Thermal Analysis Simulation of Germanium Zone Refining Process Assuming a Constant Radio-Frequency Heating Source

Three-dimensional thermal a nalysis simulation of a horizontal zone refining system is conducted for germanimn semiconductor materials. The considered geometry includes a g＇ral）hite boat filled with germanium placed in a cylindrical quartz tube. A flow of Ar and H2 gas mixture is purged througll the tube. A narrow section of the, boat is assmned to be exposed to a constant heat rate produced b v an rf coil located outside the quartz tube. The results of this analysis provide essential information about various parameters such as the shape of tile molten zone, required power and temperature gradient in the system.

Alterations in intestinal microbiota composition coincide with impaired intestinal morphology and dysfunctional ileal immune response in growing-finishing pigs under constant chronic heat stress

Background:Previous studies had shown that short-term acute heat stress(HS)affected the host’s metabolism and intestinal microbiota independent of feed intake(FI)reduction,and long-term calorie restriction caused intestinal morphological injuries and gut microbial alterations.However,research on the effects of constant chronic HS on intestinal microbial composition and the roles of FI reduction played in is limited.This study aimed to investigate the effects of 7-day constant chronic HS on the composition of intestinal microbes in growing-finishing pigs,and its relationship with pigs’performance,intestinal morphology,and ileal immune response.Twenty-four growingfinishing pigs(Duroc×Large White×Landrace,30±1 kg body weight)were randomly assigned to three treatments(n=8),1)thermal neutral(TN)conditions(25±1℃)with ad libitum FI,2)HS conditions(35±1℃)with ad libitum FI,3)pair-fed(PF)with HS under TN conditions to discriminate the confounding effects of dissimilar FI,and the FI was the previous day’s average FI of HS.The small intestinal segments(duodenum,jejunum,and ileum)and feces were collected on d 8.Results:Results indicated that HS drastically declined(P<0.05)average daily gain(ADG)and average daily feed intake(ADFI)(about 61%)in comparison with TN,and caused hyperpyrexia,meanwhile PF caused hypothermia.Morphological observation by light and electron microscopes showed that both HS and PF treatment decreased(P<0.05)the villus and microvillus height compared with TN.Additionally,HS increased(P<0.05)protein expression of heat shock protein 70 in the duodenum,jejunum,and ileum.Furthermore,the expression of tight junction protein zonula occluden-1(ZO-1)in the duodenum and ileum,and Occludin in the ileum were enhanced(P<0.05)compared with TN and PF.Moreover,HS significantly enhanced(P<0.05)the mRNA relative expression of inflammatory cytokines(TLR-2,TLR-4,and tumor necrosis factor-α(TNF-α),IL-6,IL-8,PG1–5,β-defensin 2(pBD-2)),mucins(mucin-1 and mucin-2)and P65 protein level in the ileal mucosa tissue.Intestinal microbiota analysis by 16S rRNA sequencing showed lower(P<0.10)αdiversity in both HS and PF,and a separated cluster ofβdiversity among groups.Compared with TN,HS but not PF mainly reduced(FDR<0.05)Bacteroidetes(phylum),Bacteroidia(class)and elevated the proportions of Proteobacteria(phylum,FDR<0.05),Bacillales(order,FDR<0.05),Planococcaceae(family,FDR<0.05),Kurthia(genus,FDR<0.05),Streptococcaceae(family,FDR<0.10)and Streptococcus(genus,FDR<0.10).Notably,Lactobacillales(order)was decreased(FDR<0.05)by PF alone.Furthermore,the Spearman correlation analysis indicated that the microbes prevalent in HS were positively(P<0.05)associated with intestinal morphological injuries indicators and ileal immune response parameters,and the microbes reduced in HS were negatively(P<0.05)with the performance data.Conclusions:Intestinal morphological injuries and ileal immune response caused by constant chronic HS independent of FI showed close connections with alterations in intestinal microbiota in growing-finishing pigs.

Numerical investigation on convective heat transfer over two heated wall-mounted cubes in tandem and staggered arrangement

In this study, laminar convective heat transfer over two heated wall-mounted cubes is investigated.Two cubes, which are under constant heat flux, are placed in different tandem and staggeredarrangements on a base plate. This problem is studied for different streamwise and spanwisedistances between two cubes in different Renolds number （Re）, by using finite-volume method.Effects of these parameters are considered on flow and heat transfer characteristics. The resultsshow that the temperature distribution is strongly dependent on flow structure and varies with anychange of flow pattern in different arrangements of cubes. In addition, it is observed that the dragcoefficient, which is influenced more by pressure forces, in staggered arrangement, is greater thantandem arrangement. Results show that by increasing the spanwise distance the amount of meanNusselt number （Nu） of Cube 2 becomes the same as Cube 1.

