采用熔化极活性气体保护焊(metal active gas arc welding,MAG焊)、等离子弧焊(plasma arc welding,PAW)和高频感应焊接方法获得铁素体+马氏体双相组织不锈钢00Cr12Ni的焊接接头,对其组织区域特征和力学性能进行了研究.典型的焊接接头...采用熔化极活性气体保护焊(metal active gas arc welding,MAG焊)、等离子弧焊(plasma arc welding,PAW)和高频感应焊接方法获得铁素体+马氏体双相组织不锈钢00Cr12Ni的焊接接头,对其组织区域特征和力学性能进行了研究.典型的焊接接头热影响区(heat affected zone,HAZ)可分为晶粒粗大,铁素体为优势相的高温热影响区(high temperature heat affected zone,HTHAZ)和晶粒细小,马氏体为优势相的低温热影响区(low temperature heat affected zone,LTHAZ).通过测量实际焊接热循环曲线的方法确定了HTHAZ及LTHAZ的温度范围,并采用热模拟研究HAZ不同区域的力学性能.结果表明,HTHAZ的热循环峰值范围为1200℃至熔点,晶粒粗大呈现为脆性;LTHAZ热循环峰值范围为800~1200℃,室温组织为非平衡低碳板条马氏体,韧性较好,但低于0℃时呈脆性.MAG焊接头由于奥氏体焊缝为钟罩形,HAZ冲击试验时断面包括奥氏体焊缝,因此冲击性能较好;PAW接头在1000℃奥氏体快冷可获得细晶粒马氏体韧性提高;高频感应焊接接头中无HTHAZ,但焊接过程中的加工硬化导致室温呈脆性,通过去应力退火后韧性恢复.展开更多
The effects of chloride,sulfate and carbonate anions on stress corrosion behaviors of ultra-high strength steel 23Co14Ni12Cr3Mo were studied by stress corrosion cracking(SCC)test method using double cantilever beam(DC...The effects of chloride,sulfate and carbonate anions on stress corrosion behaviors of ultra-high strength steel 23Co14Ni12Cr3Mo were studied by stress corrosion cracking(SCC)test method using double cantilever beam(DCB)specimens.The SCC morphology was observed by using scanning electron microscopy(SEM)and the composition of corrosion products was analyzed by using energy dispersive spectrometer(EDS).The results show that the crack propagates to bifurcation in NaCl and Na2SO4 solution,while the crack in Na2CO3 solution propagates along the load direction.The SCC rate in NaCl solution is the highest,while lower in Na2SO4 solution and little in Na2CO3 solution.From the SEM morphologies,quasi-cleavage fracture was observed in NaCl and Na2SO4 solutions,but intergranular features in Na2CO3 solution.The mechanism of anion effect on SCC of steel 23Co14Ni12Cr3Mo was studied by using full immersion test and electrochemical measurements.展开更多
In the last three decades new stronger modified 9%Cr steels have been introduced in new power plants with steam parameters up to 300 bar(1 bar =10~5 Pa) and 600℃. In order to further increase the steam parameters of ...In the last three decades new stronger modified 9%Cr steels have been introduced in new power plants with steam parameters up to 300 bar(1 bar =10~5 Pa) and 600℃. In order to further increase the steam parameters of steel based power plants up to a target value of 650℃/ 325 bar it is necessary to double the creep strength compared with todays strongest 9%Cr steels,and at the same time the resistance against steam oxidation must be improved by adding 12%Cr to the steel. However,so far all attempts to make stronger 12%Cr steels have been unsuccessful because the high chromium content introduced severe microstructure instabilities in the tested steels.Recently,it was found that the microstructure instabilities in 11%- 12%Cr steels can be explained by the precipitation of coarse Cr(V,Nb)N Z-phases, which dissolve fine(V,Nb)N nitrides. A new possibility to use the Z-phase for strengthening of 12%Cr steels has been identified,and the development of stable strong martensitic 12%Cr steels based on this concept is expected to allow the construction of 325 bar/ 650℃steam power plants all based on steel.展开更多
Ta and C ions extracted from a MEVVA ion source were implanted into Cr12 steel, with an implantation dose of (1-5)ｘ1017cm-2, extraction acceleration 42kV, and average ion beam flux about 20-50μA·cm-2. Rutherfor...Ta and C ions extracted from a MEVVA ion source were implanted into Cr12 steel, with an implantation dose of (1-5)ｘ1017cm-2, extraction acceleration 42kV, and average ion beam flux about 20-50μA·cm-2. Rutherford backscattering spectrum (RBS) was used to measure the surface composition after Ta and Ta+C implantation. Analysis of phase formed by Ta and C implantation was carried out by X-ray diffraction analysis (XRD). Experiment results showed that the wear rate of the implanted layer dropped 40% for Ta ion implantation and by a factor of 2.7 for Ta+C dual ion implantation. Ta+C dual ion implantation was found to reduce the friction coefficient of Cr12 steel. The wear mechanisms of the implanted layer were discussed.展开更多
The effect of W on mechanical properties of 12% Cr-W-V-Nb heat resistant steel at high temperatures and room temperature is reported.The experimental results indicated that if the W content was about 2.2—3.0 wt-%,the...The effect of W on mechanical properties of 12% Cr-W-V-Nb heat resistant steel at high temperatures and room temperature is reported.The experimental results indicated that if the W content was about 2.2—3.0 wt-%,there was no obviously change of R.T.tensile strength, but impact toughness decreased with the rise of W content.On the other hand,the increase of W content enhanced the short time stress rupture strength,but did not for the long time one. The increase of W have two effects on the precipitation behavior,promoting Laves formation of type Fe_2W,increasing the precipitated phase amount and speeding up the coarsening pro- cess of precipitated phase at high temperatures.The effect of W on the mechanical properties is closely associated with precipitation behaviors.When the rupture life is short,there has no enough time to coarsen the precipitated phases,so the increase of precipitated phases results in strengthening effect,i.e.the W increases the high temperature strength.After prolonged expo- sure,the evident coarsening took plaee,that decreased the effect of precipitation.展开更多
