β-Cyclodextrin( β-CyD) is cyclic oligosaccharide of a glucopyranose, containing a relatively hydrophobic central cavity and hydrophilic outer surface. However, the usefulness of β-CyD is limited owing to its low aq...β-Cyclodextrin( β-CyD) is cyclic oligosaccharide of a glucopyranose, containing a relatively hydrophobic central cavity and hydrophilic outer surface. However, the usefulness of β-CyD is limited owing to its low aqueous solubility whereas we found that its apparent high solubility was evident in some injectable solvents including 2-pyrrolidone(PYR), Nmethyl pyrrolidone(NMP) and dimethyl sulfoxide(DMSO). Therefore, in the present study, the physicochemical properties of the 30–60% w/w β-CyD in PYR, NMP and DMSO were investigated such as viscosity, water resistant, matrix formation rate and syringeability. The higher the concentration of β-CyD resulted in the increased viscosity and the higher force and energy of syringeability. β-CyD in PYR gave the highest viscosity which contributed to the lowest syringeability while β-CyD in DMSO exhibited the highest syringeability. The β-CyD in DMSO and NMP exhibited the higher rate of matrix formation. β-CyD in PYR showed the highest water resistant for phase separation while β-CyD in NMP gave the faster de-mixing rate compared to that from PYR. The difference in physicochemical properties of β-CyD dried ppts studied by scanning electron microscope(SEM), differential scanning calorimetry(DSC), X-ray diffraction(XRD), Fourier-transform infrared spectroscopy(FT-IR) and thermogravimetric analysis(TGA) revealed that there was partial complexation of β-CyD with respective solvents. Both solution and precipitate characteristic properties will be useful for using β-CyD in further investigation as matrix material dissolved in the injectable vehicles as the in situ forming gel for periodontitis treatment.展开更多
Characteristics of the precipitate α″-Fe16N2 phase have been investigated by X-ray diffraction and TEM analysis. VSM measurements give the saturation magnetization of the α″ phase.
Due to isothermal heat treatment or welding,duplex stainless undergoes a variety of decomposition processes at a temperature ranging from 300 - 1 100℃,which could form inter-metallic phases likeσ-phase and xphase,as...Due to isothermal heat treatment or welding,duplex stainless undergoes a variety of decomposition processes at a temperature ranging from 300 - 1 100℃,which could form inter-metallic phases likeσ-phase and xphase,as well as Cr_2N and M_(23)C_6,etc.These processes are not only influenced by temperature and cooling speed, but also are affected by alloy element content.The purpose of the research was to work out the qualitative and quantitative analysis of precipitate phases in 2 205 duplex stainless steel with different isothermal heat treatment situation.After choosing the electrolyte and electrolytic systems,we use electrochemical method to extract precipitate phases from the matrix.Scanning electron microscope(SEM) and X-ray diffraction(XRD) were used to examine their modality and structure.Particle size distribution was performed by dynamic laser scattering sizer (DLS-Sizer).Furthermore,oxygen-nitrogen analyzer and carbon-sulfur analyzer were applied to measure the content of nitrogen and carbon in precipitate phases.Separation and quantitative analysis of precipitate phases were carried out by wet chemical analysis and inductively coupled plasma spectrometry(ICP).In a word,combining chemical and physical methods,our research reveals the transformation of precipitate phases'species,content, elemental composition and particle size distribution during different isothermal heat treatment situation.展开更多
介绍了10Cr21Mn16NiN钢线材成分设计、增氮原理、冶炼工艺、轧制和固溶工艺、Cr_(2)N相析出的生产工艺。采用30 t AOD精炼,吹氮气增氮,精炼后期加氮化锰。轧制时采用1240℃加热、控轧控冷,保证了盘条表面质量,避免了中心缩孔等问题;固...介绍了10Cr21Mn16NiN钢线材成分设计、增氮原理、冶炼工艺、轧制和固溶工艺、Cr_(2)N相析出的生产工艺。采用30 t AOD精炼,吹氮气增氮,精炼后期加氮化锰。轧制时采用1240℃加热、控轧控冷,保证了盘条表面质量,避免了中心缩孔等问题;固溶温度应控制在1100℃左右,且保温30 min后快冷,可防止Cr_(2)N相析出。成功生产出表面质量和性能优良的10Cr21Mn16NiN不锈钢线材。展开更多
