All-inorganic cesium lead bromide(CsPbBr3)perovskite is attracting growing interest as functional materials in photovoltaics and other optoelectronic devices due to its superb stability.However,the fabrication of high...All-inorganic cesium lead bromide(CsPbBr3)perovskite is attracting growing interest as functional materials in photovoltaics and other optoelectronic devices due to its superb stability.However,the fabrication of high-quality CsPbBr3 films still remains a big challenge by solution-process because of the low solubility of the cesium precursor in common solvents.Herein,we report a facile solution-processed approach to prepare high-quality CsPbBr3 perovskite films via a two-step spin-coating method,in which the Cs Br methanol/H2 O mixed solvent solution is spin-coated onto the lead bromide films,followed by an isopropanol-assisted post-treatment to regulate the crystallization process and to control the film morphology.In this fashion,dense and uniform CsPbBr3 films are obtained consisting of large crystalline domains with sizes up to microns and low defect density.The effectiveness of the resulting CsPbBr3 films is further examined in perovskite solar cells(PSCs)with a simplified planar architecture of fluorine–doped tin oxide/compact Ti O2/CsPbBr3/carbon,which deliver a maximum power conversion efficiency of 8.11%together with excellent thermal and humidity stability.The present work offers a simple and effective strategy in fabrication of high-quality CsPbBr3 films for efficient and stable PSCs as well as other optoelectronic devices.展开更多
Sn-based perovskite solar cells(PSCs)demonstrate a potential development in eco-friendly devices due to their hypotoxicity.However,poor stability and crystalline quality are still the challenges for achieving high-per...Sn-based perovskite solar cells(PSCs)demonstrate a potential development in eco-friendly devices due to their hypotoxicity.However,poor stability and crystalline quality are still the challenges for achieving high-performance and long-term operating devices.In this work,inspired by biological protein,nickelporphyrin(Ni-P)with electron cloud on conjugate ring is applied into Sn-based perovskite to prevent perovskite from being eroded.The synergistic effect of water and oxygen is broken in grain boundaries and surface so that the stability of PSCs can be improved obviously,despite there is hardly any barrier for water to erode.Simultaneously,the electron-rich molecules can passivate the defects of perovskite such as iodine vacancy.Moreover,the ester group in Ni-P molecule can bind with SnI;to form complex and then restrain nucleation.Combining with the template effect of 2D molecular,the crystallization of perovskite films is optimized.Therefore,the Sn-based PSCs with Ni-P achieve a stabilized power conversion efficiency(PCE)of 7.79%with negligible hysteresis in fexible devices,respectively.Moreover,the PSCs can maintain 80%of the pristine PCE after 300 h under air environment.展开更多
Solar energy is a fast growing energy resource among the renewable energy resources in the market and potential for solar power is huge to contribute towards the power demand almost in all the countries. To capture th...Solar energy is a fast growing energy resource among the renewable energy resources in the market and potential for solar power is huge to contribute towards the power demand almost in all the countries. To capture the maximum power from the sun light in order to generate maximum power from the inverter, control system must be an equally efficient with the well designed power electronic circuits. Maximum power point tracking (MPPT) control system in general is taking care of extraction of maximum power from the sun light whereas current controller is mainly designed to optimize the inverter power to feed to power grid. In this paper, a novel MPPT algorithm using neuro fuzzy system is presented to ensure the maximum MPPT efficiency in order to ensure the maximum power across the inverter terminals. Simulation and experimental results for residential solar system with power electronic converters and analysis have been presented in this paper in order to prove the proposed algorithm.展开更多
In this work, ZnO nanorod arrays grown by an electrochemical deposition method are investigated. The crucial parameters of length, diameter, and density of the nanorods are optimized over the synthesize process and na...In this work, ZnO nanorod arrays grown by an electrochemical deposition method are investigated. The crucial parameters of length, diameter, and density of the nanorods are optimized over the synthesize process and nanorods growth time. Crystalline structure, morphologies, and optical properties of ZnO nanorod arrays are studied by different techniques such as x-ray diffraction, scanning electron microscope, atomic force microscope, and UV-visible transmission spectra. The ZnO nanorod arrays are employed in an inverted bulk heterojunction organic solar cell of Poly (3-hexylthiophene):[6- 6] Phenyl-(6) butyric acid methyl ester to introduce more surface contact between the electron transporter layer and the active layer. Our results show that the deposition time is a very important factor to achieve the aligned and uniform ZnO nanorods with suitable surface density which is required for effective infiltration of active area into the ZnO nanorod spacing and make a maximum interfacial surface contact for electron collection, as overgrowing causes nanorods to be too dense and thick and results in high resistance and lower visible light transmittance. By optimizing the thickness of the active layer on top of ZnO nanorods, an improved efficiency of 3.17% with a high FF beyond 60% was achieved.展开更多