文摘采用熔化极活性气体保护焊(metal active gas arc welding,MAG焊)、等离子弧焊(plasma arc welding,PAW)和高频感应焊接方法获得铁素体+马氏体双相组织不锈钢00Cr12Ni的焊接接头,对其组织区域特征和力学性能进行了研究.典型的焊接接头热影响区(heat affected zone,HAZ)可分为晶粒粗大,铁素体为优势相的高温热影响区(high temperature heat affected zone,HTHAZ)和晶粒细小,马氏体为优势相的低温热影响区(low temperature heat affected zone,LTHAZ).通过测量实际焊接热循环曲线的方法确定了HTHAZ及LTHAZ的温度范围,并采用热模拟研究HAZ不同区域的力学性能.结果表明,HTHAZ的热循环峰值范围为1200℃至熔点,晶粒粗大呈现为脆性;LTHAZ热循环峰值范围为800~1200℃,室温组织为非平衡低碳板条马氏体,韧性较好,但低于0℃时呈脆性.MAG焊接头由于奥氏体焊缝为钟罩形,HAZ冲击试验时断面包括奥氏体焊缝,因此冲击性能较好;PAW接头在1000℃奥氏体快冷可获得细晶粒马氏体韧性提高;高频感应焊接接头中无HTHAZ,但焊接过程中的加工硬化导致室温呈脆性,通过去应力退火后韧性恢复.
基金Project(51171011)supported by the National Science Foundation of China
文摘The effects of chloride,sulfate and carbonate anions on stress corrosion behaviors of ultra-high strength steel 23Co14Ni12Cr3Mo were studied by stress corrosion cracking(SCC)test method using double cantilever beam(DCB)specimens.The SCC morphology was observed by using scanning electron microscopy(SEM)and the composition of corrosion products was analyzed by using energy dispersive spectrometer(EDS).The results show that the crack propagates to bifurcation in NaCl and Na2SO4 solution,while the crack in Na2CO3 solution propagates along the load direction.The SCC rate in NaCl solution is the highest,while lower in Na2SO4 solution and little in Na2CO3 solution.From the SEM morphologies,quasi-cleavage fracture was observed in NaCl and Na2SO4 solutions,but intergranular features in Na2CO3 solution.The mechanism of anion effect on SCC of steel 23Co14Ni12Cr3Mo was studied by using full immersion test and electrochemical measurements.
文摘In the last three decades new stronger modified 9%Cr steels have been introduced in new power plants with steam parameters up to 300 bar(1 bar =10~5 Pa) and 600℃. In order to further increase the steam parameters of steel based power plants up to a target value of 650℃/ 325 bar it is necessary to double the creep strength compared with todays strongest 9%Cr steels,and at the same time the resistance against steam oxidation must be improved by adding 12%Cr to the steel. However,so far all attempts to make stronger 12%Cr steels have been unsuccessful because the high chromium content introduced severe microstructure instabilities in the tested steels.Recently,it was found that the microstructure instabilities in 11%- 12%Cr steels can be explained by the precipitation of coarse Cr(V,Nb)N Z-phases, which dissolve fine(V,Nb)N nitrides. A new possibility to use the Z-phase for strengthening of 12%Cr steels has been identified,and the development of stable strong martensitic 12%Cr steels based on this concept is expected to allow the construction of 325 bar/ 650℃steam power plants all based on steel.
文摘Ta and C ions extracted from a MEVVA ion source were implanted into Cr12 steel, with an implantation dose of (1-5)ｘ1017cm-2, extraction acceleration 42kV, and average ion beam flux about 20-50μA·cm-2. Rutherford backscattering spectrum (RBS) was used to measure the surface composition after Ta and Ta+C implantation. Analysis of phase formed by Ta and C implantation was carried out by X-ray diffraction analysis (XRD). Experiment results showed that the wear rate of the implanted layer dropped 40% for Ta ion implantation and by a factor of 2.7 for Ta+C dual ion implantation. Ta+C dual ion implantation was found to reduce the friction coefficient of Cr12 steel. The wear mechanisms of the implanted layer were discussed.
文摘The effect of W on mechanical properties of 12% Cr-W-V-Nb heat resistant steel at high temperatures and room temperature is reported.The experimental results indicated that if the W content was about 2.2—3.0 wt-%,there was no obviously change of R.T.tensile strength, but impact toughness decreased with the rise of W content.On the other hand,the increase of W content enhanced the short time stress rupture strength,but did not for the long time one. The increase of W have two effects on the precipitation behavior,promoting Laves formation of type Fe_2W,increasing the precipitated phase amount and speeding up the coarsening pro- cess of precipitated phase at high temperatures.The effect of W on the mechanical properties is closely associated with precipitation behaviors.When the rupture life is short,there has no enough time to coarsen the precipitated phases,so the increase of precipitated phases results in strengthening effect,i.e.the W increases the high temperature strength.After prolonged expo- sure,the evident coarsening took plaee,that decreased the effect of precipitation.