Electrical Calibration for Calvet Type Microcalorimetry

The device construction and working principle of Calvet type heat conductive microcalorimetry are generally introduced in this paper. Based on previous work, we design a reactor vessel and its electrical calibration equipment according to our special study systems. The heat constant of our improved microalorimetry is gotten by means of electrical calibration on the basis of Tian's equation. The results gotten by integration method are identical with ones gotten by peak method. It shows that our improved device works well enough to develop further studies.

Studies of Thermodynamic Properties and Relative Stability of Polybrominated Xanthones by Density Functional Theory

The thermodynamic properties of xanthone（XTH） and 135 polybrominated xanthones（PBXTHs） in the standard state have been calculated at the B3LYP/6-31G＊ level using Gaussian 03 program.The isodesmic reactions were designed to calculate the standard enthalpy of formation（△fHθ） and standard free energy of formation（△fGθ） of PBXTH congeners.The relations of these thermodynamic parameters with the number and position of Br atom substitution（NPBS） were discussed,and it was found that there exist high correlation between thermodynamic parameters（entropy（Sθ）,△fHθ and △fGθ） and NPBS.According to the relative magnitude of their △fGθ,the relative stability order of PBXTH congeners was theoretically proposed.The relative rate constants of formation reactions of PBXTH congeners were calculated,Moreover,the values of molar heat capacity at constant pressure（Cp,m） from 200 to 1000 K for PBXTH congeners were also calculated,and the temperature dependence relation of them was obtained,suggesting very good relationships between Cp,m and temperature（T,T^1 and T^2） for almost all PBXTH congeners.

DFT Study on Some Properties of Polybrominated Phenoxathiin 10-Oxides

With the B3LYP calculation method of density functional theory（DFT）and the 6-31G＊ basis set,full optimization calculation was made for phenoxathiin10-oxide（PTO）and 135 polybromine phenoxathiin 10-oxides（PBPTOs）with the Gaussian 03 program and molar heat capacity in constant volume（CVθ）value of each molecule in the standard state was obtained.The relation between CVθ and the substitution position and number of bromine atom（NPBS）was studied,and the results indicated good correlation（R2 = 1.000）between CVθ and NPBS of PBPTO compounds.Based on the output file of Gaussian 03 program,molar heat capacity at constant pressure（Cp,m）of PBPTO compounds from 200 to 1,000 K was calculated with the statistical thermodynamics program,and the correlation equation between Cp,m and temperature（T,T-1 and T-2）was obtained with the least-squares method,and the correlation coefficient of the correlation equation（R2）was 1.000.In addition,based on the partition function of each molecule calculated by vibration analysis,the relative rate constant of formation of each molecule was calculated.

Effects of different heating patterns on the decomposition behavior of white pine wood during slow pyrolysis

This study investigated the effect of different heating rates on the pyrolysis behavior of the white pine wood residues.The raw materials were tested via two heating patterns with variable heating rates and compared with three other heating patterns with constant heating rates.The yields and characteristics of products such as char,pyrolysis oil and non-condensable gases under different heating rates were also determined.The gas,liquid,and solid phase yields of the products via heating with decreasing heating rates were similar to the yields obtained from constant heating rate at 2.3℃/min.The pyrolysis process by decreasing heating rates resulted in 30.04% char,44.53% bio-oil,and 25.43% non-condensable gases,which displayed higher char yield and pyrolysis gas than the other heating patterns.The results of thermo-gravimetric analysis showed that variable heating rate significantly changed the weight loss profiles during pyrolysis.It was observed during gas chromatography test that CO and CO_(2) were released earlier than CH_(4) and H_(2).The analysis of the chemical components confirmed that the bio-oil produced by heating process with decreasing rates contains less macromolecular organic matter content than the other patterns.

Frictional resistance of supercritical pressure RP-3 flowing in a vertically downward tube at constant heat fluxes

Based on the demands of compact heat exchangers and micro cooling channels applied for aviation thermal protection, the flow resistance characteristics of aviation kerosene RP-3 were experimentally studied in a vertically downward circular miniature tube with an inner diameter of 1.86 mm at supercritical pressures and constant heat fluxes. A long and short tube method was used to accurately calculate the frictional pressure drop, and experimental conditions are supercritical pressures of 4 MPa, mass flow rates of 2–4 g/s(i.e., mass fluxes of 736–1472 kg/(m^(2)·s)), heat fluxes of 100–500 kW/m^(2), and inlet temperatures of 373–673 K. Results show that the sharp variations of thermophysical properties, especially density, have significant influences on frictional resistances.Generally, the frictional pressure drop and the friction factor increase with increasing inlet temperatures, and this trend speeds up in the relatively high-temperature region. However, the friction factor has a sudden decline when the fuel outlet temperature exceeds the pseudo-critical temperature.The frictional pressure drop and the friction factor basically remain unchanged with increasing heat flux when the inlet temperature is relatively low, but increase quickly when the inlet temperature is relatively high. Besides, a larger mass flux yields a higher pressure drop but does not necessarily yield a higher friction factor. Finally, an empirical friction factor correlation is proposed and shows better predictive performance than those of previous models.