With advances in material science and a more in-depth understanding of device engineering,the power conversion efficiency(PCE)of solution-processed organic photovoltaic(OPV)cells have significantly boosted in the past...With advances in material science and a more in-depth understanding of device engineering,the power conversion efficiency(PCE)of solution-processed organic photovoltaic(OPV)cells have significantly boosted in the past few years.In 2019,a high PCE of 15.7%was achieved in the OPV cells adopting a wide bandgap polymer PM6 and a new emerging non-fullerene acceptor Y6.Such outstanding performance has attracted lots of research attention,driving considerable efforts to improve or take advantage of the high-performance PM6:Y6-based system.In this review,we first concentrate on the structural characteristics of PM6 and Y6 with the focus on understanding why their combination for OPV application can obtain such high efficiency.We also update the recent progress in highly efficient PM6:Y6-based OPV cells via various optimizing strategies.Then we summarize the other applications of the PM6:Y6-based system in semi-transparent,flexible or lay e-by-layer devices.The prospects for future OPV studies will be suggested in the end.展开更多
In this paper, modeling and decentralize control principles of a MicroGrid (MG) whom equipped with three Distributed Generation (DG) systems (consist of: Solar Cell System (SCS), MicroTurbine System (MTS) and Wind Ene...In this paper, modeling and decentralize control principles of a MicroGrid (MG) whom equipped with three Distributed Generation (DG) systems (consist of: Solar Cell System (SCS), MicroTurbine System (MTS) and Wind Energy Conversion System (WECS)) is simulated. Three arrangement of load changing have investigated for the system. In first one the system doesn’t have transfer of power between MG and grid. In other two arrangements system have transfer of power between MG and utility grid. Of course in third case transfer of power between DG resources is considerable. Case study system is equipped by energy storage devices (battery bank) for each DG’s separately by means of increasing the MG reliability. For WECS and SCS, MPPT control and for MTS, voltage and frequency (V&F) controller has designed. The purpose of this paper is load respond in MG and storage process of surplus energy by consider of load changing. MATLAB/Simulink and its libraries (mainly the Sim Power Systems toolbox) were employed in order to develop a simulation platform suitable for identifying MG control requirements. This paper reported a control and op- eration of MG in network tension by applying a three phase fault.展开更多
In recent years,the power conversion efficiency of organic solar cells(OSCs)and perovskite(PVSCs)has increased to over 19%and25%,respectively.Meanwhile,the long-term stability of OSCs and PVSCs was also significantly ...In recent years,the power conversion efficiency of organic solar cells(OSCs)and perovskite(PVSCs)has increased to over 19%and25%,respectively.Meanwhile,the long-term stability of OSCs and PVSCs was also significantly improved with a better understanding of the degradation mechanism and the improvement of materials,morphology,and interface stability.As both the efficiency and lifetime of solar cells are approaching the commercialization limit,fabrication methods for large-area OSCs and PVSCs that can be directly transferred from lab to fab become essential to promote the industrialization of OSCs and PVSCs.Compared with the coating methods,inkjet printing is a mature industrial technology with the advantages of random digital patterning,excellent precision and fast printing speed,which is considered to have great potential in solar cell fabrication.Many efforts have been devoted to developing inkjet-printed OSCs and PVSCs,and much progress has been achieved in the last few years.In this review,we first introduced the working principle of inkjet printing,the rheology requirements of inks,and the behaviors of the droplets.We then summarized the recent research progresses of the inkjet-printed OSCs and PVSCs to facilitate knowledge transfer between the two technologies.In the end,we gave a perspective on inkjet-printed OSCs and PVSCs.展开更多
