A study is conducted on the performances of a solar powered continuous-adsorption refrigerator considering two particular days as references cases,namely,the summer solstice(June 21st)and the autumn equinox(September ...A study is conducted on the performances of a solar powered continuous-adsorption refrigerator considering two particular days as references cases,namely,the summer solstice(June 21st)and the autumn equinox(September 21st).The cooling capacity,system performance coefficient and the daily rate of available cooling energy are assessed.The main goal is to compare the performances of a solar adsorption chiller equipped with a hot water tank(HWT)with an equivalent system relying on solar collectors with no heat storage module.The daily cooling rates for the solar refrigerator are found to be 102.4 kWh and 74.3 kWh,respectively,on June 21st and on September 21st,using a total collector’s area of 43.47 m2.The corresponding values for the adsorption chiller equipped with a hot water tank of 2 m3(and using a total collector’s area of 72.45 m2),are 127.1 kWh and 106.13 kWh,respectively.展开更多
BACKGROUND:Blood hemoperfusion with resin adsorption can clean larger molecules that exceed the molecular weight cutoff of combined continuous veno-venous hemofiltration(CWH).Hence blood hemoperfusion with resin adsor...BACKGROUND:Blood hemoperfusion with resin adsorption can clean larger molecules that exceed the molecular weight cutoff of combined continuous veno-venous hemofiltration(CWH).Hence blood hemoperfusion with resin adsorption combined CWH(HP+CWH) has higher ability of mediator clearance,and can improve clinical outcomes in theory.This study aimed to investigate the effect of blood hemoperfusion with resin adsorption combined continuous veno-venous hemofiltration(HP+CWH) on plasm cytokines like TNF-α,IL-1β,IL-6,cellular immunity and prognosis in patients with multiple organ dysfunction syndrome(MODS).METHODS:This was a prospective,randomized clinical trial.A total of 30 patients who had been diagnosed with MODS were enrolled in this study.Patients were randomly allocated to routine treatment+HP+CWH group(treatment group) and routine treatment+only CWH group(control group).In the treatment group,patients received blood hemoperfusion with resin adsorption for 2hours,and then received CWH for 10 hours every day.In the control group,patients received CWH for 12 hours only every day.The patients in the two groups received blood purification therapy for three days.The plasma of patients in the treatment group was obtained at 0,2,12,24,26,36,48,50,60 hours,5th day,7th day and 10 th day,respectively.The plasma of patients in the control group was obtained at 0,12,24,36,48,60 hours,5th day,7th day and 10 th day,respectively.APACHE Ⅱscore,T-lymphocytes subpopulations,blood lactate acid concentration,heart rate,breathing rate,and oxygenation index were observed.RESULTS:Plasma cytokines like TNF-α,IL-1β,IL-6 decreased markedly after HP(P<0.01);T-lymphocytes subpopulations CD3+,CD4+,CD8+,CD4+/CD8+ increased after HP+CWH or only CWH.The plasma concentrations of TNF-α,IL-1β and IL-6 in the two groups were not markedly different at 12,36,and 50 hours.But on the 5th day,the plasma concentrations of TNF-α,IL-1β and IL-6 in the treatment group were lower than those in the control group(P<0.05).On the 28 th day,5patients died in the treatment group,and 6 patients in the control group.CONCLUSIONS:Both HP+CWH and CWH can clean plasma cytokines like TNF-α,IL-1β,and IL-6,and improve cellular immunity and clinical symptoms and signs of patients.Compared with only CWH,the plasma concentrations of TNF-α,IL-1β and IL-6 were lower on the 5th day,and patients have an increased survival rate on the 28 day in the HP+CWH group.展开更多
Objective:To investigate the clinical effects of continuous plasma filtration with adsorption and continuous hematodialysis on improving the immune level of patients with sepsis in ICU. Methods:A total of 80 patients ...Objective:To investigate the clinical effects of continuous plasma filtration with adsorption and continuous hematodialysis on improving the immune level of patients with sepsis in ICU. Methods:A total of 80 patients with sepsis were randomly divided into study group and control group, 40 patients in each group. All the patients were treated by routine treatment. Patients in study group were treated by continuous plasma filtration with adsorption and patients in control group were treated by continuous hematodialysis. The blood samples were collected before and after treatment. The immune cell level, inflammatory factors level, APACHEⅡ score and death rate were compared between two groups.Results:All immune cell indexes were significantly improved in both groups. All immune cell indexes in study group were significantly better than those in control group, after treatment. All inflammatory factors were significantly decreased in both groups. All inflammatory factors in study group were significantly better than those in control group, after treatment. The APACHEⅡ in study group was significantly better than that in control group, after treatment. The death rate in study group was significantly less than that in control group.Conclusion:Continuous plasma filtration with adsorption has a great clinical efficacy on patients with sepsis in ICU, which can improve the immune level and prognosis, makes it worth for clinical application.展开更多
