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Effects of biodegradation on diamondoid distribution in crude oils from the Bongor Basin,Chad
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作者 Huanxin Song Menghan Chen +2 位作者 Lirong Dou Dingsheng Cheng Zhigang Wen 《Energy Geoscience》 EI 2024年第2期120-128,共9页
The sensitivity of biodegradation on diamondoids was investigated using a series of biodegraded oil samples from the Ronier tectonic unit of Bongor Basin,Chad.The results suggest that diamondoids,including adamantanes... The sensitivity of biodegradation on diamondoids was investigated using a series of biodegraded oil samples from the Ronier tectonic unit of Bongor Basin,Chad.The results suggest that diamondoids,including adamantanes(As)and diamantanes(Ds),are relatively resistant to biodegradation and obvious biodegradation was observed in oils with a Peters-Moldowan(PM)biodegradation rank of 6 or more.Overall,the sensibility of biodegradation on diamondoids is generally similar to hopanes and regular steranes.As biodegradation evolves,the changes in concentration and components of diamondoids show that the biodegradation process is selective and stepwise.The significant increase of MD/MA and DMD/DMA for oils with a PM ranking 6^(+) indicates that diamantanes are generally more resistant to biodegradation than adamantanes.The similar trends of DMA/MA,EA/MA,MD/D,DMD/MD and other relevant indexes,show that higher alkylation homologs are more resistant to biodegradation.The commonly used diamondoid ratios,such as MAI,EAI,MDI and DMID-1,are obviously affected by biodegradation at the stage of high-level biodegradation,which may indicate that these ratios should be used with caution in case of severely degraded oils. 展开更多
关键词 DIAMONDOIDS BIODEGRADATION Sensitivity crude oil Bongor Basin CHAD
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The effect of slight to minor biodegradation on C_6 to C_7 light hydrocarbons in crude oils: a case study from Dawanqi Oilfield in the Tarim Basin,NW China 被引量:7
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作者 Lu Yang Chunming Zhang +3 位作者 Meijun Li Jing Zhao Xuening Qi Jinxiu Du 《Acta Geochimica》 EI CAS CSCD 2016年第2期203-214,共12页
Light hydrocarbons (LHs) are one of the main petroleum fractions in crude oils, and carry much infor- mation regarding the genetic origin and alteration of crude oils. But secondary alterations--especially biodegrad... Light hydrocarbons (LHs) are one of the main petroleum fractions in crude oils, and carry much infor- mation regarding the genetic origin and alteration of crude oils. But secondary alterations--especially biodegrada- tion--have a significant effect on the composition of LHs in crude oils. Because most of the LHs affected in oils underwent only slight biodegradation (rank 1 on the biodegradation scale), the variation of LHs can be used to describe more the refined features of biodegradation. Here, 23 crude oils from the Dawanqi Oilfield in the Tarim Basin, NW China, eleven of which have been biodegraded to different extents, were analyzed in order to investigate the effect of slight to minor biodegradation on C6--C7 LHs. The study results showed that biodegradation resulted in the prior depletion of straight-chained alkanes, followed by branched alkanes. In slight and minor biodegraded oils, such biodegradation scale could not sufficiently affect C6- C7 cycloalkanes. For branched C6--C7 alkanes, generally, monomethylalkanes are biodegraded earlier than dimethylalkanes and trimethylalkanes, which indicates that branched alkanes are more resistant to biodegradation, with the increase of substituted methyl groups on parent rings. The degree of alkylation is one of the primary controlling factors on the biodegradation of C6-Cv LHs. There is a particular case: although 2,2,3-trimethylbutane has a rela- tive higher alkylation degree, 2,2-dimethylpentane is more resistant to biodegradation than 2,2,3-trimethylbutane. 2,2- Dimethylpentane is the most resistant to biodegradation in branched C6-C7 alkanes. Furthermore, the 2-methylpen- tane/3-methylpentane and 2-methylhexane/3-methylhexane ratios decreased steadily with increasing biodegradation, which implies that isomers of bilateral methyl groups are more prone to bacterial attack relative to mid-chain iso- mers. The position of the alkyls on the carbon skeleton is also one of the critical factors controlling the rate of biodegradation. With increasing biodegradation, Mango's LH parameters K1 values decrease and K2 values increase, the values of n-heptane and isoheptane decrease, and the indices of methylcyclohexane and cyclohexane increase. LH parameters should be applied cautiously for the biodegraded oils. Because biodegraded samples belong to slight or minor biodegraded oils, the values of n-heptane and isoheptane from Dawanqi Oilfield can better reflect and determine the "Biodegraded" zone. When the heptane value is 0-21 and the isoheptane value is 0-2.6, the crude oil in Dawanqi Oilfield is defined as the "Biodegraded" zone 展开更多
关键词 crude oils - Light hydrocarbons BIODEGRADATION Dawanqi Oilfield Tarim Basin
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Corresponding Factors Influencing Crude Oils Assay Using Low-field Nuclear Magnetic Resonance 被引量:4