Polythiophenes(PTs)are prospective polymer donors for large-scale manufacturing and industrialization owing to their simple structures and low synthetic cost.However,the fabrication of PT solar cells depends on highly...Polythiophenes(PTs)are prospective polymer donors for large-scale manufacturing and industrialization owing to their simple structures and low synthetic cost.However,the fabrication of PT solar cells depends on highly toxic chlorinated solvents,and less research has been done on the use of more environmentally friendly non-halogenated solvents.Herein,highly efficient PT solar cells based on top-performance polythiophene,P5TCN-F25,processed from a non-halogenated solvent are reported by delicate aggregation control.A power conversion efficiency of up to 15.68%was achieved by depositing the active layer from a hot o-xylene solution,which is the record efficiency of non-halogenated processed PT solar cells up to date.The appropriate solution temperature is beneficial to the formation of ordered polymer stacking and desirable phase separation size,which thereby contributes to enhanced charge transfer efficiency,more balanced hole/electron mobility,and reduced trap-assisted recombination.These results provide valuable implications for improving the efficiency of PT solar cells via environmentallyfriendly processing.展开更多
The slot-die coating is recognized as the most compatible method for the roll-to-roll(R2R)processing of large-area flexible organic solar cells(OSCs).However,the photovoltaic performance of the large-area flexible all...The slot-die coating is recognized as the most compatible method for the roll-to-roll(R2R)processing of large-area flexible organic solar cells(OSCs).However,the photovoltaic performance of the large-area flexible all-polymer solar cells was significantly lagging behind that of polymer donors with small molecule non-fullerene acceptors devices.In this work,the 1 cm^(2) flexible device of an all-polymer system,PTQ10:PYF-T-o,fabricated by slot-die coating,achieves an excellent efficiency of 11.24%via controlling the coating temperatures.It is found that,compared with the donor,the crystallinity of PYF-T-o plays a crucial role in device performance.The all-polymer flexible devices show superior mechanical bending stability,maintaining an efficiency of over 95%of the initial value during a 1000-cycle bending test.展开更多
The strong aggregation tendency of hole transport material poly[3-(4-carboxylbutyl)thiophene-K(P3CT-K)restricts its further application in inverted perovskite solar cells(PSCs).Here,we report an effective strategy to ...The strong aggregation tendency of hole transport material poly[3-(4-carboxylbutyl)thiophene-K(P3CT-K)restricts its further application in inverted perovskite solar cells(PSCs).Here,we report an effective strategy to address this issue and achieve the superior performance of inverted methylammonium lead triiodide(MAPbI3)PSCs,in which graphdiyne oxide(GDYO)doped P3CT-K nanocomposites are applied as the hole transport nanolayer(HTL).It is revealed that the strongπ–πstacking interaction occurs between GDYO and P3CT-K,which is proved by the blue shift of the absorption peak of P3CT-K nanolayer.The aggregation control via GDYO contributes to the property improvement of P3CT-K HTL.Moreover,the homogeneous coverage induces the growth of perovskite grain with larger size than that based on the undoped one.As a result,the optimized surface morphology,enhanced conductivity,charge extraction as well as better crystal quality,finally improve the device performance.An optimal power conversion efficiency of 19.06%is achieved,with simultaneously improved fill factor and short circuit current density.This work presents the potential of functional graphdiyne(GDY)in the development of highly efficient photovoltaic device.展开更多
Screen printing technique has been widely applied for the manufacturing of both traditional silicon solar cells and emerging photovoltaics such as dyesensitized solar cells(DSSCs)and perovskite solar cells(PSCs).Parti...Screen printing technique has been widely applied for the manufacturing of both traditional silicon solar cells and emerging photovoltaics such as dyesensitized solar cells(DSSCs)and perovskite solar cells(PSCs).Particularly,we have developed a printable mesoscopic PSC based on a triple layer scaffold of TiO2/ZrO2/carbon.The deposition of the scaftold is entirely based on screen printing process,which provides a promising prospect for low-cost photovoltaics.However,the optimal thickness of the TiO2 layer for fabricating efficient printable PSCs is much smaller than the typical thickness of screen printed films.Here,we tune the concentration of the pastes and the printing parameters for coating TiO?films,and successfully print TiO2 films with the thickness of 500-550 nm.The correlation between the thickness of the films and printing parameters such as the solid content and viscosity of the pastes,the printing speed and pressure,and the temperature has been investigated.Besides,the edge effect that the edge of the TiO2 films possesses a much larger thickness and printing positional accuracy have been studied.This work will significantly benefit the further development of printable mesoscopic PSCs.展开更多