In this work, the use of sepiolite for the removal of carbon dioxide from a carbon dioxide/methane mixture by a pressure swing adsorption (PSA) process has been researched. Adsorption equilibrium and kinetics have b...In this work, the use of sepiolite for the removal of carbon dioxide from a carbon dioxide/methane mixture by a pressure swing adsorption (PSA) process has been researched. Adsorption equilibrium and kinetics have been measured in a fixed-bed, and the adsorption equilibrium parameters of carbon dioxide and methane on sepiolite have been obtained. A model based on the LDF approximation has been employed to simulate the fixed-bed kinetics, using the Langmuir equation to describe the adsorption equilibrium isotherm. The functioning of a PSA cycle for separating carbon dioxide/methane mixtures using sepiolite as adsorbent has also been studied. The experimental results were compared with the ones predicted by the model adapted to a PSA system. Methane with purity higher than 97% can be obtained from feeds containing carbon dioxide with concentrations ranging from 34% to 56% with the proposed PSA cycle. These results suggest that sepiolite is an adsorbent with good properties for its employment in a PSA cycle for carbon dioxide removal from landfill gases.展开更多
Polymer-supported hydrous iron oxides(HFOs) are promising for heavy metals removal from aqueous systems.The ubiquitous inorganic ligands, e.g., sulfate, are expected to exert considerable impacts on pollutants removal...Polymer-supported hydrous iron oxides(HFOs) are promising for heavy metals removal from aqueous systems.The ubiquitous inorganic ligands, e.g., sulfate, are expected to exert considerable impacts on pollutants removal by these hybrid sorbents. Herein, we obtained a hybrid sorbent HFO-PS by encapsulating nanosized HFO into macroporous polystyrene(PS) resin. Both batch and column sorption experiments of Cu(Ⅱ) by HFO-PS were carried out in the presence of sulfate. Obviously, the presence of sulfate is favorable for Cu(Ⅱ) sorption onto HFO-PS.The performances of column Cu(Ⅱ) removal were fitted and predicted with Adams–Bohart, Clark, Thomas and BDST models. Thomas model is suggested best-fit to predict the breakthrough curves. Besides, a linear correlation is observed between breakthrough time and column length based on BDST model, which might be useful for predicting the breakthrough time for Cu(Ⅱ) removal by HFO-PS.展开更多
Electrocoagulation(EC) is among the most effective techniques that remove color and decontaminate effluent.Coagulants are delivered in situ by anode corrosion.In this research,indigo dye removal using iron electrodes ...Electrocoagulation(EC) is among the most effective techniques that remove color and decontaminate effluent.Coagulants are delivered in situ by anode corrosion.In this research,indigo dye removal using iron electrodes in continuous electrocoagulation process and the responsible species for decolorization were investigated.The Response Surface Methodology(RSM) was used to optimize the process parameters.The finding in this study shows that at fixed conductivity at 15,000 μS·cm^(-1) the neutral conditions(pH from 6 to 8),the low absorbance,the low flow rate and the high voltage level enhance the color removal efficiency.The high R~2 value of 97.8% and ANOVA analyses show a good correlation between the experimental and predicted results.Under the optimum conditions,which are pH of 7.5, solution concentration of 60 mg·L^(-1), inlet flow rate of 2 L·min^(-1) and voltage of 47 V, the predicted decolorization of 94.083% was achieved at 93.972% with a total cost of 0.0927 USD·m^(-3) of treated effluent.At the optimum pH(7.5),the zeta potential value(-4 mV) of the effluent during EC match with the one of iron Ⅲ hydroxide.The dye removal is ensured thanks to physical adsorption and flocculation.The results exposed in this work prove that the continuous electrocoagulation process could be successfully used for indigo dye removal at industrial scale.展开更多
The separation of ethylene glycol(EG)and 1,2-butanediol(1,2-BDO)azeotrope in the synthesis process of EG via coal and biomass is becoming of increasing commercial and environmental importance.Selective adsorption is d...The separation of ethylene glycol(EG)and 1,2-butanediol(1,2-BDO)azeotrope in the synthesis process of EG via coal and biomass is becoming of increasing commercial and environmental importance.Selective adsorption is deemed as the most promising methods because of energy saving and environment favorable.In this paper,NaY zeolite was used to separate 1,2-BDO from EG,and its adsorption properties was then investigated.The isotherms of EG and 1,2-BDO in vapor and liquid phases from 298 to 328 K indicated that they fitted Langmuir model quite well,and the NaY zeolite absorbent