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作者 Feng Yunxia Chu Xiaoli +1 位作者 Xu Yupeng Tian Songbai 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2014年第2期34-39,共6页
In this study, the main factors influencing the measurements by means of the off-line low-field 1H NMR in the lab were discussed base on a robust calibration model established by the PLS algorithm using 255 crude oil ... In this study, the main factors influencing the measurements by means of the off-line low-field 1H NMR in the lab were discussed base on a robust calibration model established by the PLS algorithm using 255 crude oil samples. The preheating temperature had a great influence on the viscosity of oil samples and the resolution of spectral analysis. The repeatability of spectral measurements was impacted by the metal and wax content of the oil samples. For the case of high wax content oils, the wax species began to crystallize in the course of determination that could affect the repeatability of spectral measurements. These factors have evidenced why the preheating devices and filter unit are necessary when low field NMR system is used in the online analysis process. The investigation is very important for the on-line application of the low field NMR. 展开更多
关键词 low-field NMR influencing factors crude oils assay
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Origin and depositional environments of source rocks and crude oils from Niger Delta Basin: Carbon isotopic evidence 被引量:2
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作者 Abiodun B Ogbesejana Oluwasesan M Bello Tijjani Ali 《China Geology》 2020年第4期602-610,共9页
Thirty-nine crude oils and twenty-one rock samples from Niger Delta Basin,Nigeria have been characterized based on their isotope compositions by elemental analysis-isotope ratio mass spectrometry and gas chromatograph... Thirty-nine crude oils and twenty-one rock samples from Niger Delta Basin,Nigeria have been characterized based on their isotope compositions by elemental analysis-isotope ratio mass spectrometry and gas chromatography-isotope ratio mass spectrometry.The bulk carbon isotopic values of the whole rock extracts,saturate and aromatic fractions range from–28.7‰to–26.8‰,–29.2‰to–27.2‰and–28.5‰to–26.7‰,respectively while the bulk carbon isotopic values of the whole oils,saturate and aromatic fractions range from–25.4‰to–27.8‰,–25.9‰to–28.4‰and–23.5‰to–26.9‰,respectively.The average carbon isotopic compositions of individual alkanes(nC12-nC33)in the rock samples range from–34.9‰to–28.2‰whereas the average isotopic values of individual n-alkanes in the oils range from–31.1‰to–23.8‰.Theδ13C isotope ratios of pristane and phytane in the rock samples range from–29.2‰to–28.2‰and–30.2‰to–27.4‰respectively while the pristane and phytane isotopic values range from–32.1‰to–21.9‰and–30.5‰to–26.9‰,respectively.The isotopic values recorded for the samples indicated that the crude oils were formed from the mixed input of terrigenous and marine organic matter and deposited under oxic to sub-oxic condition in lacustrine-fluvial/deltaic environments.The stable carbon isotopic compositions were found to be effective in assessing the origin and depositional environments of crude oils in the Niger Delta Basin. 展开更多
关键词 crude oils Source rocks Isotopic compositions ORIGIN Niger Delta Basin Depositional environment NIGERIA
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Improved Correlations for Prediction of Viscosity of Iranian Crude Oils
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作者 Majid Taghizadeh Mehdi Eftekhari 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2014年第3期346-354,共9页
Empirical equations for predicting the viscosity of Iranian crude oils above, at and below the bub-ble-point pressure were developed based on pressure-volume-temperature(PVT) data of 57 bottom hole samples collected f... Empirical equations for predicting the viscosity of Iranian crude oils above, at and below the bub-ble-point pressure were developed based on pressure-volume-temperature(PVT) data of 57 bottom hole samples collected from central, southern and offshore oil fields of Iran. Both statistical and graphical techniques were employed to evaluate these equations compared with other empirical correlations. The results show that the developed correlations present better accuracy and performance for predicting the viscosity of Iranian crude oils than those correlations in literature. 展开更多
关键词 viscosity correlations pressure-volume-temperature (PVT) data viscosity prediction Iranian crude oils
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Molecular Organic Geochemistry of Crude Oils from the Albertine Graben, Uganda: Possible Implications on the Expulsion of the Oils from the Source Rocks
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作者 Joshua Lukaye Godfrey Etano Geoffrey Abbott 《Journal of Earth Science and Engineering》 2017年第4期181-193,共13页
