The microstructure and hydrogen storage properties of low V content （Ti0.46Cr0.54）100-xVx （x = 2.5-7.1, at%） and （TiyCr1-y）95V5 （y= 0.38-0.54） alloys were investigated. These alloys were prepared by arc meltin...The microstructure and hydrogen storage properties of low V content （Ti0.46Cr0.54）100-xVx （x = 2.5-7.1, at%） and （TiyCr1-y）95V5 （y= 0.38-0.54） alloys were investigated. These alloys were prepared by arc melting and copper mould suction casting. The structures of as-cast （Ti0.46Cr0.54）100-xVx （x = 2.5, 5.0, and 7.1） alloy ingots evolve with V contents from pure Laves-（x = 2.5） to dual-phase TiCr2-BCC structures （5.0 and 7.1）, whereas the suction-cast （Ti0.46Cr0.54）100-xVx （x =2.5, 5.0, and 7.1） alloys only contain single BCC phase. The suction-cast alloy rod （Ti0.46Cr0.54）95V5, containing only 5.0 at% V is shown to possess the optimum hydrogen absorption capacity, with the maximum hydrogen content of 3.14 wt%. Furthermore, the hydrogen storage properties of the suction-cast low V alloys （TiyCr1-y）95V5 （y = 0.38-0.54） are sensitive to Ti/Cr ratios and only those alloys with Ti/Cr ratios close to the CN14 cluster [TiTCrs] have good hydrogen storage properties.展开更多
Phases of Cu-（0.4%-2.0%） Cr-（0.05%-0.16%） Zr alloys were analyzed in both as cast and deformed state. Solute-rich clusters of Cr, which was supposed to form during aging treatment, were observed in as cast state; ...Phases of Cu-（0.4%-2.0%） Cr-（0.05%-0.16%） Zr alloys were analyzed in both as cast and deformed state. Solute-rich clusters of Cr, which was supposed to form during aging treatment, were observed in as cast state; along with the morphology character, corresponding preferential orientation of Cr phase in as cast state was also investigated. Precipitates were observed to distribute in the matrix with a bimodal distribution, viz. coarse precipitates with dimension larger than several hundred nanometers and fine precipitates with size of 2- 10 nm. Three types of intermetallics, the common compound of Cu51Zr14, correspondingly infrequent Cu5Zr and rare Cu5Zr3, were characterized in different samples.展开更多
A new cluster line approach for the composition rule of Laves phase-related BCC solid solution hydrogen-storage alloys was presented. The cluster line in a ternary phase diagram refers to a straight composition line l...A new cluster line approach for the composition rule of Laves phase-related BCC solid solution hydrogen-storage alloys was presented. The cluster line in a ternary phase diagram refers to a straight composition line linking a specific binary cluster to the third element. In the Laves phase-related BCC solid solution alloy system such as Ti-Cr-V, Ti-Cr tends to form binary Cr2Ti Laves phase while Ti-V and Cr-V to form solid solutions. This Laves phase is characterized by a close-packing icosahedral cluster Cr7Ti6. A cluster line Cr7Ti6-V is then constructed in this system. Alloy rods with a diameter of 3 mm of compositions along this line were prepared by copper-mould suction method. The alloy structure is found to vary with the V contents. Furthermore, the P-C-T measurements indicate that the cluster-line (Cr7Ti6)1-xVx alloys have large hydrogen storage capacities.展开更多
The present study of the open cluster Collinder 223 (Cr 223) depended greatlyon the photoelectric data of Claria and Lapasset. We use the data in conjunction with the AAO/DSS^1image of the cluster in a re-investigatio...The present study of the open cluster Collinder 223 (Cr 223) depended greatlyon the photoelectric data of Claria and Lapasset. We use the data in conjunction with the AAO/DSS^1image of the cluster in a re-investigation to improve the main parameters of Cr 223, including thestellar density, the position of the cluster's center, the cluster's diameter. Its luminosityfunction, mass function, and total mass are also estimated.展开更多
基金financially supported by the National Natural Science Foundation of China(Nos.51171035 and 11174044)
文摘The microstructure and hydrogen storage properties of low V content （Ti0.46Cr0.54）100-xVx （x = 2.5-7.1, at%） and （TiyCr1-y）95V5 （y= 0.38-0.54） alloys were investigated. These alloys were prepared by arc melting and copper mould suction casting. The structures of as-cast （Ti0.46Cr0.54）100-xVx （x = 2.5, 5.0, and 7.1） alloy ingots evolve with V contents from pure Laves-（x = 2.5） to dual-phase TiCr2-BCC structures （5.0 and 7.1）, whereas the suction-cast （Ti0.46Cr0.54）100-xVx （x =2.5, 5.0, and 7.1） alloys only contain single BCC phase. The suction-cast alloy rod （Ti0.46Cr0.54）95V5, containing only 5.0 at% V is shown to possess the optimum hydrogen absorption capacity, with the maximum hydrogen content of 3.14 wt%. Furthermore, the hydrogen storage properties of the suction-cast low V alloys （TiyCr1-y）95V5 （y = 0.38-0.54） are sensitive to Ti/Cr ratios and only those alloys with Ti/Cr ratios close to the CN14 cluster [TiTCrs] have good hydrogen storage properties.
文摘Phases of Cu-（0.4%-2.0%） Cr-（0.05%-0.16%） Zr alloys were analyzed in both as cast and deformed state. Solute-rich clusters of Cr, which was supposed to form during aging treatment, were observed in as cast state; along with the morphology character, corresponding preferential orientation of Cr phase in as cast state was also investigated. Precipitates were observed to distribute in the matrix with a bimodal distribution, viz. coarse precipitates with dimension larger than several hundred nanometers and fine precipitates with size of 2- 10 nm. Three types of intermetallics, the common compound of Cu51Zr14, correspondingly infrequent Cu5Zr and rare Cu5Zr3, were characterized in different samples.
基金This project was financially supported by the National Natural Science Foundation of China (No.50401020)by a Joint Research Funding of Dalian University of Technology and Dalian Institute of Chemical Physics.
文摘A new cluster line approach for the composition rule of Laves phase-related BCC solid solution hydrogen-storage alloys was presented. The cluster line in a ternary phase diagram refers to a straight composition line linking a specific binary cluster to the third element. In the Laves phase-related BCC solid solution alloy system such as Ti-Cr-V, Ti-Cr tends to form binary Cr2Ti Laves phase while Ti-V and Cr-V to form solid solutions. This Laves phase is characterized by a close-packing icosahedral cluster Cr7Ti6. A cluster line Cr7Ti6-V is then constructed in this system. Alloy rods with a diameter of 3 mm of compositions along this line were prepared by copper-mould suction method. The alloy structure is found to vary with the V contents. Furthermore, the P-C-T measurements indicate that the cluster-line (Cr7Ti6)1-xVx alloys have large hydrogen storage capacities.
文摘The present study of the open cluster Collinder 223 (Cr 223) depended greatlyon the photoelectric data of Claria and Lapasset. We use the data in conjunction with the AAO/DSS^1image of the cluster in a re-investigation to improve the main parameters of Cr 223, including thestellar density, the position of the cluster's center, the cluster's diameter. Its luminosityfunction, mass function, and total mass are also estimated.
