Synthesis,Crystal Structure and Photoluminescent Property of a Novel Dy^(3+) Coordination Compound Containing Rare(H_2O)_(22) Clusters

A novel Dy^（3＋） coordination compound,（H_2pipz）（H_3O）[Dy（pydc）_3]·11H_2O（1,pipz = piperazine and H_2pydc = pyridine-2,6-dicarboxylic acid）,has been hydrothermally synthesized and characterized by X-ray single-crystal diffraction,elemental analysis. It is interesting that the packing structure of compound 1 contains 22-core water clusters. Compound 1 is extended into a threedimensional supramolecular structure via O···H···O hydrogen bonding interactions. Furthermore,the luminescent property of compound 1 was also investigated.

Synthesis,Crystal Structure and Characterization of a New Coordination Polymer Based on Trinuclear Mn(Ⅱ) Cluster:[Mn_3(L)_2(adip)_3]·2H_2O

The coordination polymer,[Mn3（L） 2（adip） 3]·2H2O（L = 2-（4-fluorophenyl） -1H-imidazo[4,5-f] [1,10]phenanthroline and H2adip = adipic acid） ,has been synthesized under hydro-thermal conditions and characterized by elemental analysis,IR and single-crystal X-ray diffraction. It crystallizes in triclinic,space group P1^- with a = 8.4085（11） ,b = 11.1273（14） ,c = 14.5758（18） ,α = 78.528（2） ,β = 75.425（2） ,γ = 78.143（2） °,V = 1276.0（3） A^3,Z = 1,C56H50F2Mn3N8O14,Mr = 1261.86,Dc = 1.642 g/cm^3,F（000） = 647,μ（MoKa） = 0.819 mm^-1,R = 0.0446 and wR = 0.1008. The backbones of the two types of adip dianions link the neighboring trinuclear Mn（Ⅱ） clusters to yield a two-dimensional layer structure. The large conjugated L ligands are located on both sides of the two-dimensional layers. Additionally,the O-H···O,O-H···N and N-H···O hydrogen bonds further stabilize the structure.

Assembly of a highly stable luminescent Zn5 cluster and application to bio-imaging

OBJECTIVE To explore a novel pH-sensitive fluorescent probe for in vivo tumor imaging.METHODS Zn5 were obtained in 140℃ after mixed with Me OH,water,Zn(NO_3)2·6 H_2O,H4L and trimethylamine.The fluorescence spectra of Zn5 with the same concentration in different pH aqueous solutions were detected.And the stability of Zn5 was investigated by time dependent fluorescence emission spectra of Zn5 in BSA aqueous solution and 5.0% serum solution.Then,the cytotoxicity of Zn5 was detected by MTT assays.To clarify whether a similar fluorescence response occurs in biological organisms,He La cells were pretreated with probe Zn5(0.5 μmol·L^(-1)) and fluorescence imaging were collected for targeting lysosomes in living cells because of lysosomes′ acidic microenvironment.The A375 tumor-bearing mice were used to assess the imaging ability of Zn5 in vivo.Mouse tumor xenografts were established by injection of A375 cells with 2×10~6 cells per flank.Probe(1 μg·g^(-1)) was administered to mice by injection.Images were obtained using IVIS Spectrum CT Imaging System.RESULTS There is a 11-fold intensity increasing as the pH values changing from 8 to 2.The almost unchanged emission intensities suggest Zn5 is stable in both BSA and serum.Zn5 has negligible cytotoxicity for He La,293 T and CHO-K1 cells.Zn5 can selectively display lysosomes in living cells.Both the 2D and 3D images in vivo distinguish the tumor from other tissues with good fluorescence contrast.CONCLUSION The high chemical stability,emission in the Vis/NIR range,pH sensitivity,a pKa located in the tumor pH range,and low toxicity make Zn5 is suitable for application as a pH-sensitive fluorescent probe for bio-imaging.

Unprecedented Pseudo Water Tapes Stabilized by a One-dimensional Cu(Ⅱ) Coordination Polymer

A new compound,[Cu（mal）（tmdpy）（H2O）]·4H2O（1,H2mal = malonic acid,tmdpy = 4,4＇-trimethylenedipyridine） has been synthesized by the hydrothermal synthesis and structurally characterized by X-ray crystallography. It crystallizes in triclinic,space group P1^- with a = 9.1662（6）,b = 10.6266（7）,c = 11.3056（7）A,α = 84.6390（10）,β = 72.1030（10）,γ = 73.0420（10） o,V = 1002.37（11）A^3,C16H26CuN2O9,Mr = 453.93,Z = 2,Dc = 1.504 g/cm^3,μ = 1.140 mm^-1,F（000） = 474,R = 0.0375 and wR = 0.0975 for 3187 observed reflections（I 〉 2σ（I）） . In the structure of 1,the tmdpy ligands link the [Cu（mal）（H2O） ] units into an infinite chain,and the water molecules and carboxylate oxygen donors（O（2） and O（4）） from the mal ligands cooperatively built an interesting hydrogen bonding network with unprecedented pseudo water tape substructures.

