IEA-R1 nuclear reactor operation has the routine to control uranium content in pool water to be in trace range below 50 μg/L. There are several routes to determine the uranium trace content in water in the lite...IEA-R1 nuclear reactor operation has the routine to control uranium content in pool water to be in trace range below 50 μg/L. There are several routes to determine the uranium trace content in water in the literature;voltammetry has been systematically employed. In the present study, the chosen chemical determination of uranium traces used the voltammetric method known as AdCSV (adsorptive cathodic stripping voltammetry). This technique, based on mercury voltammetry, is an adequate methodology to determine uranium traces. The chloranilic acid [CAA] (2,5-dichloro-3,6-dihydroxy-1,4-benzo-quinone) is indicated as chelating agent. The redox reaction of UO2+2?with CAA is sensitive in the range of 2 2(CAA)2] reduction potential. In this work, we present the uranium trace results for IEA-R1 reactor water, sampled after an operation routine shutdown. The uranium trace determination for IEA-R1 pool water showed content around 1 μg/L [U] with statistical significance. Therefore the IEA-R1-reactor-water purification showed to be adequate and safe.展开更多
The purpose of the study is to analyze the breeding ratio of a supercritical water cooled fast reactor (SCFR) and to increase the breeding core of SCFR. The sensitivities of assembly parameters, core arrangements and ...The purpose of the study is to analyze the breeding ratio of a supercritical water cooled fast reactor (SCFR) and to increase the breeding core of SCFR. The sensitivities of assembly parameters, core arrangements and fuel nuclide components to the breeding ratio are analyzed. In assembly parameters, the seed fuel rod diameter has higher sensitivities to the conversion ratio (CR) than the coolant tube diameter in blanket. Increasing heavy metal fraction is good to CR improvement. The CR of SCFR also increases with a reasonable core arrangement and Pu isotope mass fraction reduction in fuel, which can achieve more negative coolant void reactivity coefficient at the same time. The breeding ratio of SCFR is 1.03128 with a new core arrangement. And the coolant void reactivity coefficient is negative, which achieves a fuel breeding in initial fuel cycle.展开更多
文摘IEA-R1 nuclear reactor operation has the routine to control uranium content in pool water to be in trace range below 50 μg/L. There are several routes to determine the uranium trace content in water in the literature;voltammetry has been systematically employed. In the present study, the chosen chemical determination of uranium traces used the voltammetric method known as AdCSV (adsorptive cathodic stripping voltammetry). This technique, based on mercury voltammetry, is an adequate methodology to determine uranium traces. The chloranilic acid [CAA] (2,5-dichloro-3,6-dihydroxy-1,4-benzo-quinone) is indicated as chelating agent. The redox reaction of UO2+2?with CAA is sensitive in the range of 2 2(CAA)2] reduction potential. In this work, we present the uranium trace results for IEA-R1 reactor water, sampled after an operation routine shutdown. The uranium trace determination for IEA-R1 pool water showed content around 1 μg/L [U] with statistical significance. Therefore the IEA-R1-reactor-water purification showed to be adequate and safe.
文摘The purpose of the study is to analyze the breeding ratio of a supercritical water cooled fast reactor (SCFR) and to increase the breeding core of SCFR. The sensitivities of assembly parameters, core arrangements and fuel nuclide components to the breeding ratio are analyzed. In assembly parameters, the seed fuel rod diameter has higher sensitivities to the conversion ratio (CR) than the coolant tube diameter in blanket. Increasing heavy metal fraction is good to CR improvement. The CR of SCFR also increases with a reasonable core arrangement and Pu isotope mass fraction reduction in fuel, which can achieve more negative coolant void reactivity coefficient at the same time. The breeding ratio of SCFR is 1.03128 with a new core arrangement. And the coolant void reactivity coefficient is negative, which achieves a fuel breeding in initial fuel cycle.
