Polycrystalline Mg1-xHgxB2 samples with x=0, 1%, 2.5%, 5%, 7.5%, and 10% have been synthesized by solid-state reaction. Different from the substitution effect of Al, C, Li, etc. on crystal structure of MgB2, Hg substi...Polycrystalline Mg1-xHgxB2 samples with x=0, 1%, 2.5%, 5%, 7.5%, and 10% have been synthesized by solid-state reaction. Different from the substitution effect of Al, C, Li, etc. on crystal structure of MgB2, Hg substitution for Mg results in an increase of the lattice constant in both a and c directions. The super- conductivity of MgB2 is also suppressed by Hg substitution. The observed suppression of super- conductivity by Hg substitution is discussed in terms of the interband impurity scattering effect in two-band superconductors.展开更多
基金This work was supported by the National Science Foundation of China under Grant No. 50372052, 50588201the National Basic Research Program of China (973 program) under Grant No. 2007CB616906+1 种基金the Program for Changjiang Scholars and Innovative Research Team in UniversityAustralian Research Council under Grant No. DP0559872, DP0881739.
文摘Polycrystalline Mg1-xHgxB2 samples with x=0, 1%, 2.5%, 5%, 7.5%, and 10% have been synthesized by solid-state reaction. Different from the substitution effect of Al, C, Li, etc. on crystal structure of MgB2, Hg substitution for Mg results in an increase of the lattice constant in both a and c directions. The super- conductivity of MgB2 is also suppressed by Hg substitution. The observed suppression of super- conductivity by Hg substitution is discussed in terms of the interband impurity scattering effect in two-band superconductors.