches as high as 77 wt.%,beneficial to enhancing the biological potency.Moreover,the FNP brings the particles a much smaller size,narrower size distribution,better size stability,and higher biological efficacy than the ones made via a traditional method of the drop and stir(DS).The nanosuspensions present superior fungicidal performances over a prevailing counterpart from Syngenta.This study proves an enhanced biological potency and reduced dosage of agrochemical nanosuspension made via the FNP,indicating a remarkable advantage of the FNP over the conventional preparation.The integration of a super-high load,eco-friendly excipients,intensified preparation process,enhanced potency,and reduced dosage creates a promising pathway to generate a green aqueous nanosuspension of agrochemicals.