A pair of copper bromide lasers in an oscillator–amplifier configuration is used to investigate the small signal gain and saturation intensity as amplifying parameters and output power of lasers, versus pressure of b...A pair of copper bromide lasers in an oscillator–amplifier configuration is used to investigate the small signal gain and saturation intensity as amplifying parameters and output power of lasers, versus pressure of buffer gas. It is shown that the amplifying parameters and laser output power have a maximum value at optimum buffer gas pressure of 11？Torr. The challenge between microscopic parameters such as stimulated emission cross section, laser upper level lifetime, and population inversion, which determine the values of laser characteristics respective to the operational pressure of buffer gas, are investigated. Thus an optimum delay time of about 10？ns is determined, and a maximum output power equivalent to about 12？W is extracted. The amplifying parameters and measured output power of laser versus delay times show some local maxima and minima at the delay time interval of 6–43？ns.展开更多
Photopromoted carbonylation of 1-bromo-6-chlorohexane with CO catalyzed by CuBr2 and CdI2 has been carried out under ambient conditions. The results indicate that the carbonylation proceeds with the major product of c...Photopromoted carbonylation of 1-bromo-6-chlorohexane with CO catalyzed by CuBr2 and CdI2 has been carried out under ambient conditions. The results indicate that the carbonylation proceeds with the major product of chloroester ClCH2（CH2）5COOCH3 under catalysis of CuBr2. Furthermore, the activity of the carbonylation can be improved by addition of basic additives （NaOAc, Na3PO4 or （n-C4H9）3N）. Among these additives, （n-C4H9）3N is the most efficient in terms of the yield of ClCH2（CH2）5COOCH3. However, the methoxycarbonyl substituting chlorine product of BrCH2（CH2）5COOCH3 is not obtained in the presence of CdI2. This is quite different from the carbonylation of monochloroalkane.展开更多
文摘A pair of copper bromide lasers in an oscillator–amplifier configuration is used to investigate the small signal gain and saturation intensity as amplifying parameters and output power of lasers, versus pressure of buffer gas. It is shown that the amplifying parameters and laser output power have a maximum value at optimum buffer gas pressure of 11？Torr. The challenge between microscopic parameters such as stimulated emission cross section, laser upper level lifetime, and population inversion, which determine the values of laser characteristics respective to the operational pressure of buffer gas, are investigated. Thus an optimum delay time of about 10？ns is determined, and a maximum output power equivalent to about 12？W is extracted. The amplifying parameters and measured output power of laser versus delay times show some local maxima and minima at the delay time interval of 6–43？ns.
基金We appreciate the National Natural Science Foundations of China （No. 20372012） the Natural Science Foundations of Liaoning （No. 20032099） for the generous financial support.
文摘Photopromoted carbonylation of 1-bromo-6-chlorohexane with CO catalyzed by CuBr2 and CdI2 has been carried out under ambient conditions. The results indicate that the carbonylation proceeds with the major product of chloroester ClCH2（CH2）5COOCH3 under catalysis of CuBr2. Furthermore, the activity of the carbonylation can be improved by addition of basic additives （NaOAc, Na3PO4 or （n-C4H9）3N）. Among these additives, （n-C4H9）3N is the most efficient in terms of the yield of ClCH2（CH2）5COOCH3. However, the methoxycarbonyl substituting chlorine product of BrCH2（CH2）5COOCH3 is not obtained in the presence of CdI2. This is quite different from the carbonylation of monochloroalkane.