Twelve representative crude oil samples recovered from six oil fields in the Albertine Graben, Uganda were chosen for this study. The study aimed to understand the genetic relationships between the oils, the inferred ... Twelve representative crude oil samples recovered from six oil fields in the Albertine Graben, Uganda were chosen for this study. The study aimed to understand the genetic relationships between the oils, the inferred depositional environment of the source rocks, maturity of the crude oils, and to gain some insight on the expulsion of the oils from source rocks. The work involved geochemical bulk analysis (asphaltene and liquid chromatographic separations), GC-FID (gas chromatography with a flame ionization detector), and GC-MS (gas chromatography-mass spectrometry) of saturate and aromatic fractions. Bulk analysis shows that the oils are dominated by saturate hydrocarbon fractions (48.7%-62.0%) and are highly waxy (35-56.2 wt%) with low sulfur content (〈 0.1 wt%). The high saturate hydrocarbon and high wax contents are probably due to organic matter input from land plants and/or long-chain alkanes from fresh water algae in lacustrine systems. The low sulfur contents alongside the high wax abundances are consistent with elastic-dominated source rock facies deposited in a non-stratified lacustrine environment. Data from GC-FID and GC-MS analyses such as n-alkane distributions, pristane/phytane ratios, biomarker terpane and sterane, dibenzothiophene and phenanthrene parameters show that the oils belong to a single family and were derived from a elastic predominantly algal source rock deposited under suboxic conditions in a non-stratified freshwater to brackish water lacustrine environment. The data further show that the oils have a very narrow range of maturities and are generated in the peak oil window. The observed narrow range of maturities and inferred lacustrine depositional setting for the source rocks suggest that the kerogen responsible for the generation of the oils is likely to be predominantly type-1 known to display narrow activation energies. This in turn implies that the expulsion of the oil from the source rock occurred as a quick single event hence, the filling of reservoirs in the Albertine Graben probably did not involve late stage expulsion and multiple charges of oil. 展开更多
关键词 Uganda Albertine Graben crude oils N-ALKANES homohopanes STERANES aromatic hydrocarbons source facies maturity oil family and oil expulsion.
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Thermodynamic Modeling of Wax Precipitation in Crude Oils 被引量:3
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作者 陈五花 赵宗昌 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2006年第5期685-689,共5页
Most of the crude oils contain waxes which precipitate when temperature drops, resulting in deposition in pipelines and production equipment. It is necessary to set up a model which can predict the wax appearance tem-... Most of the crude oils contain waxes which precipitate when temperature drops, resulting in deposition in pipelines and production equipment. It is necessary to set up a model which can predict the wax appearance tem-perature and the amount of solid precipitated in the different conditions. A modified thermodynamic solid-liquid equilibrium model to calculate wax precipitation in crude oil systems has been developed recently. The assumption that precipitated waxes consist of several solid phases is adopted in this research, and the solid-solid transition is also considered in the modified model. The properties of the pseudo-components are determined by using empirical correlations. New correlations for properties of solid-solid and solid-liquid transitions are also established in this work on the basis of the data from the literature. The results predicted by the proposed model for three crude oil systems are compared with the experimental data and the calculated results from the literature, and good agreement is observed. 展开更多
关键词 waxy crude oil solid-solid transition solid-liquid equilibrium thermodynamic model wax precipitation
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Organic geochemical characteristics of Eocene crude oils from Zhanhua Depression,Bohai Bay Basin,China 被引量:1
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作者 Yujiao Zhang Hong Lu +2 位作者 Yao-Ping Wang Xin Zhan Ping'an Peng 《Acta Geochimica》 EI CAS CSCD 2020年第5期655-667,共13页
Geochemical studies of crude oil and source rock play an important role in future exploration in Zhanhua Depression.In this study,thirty-one oil samples collected from Shahejie Formation in Zhanhua Depression,Bohai Ba... Geochemical studies of crude oil and source rock play an important role in future exploration in Zhanhua Depression.In this study,thirty-one oil samples collected from Shahejie Formation in Zhanhua Depression,Bohai Bay Basin,NE China have been geochemically analyzed and their organic geochemical characteristics have been applied to differentiate groups of oils.These oil samples can be classified into two families based on multiple biomarker proxies and stable carbon isotopic values.FamilyⅠis characterized by a low ratio of pristane over phytane(Pr/Ph<0.7),a relatively high ratio of phytane over n-C18(Ph/n-C18),varying ratios of gammacerane over C30 hopane(Ga/C30H)and C22/C21 tricyclic terpane,and a low ratio of C19/C23 tricyclic terpane.FamilyⅡis marked by a relatively high Pr/Ph ratio(0.7-1.6),relative low ratios of Ph/n-C18 and C22/C21 tricyclic terpane,and avarying ratio of C19/C23 tricyclic terpane.Both familiesⅠandⅡwithin these crude oils can be subdivided into two families based on different values of stable carbon isotopic composition of individual n-alkanes.Moreover,the potential source rocks of oil samples in FamilyⅠand FamilyⅡwere likely derived from the upper Es4 member and Es3 member,respectively,based on the correlation of organic geochemical characteristics of the oils and source rocks.The results of oil-source rock correlation provide insight into the process from oil generation to migration and to final accumulation,providing a better understanding of factors controlling oil-gas distribution for prediction of sweet spots. 展开更多