A Novel Three-dimensional Mn(Ⅱ) Coordination Polymer Constructed from Biphenyl-3,3',5,5'-tetracarboxylic Acid and Water

The title Mn（Ⅱ） coordination polymer,poly{[heptaaqua-（μ4-bi-phenyl-3,3？,5,5？-tetracarboxylate）-bimanganese（Ⅱ）] pentahydrate},[Mn_2（bpta）（H_2O）_7]_n·5n H_2O（I）,is crystallized from a mixture of biphenyl-3,3？,5,5？-tetracarboxylic acid（H_4bpta） and MnCl_2·4H_2O in waterethanol under room temperature. Its asymmetric unit consists of one and two halves of crystallographically independent Mn（Ⅱ） cations,one fully deprotonated H4 bpta ligand,seven coordinated water molecules and five solvent water as guest molecules. In I,each Mn（Ⅱ） atom is octahedrally coordinated by six oxygen atoms from bpta^（4-） anions and coordinated water molecules. In the Mn（Ⅱ） cations,one half Mn（Ⅱ） ion of them located at a 2-fold axis generating a trinuclear [Mn_3（H_2O）_2（RCOO）_2] linker by μ1,1-O（water） and μ1,3-O,O？（carboxylate） bridges and another half Mn（Ⅱ） ion with an inversion is a mononuclear linker. These neighbouring trinuclear and mononuclear Mn（Ⅱ） cations are linked together by biphenyl-3,3？,5,5？-tetracarboxylates to form a three-dimensional framework with a（42.84） topology of a（4,4）-connected net,in which the positions of the trinuclear [Mn_3（H_2O）_2（R-COO）_2] linker as a 4-connector linking four bpta^（4-） ligands in I reproduce an eagle-shaped arrangement. The polymeric structure exhibits a water channel with an accessible void of 797.1 ？~3,amounting to 15.7% of the total unit-cell volume. Each of the cavities in the network is occupied by solvent water molecules.

ECBK: Enhanced Cluster Based Key Management Scheme for Achieving Quality of Service

Wireless sensor networks consist of many small nodes with distributing devices to monitor conditions at different locations. Usually wireless sensor nodes are sprinkled in a sensor field grouping limited areas. This paper highlights the Enhanced Cluster Based Key management (ECBK) protocol to achieve secure data delivery based on clustering mechanism. This protocol gives more importance to Cluster Coordinator node, which is used to coordinate the members and provide protective communication among the sensor nodes to enhance reliability. In Enhanced Cluster Based Key management two types of nodes are deployed. The high power nodes form clusters with surrounding nodes to enable the routing process without interference. This paper introduces ECBK protocol that balances the load among the clusters, achieves high throughput, end to end delay will be reduced, routing overhead also reduced and also it prolongs the network lifetime. Simulation results show that the presence of high transmission nodes reduces the delay, load balance, routing overhead, and enhances the throughput increased by 45% compared to other similar methods.

High-Order Finite Difference Schemes for the First Derivative in Von Mises Coordinates

Third- and fourth-order accurate finite difference schemes for the first derivative of the square of the speed are developed, for both uniform and non-uniform grids, and applied in the study of a two-dimensional viscous fluid flow through an irregular domain. The von Mises transformation is used to transform the governing equations, and map the irregular domain onto a rectangular computational domain. Vorticity on the solid boundary is expressed in terms of the first partial derivative of the square of the speed of the flow in the computational domain, and the schemes are used to calculate the vorticity at the computational boundary grid points using up to five computational domain grid points. In all schemes developed, we study the effect of coordinate clustering on the computed results.

Coordinated target localization base on pseudo measurement for clustered space robot

This paper presents a coordinated target localization method for clustered space robot.According to the different measuring capabilities of cluster members,the master-slave coordinated relative navigation strategy for target localization with respect to slavery space robots is proposed;then the basic mathematical models,including coordinated relative measurement model and cluster centralized dynamics,are established respectively.By employing the linear Kalman flter theorem,the centralized estimator based on truth measurements is developed and analyzed frstly,and with an intention to inhabit the initial uncertainties related to target localization,the globally stabilized estimator is designed through introduction of pseudo measurements.Furthermore,the observability and controllability of stochastic system are also analyzed to qualitatively evaluate the convergence performance of pseudo measurement estimator.Finally,on-orbit target approaching scenario is simulated by using semi-physical simulation system,which is used to verify the convergence performance of proposed estimator.During the simulation,both the known and unknown maneuvering acceleration cases are considered to demonstrate the robustness of coordinated localization strategy.

Identifying the skeptics and the undecided through visual cluster analysis of local network geometry

By skeptics and undecided we refer to nodes in clustered social networks that cannot be assigned easily to any of the clusters.Such nodes are typically found either at the interface between clusters(the undecided)or at their boundaries(the skeptics).Identifying these nodes is relevant in marketing applications like voter targeting,because the persons represented by such nodes are often more likely to be affected in marketing campaigns than nodes deeply within clusters.So far this identification task is not as well studied as other network analysis tasks like clustering,identifying central nodes,and detecting motifs.We approach this task by deriving novel geometric features from the network structure that naturally lend themselves to an interactive visual approach for identifying interface and boundary nodes.