The conversing relation among the Bond Work Index Wp specific output of mill and the energy efficiency of grinding were developed using dimensional analysis.The relations of which were proved and the value of the cove...The conversing relation among the Bond Work Index Wp specific output of mill and the energy efficiency of grinding were developed using dimensional analysis.The relations of which were proved and the value of the coversion coefficient i was also obtained using a new installed device for measuring grindability of ores.With the new simulating algorithm,the mill specifications,output and size distribution of griding products of industrial mills can be calculated based on laboratory measuring results.This algorithm is more accurate and simpler than any of the others.展开更多
Alloys of Se80-xTe20Inx glassy system are obtained by quenching technique and crystallization kinetics has been studied using Differential Scanning Calorimetric [DSC] technique. Well defined endothermic and exothermic...Alloys of Se80-xTe20Inx glassy system are obtained by quenching technique and crystallization kinetics has been studied using Differential Scanning Calorimetric [DSC] technique. Well defined endothermic and exothermic peaks are ob- served at glass transition temperature (Tg) and crystallization temperature (Tc). From DSC scans, Tc is obtained at dif- ferent heating rates (5, 10, 15, 20, 25 K/min). It is observed that Tc increases with increasing heating rate for a particular glassy alloy. Activation energy of crystallization (Ec) has been calculated by different Non-isothermal Iso-conversional methods, i.e., Kissinger-Akahira-Sunose [KAS], Friedman, Flynn-wall-Ozawa [FWO], Friedman-Ozawa [FO] and Sta-rink methods. It is observed that Ec is dependent on extent of crystallization (α). Activation energy is also found to vary with atomic percentage of In in ternary Se80-xTe20Inx glassy system. The compositional dependence of Ec shows a re-versal in the trend at x = 15 in Se80-xTe20Inx, which is explained in terms of mechanically stabilized structure at this composition.展开更多
为获得可靠的煤焦-CO_2气化反应动力学参数,采用Flunm-Wall-Ozawa(FWO)等转化率法进行煤焦-CO_2气化动力学研究。在3个不同升温速率下进行了煤焦-CO_2气化热重试验,计算不同碳转化率下的反应活化能,用主曲线法分析了气化机理模型,并采...为获得可靠的煤焦-CO_2气化反应动力学参数,采用Flunm-Wall-Ozawa(FWO)等转化率法进行煤焦-CO_2气化动力学研究。在3个不同升温速率下进行了煤焦-CO_2气化热重试验,计算不同碳转化率下的反应活化能,用主曲线法分析了气化机理模型,并采用拟合法对等转化率法的结果进行验证。结果表明,气化主反应区不同碳转化率下(α为0.2~0.8)活化能的变化较小,为(228.25±5.22)k J/mol。煤焦-CO_2气化反应为均相模型,该模型标准曲线与试验曲线重合度较好,并符合目前常用的煤气化动力学模型。拟合法计算的活化能仅与等转化率法相差0.74 k J/mol,说明等转化率法研究煤焦-CO_2动力学可行。展开更多
利用热重法对裂殖壶藻的热解特性进行分析,升温速率分别为5、10、20、30、40、50℃/min。结果表明：微藻主要失重温度是158-519℃;随着升温速率的增大,主要热解区间的初始温度和最大峰值温度都向高温方向移动,热滞后现象加重。利用等转...利用热重法对裂殖壶藻的热解特性进行分析,升温速率分别为5、10、20、30、40、50℃/min。结果表明：微藻主要失重温度是158-519℃;随着升温速率的增大,主要热解区间的初始温度和最大峰值温度都向高温方向移动,热滞后现象加重。利用等转化率法中的FWO法和Kissinger法求得平均活化能为46.8915 k J/mol。采用主曲线法来确定热解过程的最可几机理函数,热解过程不能由单一的动力学方程描述,这是由于不同升温速率下,热解反应的主要控制因素不同。展开更多
基金supported by the Doctoral Foundation of the National Education Committee
文摘The conversing relation among the Bond Work Index Wp specific output of mill and the energy efficiency of grinding were developed using dimensional analysis.The relations of which were proved and the value of the coversion coefficient i was also obtained using a new installed device for measuring grindability of ores.With the new simulating algorithm,the mill specifications,output and size distribution of griding products of industrial mills can be calculated based on laboratory measuring results.This algorithm is more accurate and simpler than any of the others.
文摘Alloys of Se80-xTe20Inx glassy system are obtained by quenching technique and crystallization kinetics has been studied using Differential Scanning Calorimetric [DSC] technique. Well defined endothermic and exothermic peaks are ob- served at glass transition temperature (Tg) and crystallization temperature (Tc). From DSC scans, Tc is obtained at dif- ferent heating rates (5, 10, 15, 20, 25 K/min). It is observed that Tc increases with increasing heating rate for a particular glassy alloy. Activation energy of crystallization (Ec) has been calculated by different Non-isothermal Iso-conversional methods, i.e., Kissinger-Akahira-Sunose [KAS], Friedman, Flynn-wall-Ozawa [FWO], Friedman-Ozawa [FO] and Sta-rink methods. It is observed that Ec is dependent on extent of crystallization (α). Activation energy is also found to vary with atomic percentage of In in ternary Se80-xTe20Inx glassy system. The compositional dependence of Ec shows a re-versal in the trend at x = 15 in Se80-xTe20Inx, which is explained in terms of mechanically stabilized structure at this composition.
文摘为获得可靠的煤焦-CO_2气化反应动力学参数,采用Flunm-Wall-Ozawa(FWO)等转化率法进行煤焦-CO_2气化动力学研究。在3个不同升温速率下进行了煤焦-CO_2气化热重试验,计算不同碳转化率下的反应活化能,用主曲线法分析了气化机理模型,并采用拟合法对等转化率法的结果进行验证。结果表明,气化主反应区不同碳转化率下(α为0.2~0.8)活化能的变化较小,为(228.25±5.22)k J/mol。煤焦-CO_2气化反应为均相模型,该模型标准曲线与试验曲线重合度较好,并符合目前常用的煤气化动力学模型。拟合法计算的活化能仅与等转化率法相差0.74 k J/mol,说明等转化率法研究煤焦-CO_2动力学可行。
文摘利用热重法对裂殖壶藻的热解特性进行分析,升温速率分别为5、10、20、30、40、50℃/min。结果表明：微藻主要失重温度是158-519℃;随着升温速率的增大,主要热解区间的初始温度和最大峰值温度都向高温方向移动,热滞后现象加重。利用等转化率法中的FWO法和Kissinger法求得平均活化能为46.8915 k J/mol。采用主曲线法来确定热解过程的最可几机理函数,热解过程不能由单一的动力学方程描述,这是由于不同升温速率下,热解反应的主要控制因素不同。