关键词 Zhanhua depression Bohai Bay Basin Biomarkers Stable carbon isotopic compositions crude oil
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Aminated Copolymers as Flow Improvers for Super-viscous Crude Oils 被引量:1
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作者 Zhang Hong Shen Benxian 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2007年第3期43-49,共7页
The new flow improvers for super-viscous crude oils were developed via esterification of polybasic high carbon alcohol with methacrylate and copolymerizafion of monomers followed by amination of copolymers. The struct... The new flow improvers for super-viscous crude oils were developed via esterification of polybasic high carbon alcohol with methacrylate and copolymerizafion of monomers followed by amination of copolymers. The structure of the synthesized polymer flow improver additive was confirmed by IR spectroscopy and the crystal structure of the flow improver additives were determined by X-ray diffrac- tion analysis. The structure of wax crystals was also studied at the same time. The results showed that the wax crystal structure was closely related with the crystal structure of the flow improver, which could change the pour point depression and viscosity reduction behavior of the crude oil. When the wax crystal structure matched well with that of the additive, the wax crystals were dispersed satisfactorily, resulting in favorable effects in terms of pour point depression and viscosity reduction. The new synthe- sized aminated polymer flow improver additive was most efficient for treating super-viscous crude oils. The super-viscous crude oil had a high content of resins and asphaltenes, which might aggregate onto the surface of wax crystals to form blocks to limit the crude oil fluidity. However, amination of copolymers having similar structure with the resins and asphaltenes contained in crude oil could dissolve the huge polar groups to make the deposit formation difficult. 展开更多
关键词 aminated copolymers flow improver super-viscous crude oil
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Waxes in asphaltenes of crude oils and wax deposits
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作者 Yulia M.Ganeeva Tatiana N.Yusupova Gennady V.Romanov 《Petroleum Science》 SCIE CAS CSCD 2016年第4期737-745,共9页
Composition and molecular mass distribution of n-alkanes in asphaltenes of crude oils of different ages and in wax deposits formed in the borehole equipment were studied. In asphaltenes, n-alkanes from C12 to C60 were... Composition and molecular mass distribution of n-alkanes in asphaltenes of crude oils of different ages and in wax deposits formed in the borehole equipment were studied. In asphaltenes, n-alkanes from C12 to C60 were detected. The high molecular weight paraffins in asphaltenes would form a crystalline phase with a melting point of 80–90 ℃. The peculiarities of the redistribution of high molecular paraffin hydrocarbons between oil and the corresponding wax deposit were detected. In the oils, the high molecular weight paraffinic hydrocarbons C50–C60were found, which were not practically detected in the corresponding wax deposits. 展开更多
关键词 Waxes ASPHALTENES Hydrocarbon composition crude oil Wax deposit
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Reaction Performance of FCC Catalyst for Cracking Inferior Crude Oils
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作者 Wei Xiaoli Song Baomei +1 位作者 Mao Anguo Long Jun (SINOPEC Research Institute of Petroleum Processing,Beijing 100083) 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2009年第4期4-9,共6页
Driven by the increasing supply of heavy oils with deteriorating quality,a high nickel-resistant catalyst for catalytic cracking of inferior crude oils was developed by the Research Institute of Petroleum Processing(R... Driven by the increasing supply of heavy oils with deteriorating quality,a high nickel-resistant catalyst for catalytic cracking of inferior crude oils was developed by the Research Institute of Petroleum Processing(RIPP).Catalyst performance was evaluated in a laboratory fixed fluidized bed reactor.The test results showed that the high nickel resistance catalyst exhibited good bottoms crackability,good nickel resistance,and good adaptability to changes in operating parameters,which had no adverse effect on the product distribution,indicating to a most promising prospect for application of this catalyst in catalytic cracking of inferior crude oil. 展开更多
关键词 catalytic cracking crude oil equilibrium catalyst NICKEL product slate
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Geochemistry and genesis on saturated hydrocarbon of crude oils in Gas Hure Oilfield in Qaidam Basin