Steady Natural Convection from a Vertical Hot Plate with Variable Radiation

The natural convection from a vertical hot plate with radiation and constant flux is studied numerically to know the velocity and temperature distribution characteristics over a vertical hot plate.The governing equations of the natural convection in two-dimension are solved with the implicit finite difference method,whereas the discretized equations are solved with the iterative relaxation method.The results show that the velocity and the temperature increase along the vertical wall.The influence of the radiation parameter in the boundary layer is significant in increasing the velocity and temperature profiles.The velocity profiles increase with the increase of the radiation parameter.The temperature profiles near the wall plate parallel each other due to the constant heat flux applied to the wall.The influence of the radiation parameter is significant either in velocity or temperature characteristics.At the same time,the effect of the Prandtl number greater than 0.71 is not sensitive to the velocity and temperature variations elsewhere.

Experiment of heat transfer in oscillating turbulent flow in a pipe with constant heat flux

Heat transfer characteristics of oscillating turbulent air flow in a pipe heated with constant heat flux were experimentally investigated.The experiments were performed over a range of 245.7 to 902 of the kinetic Reynolds number and 25 to 175 of the dimensionless oscillation amplitude.The effects of these two dimensionless parameters were analyzed.The results show that the cycle-averaged local Nusselt number increases with both the kinetic Reynolds number and the dimensionless oscillation amplitude.The space-cycle averaged Nusselt number also effectively increases with the kinetic Reynolds number and the dimensionless oscillation amplitude.Based on the experimental data,a correlation equation of the space-cycle averaged Nusselt number for air in terms of these two dimensionless parameters has been obtained.

Numerical simulation of thermal convection of viscoelastic fluids in an open-top porous medium with constant heat flux

This paper makes a numerical study of the buoyancy-driven convection of a viscoelastic fluid saturated in an open-top porous square box under the constant heat flux boundary condition. The effects of the relaxation and retardation times on the onset of the oscillatory convection, the convection heat transfer rate and the flow pattern transition are investigated. It is shown that a large relaxation time can destabilize the fluid flow leading to an early onset of the thermal convection and a high heat transfer rate, while a large retardation time tends to stabilize the flow and suppress the convection onset and the heat transfer. After the convection sets in, the flow bifurcation appears earlier with the increase of the relaxation time and the decrease of the retardation time, resulting in more complicated flow patterns in the porous medium. Furthermore, with the increase of the ratio of the relaxation time to the retardation time, the fluid may be blocked from flowing through the open-top boundary, which may be caused by the viscoelastic effect. Finally, the comparison of our results with those under isothermal heating boundary conditions reveals that the heat transfer rate correspo- nding to a constant heat flux boundary is always higher.

Speed of Sound and Ideal-Gas Heat Capacity at Constant Pressure for HFC-125

The gaseous speed of sound, the ideal gas heat capacity at constant pressure, and the second Virial coefficient were determined for pentafluoroethane (HFC 125). A total of 49 data points of speed of sound for gaseous HFC 125 were measured for temperatures from 273 to 313 K and pressures from 32 to 479 kPa with a cylindrical, variable path acoustic interferometer. The ideal gas heat capacity at constant pressure and the second acoustic Virial coefficient were determined over the temperature range from the speed of sound measurements and were correlated as functions of temperature. An analytical expression for the second Virial coefficient derived using the square well intermolecular potential model was compared with the data.

Wall-to-bed heat transfer in supercritical water fluidized bed using CFD-DEM

Supercritical water fluidized bed(SCWFB)reactors are designed to gasify biomass or coal with high efficiency.In this paper,the wall-to-bed heat transfer characteristics in SCWFB are studied using the computational fluid dynamics and discrete element method(CFD-DEM)coupled with a constant heat flux boundary.Two different methods are considered to deal with the multiphase heat flux boundary in CFD-DEM because there is currently no single widely accepted approach.Zhang’s method predicts a more accurate wall-to-bed heat transfer coefficient in SCWFB than Lattanzi’s method according to comparisons of the simulation results with an empirical correlation.The influences of temperature,pressure,velocity,and the solid phase properties,such as the particle diameter,particle heat capacity,particle thermal conductivity,and particle density,on the SCWFB wall-to-bed heat transfer characteristics are studied based on Zhang’s method.The simulation results help reveal the SCWFB heat transfer characteristics.

An exact analytical solution for convective heat transfer in rectangular ducts

An exact analytical solution is obtained for convective heat transfer in straight ducts with rectangular cross-sections for the first time.This solution is valid for both H1 and H2 boundary conditions,which are related to fully developed convective heat transfer under constant heat flux at the duct walls.The separation of variables method and various other mathematical techniques are used to find the closed form of the temperature distribution.The local and mean Nusselt numbers are also obtained as functions of the aspect ratio.A new physical constraint is presented to solve the Neumann problem in non-dimensional analysis for the H2 boundary conditions.This is one of the major innovations of the current study.The analytical results indicate a singularity occurs at a critical aspect ratio of 2.4912 when calculating the local and mean Nusselt numbers.