基金financial support by the National Natural Science Foundation of China(21975038,21606039,and 51661135021)the Swiss National Science Foundation(IZLCZ2_170177)+3 种基金the Fundamental Research Funds for the Central Universities(DUT17JC39)the Swedish Foundation for Strategic Research(SSF)the Swedish Energy Agencythe Knut and Alice Wallenberg Foundation。
文摘All-inorganic cesium lead bromide(CsPbBr3)perovskite is attracting growing interest as functional materials in photovoltaics and other optoelectronic devices due to its superb stability.However,the fabrication of high-quality CsPbBr3 films still remains a big challenge by solution-process because of the low solubility of the cesium precursor in common solvents.Herein,we report a facile solution-processed approach to prepare high-quality CsPbBr3 perovskite films via a two-step spin-coating method,in which the Cs Br methanol/H2 O mixed solvent solution is spin-coated onto the lead bromide films,followed by an isopropanol-assisted post-treatment to regulate the crystallization process and to control the film morphology.In this fashion,dense and uniform CsPbBr3 films are obtained consisting of large crystalline domains with sizes up to microns and low defect density.The effectiveness of the resulting CsPbBr3 films is further examined in perovskite solar cells(PSCs)with a simplified planar architecture of fluorine–doped tin oxide/compact Ti O2/CsPbBr3/carbon,which deliver a maximum power conversion efficiency of 8.11%together with excellent thermal and humidity stability.The present work offers a simple and effective strategy in fabrication of high-quality CsPbBr3 films for efficient and stable PSCs as well as other optoelectronic devices.
基金support from the National Natural Science Foundation of China(NSFC)(22005131,52173169 and 11564025)。
文摘Sn-based perovskite solar cells(PSCs)demonstrate a potential development in eco-friendly devices due to their hypotoxicity.However,poor stability and crystalline quality are still the challenges for achieving high-performance and long-term operating devices.In this work,inspired by biological protein,nickelporphyrin(Ni-P)with electron cloud on conjugate ring is applied into Sn-based perovskite to prevent perovskite from being eroded.The synergistic effect of water and oxygen is broken in grain boundaries and surface so that the stability of PSCs can be improved obviously,despite there is hardly any barrier for water to erode.Simultaneously,the electron-rich molecules can passivate the defects of perovskite such as iodine vacancy.Moreover,the ester group in Ni-P molecule can bind with SnI;to form complex and then restrain nucleation.Combining with the template effect of 2D molecular,the crystallization of perovskite films is optimized.Therefore,the Sn-based PSCs with Ni-P achieve a stabilized power conversion efficiency(PCE)of 7.79%with negligible hysteresis in fexible devices,respectively.Moreover,the PSCs can maintain 80%of the pristine PCE after 300 h under air environment.
文摘Solar energy is a fast growing energy resource among the renewable energy resources in the market and potential for solar power is huge to contribute towards the power demand almost in all the countries. To capture the maximum power from the sun light in order to generate maximum power from the inverter, control system must be an equally efficient with the well designed power electronic circuits. Maximum power point tracking (MPPT) control system in general is taking care of extraction of maximum power from the sun light whereas current controller is mainly designed to optimize the inverter power to feed to power grid. In this paper, a novel MPPT algorithm using neuro fuzzy system is presented to ensure the maximum MPPT efficiency in order to ensure the maximum power across the inverter terminals. Simulation and experimental results for residential solar system with power electronic converters and analysis have been presented in this paper in order to prove the proposed algorithm.
文摘In this work, ZnO nanorod arrays grown by an electrochemical deposition method are investigated. The crucial parameters of length, diameter, and density of the nanorods are optimized over the synthesize process and nanorods growth time. Crystalline structure, morphologies, and optical properties of ZnO nanorod arrays are studied by different techniques such as x-ray diffraction, scanning electron microscope, atomic force microscope, and UV-visible transmission spectra. The ZnO nanorod arrays are employed in an inverted bulk heterojunction organic solar cell of Poly (3-hexylthiophene):[6- 6] Phenyl-(6) butyric acid methyl ester to introduce more surface contact between the electron transporter layer and the active layer. Our results show that the deposition time is a very important factor to achieve the aligned and uniform ZnO nanorods with suitable surface density which is required for effective infiltration of active area into the ZnO nanorod spacing and make a maximum interfacial surface contact for electron collection, as overgrowing causes nanorods to be too dense and thick and results in high resistance and lower visible light transmittance. By optimizing the thickness of the active layer on top of ZnO nanorods, an improved efficiency of 3.17% with a high FF beyond 60% was achieved.