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作者 MO Xiaoye ZHANG Min 《Global Geology》 2011年第1期7-14,共8页
Gas Hure Oilfield is the biggest one in the Qaidam Basin. Through intensive sampling and GC-MS a- nalysis, the authors analyzed the geochemical characteristics of the crude oils in the Gas Hure Oilfield. The re- sults... Gas Hure Oilfield is the biggest one in the Qaidam Basin. Through intensive sampling and GC-MS a- nalysis, the authors analyzed the geochemical characteristics of the crude oils in the Gas Hure Oilfield. The re- sults show that the crude oils have even-odd carbon predominance for n-alkanes. In shallow reservoir, part of crude oils suffered biogenic degradation. As for normal oils, they have low Pr/Ph ratios with abundant gammac- erane and C35 homohopane, which indicate that the crude oils are formed in strong reducing salt water environ- ment. Compared deep ( E~ ) reservoir with shallow ( N1 - N2^1 ) reservoir, the ancient salinity of sedimentary en- vironment of Nj-N1 crude oils is slightly higher than that of E3^1crude oils; the C21-/C22+ ratios of crude oils are 1.02-1.71 with a higher abundance of C27sterane, which shows that their mainly origin matrix are bacteria and algae; the C29 sterane 20S/(20S + 20R)is generally low, the ratio in deep E3^1 reservoir distributes between 0.31 and 0. 40, but in shallow reservoir is relatively low with 0. 29-0. 36. At the same time, C29sterane αββ(αββ +ααα) and Ts/Tm both are extremely lower. All the above show that the crude oils in Gas Hure are mainly low mature oils, although the maturity of deep reservoir crude oils is slightly higher than shallow one. 展开更多
关键词 Qaidam Basin Gas Hure Oilfield crude oil saturated hydrocarbon geochemical characteristics
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Heavy Metal Levels and Ecological Risk in Crude Oil-Contaminated Soils from Okpare-Olomu, Niger Delta, Nigeria
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作者 Adedoyin Olubunmi Bankole Akinyemi Olufemi Ogunkeyede +5 位作者 Harrison Agboro Prince Alex Ekhorutomwen Osasenaga Israel Otuomagie Khadijah Ateda Isimekhai Ekaette Akpan Fadairo Efe Jeffery Isukuru 《Journal of Environmental Protection》 2024年第4期415-438,共24页
Crude oil spills have inflicted extensive disruption upon the Niger Delta ecosystem, resulting in crop loss and severe environmental damage. Such spills exacerbate heavy metal concentration within soil due to the pres... Crude oil spills have inflicted extensive disruption upon the Niger Delta ecosystem, resulting in crop loss and severe environmental damage. Such spills exacerbate heavy metal concentration within soil due to the presence of metallic ions. The Okpare-Olomu community has borne the brunt of crude oil pollution from illicit bunkering, sabotage, and equipment malfunction. This study targets an evaluation of ecological hazards linked to heavy metals (HMs) in crude oil impacted agriculturally soils within Okpare-Olomu in Ughelli South LGA of Delta State. In this study, 24 topsoil samples were obtained from areas affected by crude oil pollution;the heavy metal content was evaluated through atomic absorption spectrometry. The concentration ranges for HMs (mg/kg) in soil were: 24.1 - 23,174 (Cu);0.54 - 37.1 (Cd);9.05 - 54 (Cr);12 - 174 (Ni);18.5 - 8611 (Pb);and 148 - 9078 (Zn) at a soil depth of 0 - 15 cm. Notably, metal concentrations were recorded to be above permissible World Health Organization limits. Predominantly, Zn and Pb recorded higher heavy metal concentration when compared to other heavy metals analysed, notably at sampling points PT7 through PT24. Zinc and Pb contamination exhibited highly significant contamination factors, and contamination severity was evidenced across all sample points, signifying a grave risk level. Pollution load indices indicated pervasive extreme pollution levels. Geoaccumulation indices signaled moderate to strong pollution, mainly by Pb and Zn. Ecological risk assessments revealed variable levels of heavy metal contamination, from low to very high, with potential ecological risk reflecting markedly elevated levels. This study underscores the imperative for soil remediation to rectify ecological imbalances in agriculturally affected soil constituents. 展开更多
关键词 Heavy Metals crude Oil POLLUTION Degree of Contamination Potential Risk Index
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Data-driven Wasserstein distributionally robust chance-constrained optimization for crude oil scheduling under uncertainty
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作者 Xin Dai Liang Zhao +4 位作者 Renchu He Wenli Du Weimin Zhong Zhi Li Feng Qian 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第5期152-166,共15页