favored EG more than 1,2-BDO.The Grand Canonical Monte Carlo(GCMC)and molecular dynamics(MD)simulation techniques were conducted to investigate the competition adsorption and diffusion characteristics in different adsorption regions.It was observed that EG and 1,2-BDO molecules all have the most probable locations of the center of the 12-membered ring near the Na cations.The diffusivities of EG are lower than those of 1,2-BDO at the same adsorption concentration.At last,the breakthrough curves of the binary mixture regressed from the empirical Dose–Response model in fixed-bed column showed that the adsorption selectivity of EG could reach to as high as 2.43,verified that the NaY zeolite could effectively separate EG from 1,2-BDO.This work is also helpful for further separation of other dihydric alcohol mixtures from coal and biomass fermentation.展开更多
A new method is proposed for the determination of the parameters in a two-dimensionalmodel which characterizes the properties of axial and radial mixing and mass transport in afixed-bed adsorber.Parameter estimation f...A new method is proposed for the determination of the parameters in a two-dimensionalmodel which characterizes the properties of axial and radial mixing and mass transport in afixed-bed adsorber.Parameter estimation for the model is carried out with methane-air-5A molecularsieve in a bed under the condition of step injection of tracer from a point on the main axis of thebed by the curve fitting method in the time domain.展开更多
Adsorption is one of the widely used processes in the chemical industry environmental application.As compared to mathematical models proposed to describe batch adsorption in terms of isotherm and kinetic behavior,insu...Adsorption is one of the widely used processes in the chemical industry environmental application.As compared to mathematical models proposed to describe batch adsorption in terms of isotherm and kinetic behavior,insufficient models are available to describe and predict fixed-bed or column adsorption,though the latter one is the main option in practical application.The present review first provides a brief summary on basic concepts and mathematic models to describe the mass transfer and isotherm behavior of batch adsorption,which dominate the column adsorption behavior in nature.Afterwards,the widely used models developed to predict the breakthrough curve,i.e.,the general rate models,linear driving force(LDF) model,wave propagation theory model,constant pattern model,Clark model,Thomas model,Bohart-Adams model,Yoon-Nelson model,Wang model,Wolborska model,and modified dose-response model,are briefly introduced from the mechanism and mathematical viewpoint.Their basic characteristics,including the advantages and inherit shortcomings,are also discussed.This review could help those interested in column adsorption to reasonably choose or develop an accurate and convenient model for their study and practical application.展开更多
Continuous processes which allow for large amount of wastewater to be treated to meet drainage standards while reducing treatment time and energy consumption are urgently needed. In this study, a dielectric barrier di...Continuous processes which allow for large amount of wastewater to be treated to meet drainage standards while reducing treatment time and energy consumption are urgently needed. In this study, a dielectric barrier discharge plasma water bed system was designed and then coupled with granular activated carbon (GAC) adsorption to rapidly remove acid fuchsine (AF) with high efficiency. Effects of feeding gases, treatment time and initial concentration of AF on removal efficiency were investigated. Results showed that compared to the N2 and air plasmas treatments, O2 plasma processing was most effective for AF degradation due to the strong oxidation ability of generated activated species, especially the OH radicals. The addition of GAC significantly enhanced the removal efficiency of AF in aqueous solution and shorten the required time by 50%. The effect was attributed to the ability of porous carbon to trap and concentrate the dye, increasing the time dye molecules were exposed to the plasma discharge zone, and to enhance the production of OH radicals on/in GAC to boost the degradation of dyes by plasma as well as in situ regenerate the exhausted GAC. The study offers a new opportunity for continuous effective remediation of wastewater contaminated with organic dyes using plasma technologies.展开更多
The equilibrium and kinetic characteristics of the adsorption of erythromycin to Sepabeads SP825 were determined.The equilibrium data in a batch system was well described by a Langmuir isotherm.The separation performa...The equilibrium and kinetic characteristics of the adsorption of erythromycin to Sepabeads SP825 were determined.The equilibrium data in a batch system was well described by a Langmuir isotherm.The separation performance was investigated in a fixed-bed system with respect to the adsorption superficial velocity,ionic strength and pH.A mathematical model was used to simulate the mass transfer mechanism,taking film mass transfer,pore diffusion and axial dispersion into account.The model predictions were consistent with the experi-mental data and were consequently used to determine the mass transfer coefficients.展开更多