基金supported by the National Natural Science Foundation of China(22005024,51873007,51961165102 and 21835006)。
文摘With advances in material science and a more in-depth understanding of device engineering,the power conversion efficiency(PCE)of solution-processed organic photovoltaic(OPV)cells have significantly boosted in the past few years.In 2019,a high PCE of 15.7%was achieved in the OPV cells adopting a wide bandgap polymer PM6 and a new emerging non-fullerene acceptor Y6.Such outstanding performance has attracted lots of research attention,driving considerable efforts to improve or take advantage of the high-performance PM6:Y6-based system.In this review,we first concentrate on the structural characteristics of PM6 and Y6 with the focus on understanding why their combination for OPV application can obtain such high efficiency.We also update the recent progress in highly efficient PM6:Y6-based OPV cells via various optimizing strategies.Then we summarize the other applications of the PM6:Y6-based system in semi-transparent,flexible or lay e-by-layer devices.The prospects for future OPV studies will be suggested in the end.
文摘In this paper, modeling and decentralize control principles of a MicroGrid (MG) whom equipped with three Distributed Generation (DG) systems (consist of: Solar Cell System (SCS), MicroTurbine System (MTS) and Wind Energy Conversion System (WECS)) is simulated. Three arrangement of load changing have investigated for the system. In first one the system doesn’t have transfer of power between MG and grid. In other two arrangements system have transfer of power between MG and utility grid. Of course in third case transfer of power between DG resources is considerable. Case study system is equipped by energy storage devices (battery bank) for each DG’s separately by means of increasing the MG reliability. For WECS and SCS, MPPT control and for MTS, voltage and frequency (V&F) controller has designed. The purpose of this paper is load respond in MG and storage process of surplus energy by consider of load changing. MATLAB/Simulink and its libraries (mainly the Sim Power Systems toolbox) were employed in order to develop a simulation platform suitable for identifying MG control requirements. This paper reported a control and op- eration of MG in network tension by applying a three phase fault.
基金financially supported by the Youth Innovation Promotion Association,CAS(No.2019317)CAS-CSIRO joint project(No.121E32KYSB20190021)of the Chinese Academy of Sciences。
文摘In recent years,the power conversion efficiency of organic solar cells(OSCs)and perovskite(PVSCs)has increased to over 19%and25%,respectively.Meanwhile,the long-term stability of OSCs and PVSCs was also significantly improved with a better understanding of the degradation mechanism and the improvement of materials,morphology,and interface stability.As both the efficiency and lifetime of solar cells are approaching the commercialization limit,fabrication methods for large-area OSCs and PVSCs that can be directly transferred from lab to fab become essential to promote the industrialization of OSCs and PVSCs.Compared with the coating methods,inkjet printing is a mature industrial technology with the advantages of random digital patterning,excellent precision and fast printing speed,which is considered to have great potential in solar cell fabrication.Many efforts have been devoted to developing inkjet-printed OSCs and PVSCs,and much progress has been achieved in the last few years.In this review,we first introduced the working principle of inkjet printing,the rheology requirements of inks,and the behaviors of the droplets.We then summarized the recent research progresses of the inkjet-printed OSCs and PVSCs to facilitate knowledge transfer between the two technologies.In the end,we gave a perspective on inkjet-printed OSCs and PVSCs.
基金supported by the Guangdong Basic and Applied Basic Research Foundation(2022B1515120008)the Guangdong Innovative and Entrepreneurial Research Team Program(2019ZT08L075)+1 种基金the National Natural Science Foundation of China(22275058,U20A6002)supported by the National Research Foundation of the Republic of Korea(NRF)grant funded by the Republic of Korea Government(MSIP)(2021R1A2C3004202)。
文摘Polythiophenes(PTs)are prospective polymer donors for large-scale manufacturing and industrialization owing to their simple structures and low synthetic cost.However,the fabrication of PT solar cells depends on highly toxic chlorinated solvents,and less research has been done on the use of more environmentally friendly non-halogenated solvents.Herein,highly efficient PT solar cells based on top-performance polythiophene,P5TCN-F25,processed from a non-halogenated solvent are reported by delicate aggregation control.A power conversion efficiency of up to 15.68%was achieved by depositing the active layer from a hot o-xylene solution,which is the record efficiency of non-halogenated processed PT solar cells up to date.The appropriate solution temperature is beneficial to the formation of ordered polymer stacking and desirable phase separation size,which thereby contributes to enhanced charge transfer efficiency,more balanced hole/electron mobility,and reduced trap-assisted recombination.These results provide valuable implications for improving the efficiency of PT solar cells via environmentallyfriendly processing.