Crude oil scheduling optimization is an effective method to enhance the economic benefits of oil refining.But uncertainties,including uncertain demands of crude distillation units(CDUs),might make the production plans... Crude oil scheduling optimization is an effective method to enhance the economic benefits of oil refining.But uncertainties,including uncertain demands of crude distillation units(CDUs),might make the production plans made by the traditional deterministic optimization models infeasible.A data-driven Wasserstein distributionally robust chance-constrained(WDRCC)optimization approach is proposed in this paper to deal with demand uncertainty in crude oil scheduling.First,a new deterministic crude oil scheduling optimization model is developed as the basis of this approach.The Wasserstein distance is then used to build ambiguity sets from historical data to describe the possible realizations of probability distributions of uncertain demands.A cross-validation method is advanced to choose suitable radii for these ambiguity sets.The deterministic model is reformulated as a WDRCC optimization model for crude oil scheduling to guarantee the demand constraints hold with a desired high probability even in the worst situation in ambiguity sets.The proposed WDRCC model is transferred into an equivalent conditional value-at-risk representation and further derived as a mixed-integer nonlinear programming counterpart.Industrial case studies from a real-world refinery are conducted to show the effectiveness of the proposed method.Out-of-sample tests demonstrate that the solution of the WDRCC model is more robust than those of the deterministic model and the chance-constrained model. 展开更多
关键词 DISTRIBUTIONS Model OPTIMIZATION crude oil scheduling Wasserstein distance Distributionally robust chance constraints
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The organic geochemistry of crude oil in the Saltpond Basin(Ghana):Organic source input,depositional environment,and thermal maturity
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作者 Kojo Amoako Ningning Zhong +1 位作者 Nancy Pearl Osei-Boakye Ebenezer Apesegah 《Acta Geochimica》 EI CAS CSCD 2024年第3期424-440,共17页
The Saltpond Basin,situated within the South Atlantic margin of Ghana,is a significant area for petro-leum exploration but has received relatively limited research attention.Previous studies have examined source rock ... The Saltpond Basin,situated within the South Atlantic margin of Ghana,is a significant area for petro-leum exploration but has received relatively limited research attention.Previous studies have examined source rock com-position,but data on crude oil organic chemistry are lack-ing,hindering understanding of the basin’s petroleum system and evolution.To address this gap,we analyzed biomarkers and stable carbon-isotope ratios in Saltpond Basin crude oil using gas chromatography–mass spectrometry and gas chromatography–isotope ratio mass spectrometry to eluci-date organic matter source,depositional environment,and thermal maturity.Findings were compared with oils from the West African segment of the South Atlantic margin,namely the Tano Basin and the Niger Delta Basin,to iden-tify potential correlations and gain insights into regional variations.Molecular and isotopic results unveiled a sig-nificant prevalence of organic matter derived from lower marine organisms.Patterns of organic matter deposition and preservation in Saltpond oil samples suggested a suboxic marine transitional environment,contradicting conventional understanding of terrestrial dominance in such settings.Moreover,the potential for degradation processes to obscure differentiation between terrestrial and marine organic mat-ter origins underscores the complex nature of organic mat-ter dynamics in transitional marine environments.Analysis of molecular thermal maturity indices suggested Saltpond oils were expelled from source rocks exhibiting thermal maturity at the early maturity stage.Correlation analysis unveiled genetic disparities among crude oils sourced from the Saltpond Basin and those from the Tano and Niger Delta Basin,primarily due to variations in source input and depo-sitional environment conditions.Saltpond oil exhibits lower terrestrial organic input than Tano Basin’s crude oils,which also have less terrestrial input than Niger Delta Basin crude oils.Additionally,its paleodepositional environment nota-bly differs from oils in the Tano Basin(anoxic transitional marine-lacustrine settings)and the Niger Delta Basin(sub-oxic–oxic terrigenous deltaic or marine or lacustrine envi-ronments).Thermal maturity range of Saltpond oil is com-parable to oils in the Tano Basin but lower than oils in the Niger Delta Basin.Thesefindings provide valuable insights into petroleum generation history and unique organic geo-chemical characteristics within the Saltpond Basin,essen-tial for exploration,production,and environmental manage-ment efforts in the region.Furthermore,correlation studies provide evidence that distinct biological,geological,and paleoenvironmental conditions shaped various oil types in the West African segment of the South Atlantic margin. 展开更多
关键词 Biomarkers Carbon isotopes crude oil Saltpond Basin Ghana
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Research on a TOPSIS energy efficiency evaluation system for crude oil gathering and transportation systems based on a GA-BP neural network
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作者 Xue-Qiang Zhang Qing-Lin Cheng +2 位作者 Wei Sun Yi Zhao Zhi-Min Li 《Petroleum Science》 SCIE EI CAS CSCD 2024年第1期621-640,共20页