基金supported by Campus France in the frame of the PHC-Maghreb 19Mag29 Project.We would like to thank also our Ministries and research units。
文摘A study is conducted on the performances of a solar powered continuous-adsorption refrigerator considering two particular days as references cases,namely,the summer solstice(June 21st)and the autumn equinox(September 21st).The cooling capacity,system performance coefficient and the daily rate of available cooling energy are assessed.The main goal is to compare the performances of a solar adsorption chiller equipped with a hot water tank(HWT)with an equivalent system relying on solar collectors with no heat storage module.The daily cooling rates for the solar refrigerator are found to be 102.4 kWh and 74.3 kWh,respectively,on June 21st and on September 21st,using a total collector’s area of 43.47 m2.The corresponding values for the adsorption chiller equipped with a hot water tank of 2 m3(and using a total collector’s area of 72.45 m2),are 127.1 kWh and 106.13 kWh,respectively.
文摘BACKGROUND:Blood hemoperfusion with resin adsorption can clean larger molecules that exceed the molecular weight cutoff of combined continuous veno-venous hemofiltration(CWH).Hence blood hemoperfusion with resin adsorption combined CWH(HP+CWH) has higher ability of mediator clearance,and can improve clinical outcomes in theory.This study aimed to investigate the effect of blood hemoperfusion with resin adsorption combined continuous veno-venous hemofiltration(HP+CWH) on plasm cytokines like TNF-α,IL-1β,IL-6,cellular immunity and prognosis in patients with multiple organ dysfunction syndrome(MODS).METHODS:This was a prospective,randomized clinical trial.A total of 30 patients who had been diagnosed with MODS were enrolled in this study.Patients were randomly allocated to routine treatment+HP+CWH group(treatment group) and routine treatment+only CWH group(control group).In the treatment group,patients received blood hemoperfusion with resin adsorption for 2hours,and then received CWH for 10 hours every day.In the control group,patients received CWH for 12 hours only every day.The patients in the two groups received blood purification therapy for three days.The plasma of patients in the treatment group was obtained at 0,2,12,24,26,36,48,50,60 hours,5th day,7th day and 10 th day,respectively.The plasma of patients in the control group was obtained at 0,12,24,36,48,60 hours,5th day,7th day and 10 th day,respectively.APACHE Ⅱscore,T-lymphocytes subpopulations,blood lactate acid concentration,heart rate,breathing rate,and oxygenation index were observed.RESULTS:Plasma cytokines like TNF-α,IL-1β,IL-6 decreased markedly after HP(P<0.01);T-lymphocytes subpopulations CD3+,CD4+,CD8+,CD4+/CD8+ increased after HP+CWH or only CWH.The plasma concentrations of TNF-α,IL-1β and IL-6 in the two groups were not markedly different at 12,36,and 50 hours.But on the 5th day,the plasma concentrations of TNF-α,IL-1β and IL-6 in the treatment group were lower than those in the control group(P<0.05).On the 28 th day,5patients died in the treatment group,and 6 patients in the control group.CONCLUSIONS:Both HP+CWH and CWH can clean plasma cytokines like TNF-α,IL-1β,and IL-6,and improve cellular immunity and clinical symptoms and signs of patients.Compared with only CWH,the plasma concentrations of TNF-α,IL-1β and IL-6 were lower on the 5th day,and patients have an increased survival rate on the 28 day in the HP+CWH group.
文摘Objective:To investigate the clinical effects of continuous plasma filtration with adsorption and continuous hematodialysis on improving the immune level of patients with sepsis in ICU. Methods:A total of 80 patients with sepsis were randomly divided into study group and control group, 40 patients in each group. All the patients were treated by routine treatment. Patients in study group were treated by continuous plasma filtration with adsorption and patients in control group were treated by continuous hematodialysis. The blood samples were collected before and after treatment. The immune cell level, inflammatory factors level, APACHEⅡ score and death rate were compared between two groups.Results:All immune cell indexes were significantly improved in both groups. All immune cell indexes in study group were significantly better than those in control group, after treatment. All inflammatory factors were significantly decreased in both groups. All inflammatory factors in study group were significantly better than those in control group, after treatment. The APACHEⅡ in study group was significantly better than that in control group, after treatment. The death rate in study group was significantly less than that in control group.Conclusion:Continuous plasma filtration with adsorption has a great clinical efficacy on patients with sepsis in ICU, which can improve the immune level and prognosis, makes it worth for clinical application.