基金supported by the National Natural Science Foundation of China(NSFC)(Nos.52073068,22135001,and 21721002)the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB36000000).
文摘The slot-die coating is recognized as the most compatible method for the roll-to-roll(R2R)processing of large-area flexible organic solar cells(OSCs).However,the photovoltaic performance of the large-area flexible all-polymer solar cells was significantly lagging behind that of polymer donors with small molecule non-fullerene acceptors devices.In this work,the 1 cm^(2) flexible device of an all-polymer system,PTQ10:PYF-T-o,fabricated by slot-die coating,achieves an excellent efficiency of 11.24%via controlling the coating temperatures.It is found that,compared with the donor,the crystallinity of PYF-T-o plays a crucial role in device performance.The all-polymer flexible devices show superior mechanical bending stability,maintaining an efficiency of over 95%of the initial value during a 1000-cycle bending test.
基金supported by the National Natural Science Foundation of China(No.21975273)Scientific Research Starting Foundation of Outstanding Young Scholar of Shandong University,and the Fundamental Research Funds of Shandong University+2 种基金We thank Guangdong Basic and Applied Basic Research Foundation(No.2019A1515012156)2020 Li Ka Shing Foundation Cross Disciplinary Research Grant(No.2020LKSFG01A)Department of Education of Guangdong Province(Nos.2021LSYS009 and 2021KCXTD032).
文摘The strong aggregation tendency of hole transport material poly[3-(4-carboxylbutyl)thiophene-K(P3CT-K)restricts its further application in inverted perovskite solar cells(PSCs).Here,we report an effective strategy to address this issue and achieve the superior performance of inverted methylammonium lead triiodide(MAPbI3)PSCs,in which graphdiyne oxide(GDYO)doped P3CT-K nanocomposites are applied as the hole transport nanolayer(HTL).It is revealed that the strongπ–πstacking interaction occurs between GDYO and P3CT-K,which is proved by the blue shift of the absorption peak of P3CT-K nanolayer.The aggregation control via GDYO contributes to the property improvement of P3CT-K HTL.Moreover,the homogeneous coverage induces the growth of perovskite grain with larger size than that based on the undoped one.As a result,the optimized surface morphology,enhanced conductivity,charge extraction as well as better crystal quality,finally improve the device performance.An optimal power conversion efficiency of 19.06%is achieved,with simultaneously improved fill factor and short circuit current density.This work presents the potential of functional graphdiyne(GDY)in the development of highly efficient photovoltaic device.
基金The authors acknowledge financial support from the National Natural Science Foundation of China(Grant Nos.21702069,91433203 and 61474049)the Ministry of Science and Technology of China(863)(No.2015AA034601)+3 种基金the Fundamental Research Funds for the Central Universities,the Science and Technology Department ofHubei Province(No.2017AAA190)the 111 Project(No.B07038)the China Postdoctoral Science Foundation(No.2017M612452)and the Double first-class research funding of China-EU Institute for Clean and Renewable Energy(Nos.ICARE-RP-2018-SOLAR-001 and ICARE-RP-2018-SOLAR-002).
文摘Screen printing technique has been widely applied for the manufacturing of both traditional silicon solar cells and emerging photovoltaics such as dyesensitized solar cells(DSSCs)and perovskite solar cells(PSCs).Particularly,we have developed a printable mesoscopic PSC based on a triple layer scaffold of TiO2/ZrO2/carbon.The deposition of the scaftold is entirely based on screen printing process,which provides a promising prospect for low-cost photovoltaics.However,the optimal thickness of the TiO2 layer for fabricating efficient printable PSCs is much smaller than the typical thickness of screen printed films.Here,we tune the concentration of the pastes and the printing parameters for coating TiO?films,and successfully print TiO2 films with the thickness of 500-550 nm.The correlation between the thickness of the films and printing parameters such as the solid content and viscosity of the pastes,the printing speed and pressure,and the temperature has been investigated.Besides,the edge effect that the edge of the TiO2 films possesses a much larger thickness and printing positional accuracy have been studied.This work will significantly benefit the further development of printable mesoscopic PSCs.