Flame heating combined with water cooling was used to straighten A6N01 aluminum alloy welded joint and effect of flame heating pass on its microstructure and mechanical properties was studied. Results showed that the ...Flame heating combined with water cooling was used to straighten A6N01 aluminum alloy welded joint and effect of flame heating pass on its microstructure and mechanical properties was studied. Results showed that the flame induced the precipitation and growth of the Mg_2Si phase on the Al substrate for the thermal aging A6N01 aluminum alloy welded joints,thus it led the decrease of micro-hardness and tensile strength of the A6N01 aluminum alloy welded joint with the increase of the heating pass. However,the fatigue property of the flame heated joint was improved because the Mg_2Si precipitation hindered the initiation and propagation of the fatigue crack.展开更多
Nano-NiO and bulk NiO were prepared from Ni(AC)_2·4 H_2O by coordination precipitation using aqueous ammonia and by a solid state reaction, respectively. The nickel oxide particles were characterized by X-ray Dif...Nano-NiO and bulk NiO were prepared from Ni(AC)_2·4 H_2O by coordination precipitation using aqueous ammonia and by a solid state reaction, respectively. The nickel oxide particles were characterized by X-ray Diffraction(XRD) and scanning electron microscopy(SEM). The results indicate that nano-sized NiO has a crystal phase with a standard face-centered cubic lattice structure, with a mean particle diameter of about 10 nm. The evaluation of the activity of nickel oxide nanoparticles in the catalytic hydrogenation of 7-methoxy-1-naphthylacetonitrile was carried out. The results demonstrate the efficient synthesis of the title compound by a one-pot catalytic hydrogenation and acetylation with NiO. The NiO nanoparticles displayed superior catalytic activity in the synthesis of agomelatine in the one-pot reaction.The total yield of agomelatine is over 81.8% with a purity of 99.2%, as determined by HPLC. The structure of agomelatine was confirmed by IR, MS, and 1 H NMR analysis.展开更多
文摘β-Cyclodextrin( β-CyD) is cyclic oligosaccharide of a glucopyranose, containing a relatively hydrophobic central cavity and hydrophilic outer surface. However, the usefulness of β-CyD is limited owing to its low aqueous solubility whereas we found that its apparent high solubility was evident in some injectable solvents including 2-pyrrolidone(PYR), Nmethyl pyrrolidone(NMP) and dimethyl sulfoxide(DMSO). Therefore, in the present study, the physicochemical properties of the 30–60% w/w β-CyD in PYR, NMP and DMSO were investigated such as viscosity, water resistant, matrix formation rate and syringeability. The higher the concentration of β-CyD resulted in the increased viscosity and the higher force and energy of syringeability. β-CyD in PYR gave the highest viscosity which contributed to the lowest syringeability while β-CyD in DMSO exhibited the highest syringeability. The β-CyD in DMSO and NMP exhibited the higher rate of matrix formation. β-CyD in PYR showed the highest water resistant for phase separation while β-CyD in NMP gave the faster de-mixing rate compared to that from PYR. The difference in physicochemical properties of β-CyD dried ppts studied by scanning electron microscope(SEM), differential scanning calorimetry(DSC), X-ray diffraction(XRD), Fourier-transform infrared spectroscopy(FT-IR) and thermogravimetric analysis(TGA) revealed that there was partial complexation of β-CyD with respective solvents. Both solution and precipitate characteristic properties will be useful for using β-CyD in further investigation as matrix material dissolved in the injectable vehicles as the in situ forming gel for periodontitis treatment.