文摘In this work, the use of sepiolite for the removal of carbon dioxide from a carbon dioxide/methane mixture by a pressure swing adsorption (PSA) process has been researched. Adsorption equilibrium and kinetics have been measured in a fixed-bed, and the adsorption equilibrium parameters of carbon dioxide and methane on sepiolite have been obtained. A model based on the LDF approximation has been employed to simulate the fixed-bed kinetics, using the Langmuir equation to describe the adsorption equilibrium isotherm. The functioning of a PSA cycle for separating carbon dioxide/methane mixtures using sepiolite as adsorbent has also been studied. The experimental results were compared with the ones predicted by the model adapted to a PSA system. Methane with purity higher than 97% can be obtained from feeds containing carbon dioxide with concentrations ranging from 34% to 56% with the proposed PSA cycle. These results suggest that sepiolite is an adsorbent with good properties for its employment in a PSA cycle for carbon dioxide removal from landfill gases.
基金Supported by the National Natural Science Foundation of China(21607080)the Natural Science Foundation of Jiangsu Province(BK20160946)Jiangsu Higher Education Institution NSF(16KJB610011)
文摘Polymer-supported hydrous iron oxides(HFOs) are promising for heavy metals removal from aqueous systems.The ubiquitous inorganic ligands, e.g., sulfate, are expected to exert considerable impacts on pollutants removal by these hybrid sorbents. Herein, we obtained a hybrid sorbent HFO-PS by encapsulating nanosized HFO into macroporous polystyrene(PS) resin. Both batch and column sorption experiments of Cu(Ⅱ) by HFO-PS were carried out in the presence of sulfate. Obviously, the presence of sulfate is favorable for Cu(Ⅱ) sorption onto HFO-PS.The performances of column Cu(Ⅱ) removal were fitted and predicted with Adams–Bohart, Clark, Thomas and BDST models. Thomas model is suggested best-fit to predict the breakthrough curves. Besides, a linear correlation is observed between breakthrough time and column length based on BDST model, which might be useful for predicting the breakthrough time for Cu(Ⅱ) removal by HFO-PS.
文摘Electrocoagulation(EC) is among the most effective techniques that remove color and decontaminate effluent.Coagulants are delivered in situ by anode corrosion.In this research,indigo dye removal using iron electrodes in continuous electrocoagulation process and the responsible species for decolorization were investigated.The Response Surface Methodology(RSM) was used to optimize the process parameters.The finding in this study shows that at fixed conductivity at 15,000 μS·cm^(-1) the neutral conditions(pH from 6 to 8),the low absorbance,the low flow rate and the high voltage level enhance the color removal efficiency.The high R~2 value of 97.8% and ANOVA analyses show a good correlation between the experimental and predicted results.Under the optimum conditions,which are pH of 7.5, solution concentration of 60 mg·L^(-1), inlet flow rate of 2 L·min^(-1) and voltage of 47 V, the predicted decolorization of 94.083% was achieved at 93.972% with a total cost of 0.0927 USD·m^(-3) of treated effluent.At the optimum pH(7.5),the zeta potential value(-4 mV) of the effluent during EC match with the one of iron Ⅲ hydroxide.The dye removal is ensured thanks to physical adsorption and flocculation.The results exposed in this work prove that the continuous electrocoagulation process could be successfully used for indigo dye removal at industrial scale.
基金the National Natural Science Foundation of China(21576272)“Transformational Technologies for Clean Energy and Demonstration”Strategic Priority Research Program of Chinese Academy of Sciences,Grant No.XDA 21030600,Science and Technology Service Network Initiative,Chinese Academy of Sciences(KFJ-STS-QYZD-138).
