The two new compounds Cs5EuCl8· 14H2O(5∶ 1 type) and Cs2EuCl5· 4H2O(2∶ 1 type) were found and synthesized from CsCl EuCl3 11% HCl H2O quaternary systems by phase equilibrium method, and were characterized ...The two new compounds Cs5EuCl8· 14H2O(5∶ 1 type) and Cs2EuCl5· 4H2O(2∶ 1 type) were found and synthesized from CsCl EuCl3 11% HCl H2O quaternary systems by phase equilibrium method, and were characterized and measured by ultra violet absorption spectrometry and fluorescence spectrum. The results show that upconversion spectrum exhibit at 590nm and 610nm exited at 790nm, and the upconversion intensity increases with the EuCl3 ratio increasing in CsCl.展开更多
The solubilities of Cs 2 SO 4 -C 2 H 5 OH-H 2 O ternary system at 30℃and 50℃have been studied using microe-quipment for solubility determination.There appears two phases,alcoh olic phase,water phase in the liquid ph...The solubilities of Cs 2 SO 4 -C 2 H 5 OH-H 2 O ternary system at 30℃and 50℃have been studied using microe-quipment for solubility determination.There appears two phases,alcoh olic phase,water phase in the liquid phase.The solubilities of Cs 2 SO 4 in water,C 2 H 5 OH and mixed solvent have been determ ined.The phase diagram indicated that C 2 H 5 OH might be salted out by Cs 2 SO 4 from this system and the equilibrium solid phase is Cs 2 SO 4 .展开更多
The attractive utilization route for one-step catalytic oxidation of dimethyl ether to dimethoxymethane was successfully carried out over the H3PW12O40（40%）/SiO2 catalyst, modified by Cs, K, Ni, and V. The Cs modifi...The attractive utilization route for one-step catalytic oxidation of dimethyl ether to dimethoxymethane was successfully carried out over the H3PW12O40（40%）/SiO2 catalyst, modified by Cs, K, Ni, and V. The Cs modification of H3PW12O40（40%）/SiO2 gave the most promising result of 20% dimethyl ether conversion and 34.8% dimethoxymethane selectivity. Dimethoxymethane could be synthe- sized via methoxy groups decomposed from dimethyl ether through the synergistic effect between the acid sites and the redox sites of Cs modified H3PW12O40（40%）/SiO2.展开更多
Cs0.35V2O5 was successfully synthesized as cathode material for lithium secondary battery by the rheological phase reaction method from Cs2CO3 and NH4VO3. The Cs0.35V2O5/Cu composite material was prepared by the displ...Cs0.35V2O5 was successfully synthesized as cathode material for lithium secondary battery by the rheological phase reaction method from Cs2CO3 and NH4VO3. The Cs0.35V2O5/Cu composite material was prepared by the displacement reaction in CuSO4 solution using zinc powder as a reductant. The structure and electrochemical property of the so-prepared powders were characterized by means of XRD （powder X-ray diffraction） and the galvanostatic discharge-charge techniques. The results show that the electrochemical property of Cs0.35V2O5/Cu composite material is significantly improved compared to the bulk Cs0.35V2O5 material. The Cs0.35V2O5/Cu composite material exhibits the first discharge capacity as high as 164.3 mAh.g -1 in the range of 4.2-1.8V at a current rate of 10 mA.g-1 and remains at a stable discharge capacity of about 110 mAh.g-1 within 40 cycles.展开更多
The title compound, Cs 2[Mg(CO 3) 2(H 2O) 4], was synthesized by the dropwise addition of an aqueous solution of Mg(NO 3) 2 to a stirred aqueous Cs 2CO 3/CsHCO 3 solution. A colorless needle shaped crystal was formed ...The title compound, Cs 2[Mg(CO 3) 2(H 2O) 4], was synthesized by the dropwise addition of an aqueous solution of Mg(NO 3) 2 to a stirred aqueous Cs 2CO 3/CsHCO 3 solution. A colorless needle shaped crystal was formed by slow evaporation. The crystal structure was established on the basis of the single crystal X ray diffraction data. Cs 2[Mg(CO 3) 2(H 2O) 4] crystallized in the orthorhombic space group Pbca (No. 61) with a =0.658 4(1) nm, b =1.257 9(1) nm, c =1.301 3(1) nm, \{ V =1.077 8 nm 3, Z =4, D x=2.971 g·cm -3 , μ =69.20 cm -1 , F (000)=888, T =298 K, final R =0.029 and R w=0.024 for 1 037 observed reflections. The crystal consists of Cs + cations and the complex trans [Mg(CO 3) 2(H 2O) 4] 2- anions with each Mg atom coordinated by the six oxygens of two carbonate groups and four water molecules [ d (Mg_O)=0.203 6(4), 0.207 4(4), 0.213 4(4) nm]. The complex trans [Mg(CO 3) 2(H 2O) 4] 2- anions are arranged in a strongly compressed bcc pattern. A 3D network was formed through the intermolecular hydrogen bonds. The Cs + cations are located in cavities, each being surrounded by nine oxygens of five complex anions with d (Cs_O)=0.306 1-0.348 8 nm. The CO 2- 3 group reveals a lowering of D 3h symmetry due to site and coordination effects, but not any observable deviation from co planarity [ d (C_O)=0.127 2(6), 0.127 5(7) , 0.130 5(6) nm and O_C_O=119.6(5)°, 120.1(5)°, 120.4(5)°].展开更多
The equilibrium solubility of one CsCl-YCl3-H2O ternary section of CsCl-YCl3-9.5%HCl-H2O quaternary sys-tem at T=298.15 K was investigated by the physico-chemical analysis method and the corresponding phase dia-gram w...The equilibrium solubility of one CsCl-YCl3-H2O ternary section of CsCl-YCl3-9.5%HCl-H2O quaternary sys-tem at T=298.15 K was investigated by the physico-chemical analysis method and the corresponding phase dia-gram was plotted. The crystallization of two new double salts Cs4YCl710H2O (4∶1 type) and Cs3Y2Cl914H2O (3∶2 type) was successful and they were obtained from the complicated system directly. Both were identified and characterized by X-ray, thermal analysis method of TG-DTG, DSC. The fluorescence experiments show that up-conversion phenomenon does not exist in compounds Cs4YCl7·0H2O and Cs3Y2Cl9·4H2O.展开更多
文摘The two new compounds Cs5EuCl8· 14H2O(5∶ 1 type) and Cs2EuCl5· 4H2O(2∶ 1 type) were found and synthesized from CsCl EuCl3 11% HCl H2O quaternary systems by phase equilibrium method, and were characterized and measured by ultra violet absorption spectrometry and fluorescence spectrum. The results show that upconversion spectrum exhibit at 590nm and 610nm exited at 790nm, and the upconversion intensity increases with the EuCl3 ratio increasing in CsCl.