文摘Characteristics of the precipitate α″-Fe16N2 phase have been investigated by X-ray diffraction and TEM analysis. VSM measurements give the saturation magnetization of the α″ phase.
文摘Due to isothermal heat treatment or welding,duplex stainless undergoes a variety of decomposition processes at a temperature ranging from 300 - 1 100℃,which could form inter-metallic phases likeσ-phase and xphase,as well as Cr_2N and M_(23)C_6,etc.These processes are not only influenced by temperature and cooling speed, but also are affected by alloy element content.The purpose of the research was to work out the qualitative and quantitative analysis of precipitate phases in 2 205 duplex stainless steel with different isothermal heat treatment situation.After choosing the electrolyte and electrolytic systems,we use electrochemical method to extract precipitate phases from the matrix.Scanning electron microscope(SEM) and X-ray diffraction(XRD) were used to examine their modality and structure.Particle size distribution was performed by dynamic laser scattering sizer (DLS-Sizer).Furthermore,oxygen-nitrogen analyzer and carbon-sulfur analyzer were applied to measure the content of nitrogen and carbon in precipitate phases.Separation and quantitative analysis of precipitate phases were carried out by wet chemical analysis and inductively coupled plasma spectrometry(ICP).In a word,combining chemical and physical methods,our research reveals the transformation of precipitate phases'species,content, elemental composition and particle size distribution during different isothermal heat treatment situation.
文摘介绍了10Cr21Mn16NiN钢线材成分设计、增氮原理、冶炼工艺、轧制和固溶工艺、Cr_(2)N相析出的生产工艺。采用30 t AOD精炼,吹氮气增氮,精炼后期加氮化锰。轧制时采用1240℃加热、控轧控冷,保证了盘条表面质量,避免了中心缩孔等问题;固溶温度应控制在1100℃左右,且保温30 min后快冷,可防止Cr_(2)N相析出。成功生产出表面质量和性能优良的10Cr21Mn16NiN不锈钢线材。
文摘Flame heating combined with water cooling was used to straighten A6N01 aluminum alloy welded joint and effect of flame heating pass on its microstructure and mechanical properties was studied. Results showed that the flame induced the precipitation and growth of the Mg_2Si phase on the Al substrate for the thermal aging A6N01 aluminum alloy welded joints,thus it led the decrease of micro-hardness and tensile strength of the A6N01 aluminum alloy welded joint with the increase of the heating pass. However,the fatigue property of the flame heated joint was improved because the Mg_2Si precipitation hindered the initiation and propagation of the fatigue crack.
基金Funded by the Natural Science Foundation of Hubei Province(2017CFB680)the Hubei University of Science and Technology Nuclear Technology Special Project(2018-19KZ06)+1 种基金the Open Fund of the State Key Laboratory of Refractories and Metallurgy(Wuhan University of Science and Technology)of China(G201703)the Key Laboratory of Measurement and Control System for Offshore Environment,Fuqing Branch of Fujian Normal University,Fujian Province University(S1-KF1604)
文摘Nano-NiO and bulk NiO were prepared from Ni(AC)_2·4 H_2O by coordination precipitation using aqueous ammonia and by a solid state reaction, respectively. The nickel oxide particles were characterized by X-ray Diffraction(XRD) and scanning electron microscopy(SEM). The results indicate that nano-sized NiO has a crystal phase with a standard face-centered cubic lattice structure, with a mean particle diameter of about 10 nm. The evaluation of the activity of nickel oxide nanoparticles in the catalytic hydrogenation of 7-methoxy-1-naphthylacetonitrile was carried out. The results demonstrate the efficient synthesis of the title compound by a one-pot catalytic hydrogenation and acetylation with NiO. The NiO nanoparticles displayed superior catalytic activity in the synthesis of agomelatine in the one-pot reaction.The total yield of agomelatine is over 81.8% with a purity of 99.2%, as determined by HPLC. The structure of agomelatine was confirmed by IR, MS, and 1 H NMR analysis.