As the main link of ground engineering,crude oil gathering and transportation systems require huge energy consumption and complex structures.It is necessary to establish an energy efficiency evaluation system for crud... As the main link of ground engineering,crude oil gathering and transportation systems require huge energy consumption and complex structures.It is necessary to establish an energy efficiency evaluation system for crude oil gathering and transportation systems and identify the energy efficiency gaps.In this paper,the energy efficiency evaluation system of the crude oil gathering and transportation system in an oilfield in western China is established.Combined with the big data analysis method,the GA-BP neural network is used to establish the energy efficiency index prediction model for crude oil gathering and transportation systems.The comprehensive energy consumption,gas consumption,power consumption,energy utilization rate,heat utilization rate,and power utilization rate of crude oil gathering and transportation systems are predicted.Considering the efficiency and unit consumption index of the crude oil gathering and transportation system,the energy efficiency evaluation system of the crude oil gathering and transportation system is established based on a game theory combined weighting method and TOPSIS evaluation method,and the subjective weight is determined by the triangular fuzzy analytic hierarchy process.The entropy weight method determines the objective weight,and the combined weight of game theory combines subjectivity with objectivity to comprehensively evaluate the comprehensive energy efficiency of crude oil gathering and transportation systems and their subsystems.Finally,the weak links in energy utilization are identified,and energy conservation and consumption reduction are improved.The above research provides technical support for the green,efficient and intelligent development of crude oil gathering and transportation systems. 展开更多
关键词 crude oil gathering and transportation system GA-BP neural network Energy efficiency evaluation TOPSIS evaluation method Energy saving and consumption reduction
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Performance Evaluation of the Halophilic Crude Oildegrading Bacterial Consortium XH-1 for Oilfield Wastewater Treatment
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作者 Gong Xihui Zhang Manlin +2 位作者 Wang Wenna Sun Zhichao Liu Chunshuang 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS CSCD 2024年第3期24-32,共9页
A total of 14 halophilic hydrocarbon-degrading strains were isolated from crude oil-contaminated sites,using petroleum as the sole carbon and energy source.Among these,four highly efficient strains were selected to cr... A total of 14 halophilic hydrocarbon-degrading strains were isolated from crude oil-contaminated sites,using petroleum as the sole carbon and energy source.Among these,four highly efficient strains were selected to create the mixed bacterial agent XH-1.These four strains were identified through 16S rRNA gene-based sequencing as belonging to Acinetobacter,Bacillus paramycoides,Rhodococcus sp.,and Enterobacter sp.,respectively.The optimal cultivation time for the mixed consortium XH-1 was found to be 48 h,and a nitrogen-phosphorus molar ratio of 10:1 was determined to be beneficial for crude oil degradation.XH-1 showed notable crude oil degradation even at a salinity of up to 30 g/L,with little inhibition observed at sulfide concentrations as high as 150 mg/L and initial oil concentrations of 500 mg/L.Gas chromatography analysis revealed that XH-1 was able to efficiently degrade C9–C29 n-alkanes.Moreover,a bio-contact oxidation reactor enhanced by XH-1 showed promising results in treating oilfield wastewater.These findings suggest that XH-1 can be applied for the treatment of oilfield wastewater. 展开更多
关键词 crude oil degradation mixed strains oilfield wastewater degradation characteristics
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Prediction Model of Wax Deposition Rate in Waxy Crude Oil Pipelines by Elman Neural Network Based on Improved Reptile Search Algorithm
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作者 Zhuo Chen Ningning Wang +1 位作者 Wenbo Jin Dui Li 《Energy Engineering》 EI 2024年第4期1007-1026,共20页
A hard problem that hinders the movement of waxy crude oil is wax deposition in oil pipelines.To ensure the safe operation of crude oil pipelines,an accurate model must be developed to predict the rate of wax depositi... A hard problem that hinders the movement of waxy crude oil is wax deposition in oil pipelines.To ensure the safe operation of crude oil pipelines,an accurate model must be developed to predict the rate of wax deposition in crude oil pipelines.Aiming at the shortcomings of the ENN prediction model,which easily falls into the local minimum value and weak generalization ability in the implementation process,an optimized ENN prediction model based on the IRSA is proposed.The validity of the new model was confirmed by the accurate prediction of two sets of experimental data on wax deposition in crude oil pipelines.The two groups of crude oil wax deposition rate case prediction results showed that the average absolute percentage errors of IRSA-ENN prediction models is 0.5476% and 0.7831%,respectively.Additionally,it shows a higher prediction accuracy compared to the ENN prediction model.In fact,the new model established by using the IRSA to optimize ENN can optimize the initial weights and thresholds in the prediction process,which can overcome the shortcomings of the ENN prediction model,such as weak generalization ability and tendency to fall into the local minimum value,so that it has the advantages of strong implementation and high prediction accuracy. 展开更多