文摘The solubilities of Cs 2 SO 4 -C 2 H 5 OH-H 2 O ternary system at 30℃and 50℃have been studied using microe-quipment for solubility determination.There appears two phases,alcoh olic phase,water phase in the liquid phase.The solubilities of Cs 2 SO 4 in water,C 2 H 5 OH and mixed solvent have been determ ined.The phase diagram indicated that C 2 H 5 OH might be salted out by Cs 2 SO 4 from this system and the equilibrium solid phase is Cs 2 SO 4 .
基金Foundation items:the National Natural Science Foundation of China(No.20373085)the Natural Science Foundation of Shanxi Province(No.20051023)
文摘The attractive utilization route for one-step catalytic oxidation of dimethyl ether to dimethoxymethane was successfully carried out over the H3PW12O40（40%）/SiO2 catalyst, modified by Cs, K, Ni, and V. The Cs modification of H3PW12O40（40%）/SiO2 gave the most promising result of 20% dimethyl ether conversion and 34.8% dimethoxymethane selectivity. Dimethoxymethane could be synthe- sized via methoxy groups decomposed from dimethyl ether through the synergistic effect between the acid sites and the redox sites of Cs modified H3PW12O40（40%）/SiO2.
文摘Cs0.35V2O5 was successfully synthesized as cathode material for lithium secondary battery by the rheological phase reaction method from Cs2CO3 and NH4VO3. The Cs0.35V2O5/Cu composite material was prepared by the displacement reaction in CuSO4 solution using zinc powder as a reductant. The structure and electrochemical property of the so-prepared powders were characterized by means of XRD （powder X-ray diffraction） and the galvanostatic discharge-charge techniques. The results show that the electrochemical property of Cs0.35V2O5/Cu composite material is significantly improved compared to the bulk Cs0.35V2O5 material. The Cs0.35V2O5/Cu composite material exhibits the first discharge capacity as high as 164.3 mAh.g -1 in the range of 4.2-1.8V at a current rate of 10 mA.g-1 and remains at a stable discharge capacity of about 110 mAh.g-1 within 40 cycles.
文摘The title compound, Cs 2[Mg(CO 3) 2(H 2O) 4], was synthesized by the dropwise addition of an aqueous solution of Mg(NO 3) 2 to a stirred aqueous Cs 2CO 3/CsHCO 3 solution. A colorless needle shaped crystal was formed by slow evaporation. The crystal structure was established on the basis of the single crystal X ray diffraction data. Cs 2[Mg(CO 3) 2(H 2O) 4] crystallized in the orthorhombic space group Pbca (No. 61) with a =0.658 4(1) nm, b =1.257 9(1) nm, c =1.301 3(1) nm, \{ V =1.077 8 nm 3, Z =4, D x=2.971 g·cm -3 , μ =69.20 cm -1 , F (000)=888, T =298 K, final R =0.029 and R w=0.024 for 1 037 observed reflections. The crystal consists of Cs + cations and the complex trans [Mg(CO 3) 2(H 2O) 4] 2- anions with each Mg atom coordinated by the six oxygens of two carbonate groups and four water molecules [ d (Mg_O)=0.203 6(4), 0.207 4(4), 0.213 4(4) nm]. The complex trans [Mg(CO 3) 2(H 2O) 4] 2- anions are arranged in a strongly compressed bcc pattern. A 3D network was formed through the intermolecular hydrogen bonds. The Cs + cations are located in cavities, each being surrounded by nine oxygens of five complex anions with d (Cs_O)=0.306 1-0.348 8 nm. The CO 2- 3 group reveals a lowering of D 3h symmetry due to site and coordination effects, but not any observable deviation from co planarity [ d (C_O)=0.127 2(6), 0.127 5(7) , 0.130 5(6) nm and O_C_O=119.6(5)°, 120.1(5)°, 120.4(5)°].
基金Project supported by the National Natural Science Foundation of China (No. 29371023).
文摘The equilibrium solubility of one CsCl-YCl3-H2O ternary section of CsCl-YCl3-9.5%HCl-H2O quaternary sys-tem at T=298.15 K was investigated by the physico-chemical analysis method and the corresponding phase dia-gram was plotted. The crystallization of two new double salts Cs4YCl710H2O (4∶1 type) and Cs3Y2Cl914H2O (3∶2 type) was successful and they were obtained from the complicated system directly. Both were identified and characterized by X-ray, thermal analysis method of TG-DTG, DSC. The fluorescence experiments show that up-conversion phenomenon does not exist in compounds Cs4YCl7·0H2O and Cs3Y2Cl9·4H2O.