文摘The separation of ethylene glycol(EG)and 1,2-butanediol(1,2-BDO)azeotrope in the synthesis process of EG via coal and biomass is becoming of increasing commercial and environmental importance.Selective adsorption is deemed as the most promising methods because of energy saving and environment favorable.In this paper,NaY zeolite was used to separate 1,2-BDO from EG,and its adsorption properties was then investigated.The isotherms of EG and 1,2-BDO in vapor and liquid phases from 298 to 328 K indicated that they fitted Langmuir model quite well,and the NaY zeolite absorbent favored EG more than 1,2-BDO.The Grand Canonical Monte Carlo(GCMC)and molecular dynamics(MD)simulation techniques were conducted to investigate the competition adsorption and diffusion characteristics in different adsorption regions.It was observed that EG and 1,2-BDO molecules all have the most probable locations of the center of the 12-membered ring near the Na cations.The diffusivities of EG are lower than those of 1,2-BDO at the same adsorption concentration.At last,the breakthrough curves of the binary mixture regressed from the empirical Dose–Response model in fixed-bed column showed that the adsorption selectivity of EG could reach to as high as 2.43,verified that the NaY zeolite could effectively separate EG from 1,2-BDO.This work is also helpful for further separation of other dihydric alcohol mixtures from coal and biomass fermentation.
基金Supported by the National Natural Science Foundation of China.
文摘A new method is proposed for the determination of the parameters in a two-dimensionalmodel which characterizes the properties of axial and radial mixing and mass transport in afixed-bed adsorber.Parameter estimation for the model is carried out with methane-air-5A molecularsieve in a bed under the condition of step injection of tracer from a point on the main axis of thebed by the curve fitting method in the time domain.
基金Project supported by the National Natural Science Foundation of China (No. 21177059)the Science Foundation of Ministry of Education of China (No. 20120091130005)+2 种基金the Natural Science Foundation of Jiangsu Province of China (No. BK2012017)the Program for New Century Excellent Talents in University of China (No. NCET10-0490)the Changjiang Scholars Innovative Research Team in University (No. IRT1019),China
文摘Adsorption is one of the widely used processes in the chemical industry environmental application.As compared to mathematical models proposed to describe batch adsorption in terms of isotherm and kinetic behavior,insufficient models are available to describe and predict fixed-bed or column adsorption,though the latter one is the main option in practical application.The present review first provides a brief summary on basic concepts and mathematic models to describe the mass transfer and isotherm behavior of batch adsorption,which dominate the column adsorption behavior in nature.Afterwards,the widely used models developed to predict the breakthrough curve,i.e.,the general rate models,linear driving force(LDF) model,wave propagation theory model,constant pattern model,Clark model,Thomas model,Bohart-Adams model,Yoon-Nelson model,Wang model,Wolborska model,and modified dose-response model,are briefly introduced from the mechanism and mathematical viewpoint.Their basic characteristics,including the advantages and inherit shortcomings,are also discussed.This review could help those interested in column adsorption to reasonably choose or develop an accurate and convenient model for their study and practical application.
基金the National Natural Science Foundation of China (Grant No.51877184)the Central Analytical Research Facility operated by the Institute of Future Environment (QUT).
文摘Continuous processes which allow for large amount of wastewater to be treated to meet drainage standards while reducing treatment time and energy consumption are urgently needed. In this study, a dielectric barrier discharge plasma water bed system was designed and then coupled with granular activated carbon (GAC) adsorption to rapidly remove acid fuchsine (AF) with high efficiency. Effects of feeding gases, treatment time and initial concentration of AF on removal efficiency were investigated. Results showed that compared to the N2 and air plasmas treatments, O2 plasma processing was most effective for AF degradation due to the strong oxidation ability of generated activated species, especially the OH radicals. The addition of GAC significantly enhanced the removal efficiency of AF in aqueous solution and shorten the required time by 50%. The effect was attributed to the ability of porous carbon to trap and concentrate the dye, increasing the time dye molecules were exposed to the plasma discharge zone, and to enhance the production of OH radicals on/in GAC to boost the degradation of dyes by plasma as well as in situ regenerate the exhausted GAC. The study offers a new opportunity for continuous effective remediation of wastewater contaminated with organic dyes using plasma technologies.
文摘The equilibrium and kinetic characteristics of the adsorption of erythromycin to Sepabeads SP825 were determined.The equilibrium data in a batch system was well described by a Langmuir isotherm.The separation performance was investigated in a fixed-bed system with respect to the adsorption superficial velocity,ionic strength and pH.A mathematical model was used to simulate the mass transfer mechanism,taking film mass transfer,pore diffusion and axial dispersion into account.The model predictions were consistent with the experi-mental data and were consequently used to determine the mass transfer coefficients.