关键词 Waxy crude oil wax deposition rate chaotic map improved reptile search algorithm Elman neural network prediction accuracy
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Optimization of Diesel and Crude Oil Degradation in a Ghanaian Soil Using Organic Wastes as Amendment
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作者 Adama Sawadogo Innocent Yao Dotse Lawson +2 位作者 Hama Cissé Cheikna Zongo Aly Savadogo 《Journal of Agricultural Chemistry and Environment》 2024年第1期1-12,共12页
Soil contamination by hydrocarbons poses numerous environmental, health and agricultural problems. The degradation of these pollutants can occur naturally but very slowly. It is therefore generally necessary to stimul... Soil contamination by hydrocarbons poses numerous environmental, health and agricultural problems. The degradation of these pollutants can occur naturally but very slowly. It is therefore generally necessary to stimulate this degradation by different means. Thus, this study aimed to improve the bio-degradation of diesel and crude oil in a Ghanaian soil by biostimulation. For this, the sampled soil was characterized by standard methods and contaminated with diesel and crude oil at a proportion of 1% (w/w). Then, contaminated soil samples were supplemented with biochar-compost, poultry manure or cow dung at the proportion of 10% (w/w). Periodically, fractions of these samples were taken to evaluate the density of hydrocarbon utilizing bacteria (HUB) and the residual quantities of diesel or crude oil. The characteristics of the soil used show the need for supplementation for better degradation of hydrocarbons. The results of the study show that supplementing the soil with organic substrates increases HUB loads in soils contaminated by diesel and crude oil. They also show that the residual quantities of diesel and crude oil are generally significantly lower in supplemented soils (p = 0.048 and p < 0.0001 respectively). In addition, the study shows that degradation was generally greater in soils contaminated by diesel compared to those contaminated by crude oil, especially at the end of the study. 展开更多
关键词 BIODEGRADATION BIOSTIMULATION SOIL DIESEL crude Oil Organic Amendment Ghana
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Improving Supply Chain Strategies towards Mitigating the Effect of Crude Oil Theft and Pipeline Vandalism in the Nigerian Oil and Gas Industry: A Case Study of the Nigerian National Petroleum Corporation (NNPC)
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作者 Ruth Agwom Panle 《Open Journal of Yangtze Oil and Gas》 2024年第3期75-93,共19页
Generically, SCM may be said to include all activities carried out to ensure proper functioning of the supply chain. The activities included in proper management of a supply chain broadly include logistics activities,... Generically, SCM may be said to include all activities carried out to ensure proper functioning of the supply chain. The activities included in proper management of a supply chain broadly include logistics activities, planning and control of the flow of information and materials in a firm, management of relationships with other organizations and government intervention, However, crude oil theft and pipeline vandalism are established products supply chain disruptors in Nigeria which are rendering the task of running an efficient petroleum supply chain onerous. This paper aims to establish the importance of effective supply chain strategies for companies in the oil and gas industry with special focus on the Nigerian oil and gas sector and the strategies by which the state oil and gas corporation in this sector may mitigate disruptions to its supply chain. This study investigates the enhancement of supply chain strategies towards meeting the challenge of crude oil theft and pipeline vandalism, using the Nigerian National Corporation (NNPC) as a case study. Based on this study, data were collected from two sources: A summary of incident reports obtained from NNPC and an interview with personnel in the PPMC Department. Incident report refers to a report produced when accidents such as equipment failure, injury, loss of life, or fire occur at the work site. Content analysis is utilized to evaluate data obtained from interview responses, CBN financial stability reports, NDIC annual reports, circulars, banking supervision reports and implementation guidelines. The study found out that NNPC should endeavor to sustain its value chain and ward of pipeline vandals and crude oil thieves by engaging in community partnership, detailing security outfits to ensure its pipelines’ right of way and bridging. Concluded that the oil supply chain of the Nigerian National Petroleum Corporation has been plagued by disruptions in the form of crude oil theft and pipeline vandalism which has had debilitating effects on its value. 展开更多
关键词 Supply Chain Strategies Management Production crude Oil THEFT Pipeline Vandalism Information Technology Operations
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